Professional Documents
Culture Documents
www.ijesci.org
GasificationofJulifloraChipsinaCirculating
FluidizedBedGasifier
M.Nagaraja1,R.Sundaresan2
SchoolofMechanicalandBuildingSciences,VITUniversity,Vellore,India
nr_theni@yahoo.com,2sunds60@yahoo.co.in
Abstract
gasifier called BIVKIN having 500kWth capacity.
Raskinetal.[6]presentedtheoperatingexperienceof
Gasification of Juliflora chips was carried out in a 0.156 m
Kymijarvi power plant located at Lahti in Southern
inner diameter and 5 m height circulating fluidized bed
Finland jointly owned by Laden and Lampovoima.
gasifier with sand of 250 m diameter as the bed material
and air as the fluidizing medium. The influence of
Thegasifierproducedaproductgasequivalentof35
equivalence ratio and gasification temperature on gas
55 MWth depending on the gasifier fuel moisture
composition,gasyield,lowerheatingvalueandgasification
contentreportingthegasheatingvalueintherangeof
efficiency was investigated. The gasification temperature
1.62.4MJ/Nm3.
1,2
1
andequivalenceratioweremaintainedintherangeof700to
900C and 0.2 to 0.3 respectively. Equivalence ratio and
temperature strongly influenced the gas composition. With
an increase in equivalence ratio, the temperature and gas
yieldwereincreaseddecreasingthegasheatingvalue.Itwas
alsoobservedthattheincreaseoftemperaturealsoincreases
the gas heating value, gas yield and gasification efficiency.
Comparison of present experimental data with findings of
other studies of different biomass fuels is also discussed in
thispaper.
Keywords
Circulating Fluidized Bed; Gasification; Juliflora Chips;
EquivalenceRatio;GasComposition;GasYield
Introduction
The first part of the paper deals with a review of
literature survey of the work done in the field of
gasification. The second part demonstrates the
experimental programme of the gasification process
and finally, the results and conclusions are discussed
in the third part. Circulating Fluidized Bed (CFB)
technologyhasbeensuccessfullyusedinmanyfields,
including power generation; cogeneration; biomass
gasification; ore roasting and oil catalytic cracking.
Numerous studies in this field have been reported in
theearlierliterature.ThoughCFBtechnologyhasbeen
used in coal combustion and petroleum industry for
morethantwodecadeswithgreatsuccess,itspractical
applicationtobiomassgasificationisstillquitelimited
[1]. There are several studies on gasification of
differentbiomassfuelsinaCFBgasifierinthelasttwo
decades[24].
VanderDriftetal.[5]successfullytestedatotaloften
different biomass fuels in a circulating fluidized bed
91
www.ijesci.orgInternationalJournalofEnergyScience(IJES)Volume3Issue2,April2013
hasbeenprovedthattheCFBgasifiercanoperateover
abroadrangeofoperatingconditionswithsatisfactory
gasificationresults.Basedonthese,CFBgasificationof
biomass seems to be a quite promising way.
Nowadays, gasification process is looking forward to
the renaissance after successful commissioning of the
biomass Atmospheric Circulating Fluidized Bed
(ACFB) gasifier at the Kymijarvi Power Station in
Lahti, Finland [2]. Table 1 shows the present work
alongwithdatafromearlierstudies.
Abriefreviewofliteraturerevealsthattheinformation
on biomass gasification in a CFB gasifier is very
limited. It appears that no work has been carried out
for gasification of Juliflora wood chips in a CFB
gasifier in India. The aim of the present work is to
study the gasification characteristics of Juliflora chips
in a CFB gasifier. The influences of various operating
parametersareanalyzed.
TABLE1LITERATUREDATAWITHPRESENTWORK
Ref.
Present
work
Lietal.
[3]
Wuetal.
[4]
Vander
driftet
al.[5]
Kersten
etal.[7,
8]
Yinetal.
[9]
Chenet
al.
[10,14]
Sheeba
etal.[13]
Xiaoetal
[20]
Garcia
Ibanezet
al.[22]
Zhouet
al.[23]
Menget
al.[24]
92
Gas
yield
(Nm3/
kg)
Gas.
Effi.
(%)
5273
5.456.4
1.6
1.95
1.72
3.30
1.24
3.30
2.055.13
5666
1.9
6570
14.5
16.2
0.47.7
48.8
4.76.2
2.2
65
12.57
16.02
6.0
2.45
3.46
1.79
1.85
6501028
3048
3855
612
3.05.7
600700
715
2025
3947
0.410.73
753893
6.98.6
1921.7
5.49.3
1.8
3.0
2.93.8
1.01
1.15
1.0
1.2
2.9
5.6
5560
0.31.0
6.0
7.7
48
0.1750.24
0.220.26
600900
6.06.5
5.0
77
81
0.330.47
730820
2227
2024
3541
3745
2225
2328
3743
3440
2.73.9
3.74.2
2.48
2.63
Sizeof
CFB
gasifie
r
(m)
0.156
dia.
0.10
Ht.
(m)
Typeof
Biomass
Equivalenc
eratio
Bed
temp.
(C)
%of
CO
%of
CO2
%of
H2
%of
CH4
Juliflora
chips
sawdust
0.20.3
700900
2126
720
710
0.20.60
700850
6.921.4
1518.3
3.07.3
2.0
8.5
0.120.30
700800
1621
1516
58
0.20
6.0
0.320.60
803861
5.34
11.65
13.94
17.10
1.80
9.02
0.00.4
740
33
19
1.8
(1MW
ecap.)
0.83
Rice
husk
Ten
residual
biomass
fuels
Willow
andpine
wood
Rice
husk
1.7
3.5
1.4
4.6
46
0.20.25
700850
1519
Mis
canthus
0.20.5
753
0.050
1.3
Coirpith
0.180.31
0.212
square
0.20
1.25
Animal
waste
Oliveoil
waster
0.83
5.5
6.5
6.5
Sawdust
Rice
husk
Agrol,
Willow
DDGS
Gas
heating
value
(MJ/Nm3
)
4.35.6
2.436.13
810
44.2
64.7
InternationalJournalofEnergyScience(IJES)Volume3Issue2,April2013
Experimental Set Up
Theparticulatesintheproducergaslikeash,char,tars
andalkalimetalswerecleanedandremovedbymeans
of a gas cleaning system which contains (i) Cyclone
separators (ii) Ceramic filter and (iii) water scrubber.
The hot producer gas with particulates was passed
through a first cyclone, where the coarser particles in
the producer gas were captured and it was recycled
back to the bottom of the riser through the LValve.
Thegasleavingthefirstcyclonewaspassedthrougha
second cyclone where ash got separated and got
collectedinanashdrum.Thehotproducergasleaving
thesecondcyclonewasagaincleanedusingaceramic
filterunit.Forinternalcombustionengineapplications
the producer gas was cooled to ambient temperature
inawetscrubber.
Airblower
Flexiblehosepipe
Bypassvalve
Pitotstatictube
Distributorplate
Screwfeeder
Fuelbunker
CFBgasifier
Electricalheater
Primarycyclone
Secondarycyclone
Ashdrum
Controlpanel
Ceramicfilter
Watersump
Wetscrubber
Tarcollectiontank
IDfan
Gastoengine
Gastoflare
2
1
www.ijesci.org
Thegassamplingportswerelocatedafterthescrubber.
Gas samples were collected using gas sampling bags
for different operating conditions and the
concentrationsofproducergaswereanalyzedusinga
gas chromatograph. Juliflora wood chips used for
experimental studies were of smaller size and
powdery in nature. These chips contained 81.8 % of
volatiles and small proportion of other elements. The
lower calorific value of wood residues used for
experimentalstudieswasfoundtobe15.5MJ/kg.
10
T
T
TThermocouple
PPressuretransducer
P
P
T
T
16
20
P
P
5
3
19
11
14
18
13
12
15
17
93
www.ijesci.orgInternationalJournalofEnergyScience(IJES)Volume3Issue2,April2013
Ultimateanalysis
(wt%)
Proximateanalysis
(wt%)
Carbon
45.55
Moisture
12.10
Hydrogen
6.44
Volatilematter
81.80
Oxygen
47.22
Fixedcarbon
16.34
Nitrogen
0.583
Ash
1.86
Sulphur
0.205
TABLEIIIEXPERIMENTALCONDITIONS
Feedstock
Juliflorawoodchips
Fuelfeedrate
565kg/h
Bedmaterial
Silicasandofmeandiameter
250m
Gasificationmedium
Air
Fluidizationvelocity
0.144m/s
Gasificationtemp.
700900C
Equivalenceratio
0.20.3
ThePrimaryairrequiredforgasificationwassupplied
through a multiorifice type distributor plate at the
bottom of the riser from an air blower. Biomass was
fedintotheCFBgasifierusingascrewtypefeeder.An
electricalheaterinstalledattheriserwallwasutilized
to preheat the gasifier to 400550C to maintain a
desiredbedtemperaturelevelbeforebiomassfuelwas
fed. After preheating, it was then switched to the
gasification mode. The atmospheric air supplied for
gasification was measured and controlled by
flowmetersand regulating valves. The temperature at
various points in the gasifier was measured for each
experimentinacentralcontrolsystem.Allequipments
were stopped after collecting all the data. In order to
cool the gasifier and to stop further reactions, air
blower was operated continuously to supply air until
thebedtemperaturedroppedtoadesiredlevel.
Results and Discussion
EffectofEquivalenceRatioonGasComposition
Theinfluenceofequivalenceratioongascomposition,
temperature,heating value andgasyield is presented
94
50
2. CO2
3. H2
4. CH 4
TABLE2ULTIMATEANDPROXIMATEANALYSISOF
JULIFLORAWOODCHIPS(DRYBASIS)
40
30
5. CO
6. CO2
7. H2
20
1
2
8. CH 4
10
0
0.16
7
8
4
0.18
0.20
0.22
0.24
0.26
0.28
0.30
0.32
Equivalence ratio
EffectofEquivalenceRatioonBedTemperature
Fig. 3 shows the variation of bed temperature with
equivalence ratio. It can be observed that the increase
in equivalence ratio linearly increases the bed
temperature. One can explain that at higher
equivalence ratio more amount of air is introduced
into the gasifier resulting in exothermic reaction of
thermal decomposition leading to complete
InternationalJournalofEnergyScience(IJES)Volume3Issue2,April2013
EffectofEquivalenceRatioonGasYield
combustionprocess.Comparisonofpresentdatawith
other works on different fuels exhibits the similar
variation.
1000
1. Present work (Juliflora chips)
2. Wu et al. [4] (Rice husk)
3. Zhou et al. [23] (Sawdust)
4. Miao et al. [21] (Rice husk)
3
800
2.00
Present work (Juliflora)
2
1
700
600
0.15
0.17
1.95
0.19
0.21
0.29
0.31
0.33
0.35
Temperature ( C)
900
www.ijesci.org
1.90
1.85
1.80
EffectofEquivalenceRatioonGasHeatingValue
Theinfluenceofequivalenceratioongasheatingvalue
isshowninFig.4.Itisfoundthatthegasheatingvalue
decreases from 5.6 to 4.3 MJ/Nm3 with increase in
equivalence ratio. This is mainly due to dilution of
nitrogenpresentintheairusedasgasificationmedium
and subsequent increase of CO2. Experimental results
of other works are also presented for comparison. In
allthecasesitisobservedthatthegasheatingvalueis
stronglyaffectedbytheequivalenceratio.Theresultof
the one dimensional model developed by Sanz and
Corella [16] using pine wood chips is also presented
for comparison which shows that they are within
acceptabledeviation.
10
9
8
7
3
2
0.17
0.22
0.24
0.26
0.28
0.30
0.32
Equivalence ratio
EffectofTemperatureonGasHeatingValue
The influence of temperature on gas heating value in
present work and other works is shown in Fig.6. It is
interestingtonotethatthegasheatingvalueincreases
with increasing bed temperature as depicted in the
present work also shown by Li et al. [3] whereas
according to other studies, it decreases. Wu et al. [4]
reported that supplied heat is derived from the
combustion enthalpy of biomass resulting in higher
temperature mainly due to more fuel for combustion
and less for gasification process producing lower
heating value. Similarly Yin et al. [9] reported the
lower value due to moisture content of rice husk,
feedingrateanddischargeofash.
2
3
0.20
EffectofTemperatureonGasYield
6
5
1.75
0.18
EffectofTemperatureonGasificationEfficiency
0.19
0.21
0.23
0.31
0.33
0.35
95
www.ijesci.orgInternationalJournalofEnergyScience(IJES)Volume3Issue2,April2013
50
6.5
6.0
4
1
5.5
40
Gas composition of CO (%)
7.0
30
20
1
5
10
5.0
4.5
600
700
800
900
0
550
1000
Temperature (C)
650
750
Temperature (C)
850
950
2.5
1. Present work (Juliflora chips)
2. Sheeba et al. [13] (Coir pith)
2.0
1.5
2
1.0
0.5
0.0
600
700
800
900
40
2
30
3
20
10
650
750
Temperature (C)
850
950
Temperature (C)
50
0
550
1000
70
60
40
30
20
1
4
10
2
0
50
600
700
800
900
1000
550
Temperature (C)
96
750
850
950
Temperature (C)
650
InternationalJournalofEnergyScience(IJES)Volume3Issue2,April2013
10
8
7
3
4
5
4
3
2
1
650
750
850
950
Temperature (C)
25
20
ACKNOWLEDGEMENT
0
550
www.ijesci.org
[1] Wu,C.,Xu,B.,Luo,L.andYin,X.Theoryandapplication
3. H2
ofbiomasscirculatingfluidizedbedgasifiers,GasandHeat,
4. CH4
15
Vol.15,pp.38,1995.
3
10
1998.
0
600
700
800
900
1000
[3] Li, X.T., Grace, J.R., Lim, C.J., Watkinson, A.P., Chen,
Temperature (C)
Conclusions
Following conclusions are drawn from the biomass
gasificationstudies:
Experiments were carried out to study the
characteristics of Juliflora chips in a 0.15 m
diameterand6mhighCFBgasifierforthefirst
time
Influencesofequivalenceratioandtemperature
ongascomposition,gasheatingvalue,gasyield
andgasificationefficiencywereinvestigated
Withanincreaseinequivalenceratiofrom0.2to
0.3, the concentration of CO decreased from 26
to 21% and CO2 increased to 7 to 22% and gas
yieldincreasedfrom1.6to1.95Nm3/kg
By increasing the bed temperature, the gas
composition of CO2 and H2 increased linearly
andCOandCH4decreased
At higher temperature, the gas heating value of
product gas was in the range of 4.3 to 5.6
MJ/Nm3
97
www.ijesci.orgInternationalJournalofEnergyScience(IJES)Volume3Issue2,April2013
agriculturalresiduesusedasfeedstockforbiomassgasification
Sci.,Vol.58,pp.725731,2003b.
andbriquettinginIndia,EnergyCon.andMang.,Vol.39,
[9] Yin, X.L., Wu, C.Z., Zheng, S.P. and Chen, Y. Design
pp.16111618,1998.
systemforricehusk,BiomassandBioenergy,Vol.23,pp.
181187,2002.
SustainableEnergyReviews,Vol.8,pp.147,2004.
[10] Chen,G.,Andries,J.,Spliethoff,H.,Fang,M.andvande
[19] Dasappa, S., Sridhar, H.V., Sridhar, G., Paul, P.J. and
Enden, P. J.Biomassgasificationintegratedwithpyrolysis
Mukunda, H. S. Biomassgasificationasubstitutetofossil
fuelforheatapplication,BiomassandBioenergy,Vol.25,
345349,2004.
pp.637649,2003.
[20] Xiao, X., Le, D.D., Morishita, K., Zhang, S., Li, L. and
Takarada,T.MultistagebiomassgasificationinInternally
717736,2005a.
animalwastederivedbiomassandparametricinvestigationat
[12]
[21] Miao, Q., Zhu, J. Yin, X.L. and Wu, C.Z. Modelling of
2005.
CirculatingFluidizedBedsIX,pp.685690,2008.
pp.166173,2009.
BiomassandBioenergy,Vol.27,pp.183194,2004.
[23] Zhou,Z.Q.,Ma,L.L.,Yin,X.L.,Wu,C.Z.,Huang,L.C.
discussion,RenewableEnergy,Vol.28,pp.985994,2003.
27,pp.:612615,2009.
[24] Meng, X., Jong, W.D., Fu, N. and Verkooijen, A.H.M.
[16] Sanz,A.andCorella,J.Modellingcirculatingfluidizedbed
gasifiers.Resultsfromapseudorigorous1dimensionalmodel
conditions
2006.
98
on
product
gas
distribution
and
tar