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PRODUCT
ABSTRACT
The purpose of this experiment is to determine the K sp of the calcium
hydroxide solid. It also demonstrates the common ion and the diverse ion effect.
For the value of Ksp in water, the value 3.01 x10-5 was obtained. This value was then
contrasted to the theoretical value, 5.5 x10-6. A percent error of 447% was
obtained. The experiment was done by preparing calcium hydroxide from calcium
nitrate and sodium hydroxide, and then using calcium hydroxide suspended in
different media as an analyte and then titrating them with HCl. From there, we can
already calculate the value of the Ksp.
INTRODUCTION
The
Ksp of
a
substance,
according
to
Petrucci,
is
the
equilibrium
constant
for
the
equilibrium between a solid ionic
solute and its ions in a saturated
aqueous solution.
The solid in question in this
experiment
is
Ca(OH)2.
Its
decomposition reaction is shown
below.
Ca(OH)2(s) Ca2+(aq) + 2 OH-(aq)
(1)
While the equation for its Ksp is:
Ksp = [Ca2+][OH-]2
(2)
One of the factors affecting K sp
is the ionic strength of the substance.
Ionic strength could be measured
through the equation displayed below:
= cizi
(3)
Where:
= Ionic strength
ci = molar concentration of each
ions
(6)
Medium
[OH-]
Trial 1
Trial 2
distilled
0.0388
0.0396
H2O
0.001 M KCl
0.0354
0.0392
0.005 M KCl
0.0384
0.0424
0.010 M KCl
0.0420
0.0420
0.050 M KCl
0.0440
0.0440
0.100 M KCl
0.0440
0.0460
0.500 M KCl
0.0492
0.0552
1.000M KCl
0.0540
0.0548
0.100 M
0.0292
0.0324
Ca2+
Based on the chemical equation
for the decomposition of calcium
hydroxide, hydroxide and calcium ions
have a two is to one ratio respectively.
By
halving
the
hydroxide
concentrations we come up with the
concentration of calcium ions and thus
the solubility values for each medium.
Table 2. [Ca2+] and s
Medium
[Ca2+] = s
Trial 1
Trial 2
d H2O
0.0194
0.0198
0.001 M
0.0177
0.0196
KCl
0.005 M
0.0192
0.0212
KCl
0.010 M
0.0210
0.0210
KCl
0.050 M
0.0220
0.0220
KCl
0.100 M
0.0220
0.0230
KCl
0.500 M
0.0246
0.0276
KCl
1.000M
0.0270
0.0274
KCl
0.100 M
0.0146
0.0162
Ca2+
The average Ksp for water is
computed to be 3.01 x 10-5.
The
literature value for Ksp is 5.5 x 10-6. The
percent difference between them is
447%.
Using the equation
= cizi
(3)
the ionic strength of each solution
could be computed. The results
obtained are tabulated below and the
calculations are found in the appendix.
Table 3. (ionic strength) of different
media
Medium
Trial 1
Trial 2
distilled
0.0582
0.0594
H2O
0.001 M KCl
0.0531
0.0588
0.005 M KCl
0.0576
0.0636
0.010 M KCl
0.0630
0.0630
0.050 M KCl
0.0660
0.0660
0.100 M KCl
0.0660
0.0690
0.500 M KCl
0.0720
0.0828
1.000M KCl
0.0810
0.0822
0.100 M
0.0438
0.0486
Ca2+
The
methodology
for
the
experiment is sufficient for the
computation of the required values
and it proved its purpose by
demonstrating the effect of common
and diverse ions.
Overall, the experiment could
be considered a failure because of the
huge percent error between the
theoretical and experimental Ksp
values.
REFERENCES
CONCLUSION AND
RECOMMENDATION
The experiment showed that
the reaction had Ksp value of 3.01 x 105
in water. This is contrasted to the
theoretical value which yielded to a
447% error. The experiment also
showed that the addition of common
ions would decrease the solubility of
the solution while the addition of
diverse ions would increase its
solubility.
[OH-] =
Solubility = [Ca2+] =
= 0.0194
M
=
= 0.0582 M
= 0.0396 M
Solubility = [Ca2+] =
= 0.0198
M
=
[OH-] =
-5
0.1M Ca(NO3)2:
= 0.0292 M
= 0.0146
Trial 1:
= 0.0492 M
= 0.0438 M
Solubility = [Ca2+] =
= 0.0246
Trial 2:
= 0.0324 M
Solubility = [Ca2+] =
= 0.0162
= 0.0720 M
= 0.0552 M
= 0.0486 M
Solubility = [Ca2+] =
= 0.0276
1.0 M KCl:
= 0.0828 M
Trial 1:
Solubility = [Ca2+] =
= 0.0270
M
=
0.500 M KCl:
[OH-] =
[OH-] =
= 0.0822 M
Solubility = [Ca2+] =
= 0.0274
Trial 1:
[OH-] =
Solubility = [Ca2+] =
M
= 0.0548 M
= 0.0594 M
3
[OH-] =
Trial 2:
0.100 M KCl:
Trial 1:
[OH-] =
= 0.0810 M
= 0.0440 M
Solubility = [Ca2+] =
= 0.0220
M
=
Trial 1:
[OH-] =
= 0.0660 M
3
-5
= 0.0420 M
Solubility = [Ca2+] =
= 0.0210
M
Trial 2:
[OH-] =
= 0.0460 M
Solubility = [Ca2+] =
= 0.0230
M
=
= 0.0690 M
3
-5
= 0.0420 M
Solubility = [Ca2+] =
= 0.0210
0.050 M KCl:
= 0.0630 M
Trial 1:
[OH-] =
= 0.0440 M
Solubility = [Ca2+] =
= 0.0220
M
=
= 0.0630 M
0.005 M KCl:
Trial 1:
[OH-] =
= 0.0660 M
3
-5
= 0.0384 M
Solubility = [Ca2+] =
= 0.0192
M
Trial 2:
[OH-] =
= 0.0440 M
Solubility = [Ca2+] =
= 0.0220
M
=
= 0.0660 M
3
-5
= 0.0576 M
= 0.0424 M
Solubility = [Ca2+] =
M
=
= 0.0636 M
= 0.0212
= 76.5 %
0.001 M KCl:
Trial 1:
[OH-] =
= 0.0354 M
Solubility = [Ca2+] =
= 0.0177
M
=
= 0.0531 M
= 0.0392 M
Solubility = [Ca2+] =
= 0.0196
M
=
= 0.0588 M
% error =
% error =
x 100%
= 447 %
Ksp = s3
s=
s=
s = 0.0111 M
save = 0.0194 + 0.0198 / 2 = 0.0196
x 100%