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O N
H
SO2CH2CH2OSO3Na
Vinyl sulphone dye (Remazol Brilliant Blue R, C.I. Reactive Blue 19)
2. Monochloro-s-triazine dyes:
Cl
SO3Na N N
OH HN N N
N H
N
NaSO3 SO3Na
SO3Na N N N N NaSO3
OH HN N N N N NH OH
N H H N
N N
Nucleophilic addition:
H H
O - NaHSO O
4
DYE S C C OSO3Na DYE S CH CH2
O H H O
O H - O
- +Cellulose O +
DYE S CH C O Cellulose DYE S CH CH2
O H O
H2O
O H H
DYE S C C O Cellulose + OH-
O H H
“Application Methods”
• Continuous:
– eg. Pad - Thermofix
• Semi-Continuous:
– eg. Pad - Batch
• Batchwise Exhaustion:
– eg. Winch, Jet, Package and Beam Dyeing
• Printing:
– eg. Print - Thermofix
Advantages:
• Full Colour Gamut
• Brilliant, bright colours
• Colvalent fixation à high WashFastness (WF)
• Varying reactivities
– Various temperatures
including low energy (cold dyeing)
• Various methods of application
• Inexpensive to apply (but dyes expensive)
Disadvantages:
• Incomplete fixation (problem with hydrolysis)
• Need for wash-off (for high WF)
• Need for high concentrations of salt
– Affect natural balance of watercourses
• High pH
• Some dyes are “AOX” – potentially harmful to the environment
“Hot And Cold Dyeing Brands”
Cold reactive dyes are very reliable and used throughout the global clothing
and textile industries to permanently colour fabrics made from plant fibres.
The dyes react with the fibre on a molecular level to produce a permanent
bond that withstands wash after wash. The colour becomes part of the fabric.