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7th Edition
Section 16
Section 16
Chemical
or Activated
Adsorption/Chemisorption
involves chemical interaction between
the adsorbed fluid and the adsorbent
solid. Frequently, the adsorption is
irreversible and it is difficult to separate
the adsorbate from the adsorbent.
Hence, only physical adsorption tends
itself to continuous stage-wise operations.
n 1
n0
n 1
Vo
mass adsorbent
mass adsorbate
V1
Y1
Yo
L1
X1
mass adsorbent
y
mass solution
VoYo V1Y1 L1 X 1 Lo X o
V o V1 V
& L o L1 L
V Y o Y1 L x1 x 0
y 0 y1
L
V
x1 x 0
y 0 y1
y1
x0
Graphical Representation
x0 , y 0
y
x1 , y1
L2
X 0 1
X 0 2
V
Yo
V
Y2
V
Y1
Y1
X1
m
Y2
X2
m
V
x 1 x 0 1
Lt
L1 L 2
V
V
V
d y
L2
y1 y 2
V
x 1 x 0 2
y 0 y1
1
y1
m
x 0 2
x0 1 x0 2 0
y1
y2
1 y0
1
.
1
n y1
n
Graphical Representation
xo , y o
L1
x1, y1
x1 , y1
L2
x 2, y 2
Countercurrent Operation
x1
V
yo
x2
x3
Stage
I
Stage
II
yn1
y2
y1
xn
n+1
Stage
N
xN+1 L
yn
x1
Stage 1
V y
o
x3
Stage 2
y1
y2
y0 y2
L
y1 y 2
V
x1 x 3
x 2 x3
Graphical Representation
x1 , y0
L
x2 , y1
x1 , y1
x3 , y2
x3 , y2
x