1

1-1

1
2

1-1

( p.8)

1.
AB P
(1) 2 Hg(l)O2(g) 2 HgO(s)
(2)
Na2O(s)CO2(g) Na2CO3(s)
(3)
2 CO(g)O2(g) 2 CO2(g)

2.
R AB
(1)
2 HgO(s)

2 Hg(l)O2(g)

(2)
2 H2O(l)

2 H2(g)O2(g)

(3)
CaCO3(s)

2 KClO3(s)

CaO(s)CO2(g)

MnO

2 KCl(s)3 O2(g)

3.

ABC ACB BAC

(1)

Cu(s)2 AgNO3(aq) 2 Ag(s)Cu(NO3)2(aq)

(2) AlFe2O3

2 Al(s)Fe2O3(s) 2 Fe(s)Al2O3(s)

(3)

4.

ABCD ADCB

K2CrO4(aq)BaCl2(aq) BaCrO4(s)2 KCl(aq)

5.
(1)
2 Mg(s)O2(g)

2 Mg(s)CO2(g)

2 MgO(s)

C(s)2 MgO(s)

(2) CnH2n2
CH4(g)2 O2(g) CO2(g)2 H2O(l)
CHCHO
CO2H2O

CaOCO2 CaCO3
2 H2O2 2 H2OO2
C6H12O66 O2 6 CO26 H2O
Ca(HCO3)2 CaCO2CO2H2O
SO2H2O H2SO3
[]

1.
(A) 2 MgO2

(B) 2 MgCO2

2 MgO

C2 MgO

(C) 2 NOO2

2 NO2

(D) 2 NaCl2

2 NaCl

[] C

NO O2

2.
(A)
(D)

(B)

(C)

(E)

[] D

CaCO32 HCl CaCl2H2CO3

CO2H2O

( p.12)

1.

(1) Zn(s) Cu2(aq) Cu(s) Zn2(aq)

(2) 2 NO(g) O2(g) 2 NO2(g)

2.

(1) 2 KClO3(s)
(2) 2 H2O2(aq)

MnO
2

MnO
2

2 KCl(s)3 O2(g)
2 H2O(l) O2(g)

O2

(3) CaCO3(s)2 H (aq) Ca2 (aq)CO2(g)H2O(l)

CO2

3.

(1) Ca(HCO3)2(aq)

CaCO3(s)H2O(l)CO2(g)

(2) Pb(NO3)2(aq)2 NaI(aq) PbI2(s)2 NaNO3(aq)

4.

(1) NaOH(aq)HCl(aq) NaCl(aq)H2O(l)

(2) 2 Mg(s)O2(g)

2 MgO(s)

(A)
(B)
(C)
(D)
(E)

[]

BCE

2 Na(s)2 H2O(l) 2 NaOH(aq)H2(g)

(A) NaOH(aq)
(D) NaOH

(A)
(B)
(C)
(D)
(E)

[] D

(A)I2

(B)ClO Cl

HClOHClCl2H2O
(C) CaCO3
(E)

(A) 2 KClO3(s)

2 KCl(s)3 O2(g)

(B) 2 H2O2(aq)

MnO2

2 H2O(l)O2(g)

(C) AgNO3(aq)HCl(aq) AgCl(s)HNO3(aq)

(D) 2 NaOH(aq) H2SO4(aq) Na2SO4(aq)2 H2O(l)
[]

1.
2

(A) Zn(s)Cu

(aq)

Cu(s)Zn

(aq)

(B) 2 H2(g)O2(g) 2 H2O(g)

(C) 2 NO(g)O2(g) 2 NO2(g)
(D) HCl(aq)NaOH(aq) NaCl(aq)H2O(l)
(E) CH4(g)2 O2(g) CO2(g)2 H2O(g)
[] AC

(A) (C)
Cu2 Zn2 NOO2NO2

2.
(A)

(B)

(C)

(D)

[] A

(A)
(B)CaCO32 HCl CaCl2CO2H2O
(C)H2SO4Ba(OH)2 BaSO42 H2O
(D)

 1
1-2 pH

1
2 pH

12

pH
( p.13)

1.

2.
(1) 1884

(2)

3.

[H][Na][SO42]2[OH]
[H][OH] [Na]2 [SO42]

(A)
(B)
(C)
(D)
(E)
[] ACE

(B)
(D)


(A)
(B)
(C)
(D)

(E)

[] BCE

(B)(C)
(E)

1 96500 1 1 M

(A) 48250
[]

(B) 96500

(C) 193000

(D) 289500

CaCl2 Ca22 ClCaCl2 1 mol

Ca2 1 molCl 2 mol
Ca2 296500 Cl

OH

 0.50
96500
M
(A) 0.50 (B) 1.0 (C) 1.5 (D) 2.0

[] A
Na2SO4 2 NaSO42
96500

SO42

0.25
0.25 mol [Na2SO4]
0.50 M
0.50

pH

( p.16)

1.
pH

pH
pHlog
M
log [H ] [H ]10
[H ]

pOH

pOHlog [OH ] [OH ]10

[H ]1.010

M pH4.00

[OH ]1.010

M pOH4.00

2. pH
(1) [H][OH]
pHpOH
[H][OH] pHpOH
(2) [H][OH] pHpOH

H2O

HOH

(3) H OH
Kw

pH 25 [H][OH]1014 M2
pHpOH14 pKw14

25 1.0 M HCl(aq)[H ]1.0 M

14

10
14
[OH ]
10 M
1.0

25 pHpOH14
25 pHpOH14

3. pH

pH

3.010
pH
(A) 3.5 (B) 4.5 (C) 5.5 (D) 6.5
[]

B
5

1 10 [H ]3.0 10
pH45

M10 10

 25 pH 2

[OH ] M
2

(A) 10

12

(B) 10

(C) 2 (D) 12

[] B

pH2 [H ]10

14
14
10
10

12
[OH ] 2 10 M
[H ]
10

 1
1-3

1
2
3

1-3

( p.19)

1.

(1) H

HCl(aq) H

(aq)Cl (aq)

CH3COOH(aq)

(aq)CH3COO (aq)

(2) OH

NaOH(aq) Na

(aq)OH

(aq)

NH3(aq)H2O(l)

NH4

(aq)OH

(aq)

(3) H(aq) OH(aq)

H(aq)OH(aq) H2O(l)

2.

(1)
(2)
(3)

(4)
(5)

(1)
(2)
(3)
(4)
(5)

HCl(aq)H2SO4(aq)
2 M(s)2n H(aq) 2 Mn(aq)n H2(g)

(A)

(B) (C)

[] D

(D)


(A) NO2

(B) H3PO4

(C) CH3OH

(D) Mg(OH)2

[] D

(C) CH3OH

( p.19)

1.
(1) H OH

HClHNO3CH3COOH
H2SO4H2CO3
H3PO4
KOHNaOHNH3

Ca(OH)2Al(OH)3

(2)

HCl

HNO3

H2SO4

NaOH
KOH
Ba(OH)2

CH3COOH NH3
HCN
Mg(OH)2

2.
[H][OH]
251014 M2

H OH

3.

HCl(aq)NaOH(aq) NaCl(aq)H2O(l)
HClNaOH NaCl

H(aq)Cl(aq)Na(aq)OH(aq) Na(aq)Cl
(aq)H2O(l)


H(aq)Cl(aq)Na(aq)OH(aq)
Na(aq)Cl(aq)H2O(l)

H(aq)OH(aq) H2O(l)

CH3COOH(aq)OH(aq) CH3COO(aq)H2O(l)

0.10 MNaOH50 mL0.10 M

HClxNaOH mL

(1)x0 [H]101 M pH1

(2) 0x50

OH

0.1050 mmol

0.10x mmol

0.10x

0.10x

5 0.10 x

H2O

H OH
[H ]

0.10500.10x

M
50x

(3) x50
pH7

(4) x50

OH

0.10 50 mmol

0.10 x mmol

0.1050

0.1050

H2O

0.10 x 5

OH H

[OH ]

0.10x0.1050

M
50x

4.
56
NaOH(aq)HCl(aq) NaCl(aq) H2O(l)
H56 kJ

56 kJ

0.060
Al(OH)3
Al(OH)3(s)3 HCl(aq) AlCl3(aq)3 H2O(l)
0.3
H1.0O16.0
Al27.0
(A) 0.26

(B) 0.47

(C) 1.4

(D) 4.2

[]

0.3
HCl0.3 0.0601.8 102 mol

Al(OH)36 10

mol6 10 780.468

1. 25 pH 0.0 1 mL
pH 13.0 10 mL
pH
(A) 13.0 (B) 7.0 (C) 6.0 (D) 1.0

[] B

pH0.0 [HCl]1 M
pH13.0 [NaOH]0.1 M

1 1mmol
1
0

OH

H2O

0.1 10mmol
1

pH7

2. 0.1 M 20 mL
0.1 M
(A) 10

(B) 20

(C) 30

(D) 40

[] D

H mol OH
0.12020.1V1V40

mol

3. 0.1 M 10 mL 0.1 M 20 mL

(A) 28

(B) 56

[]

(C) 112 (D) 140

0.11010

mol

56 kJ 10356 J

( p.22)

1. pH

pH

HIn

H In

pH4.5 [HIn][In ]

pH8.3 [In ][HIn]

2.

pH

3.24.4

4.86.0

4.58.3

BTB

6.07.6

6.88.4

PP

8.210.0

25
pH8.2

pH
(A)

(B)

(C)

(D)

[]

B
pH7 pH7
pH


0.1 M

(1)
(2)

(A)

(B)

(C)

(D)

[] B

(1) NaOH(aq)
(2)
HCl(aq)

 1
1-4

1
2

1-4

( p.26)

1.


(1)
C(s)O2(g)

CO2(g)

(2)
Fe2O3C

2 Fe2O3(s)3 C(s)

4 Fe(s)3 CO2(g)

2.

(1)

2 Na(s)Cl2(g) 2 NaCl(s)

(2)

3.
(1)

(2)

(3)

(4)

2 Na(s) 2 Na(s)2 e
Cl2(g)2 e 2 Cl(s)

NaCl2

Zn(s)Cu

(aq)

Cu(s)Zn

(A) Zn
(B) Cu
(C) Zn
(D) Cu2

(aq)

[] D
Zn 0 2 2
2

Cu 20 2

(A) 2 MgCO2 2 MgOC

(B)
(C)
(D)

[] C

(C) Mg0 MgO2

(1)(2)
(3)(4)

1
(A) H2(g)
O2(g) H2O(l)
2

[] ABCE

(B) 2 Mg(s)CO2(g) 2 MgO(s)C(s)

(C) Zn(s)I2(s) ZnI2(s)
(D) AgNO3(aq)NaCl(aq) AgCl(s)NaNO3(aq)
(E) Fe(s)2 HCl(aq) FeCl2(aq)H2(g)


1
(A) H2(g)
O2(g) H2 O(l)
2
0
0
12
(B) 2 Mg(s)CO2(g) 2 MgO(s)C(s)
0

(C) Zn(s) I2(s) Zn I2(s)

0

21

(D) AgNO3(aq) NaCl(aq) Ag Cl(s) NaNO3(aq)

1

11

(E) Fe(s) 2H Cl2(aq) Fe Cl2(aq) H2(g)

0

1 1

21


(A) 2 Na2 H2O 2 NaOHH2
(B) MgSO4Na2CO3 MgCO3Na2SO4
(C) Zn2 HCl ZnCl2H2
(D) NaOHHCl NaClH2O
(E) 2 H2O

2 H2O2

[] BD
(B)(D)(E)

( p.30)

1.

NaClOH2O2
Cl2O3

SO2

H2O2

(1)

H+

MnO4 Mn2
MnO
MnO4
2
MnO 2
MnO4
4
Cr2O72 Cr3
H2O2 H2O

MnO48 H5 e
Mn24 H2O
MnO42 H2O3 e
MnO24 OH
MnO4e MnO42
Cr2O7214 H6 e
2 Cr37 H2O
H2O22 H2 e
2 H2O


CuAg NO
HNO3
2
CuAg NO
HNO3
Zn NH
HNO3
4

HNO3 He
NO2H2O
HNO3 3 H3 e
NO2 H2O
HNO39 H8 e
NH43 H2O

CuAg
H2SO4
Zn S
H2SO4

SO2

H2SO42 H 2 e
SO22 H2O
H2SO46 H6 e
S4 H2O

X2 X

X22 e 2 X

Ce4 Ce3

Ce4e Ce3

Fe3 Fe2

Fe3e Fe2

(2)

C2O42H2C2O4 CO2

H2C2O4 2 CO22 H
2 e

H2S S

H2S S 2 H2 e

H2O2 O2

H2O2 O22 H2 e

NO2 NO3

NO2H2O NO3
2 H2 e

SO2SO32HSO3
SO42
2

I2

2
Cl
Cr
O
MnO4
2
2
7

S2O3

S2O3
2
SO4

S4O6

SO22 H2O SO424 H

2 e
2

2
S2O3

2
S2O3 5

S4O6 2 e

H2O 2 SO4

8 e 10 H


Sn2 Sn4
2

Fe

Fe

X X2

Sn2 Sn42 e
2

Fe

Fe e

2 X X22 e

2.
(1)Fe2O3 CaCO3

(2)

(3)3 C(s)2 Fe2O3(s) 3 CO2(g)4 Fe(s)

2 C(s)O2(g) 2 CO(g)
3 CO(g)Fe2O3(s) 3 CO2(g)2 Fe(s)
(4)

CaO(s)SiO2(s)

CaSiO3(s)

(A)

(B)

(C)

(D)

(E)

[]

BCDE

(A)


(A) Fe2O3

(B)

(C)
(D) CaSiO3

[] D

(A) Fe3O4(B)
(C)

(A) MnO2

(B) C

(C)

(D)
(E)

[]

BC
(A) MnO2 (D) H2O2(aq)
(E) SO2

1.
(A) (B) (C) (D) (E)

[] AD

2.NaNO2

Fe

Fe2 Fe3
C
C

(A) C
(B) C

(C) C

(D) C
(E) C

[] C

C E antioxidant
C

NO2 NO

 1
1-5

1-5

( p.37)

1.

AgNO3NaCl

AgCl
ClAg

 AgNO3(aq) NaCl(aq)

2.

(1)

AgNO3(aq)NaCl(aq) AgCl(s)NaNO3(aq)
(2)

Ag(aq)NO3(aq)Na(aq)Cl(aq) AgCl(s)
Na(aq)NO3(aq)

(3)
Ag(aq)Cl(aq) AgCl(s)
(2)

3.

AgClPbCl2PbSO4BaSO4CaCO3
ZnSAl(OH)3CaC2O4

AgIAgBrPbCrO4PbI2
BaCrO4

Ag2SCuO

Ag2CrO4Fe(OH)3

MnSCu(OH)2

4.

NO3

CH3

AgHg22

ANH4

COO

ClBrI

AgPb2Hg22
Cu
Tl

SO42

Ca2
Sr2Ba2Pb2

CrO42

AgPb2Ba2

S2

ANH4A2

OH
CO32C2O42

ANH4Sr2
Ba2
Ca2
ANH4
Mg2

SO32PO43 ANH4


(1) AA2
(2) H

5.
(1) Mg22 OH Mg(OH)2
(2) AgCl AgCl
(3) Ca2CO32 CaCO3
(4) Mg2CO32 MgCO3

(5) Pb22 I PbI2

(6) Ba2SO42 BaSO4

Cl SO4

(A) Ba2 (B) NH4

(C) Na (D) K

[] A

(A)

() K2SO4 () K2CO3 () KCl

(A)

(B)

(C)

(D)

[] D

(A) CH3COONa (B) PbSO4 (C) ZnS

(D) K3PO4 (E) CuCl2
[] ADE
(A)(D) NaK(E) Cl Cu
CuCl2


(A) AgCl

(B) CaCO3

(C) Mg(OH)2

(D) PbI2

[] D

I AgIPbI2

 1
1-6
1

2
3
4

1-6

( p.42)

1.

Al(OH)
3

KAl(SO4)212 H2O
Al 3

3
H
O

3
H
(aq)
2 (l)
(aq)

Al(OH)3(s)

0.21 ppm

2.

(A)

(B)

(C)

(D) Al2(SO4)3
3

Al

91.

[] D

(A)(B)
(C)

1.

(A)

(B)

(C)

(D)

[] B

(B) Al(OH)3 Mg2 Ca2

2.

(A)

[]

(B)

(C)

(D)

( p.43)

1.Mg2Ca2

2.
(1)HCO3
(2)SO42
Cl
Ca2Mg2
CaCO3MgCO3 CaSO4

3.

MgCO3(s)CO2(g)H2O(l)
Mg(HCO3)2(aq)

CaCO3(s)CO2(g)H2O(l)
Ca(HCO3)2(aq)

CaO
H
O
Ca
2
OH
(s)
2 (l)
(aq)
(aq)

2
Mg
2
OH
Mg(OH)2(s)
(aq)
(aq)

CO2(aq)OH(aq) HCO3(aq)

HCO3 (aq)OH (aq) CO32 (aq) H2O(l)

Ca2(aq)CO32(aq) CaCO3(s)

NaAlSiO4
NaZ

M2(aq)2 NaZ(s)

M Ca Mg

MZ2(s)2 Na(aq)

NaAlSiO4
NaZ
M2(aq)2 NaZ(s)

MZ2(s)2 Na(aq)

M Ca Mg


(1)


(2)

Ca (aq)

Mg2(aq)2 C17H35COO (aq)

Ca(C17H35COO)2(s)
Mg(C17H35COO)2(s)


(3)
RH
R'OH


RH(s)M(aq) RM(s)H(aq)
R'OH(s)X(aq) R'X(s)OH(aq)
H(aq)OH(aq) H2O(l)
MX

(A)
(B)

(C)
(D)

[] C

(A)(B) NaCl
(D)

(A) HCl

(B) C17H35COONa

(C)

(D) Na2CO3

[]

Cl Mg2

234
Na
23Cl36.5
(A) 0.5 (B) 1.0 (C) 2.0 (D) 4.0
[] C

2 NaZCa

CaZ22 Na

234 NaCl 4 mol Ca2 2 mol

 NaOH 5 MNaCl 5 M Ca(NO3)2 2 M

1 RH

(A) 4

[]

(B) 9

(C) 14

(D) 12

B
n RHM

MRnn H NaOH

5 mmol HNaCl 5 mmolCa(NO3)2

4 mmol H 14 mmol OH
5 mmol 9 mmol

( p.46)

1.
(1)

(2)

2.
BOD
1 atm20 5

COD

K2Cr2O7

mgL

mgL

1 mgL1 ppm

BOD

16.2 ppm C6H10O5

ppm
[] 0.0192 gL19.2 ppm

C6H10O56 O2 6 CO25 H2O

16.2
O2
6 3219.2 ppm
162

 5.0 mL 100 mL
3

20 8.510
3

L 2.010

gL

BOD ppm
(A) 10

(B) 13

[]

(C) 130

(D) 300

8.52.010

gL6.5 ppm

100
BOD6.5
130 ppm
5.0

( p.48)

1.

SO2(g)H2O(l) H2SO3(aq)
2 SO2(g)O2(g) 2 SO3(g)

SO3(g)H2O(l) H2SO4(aq)
pH 5.67.0

2.
3. SO2

CaSO3 CO2
SO2(g)CaCO3(s) CaSO3(s) CO2(g)

 CaCO3 SO2

(A)
(B)
(C) 7
(D)
[] B

(A) PO43

(C) pH5.0(D) NOx SOx

 pH

(A)
(B) CO
(C)

(D)

[]

A
(B) CO (C) NOx
(D)