Steam Calculations

cf. IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use
J.Phys.Chem.Ref.Data, 31(2):387-535, (2002)

PV
Gibb's energy
Cv

0.0615599876
-767.1275305043
6.1831572767

T
P

647
22.0384755707

K
MPa

0.0027933

m3/kg

252.14507827

358

kg/m

97.7193269499

2028.5096931668

kJ/kg

-12.6424993606

1966.9497055392

kJ/kg

0.0035804118

4.320923066

kJ/kgwK

Cp

1.0001483771

Tc ( K )

1.1118012422

322

647.096 R (kj/kg K)

3.5318E+03
0.46151805

for r

Table of Residual Coefficients

i

ci

di

ti

ni

niditi

0.5

0.0125335479

0.0139337805

0.875

7.8957634723

8.7796593414

8.7803203304 9.7634195037

4
5
6
7

0
0
0
1

2
2
3
4

0.5
0.75
0.375
1

0.3180250935
0.2614553386
0.0078199752
0.0088089493

0.3931406181
0.3232214319
0.0107475878
0.013461615

ci

di

ti

ni

niditi*exp(-ci)

8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2

1
1
1
2
2
3
4
4
5
7
9
10
11
13
15
1

4
6
12
1
5
4
2
13
9
3
4
11
4
13
1
7

0.6685657231
0.2043381095
6.62126E005
0.1923272116
0.25709043
0.1607486849
0.0400928289
3.934342E007
7.59414E006
0.0005625098
1.56087E005
1.153800E009
3.658217E007
1.32512E012
6.26396E010
0.1079360091

Page 1

-2.4467E-01
7.4802E-02
-2.4260E-05
-7.8219E-02
-1.0462E-01
7.2717E-02
-2.0158E-02
1.9814E-07
-4.2496E-06
3.8874E-04
-1.3336E-05
1.0971E-09
3.8635E-07
-1.7322E-12
-1.0103E-09
-3.4899E-02

Steam Calculations

24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50

2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
4
6
6
6

2
2
2
3
4
4
4
5
6
6
7
9
9
9
9
9
10
10
12
3
4
4
5
14
3
6
6

1
9
10
10
3
7
10
10
6
10
10
1
2
3
4
8
6
9
8
16
22
23
23
10
50
44
46

0.017611491
0.2213229517
0.4024766976
0.5808339999
0.0049969147
0.0313587007
0.7431592971
0.4780732992
0.0205279409
0.1363643511
0.0141806344
0.0083326505
0.029052336
0.0386150856
0.0203934865
0.001655405
0.0019955572
0.0001587031
1.63886E005
0.0436136157
0.0349940055
0.0767881978
0.0224462773
6.26897E005
5.57111E010
0.1990571835
0.3177749733

6.3253E-03
7.9584E-02
-1.4475E-01
2.3224E-01
2.2191E-03
-1.3934E-02
-3.3037E-01
2.3629E-01
1.1274E-02
-7.4933E-02
8.6636E-03
6.2843E-03
-2.1914E-02
2.9131E-02
-1.5387E-02
-1.2498E-03
1.6745E-03
1.3323E-04
-1.7004E-05
1.5201E-02
1.3573E-02
-2.9788E-02
9.6808E-03
-6.0068E-05
-1.1668E-10
-5.7243E-02
9.1410E-02

51

50

0.1184118243

-3.4082E-02

ci

di

ti

ni

52
53
54

0
0
0

3
3
3

0
1
4

31.306260323 20
31.5461402378 20
2521.3154342 20

ai

bi

Bi

ni

55
56

3.5
3.5

0.85
0.95

0.2
0.2

0.1487464086 28
0.3180611088 32

Ci

real-gas part and derivatives

ideal-gas part and derivatives

1.21202657

1.56319605

0.714012024

0.899441341

0.47573070

0.808994726

3.21722501

9.80343918

Page 2

Steam Calculations

9.96029507

3.43316334

1.33214720

0.00000000

Page 3

Steam Calculations

ce for General and Scientific Use

the key equations
647
2.2038E+01
0.0027932961
358
2.0285E+03
1966.949705539
4.320923066

forr

forr

for r

forr

nididi-1ti

nidi(di-1)di-2ti

nitiditi-1

niti(ti-1)diti-2

niditidi-1ti-1

0.0125326182

-0.006965857 0.0104472349

-0.006265379

7.8967885696

7.6810622298 -0.9599903381

6.9086649106

8.781623129

-9.761971051 0

-8.78032033

0.7072138493
0.5814374361
0.0290004744
0.0484317321

0.6360973728
0.5229688671
0.0521684511
0.1306845063

0.1965411468
-0.24238011
-0.004029748
0.0134596179

0.3535544652
-0.436013383
-0.010873564
0.048424547

forr

-0.0982559945
0.060586038
0.0025182185
0

niexp(-ci)[di-1ti(di-ci niexp(-ci)[di-2ti((di-cnitiditi-1exp(-ci niti(ti-1)diti-2exp(-ci) nitidi-1ti-1(di-cici)exp(-ci)

2.4604E-02
-7.5220E-03
2.4396E-06
-6.2488E-02
-8.3579E-02
1.2350E-01
-5.2367E-02
5.1472E-07
-1.4862E-05
2.0588E-03
-9.4617E-05
8.7710E-09
3.4361E-06
-1.8522E-11
-1.2621E-08
4.6212E-02

0.1954622358
0.0597581296
1.938094E005
0.0766367525
0.1025038098
0.0332550783
0.0708043195
6.959435E007
3.47848E005
0.0087022803
0.0005742077
6.124306E008
2.712217E005
1.79832E010
1.45395E007
0.0368390448

-0.978532856
0.4487462216
-0.000291078
-0.078207049
-0.523020629
0.2908258754
-0.040310725
2.57542E-006
-3.8240E-005
0.0011660607
-5.3335E-005
1.20667E-008
1.54516E-006
-2.2515E-011
-0.000000001
-0.24425636

-2.9351630565
2.2433982389
-0.003201378
0
-2.0917721456
0.8723481896
-0.0403047444
3.0900463368E-005
-0.0003058783
0.0023317754
-0.0001599819
1.2064946527E-007
4.6347795401E-006
-2.701418094E-010
0
-1.465320737

Page 4

0.098399952
-0.045125318
2.92704E-005
-0.062478257
-0.417832123
0.4939165705
-0.104717805
6.69034E-006
-0.000133735
0.0061755616
-0.000378412
9.64665E-008
1.37424E-005
-2.4075E-010
-1.2619E-008
0.3234347804

Steam Calculations

-2.6865E-03
-3.3801E-02
6.1477E-02
1.1025E-01
3.0494E-03
-1.9148E-02
-4.5398E-01
5.3723E-01
3.5772E-02
-2.3777E-01
3.5282E-02
3.6898E-02
-1.2867E-01
1.7104E-01
-9.0344E-02
-7.3379E-03
1.1338E-02
9.0208E-04
-1.4572E-04
-1.5353E-02
-1.5003E-03
3.2927E-03
7.6372E-03
-4.2618E-04
8.7443E-10
2.7454E-01
-4.3840E-01

0.0217439406
0.2735798189
0.497579844
0.975804261
0.0074286913
0.0466472639
1.105969967
0.2069171228
0.0362361684
0.2408548906
0.0772981515
0.1583152864
0.5520585979
0.7338808509
0.3876363261
0.0314843688
0.0598706378
0.0047635242
0.0010496836
0.1227928114
0.1342968545
0.2947345816
0.0977123609
0.0014524133
9.21702E010
1.5851102817
2.5312217181

1.6346E-01 0.9437637835

0.0063243829
0.7161540807
-1.447247085
2.3221011198
0.0066562312
-0.097525694
-3.303225083
2.3625330681
0.067631569
-0.749223537
0.0866230313
0.0062834083
-0.043821537
0.0873814489
-0.061539915
-0.009996717
0.010045623
0.0011988991
-0.000136011
0.2431863894
0.2985570205
-0.68501124
0.2226253944
-0.000600588
-5.8331E-009
-2.518327778
4.2042459678

0
5.728382685
-13.0232914045
20.895809618
0.0133104875
-0.5850673526
-29.7246152963
21.2596431682
0.3381076777
-6.7420114755
0.7794916233
0
-0.0438150357
0.1747369707
-0.1845923553
-0.0699666394
0.0502206633
0.0095897696
-0.0009519392
3.6472546716
6.2687672886
-15.0680115303
4.8970320694
-0.0054044931
-2.857790547E-007
-108.2720293826
189.1630010887

-1.703858042 -83.4766580185

150
150
250

1.21
1.21
1.25

1
1
1

Di

Ai

700
800

0.32
0.32

0.3
0.3

Page 5

-0.002686091
-0.30416482
0.6146744966
1.1023514147
0.0091467459
-0.134016188
-4.539169289
5.3714651522
0.2145980498
-2.377320419
0.3527711605
0.0368922124
-0.257292439
0.5130487809
-0.361323584
-0.058694422
0.0680170138
0.0081175189
-0.001165577
-0.245613872
-0.033002685
0.0757215833
0.1756293289
-0.004261162
4.37151E-008
12.077899847
-20.16356336
8.1717030473

Steam Calculations

Page 6

Steam Calculations

Ideal-Gas Coefficients

ni

8.320446482 0

6.6832105268 0

for o

3.00632

nioln(1-exp(-io)) nioio[(1-exp(-io))-1-1]nio(io)2exp(-io)(1-exp(-

4
5
6
7

0.012436
0.97315
1.2795
0.96956

1.28728967
3.53734222
7.74073708
9.24437796

0.00401578
0.028714093
0.000555746
9.3587E005

0.24873

27.5075105

2.8029E013 7.710024E012 2.12079E010

column sum=

0.033379207 0.1143546547

Page 7

foro
0.006101713
0.1030849237
0.0043028186
0.0008651995

for o
0.0108484725
0.375566348
0.0333214571
0.0079990034
0.4277352811

Steam Calculations

for r

forr

forr

forr

for r

forr

niditi*exp[-ai(-niditiexp{-i(-i)2- nitiexp(-i(-i)2-i(-i)2)[-2
niditiexp(-i(-i)2-niditiexp(-i(-i)2- niditiexp(-i(-i)20.0453256 0.0803951637
0.04567967 -0.0810232008
0.0004504 0.0007988857

1.780429157
1.7943376497
0.0176921018

-2.8534946343
2.9214586739
-0.0580678945

-166.0454667276
173.0933116993
-7.2594149827

5.0613166737
-5.1818662352
0.1029965149

d/d

d2/d2

dbi/d

4.816E008 6.70525E005 0.7046867448

4.816E008 6.70525E005 0.670318584

3.59541E006 0.0002472143
3.59541E006 0.0002472143

3.82614E005
7.93116E006
d/d
4.411951794
4.796316825

Page 8

Steam Calculations

for r
nibi

forr

forr

forr

for r

forr

bi
2 b2i
bi
2
i 2 2
ni[
/d(+d/d)+d
dbi/d+ bi d/d]
n2i(d
bi/d
/d
]2 +2 dbi/d
ni[d/d+
(d/d b+
d /d
d /dd)+
)
dbi/d
ni[bi(+d/d)+dni[bi(2d/d+d2/d2+2d

7.03E008 4.0822E006 -0.0002068742

2.651E008 1.71415E006 9.8045306136174E-005

0.0001663276
-7.0127870

Page 9

-2.4108487369
1.0360000128

0.0131780807
-0.0060169909

Steam Calculations

)2exp(-io)(1-exp(-io))-2

Page 10

Steam Calculations

exp(-i(-i)2-i(-i)2[di/-2i(-i)][ti/-2i(-i)]

d2bi/d2

dbi/d

d2bi/d2

d2bi/dd

0.0022023493 0.0014271064 20.687379961 0.1207231708

0.0005157293 0.0002958235 4.3706356123 0.0272329254
d2/d2
11.839803

d/d
d2/d2
d2/dd
0.1463831507 986.5310349 0.9164858131

8.58140191

0.1591359111 1072.471955 1.1386619231

Page 11

Steam Calculations

(d/d + d2/dd)+ dbi/d d/d+dbi/d(+ d/d)+ d2bi/dd ]

Page 12

Revisions
8/11/2005

Thanks to user Edward D. Throm for correcting calculation of Cp and speed of sound.