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The complex is moderately soluble in benzene, chloroform, and
dichloromet hane.
Tricarbonylbis(triphen~1phosphinejrutheiitm)forms pale yetlow microcrystals which melt a t 170-173' in air and at 262-266"
in a capilIary sealed under nitrogen. The infrared spectrum shows
a single very strong band at 1900 cm.-' attributable to v ( C 0 ) .
The complex is moderately soluble in benzene and dichlorornethane.
Trichloroni trosylbis(tripheny1phosphine)ruteium(11) was originally prepared by heating a mixture of [RuCl,(NO)], and triphenylphosphine in ethanol for 5-10 minutes. ' ' It has subsequently
been prepared by treating the complexes RuCl(COj(N0)[P(C,M,),]," or RUCI(NO)[P(C~H~)~]~~~
with chlorine. The procedure
described below is based o n ruthenium trichlotide and eliminates
the need to use preformed ruthenium nitrosy1 derivatives.