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University of Nevada, Chemical and Materials Engineering Department, Reno NV, 89557,
USA.
b
Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku,
Kyoto 615-8510, Japan.
c
Department of Molecular Engineering, Graduate School of Engineering, Kyoto University,
Nishikyo-ku, Kyoto 615-8510, Japan.
electrochemical analyzer. The working electrode was irradiated with a 500W Newport
Xenon lamp equipped with 0.5 M CuSO4 solution as a far UV cutoff filter; this also
2
performed in a GAMRY setup, over the frequency range 0.01 to 105 Hz with 0.5 bias
voltages.
All the impedance measurements were carried out using the same
electrochemical set-up described above, with 0.1 N Na2SO4 as an electrolyte and the
obtained spectra were fitted to obtain equivalent circuits.
Figure SI 3. The crystalline phase of the rod TiO2 (rTiO2) and the branched TiO2 (bTiO2)
are examined using XRD over a 2 range from 20 to 80. The XRD shows that both
structures are in tetragonal rutile phase. A relative higher intensity peak at 2=62.9
suggests that TiO2 growth takes place along the (002) plane.
Intensity, a.u.
002
112
110
20
40
60
80
2, degree
Figure SI 5. (A) Shows the XRD diffraction pattern of the CdS nanocrystals, the peaks
at 002, 110, and 112 corresponds to the wurtzite phase of CdS (JCPDF card # 77-2303)
while (C), (D), and (E) shows the decoupled color distribution of CdS, Cd2+ and S2respectively.
Figure SI 7.
potential values were determined for the photoanodes (a) bTiO2/RGO/CdS and (b)
bTiO2/CdS. The measurements were performed using a three electrode set-up in the
presence of 0.1 N Na2S as an electrolyte.