Seamless Pipes and Tubes For The Chemical Industry: (Stainless Steel and Ni-Based Alloys)

Pipe Products
NIPPON STEEL & SUMITOMO METAL
Seamless Pipes and Tubes

for the Chemical Industry
(Stainless Steel and Ni-based Alloys)
http://www.nssmc.com/
2-6-1 Marunouchi, Chiyoda-ku,Tokyo 100-8071 Japan

Tel: +81-3-6867-4111
Seamless Pipes and Tubes for the Chemical Industry

P007en_03_201512f
2013,2015 NIPPON STEEL & SUMITOMO METAL CORPORATION
Seamless Pipes and Tubes for

the Chemical Industry
Stainless steel and Ni-based alloy pipes and tubes

have superior corrosion resistance, heat resistance, and low-temperature properties, and have
been used as raw materials that can withstand
harsh environments as seen in petroleum refining,
petroleum chemistry, and energy fields, such as
power and gas. Recently, they have proliferated
in fields for building construction applications with
their high aesthetic quality advantages, as well as
in fields of new demand including semiconductor
and liquid-crystal manufacturing equipment applications requiring a high level of cleanliness.
Our stainless steel and Ni-based alloy pipes and

tubes have been manufactured based on excellent technology and strict quality control, from raw
materials to final products, and have gained a
favorable reputation from various fields. Without
remaining complacent with the status quo, we
will continue to research and develop improved
products and will strive to meet the demands of
the industry which is undergoing remarkable
technological innovation and so we hope you
will continue to do business with us.
Contents
Features
2
3
Manufacturing Bases
4
Manufacturing Process
6
Available Size Range (typical examples)
Product outline (applications and standards) 8
System diagram of stainless steel
12
and Ni-based alloy
Introduction to high-function steel grades
14
YUS270
15
347AP
16
NSSMC317CU
17
YUSDX1
18
DP3W
19
DP28W
20
YUS190
21
Grade HPM
22
NSSMC696
23
NSSMC845
24
HRX19
25
Examples of Application
26
Example of Packing
27
Example of Indications
27
Requests during orders
Notice: While every effort has been made to ensure the accuracy of the information contained within this publication, the
use of the information is at the readers risk and no warranty is implied or expressed by Nippon Steel & Sumitomo Metal
Corporation with respect to the use of the information contained herein. The information in this publication is subject to change
or modification without notice. Please contact the Nippon Steel & Sumitomo Metal Corporation office for the latest information.
Please refrain from unauthorized reproduction or copying of the contents of this publication.
The names of our products and services shown in this publication are trademarks or registered trademarks of Nippon Steel
& Sumitomo Metal Corporation, affiliated companies, or third parties granting rights to Nippon Steel & Sumitomo Metal
Corporation or affiliated companies. Other product or service names shown may be trademarks or registered trademarks of
their respective owners.
Features
Manufacturing Bases
Consistent quality control
Consistent control is performed from the material design stage, in order to deliver materials that meet customer needs.
Strict quality control is performed from the raw material processing and steel-making stages to deliver high quality
materials.
Abundant steel grades
In addition to the steel grades specified in the JIS and ASTM standards, our proprietary characteristic steel grades are
also available.
Facilities
1
2
3
4
5
6
7
Numerous acquired certifications
Many JIS, TV, and ship-class standard certifications and approvals have been acquired.
8
9
Substantial process control and service organization
Production is based on rational process control to ensure that you are satisfied about the delivery date.
Appropriate technical services are also provided based on state-of-art research, experience, and track records.
10
11
12
13
14
15
16
17
18
Main production specifications
ASTM/ASME
EN
JIS
Standard No.
Title
A182/SA-182
Forged or Rolled Alloy and Stainless Steel Flanges, Forged fittings, and Valves and Patrs for High
Temperature Service
A213/SA-213
Seamless Ferritic and Austenitic Alloy-Steel Boiler, Superheater and Heat-Exchanger Tubes
A268/SA-268
Seamless and Welded Ferritic and Martensitic Stainless Steel Tubing for General Service
A312/SA-312
Seamless, Welded and Heavy Cold Worked Austenitic Stainless Steel Pipes
A335/SA-335
Seamless Ferritic Alloy-Steel Pipe for High-Temperature Service
A376/SA-376
Seamless Austenitic Steel Pipe for High-Temperature Central-Station Service
A403/SA-403
Wrought Austenitic Stainless Steel Piping Fittings
A789/SA-789
Seamless and Welded Ferritic/Austenitic Stainless Steel Tubing for General Service
A790/SA-790
Seamless and Welded Ferritic/Austenitic Stainless Steel Pipes
B161/SB-161
Nickel Seamless Pipes and Tubes
B163/SB-163
Seamless Nickel and Nickel Alloys Condensor and Heat Exchanger Tubes
B167/SB-167
Nicke-Chromium-Iron Alloys and Nickel-Chromium-Cobalt-Molybdenum Alloy Seamless Pipes and

Tubes
10216-5
Seamless Steel Tubes for Pressure Purposes, Technical Delivery Conditions, Stainless Steel Tubes
G 3446
Stainless steel pipes for machine and structural purposes
G 3459
Stainless steel pipes
G 3463
Stainless steel boiler and heat exchanger tubes
G 3467
Steel tubes for fired heater
G 4906
Seamless nickel-chromium-iron alloy heat exchanger tubes
H 4552
Nickel and nickel alloy seamless pipes and tubes
Muroran Works
Kamaishi Works
Kashima Works:
Hot electric resistance-welded steel pipes
UO steel pipes
Kimitsu Works
Kimitsu Area:
Electric resistance-welded steel pipes
Spiral steel pipes, UO steel pipes
Tokyo Area:
Seamless steel pipes (Mannesmann process)

Naoetsu Works
Nagoya Works:
Wakayama Works Wakayama Area:
Kainan Area:

Sakai Area
Osaka Steel Works
Amagasaki Works:
Seamless steel pipes (Ugine process)
Hirohata Works
Yawata Works
Yawata Area
Spiral steel pipes
Tobata Area:
Kokura Area
Oita Works
Oita Area
Hikari Area:

Seamless steel pipes (Ugine process)
2
6
5
4
13
18
15
14 16
12 11
10
8
9
17
Manufacturing Process
Melting
Refining
Casting
Billet Making
Hollow forging process (Ehrhardt Push Bench process)
Hot finished seamless
steel pipe
OD: 6.5~37.5inch
Argon-Oxygen
Decarburization (AOD)
Electric arc furnace
Manufacturable size range

Outside diameter:
165.2~952.5mm
Super forging press

Horizontal push bench
Vertical piercing press
Ingot casting
Extrusion process (Ugine-Sejournet process)

Hot finished seamless
steel pipe and tube
Vacuum-Oxygen
Decarburization (VOD)
Blast furnace
Continuous casting
Vertical expanding press
Blooming mill
Horizontal extrusion press
OD: 1.3~10.8inch
Outside diameter:
33.4~275.0mm
Secondary Melting
Cold working (Cold-rolling process and cold-drawing process)
Mannessman process
(Mannessman and Mandrel mill processes)
Vacuum Arc Remelting (VAR)
Cold pilger mill
3-roller stretch reducer

Vacuum Induction
Melting (VIM)
Toe-angle piercer
Cold finished seamless

steel pipe and tube
OD: 0.24~20inch
Outside diameter:
6~508mm
Mandrel mill
Cold drawing bench
3-roller extracting sizer

Electro Slag Remelting (ESR)
Item
Main Facillities
Steel Making Facilities
Electric arc furnace, AOD (Argon Oxygen Decarburizing) equipment

VOD (Vacuum Oxygen Decarburizing) equipment, VIM (Vacuum Induction Melting) furnace
VAR (Vacuum Arc Remelting) furnace, ESR (Electro-Slag Remelting) equipment
Forging Facility
Super forging press, Blooming mill
Hot Finished Pipe and Tube-Making Facilities
(Toe-angle piercing type tube making mill)

Extrusion tube mill, Hollow forging pipe mill (Vertical press, Horizontal press)
Boring and trepanning machines, Lathes for OD machine
Cold Finished Pipe and Tube-Making Facilities
Hydraulic cold drawing bench, Oil hydraulic drawing bench

Chain type cold drawing bench, High pressure drawing bench
Cold pilger mill
Heat Treatment Furnaces
Continuous type/Batch type/Barrel type, Atomsphere controlled type/Vacuum annealing type
Electric arc farnace
Horizontal push bench
Horizontal extrusion press
Cold pilger mill
Cold drawing bench
Heat treatment furnace
Available Size Range (typical examples)

Hot-finished seamless pipes and tubes
Nominal
diameter
Cold-finished seamless pipes and tubes
Outside
diameter
A B mm
Wall Thickness (mm)
2.8
3.5
10
11
12
13
14
15
17
20
25
30
35
40
45
Outside
diameter
Nominal
diameter
Outside
diameter
mm
A B
mm
25
34.0
34.0
40
38.1
38.1
1 /2
48.6
48.6
50
60.5
65
21/2
1.2 1.6
2.6 3.2
4.5
Wall Thickness (mm)
Outside
diameter
mm
10 11 12 13 14 15 17 20 25 30 35
6.0
6.0
8.0
8.0
/8
10.5
10.5
60.5
10
/8
17.3
17.3
76.3
76.3
15
/2
21.7
21.7
82.6
82.6
20
/4
27.2
27.2
25
34.0
34.0
38.1
38.1
80
89.1
89.1
90
31/2
101.6
101.6
100
114.3
114.3
32
11/4
42.7
42.7
120.0
120.0
40
11/2
48.6
48.6
130.0
130.0
50
60.5
60.5
65
76.3
76.3
82.6
82.6
125
2 /2
139.8
139.8
150.0
150.0
165.2
165.2
80
89.1
89.1
170.0
170.0
90
31/2
101.6
101.6
190.7
190.7
100
114.3
114.3
200
216.3
216.3
120.0
120.0
250
10
267.4
267.4
130.0
130.0
300
12
318.5
318.5
139.8
139.8
350
14
355.6
355.6
150.0
150.0
400
16
406.4
406.4
165.2
165.2
170.0
170.0
190.7
190.7
200
216.3
216.3
250
10
267.4
267.4
300
12
318.5
318.5
350
14
355.6
355.6
400
16
406.4
406.4
150
A B mm
Nominal
diameter
Outside
diameter
2.8
3.5
10
11
12
13
14
15
17
Wall Thickness (mm)
Remarks 1. Notice-there is a range where available size can be difficult, depending on the material properties.
2. Consult with us about ultra-thin items near the available size limit beforehand.
3. Consultation regarding size for anything not in this table is also available.
20
25
30
35
40
45
125
150
mm
Outside
diameter
A B
mm
Nominal
diameter
Outside
diameter
1.2 1.6
2.6 3.2
4.5
10 11 12 13 14 15 17 20 25 30 35
Wall Thickness (mm)
mm
Outside
diameter
Remarks Consultation about size regarding that other than this table is also offered.
Product outline (applications and standards)

Common grade seamless pipes and tubes for the chemical industry
Classification
Grade
Component
303
304
304H
304L
18Cr-8Ni-S
18Cr-8Ni
18Cr-8Ni-High C
18Cr-8Ni-Low C
304N
304LN
Austenitic
stainless steel
309
309S
310
310S
312L
316
316H
316L
316Ti
317
317L
Duplex
stainless steel
Martensitic
stainless steel
Ferritic
stainless steel
High Ni alloy
Applicable standard
ASTM/ASME
(example of a standard)
S30300
S30400
S30409
S30403
S30451
18Cr-8Ni-N
ASTM A213 TP304N
S30453
18Cr-8Ni-Low C-N
ASTM A213 TP304LN
22Cr-12Ni
S30909
22Cr-12Ni
S30908
25Cr-20Ni
S31009
25Cr-20Ni
S31008
20Cr-18Ni-6Mo-0.2N
S31254
18Cr-12Ni-2Mo
S31600
18Cr-12Ni-2Mo-High C
S31609
18Cr-12Ni-2Mo-Low C
S31603
S31635
18Cr-12Ni-Mo-Ti
ASTM A213 TP316Ti
18Cr-12Ni-3Mo
S31700
18Cr-12Ni-3Mo-Low C
S31703
EN, etc.
1.4305
1.4301
1.4948
1.4307
JIS
SUS303
SUS304
SUS304H
SUS304L
8.011.0
18.020.0
0.100.16
550
240
8.011.0
18.020.0
0.100.16
515
205
35
1.4829
SUS309
SUS309S
SUS310
SUS310S
SUS312L
SUS316
SUS316H
SUS316L
0.15max.
0.08max.
0.15max.
0.08max.
0.02max.
0.08max.
0.040.10
0.030max.
1.00max.
1.00max.
1.50max.
1.50max.
0.80max.
1.00max.
0.75max.
1.00max.
2.00max.
2.00max.
2.00max.
2.00max.
1.00max.
2.00max.
2.00max.
2.00max.
0.040max.
0.045max.
0.040max.
0.045max.
0.030max.
0.045max.
0.030max.
0.045max.
0.030max.
0.030max.
0.030max.
0.030max.
0.015max.
0.030max.
0.030max.
0.030max.
12.0015.00
12.0015.00
19.0022.00
19.0022.00
17.5019.50
10.0014.00
11.0014.00
12.0016.00
22.0024.00
22.0024.00
24.0026.00
24.0026.00
19.0021.00
16.0018.00
16.0018.00
16.0018.00
6.007.00
2.003.00
2.003.00
2.003.00
0.160.23
Cu:0.501.00
520
520
520
520
650
520
520
480
205
205
205
205
300
205
205
175
35
35
35
35
35
35
35
35
0.08max.
0.75max.
2.00max.
0.030max.
0.030max.
11.0014.00
16.0018.00
2.003.00
520
205
35
0.08max.
0.030max.
1.00max.
1.00max.
2.00max.
2.00max.
0.045max.
0.045max.
0.030max.
0.030max.
11.0015.00
11.0015.00
18.0020.00
18.0020.00
3.004.00
3.004.00
520
480
205
175
35
35
0.08max.
1.00max.
2.00max.
0.045max.
0.030max.
9.0013.00
17.0019.00
Ti:5 C ,min
520
205
35
0.040.10
0.75max.
2.00max.
0.030max.
0.030max.
9.0013.00
17.0020.00
Ti:4 C0.60
520
205
35
0.08max.
1.00max.
2.00max.
0.045max.
0.030max.
9.0013.00
17.0019.00
Nb:10 C ,min
520
205
35
Nb:8 C1.00
520
205
35
540
255
25
1.4842
1.4547
1.4401
1.4918
1.4404
1.4571
1.4573
1.4438
SUS317
SUS317L
13Cr
430
18Cr
444
19Cr-2Ni-Ti/Nb
446
25Cr-N
1.4466
1.4462
S31803ASTM A789 NORSOK
M-630/M-650
S31260ASTM A789
S31500ASTM A789
1.4462
M-630/M-650
1.4410
M-630/M-650
S40500
1.4002
ASTM A268 TP405
S41000
ASTM A213 TP444
S43000
ASTM A268 TP430
S44400
ASTM A213 TP444
S44600
ASTM A268 TP446-1
Oxidation resistance: Chemical plant pipes and tubes

Radiant tubes
Thermocouple protection tubes
Seawater resistance: Seawater desalination plant pipes
Corrosion resistance: LNG plant pipes
Boilers, nuclear power and chemical
industry pipes and tubes
SUS316TiJIS G3163 Intergranular corrosion resistance
SUS347H
13Cr-Al
Pitting corrosion resistance:

Chemical tanker pipes
Intergranular corrosion resistance:
Chemical plant pipes
High-temperature strength:
Boiler heater tubes and reheater tubes
Intergranular corrosion resistance:
Chemical plant pipes and tubes
High-temperature strength: Boiler heater tubes and
reheater tubes
Intergranular corrosion resistance: Urea reactor tubes
SUS329J3L
SUS329J4L
High strength, high corrosion resistance:

Various heat exchanger tubes

Seawater desalination plant pipes
SUS405JIS G3463
0.040.10
1.00max.
2.00max.
0.030max.
0.030max.
9.0013.00
17.0020.00
0.025max.
0.40max.
2.00max.
0.020max.
0.030max.
21.023.0
24.026.0
2.003.00 0.100.16
1.00max.
1.50max.
0.030max.
Low thermal expansion:

Automotive exhaust system pipes
1.4006
SUS410JIS G3463
1.4016
SUS430JIS G3463
1.4521
SUS444JIS G3463 resistance:
Chloride corrosion resistance and stress corrosion crack

Water
heater pipes
800
20Cr-30Ni-Ti
N08800ASTM B163
1.4558
800H
20Cr-30Ni-Ti-High C
N08810ASTM B163
1.4876
NCF800HJIS G4904
904L
28
20Cr-25Ni-4.5Mo-Cu
27Cr-31Ni-3.5Mo-Cu
N08904ASTM A312
N08028ASTM B668
1.4539
1.4563
SUS890LJIS G3463 High corrosion resistance:
NCF800JIS G4904 High corrosion resistance

Chemical plant heater tubes and reheater tubes
Various
heat exchanger tubes

High pitting corrosion resistance:
Seawater heat exchanger tubes
0.030max.
0.030max.
1.00max.
1.50max.
1.402.00 1.202.00
0.040max.
0.030max.
4.506.50
21.0024.00
2.503.50 0.080.20
620
450
18
0.040max.
0.030max.
0.030max.
0.030max.
5.507.50
4.35.2
24.0026.00
18.0020.00
2.503.50 0.080.30
2.503.50 0.050.10
620
630
450
440
18
30
0.030max.
1.00max.
2.00max.
0.030max.
0.020max.
4.56.5
22.023.0
3.03.5
0.140.20
655
450
25
0.030max.
0.80max.
1.20max.
0.035max.
0.020max.
6.08.0
24.026.0
3.05.0
0.240.32
Cu:0.50max.
800
550
15
0.08max.
1.00max.
1.00max.
0.040max.
0.030max.
0.60max.
11.5014.50
Al:0.100.30
410
205
20
0.15max.
1.00max.
1.00max.
0.040max.
0.030max.
11.5013.50
410
205
20
0.12max.
0.75max.
1.00max.
0.040max.
0.030max.
16.0018.00
410
245
20
0.025max.
1.00max.
1.00max.
0.040max.
0.030max.
17.0020.00
1.752.50
0.025max.
Ti+Nb+Zr:
8 C +N0.80
410
245
20
0.20max.
1.00max.
1.50max.
0.040max.
0.030max.
0.75max.
23.0027.00
0.100.25
485
275
18
450
175
30
450
175
30
490
500
215
214
35
40
0.10max.
1.00max.
1.50max.
0.030max.
0.015max.
30.0035.00
19.0021.00
0.050.10
1.00max.
1.50max.
0.030max.
0.015max.
30.0035.00
19.0021.00
0.02max.
0.030max.
1.00max.
1.0max.
2.00max.
2.50max.
0.040max.
0.030max.
0.030max.
0.030max.
23.0028.00
30.0034.00
19.0023.00
26.028.0
4.005.00
3.04.0
0.020max.
0.80max.
1.00max.
0.030max.
0.010max.
17.518.5
19.520.5
6.06.5
0.180.22
0.07max.
1.00max.
2.00max.
0.045max.
0.035max.
32.038.0
19.0021.00
2.003.00
0.05max.
0.50max.
1.00max.
0.030max.
0.015max.
38.0046.00
19.5023.50
2.503.50
0.15max.
0.50max.
1.00max.
0.030max.
0.015max.
72.00min
14.0017.00
0.10max.
0.5max.
1.5max.
0.015max.
58.0063.00
21.025.0
0.10max.
0.50max.
0.50max.
0.015max.
0.015max.
58.00min
20.0023.00
8.00
10.00
254SMO
20Cr-18Ni-6Mo-Cu-N
S31254ASTM A312
1.4547
20
20Cr-35Ni-2Mo-3Cu-Nb
N08020ASTM B729
2.4660
825
20Cr-42Ni-3Mo-2Cu-Ti
N08825ASTM B163
2.4858
600
15Cr-8Fe-Ni base
N06600ASTM B163
2.4816
601
23Cr-1.4Al-Ni base
N06601ASTM B163
2.4581
625
22Cr-9Mo-Ni base
N06625ASTM B444
2.4856
NCF625JIS G4904 resistance:
690
29Cr-9Fe-Ni base
N06690ASTM B163
2.4642
NCF690JIS G4904 High corrosion resistance
0.05max.
0.50max.
0.50max.
0.030max.
0.015max.
58.00min
27.0031.00
C22
21Cr-13Mo-3W-Ni base
N06022ASTM B622
2.4602
NW6022JIS H4552
0.015max.
0.08max.
0.50max.
0.025max.
0.020max.
Remnant
20.022.5
12.514.5
276
15.5Cr-16Mo-5Fe-Ni
base
N10276ASTM B622
2.4819
NW0276JIS H4552
0.010max.
0.08max.
1.00max.
0.040max.
0.030max.
Remnant
14.516.5
15.017.0
200
Ni
N02200ASTM B161
2.4066
NW2200JIS H4552 High corrosion resistance:
0.15max.
0.3max.
0.3max.
0.010max.
99.0min
201
Ni-Low C
N02201ASTM B161
2.4068
NW2201JIS H4552
0.02max.
0.3max.
0.3max.
0.010max.
99.0min
High corrosion resistance

High corrosion resistance and stress corrosion crack
NCF825JIS G4904 resistance:

Heat
exchanger tubes for petroleum refining

Oxidation resistance:
NCF600JIS G4904
Thermocouple protection tubes
Oxidation resistance and carburization resistance
High corrosion resistance and stress corrosion crack
Seawater
heat exchanger tubes
Ni-based alloy
UNS No.
35
0.030max.
1.4942
410
40
35
35
35
0.030max.
SUS347
405
205
205
205
175
0.045max.
1.4550
25Cr-7Ni-4Mo-0.3N
520
520
520
480
0.045max.
S34700
S32750
2.00max.
18Cr-9Ni-Nb
22.5Cr-6Ni-3Mo-0.2N
Others
2.00max.
347
S32205
1.00max.
SUS321H
25Cr-7Ni-3Mo-0.2N
18.5Cr-5Ni-2.7Mo
Mo
0.60max.
1.00max.
1.4940
22Cr-5Ni-3Mo-0.15N
Cr
17.0019.00
18.0020.00
18.0020.00
18.0020.00
0.08max.
S32109
329J3L
Ni
8.0010.00
8.0011.00
8.0011.00
9.0013.00
0.035max.
18Cr-9Ni-Ti-High C
329J4L
S31500
S
0.15max.
0.030max.
0.030max.
0.030max.
Intergranular corrosion resistance
321H
S34709
P
0.20max.
0.045max.
0.040max.
0.045max.
High strength
SUS321
S31050ASTM A213
Mn
2.00max.
2.00max.
2.00max.
2.00max.
SUS304LN
1.4541
25Cr-22Ni-2Mo-N
Si
1.00max.
1.00max.
0.75max.
1.00max.
SUS304N1
S32100
18Cr-9Ni-Nb-Low C
C
0.15max.
0.08max.
0.040.10
0.030max.
Room-temperature
tensile property
TS, min.
YS, min.
EL, min.
MPa
MPa
%
1.4311
18Cr-9Ni-Ti
347H
Free cutting steel

Basic steel grade:
General-purpose steel for numerous applications in many
fields
Chemical compositions (mass%)
1.4315
321
310MoLN
Characteristics
of an application
Example
High acid resistance:

Heat exchanger tubes for chemical plants
Heat
exchanger tube for caustic soda and hydrogen

chloride plants
Cu:0.75max.
Al:0.150.60
Ti:0.150.60
Cu:0.75max.
Al:0.150.60
Ti:0.150.60
Cu:1.002.00
Cu:0.6-1.4
Cu:0.501.00
Cu:3.004.00
Nb+Ta:8 C-1.00
Cu:1.503.00
Al:0.20max.
Ti:0.601.20
Fe:6.001.00
Cu:0.50max.
Al:1.01.7
Cu:1.0max.
Fe:5.00max.
Al:0.40max.
Ti:0.40max.
Nb+Ta:3.154.15
Fe:7.011.0
Cu:0.50max.
Fe:4.06.0
Co:2.5max.
W:2.53.5
V:0.35max.
Fe:4.07.0
Co:2.5max.
W:3.04.5
Fe:0.4max.
Cu:0.2max.
Fe:0.4max.
Cu:0.2max.
655
310
35
550
240
30
585
235
30
550
245
30
550
205
30
690
Solution
275
Solution
30
590
245
30
690
310
45
690
260
40
380
105
35
345
85
35
Product outline (applications and standards)

Developed seamless steel pipes and tubes for the chemical industry
Applicable standard
Classification
Austenitic
stainless steel
Duplex
stainless steel
Ferritic
stainless steel
Grade
Composition
ASTM/ASME
S31254
JIS
YUS 270
20Cr-18Ni-6Mo-0.7Cu0.2N-LC
ASTM A312
347AP
18Cr-10Ni-0.3Nb
ASTM A312
NSSMC
317CU
18Cr-18Ni-3.5Mo-4Cu
HRX19
22Cr-13Ni-5Mn2Mo-0.3N
ASME
TPXM-19
YUSDX1
22Cr-5Ni-3Mo-0.13CuLC
ASTM A789
DP11A
24Cr-4Ni-Mo-Cu-N
DP12
25Cr-7Ni-2.7Mo-W-N
ASTM A789
S31260
JIS G3463
SUS329J4L
DP3
DP3N
25Cr-7Ni-3.3Mo-N-W
S31260
(ASTM A789)
JIS G3463
SUS329J4L
DP3W
25Cr-7Ni-3.2Mo-2W-N
ASTM A789
DP28W
27.5Cr-7.7Ni-2.2WMo-N
ASTM A789
YUS190
19Cr-2Mo-Ti-Nb-ULCLN
S44400
ASTM A268
HK4M
25Cr-25Ni
Grade
HPM
25Cr-38Ni-Mo-Si
NSSMC
845
22.5Cr-47Ni-3Cu-6Mo3.5W
N06845
ASTM B423
NSSMC
696
30Cr-60Ni-2Cu-1.5Si
ASTM B167
JIS G3463
SUS312LTB
High corrosion resistance (pitting corrosion resistance,

seawater resistance and acid resistance):
Heat exchanger pipes and tubes for seawater desalination
plants
Seawater heat exchanger pipes and tubes for various
chemical plants
Food plant pipes handling high salinity
Polythionic acid stress corrosion crack resistance and weld
crack resistance:
Petroleum refining plant furnace tubes
ASME CC2196
Sulfuric and hydrochloric acid dew point corrosion resistance

(comparable to Ni-based alloy):
Exhaust gas pipes and heat exchanger tubes for sulfur fuel
boilers
S31803
S39274
ASME CC2427
Hydrogen embrittlement resistance, High strength

High pressure gaseous hydrogen supply tubes for
hydrogen stations
1.4462
JIS G3463
SUS329J3LTB
NORSOK
M-630/M-650
S32808
ASME CC2496
1.4521
JIS G3463
SUS444TB
High corrosion resistance (stress corrosion crack, general

corrosion and crevice corrosion resistance):
Heat exchanger pipes and tubes for various chemical
plants
N06696
ASME CC2652
Room-temperature
tensile property
Compositions (mass%)
Others
TS, min.
MPa
0.2% PS, min.

MPa
EL, min.
%
Cu:0.501.00
650
300
35
0.060.10
Nb:0.200.50
Nb 15C
515
205
35
0.045max.
Cu:3.55.0
480
175
35
1.503.00 0.250.40
Nb:0.150.30
V:0.150.30
800
430
35
Si
Mn
Ni
Cr
0.020max.
0.80max.
1.00max.
0.030max.
0.015max.
17.5019.50
19.0021.00
0.005
0.020
1.00max.
2.00max.
0.045max.
0.030max.
9.0013.00
17.0020.00
0.030max.
1.00max.
2.00max.
0.040max.
0.010max.
15.1016.50
17.0019.00
3.104.00
0.030max.
0.010max.
12.013.5
21.523.5
0.005
0.060
0.201.00 4.306.00
Mo
6.007.00 0.160.25
0.030max.
1.00max.
2.00max.
0.030max.
0.020max.
4.506.50
21.0023.00
2.503.50 0.080.20
620
450
18
0.030max.
1.5max.
2.00max.
0.040max.
0.015max.
3.05.0
22.025.0
0.150.50 0.050.25
Cu:1.02.0
600
400
25
High corrosion resistance (urea corrosion and stress

corrosion crack resistance):
Urea reactor tubes
0.030max.
1.00max.
1.50max.
0.040max.
0.030max.
5.57.5
24.0026.00
2.503.50 0.080.30
620
450
18
High corrosion resistance (pitting corrosion, seawater and

crevice corrosion resistance):
Seawater heat exchanger tubes for various chemical plants
0.030max.
1.00max.
1.50max.
0.040max.
0.030max.
5.57.5
24.0026.00
2.503.50 0.080.30
620
450
18
High corrosion resistance (pitting corrosion, seawater and

crevice corrosion resistance):
Umbilical tubes and seawater heat exchanger tubes
0.030max.
0.80max.
1.00max.
0.030max.
0.020max.
6.08.0
24.026.0
0.240.32
Cu:0.200.80
W:1.502.50
800
550
15
High corrosion resistance (urea corrosion and stress

corrosion crack resistance):
Urea reactor tubes
0.030max.
0.50max.
1.10max.
0.030max.
0.010max.
7.08.2
27.027.9
0.801.20 0.300.40
W:2.102.50
800
550
15
Stress corrosion crack resistance (general corrosion

resistance at SUS304 or higher):
Heat exchanger pipes and tubes for various chemical
plants
Small hot-water/steam boilers
0.015max.
0.50max.
0.50max.
0.040max.
0.030max.
18.0020.00
1.752.25
410
245
20
0.20.3
0.75max.
1.50max.
0.020max.
0.030max.
24.026.0
24.026.0
Ti:0.200.60
Al:0.200.60
B:0.0020.007
520
235
25
1.50max.
0.020max.
0.030max.
37.040.0
23.026.0
1.003.00
Ti:0.200.60
B:0.010max.
Zr:0.050max.
520
206
25
Oxidation resistance, carburization resistance, and hightemperature strength (700 to 1,100C)

Cracking tubes for ethylene plants
Furnace pipes for hydrogen refineries
Example of use: HK4M to 1,050C and HPM to 1,100C
Ni-based alloy
Note 1: DP28W is steel developed

jointly with Toyo Engineering
Corporation.
1.4547
S34751
High Ni alloy
10
EN, etc.
Characteristics
Example of an application
0.100.20 1.402.00
2.53.5
0.025max. Ti+Nb 16C+N
Pitting corrosion resistance and acid resistance (sulfuric acid,

hydrochloric acid, nitric acid, formic acid, etc.)
Highly corrosion-resistant pipes and heat exchanger tubes
for the chemical industry
0.05max.
0.50max.
0.5max.
0.010max.
44.055.0
20.025.0
5.07.0
Cu:2.04.0
W:2.005.00
690
276
30
Metal dusting corrosion resistance, carburization resistance,

and high-temperature strength
Heating furnace pipes for synthetic gas plants
High-temperature pipes for direct reduction iron plants
0.15max.
1.02.5
1.0max.
0.010max.
Remnant
28.032.0
1.03.0
Fe:2.06.0
Cu:1.53.0
Ti:1.0max.
586
240
30
UNS No.
11
System diagram of stainless steel and Ni-based alloy

Ni, high Ni alloy and Ni-based alloy
Austenitic stainless steel

18Cr-8Ni-S
TP303
Free-cutting
18Cr-8Ni-LC
18Cr-8Ni
TP304
18Cr-8Ni-LC-N
TP304L
Corrosion
resistance
20Cr-32Ni-Ti-Al
N08810, N08811
TP304LN
1050C
1100C
25Cr-25Ni
25Cr-38Ni-Mo-Si
HK4M
Carburization
resistance
18Cr-12Ni-2Mo-HC
TP316H
Heat resistance
N08020
Creep
strength
TP316Ti
TP316L
Intergranular
corrosion
resistance
27Cr-31Ni-3.5Mo-Cu
N08028
HRX19
Hydrogen embrittlement
resistance
18Cr-18Ni-3.5Mo-4Cu
20Cr-32Ni-Ti-Al
NSSMC317CU
TP317L
Intergranular
corrosion
resistance
22Cr-12Ni
Pitting corrosion resistance
YUS270
S31254
22Cr-42Ni-3Mo-2Cu-Ti
18Cr-9Ni-Ti-HC
TP321
Intergranular
corrosion
resistance
Heat esistance
Urea corrosion
resistance
S31050
18Cr-9Ni-Nb-HC
TP347
NW2200
Intergranular
corrosion resistance
18Cr-10Ni-0.3Nb-Extra LC
Polythionic acid
SCC resistance
25Cr-20Ni
347AP
Ni
NW2201
Pitting corrosion resistance High strength
22Cr-5Ni-3Mo-0.15N
S31803
Pitting
corrosion
resistance
Pitting corrosion
resistance
S32205
DP11A
YUSDX1
S31803
Oxidation
resistance
23Cr-60Ni-1.4Al
30Cr-60Ni-2Cu-Si
Metal dusting
resistance
NSSMC696
21Cr-62Ni-8.5Mo-3.5Nb-Ti
N06601
N10276
S31260
Pitting corrosion
resistance
25Cr-7Ni-2.7Mo-N
25Cr-7Ni-3Mo-N
DP3
DP12
Urea
corrosion
resistance
Pitting corrosion
resistance
18Cr
19Cr-2Mo-TiNb
Pitting corrosion
resistance
TP444
27.5Cr-7.7Ni-2.2W-Mo-N
Urea
corrosion
resistance
25Cr-7Ni-4Mo-0.3N
Pitting
corrosion
resistance
S32750
Ferritic stainless steel

TP430
30Cr-60Ni
N06690
N06625
HR13
15.5Cr-58Ni-16Mo-4W
25Cr-7Ni-3Mo-0.2N
Pitting
corrosion
resistance
22.5Cr-6Ni-3Mo-N
24Cr-4Ni-Mo-Cu-N
N06600
High-temperature strength
Corrosion resistance
22Cr-5Ni-3Mo
22Cr-5Ni-1.5Mo
Acid resistance
Corrosion
resistance
NSSMC845
25Cr-50Ni-6Mo-Cu-Ti
Duplex stainless steel
S31500
16Cr-75Ni
23Cr-47Ni-6Mo-3Cu
Corrosion
resistance
TP310S
Corrosion
resistance
18.5Cr-5Ni-2.7Mo
Corrosion
resistance
Ni
TP347H
Heat resistance
N08825
22Cr-22Ni-2Mo
TP321H
18Cr-9Ni-Nb
Intergranular
corrosion
resistance
Pitting corrosion
resistance
N08904
Corrosion
resistance
18Cr-9Ni-Ti
S32900
20Cr-25Ni-4.5Mo-Cu
TP309S
Corrosion
resistance
HR8
High-temperature strength
20Cr-18Ni-6Mo-0.2N
18Cr-12Ni-3Mo-LC
TP317
22Cr-26Ni-5Mo-Ti
N08800
Sulfuric acid corrosion resistance
18Cr-12Ni-3Mo
Corrosion
resistance
22Cr-13Ni-5Mn-2Mo-N,V
18Cr-12Ni-2Mo-LC
TP316
Corrosion
resistance
Grade HPM
20Cr-35Ni-2Mo-3Cu-Nb
18Cr-12Ni-Mo-Ti
18Cr-12Ni-2Mo
High strength
and carburization
resistance
21Cr-57Ni-13Mo-3W
Acid corrosion
resistance
N06022
DP28W
25Cr-7Ni-3.2Mo-2W-N
Pitting
corrosion
resistance
Weldability
DP3W
19Cr-2Mo-TiNb
Pitting corrosion
resistance
YUS190
Martensitic stainless steel

13Cr-0.2Al
13Cr
TP410
12
Weldability
TP405
13
347AP
Austenitic stainless steel pipes and tubes with seawater-resistance
20Cr-18Ni-6Mo-0.7Cu-0.2N-LCEquivalent steel gradesASTM S31254JIS G3463 SUS312LTB
18Cr-10Ni-0.3NbEquivalent steel gradesASTM S34751ASME Code Case 2196
Superior corrosion resistance against chlorides, such as seawater.
Excellent polythionic acid SCC resistance with no PWHT (post-weld heat treatment) .
Features
Favorable corrosion resistance against hydrochloric acid and organic acid.
Equivalent weldability to Type304 and superior one to Type347.
Superior stress corrosion crack resistance to Type316 and 25Cr duplex stainless steel.
Equivalent high-temperature strength to Type347.
Equivalent weldability to common austenitic stainless steel using 625 welding consumable.
Specification
Si
Mn
Ni
Cr
Mo
0.020max.
0.80max.
1.00max.
0.030max.
0.015max.
17.50
19.50
19.00
21.00
Cu
6.007.00 0.160.25 0.501.00
Quality property
property
Pitting
Tensile strength
MPa
0.2% proof
stressMPa
Elongation
%
Specification
650min.
300min.
35min.
Typical example
712
348
61
corrosion resistance
JIS G 0578: 6%FeCl3 N/20 HCl, 24h

90
Critical pitting temperature ()
Mechanical
80
pitting corrosion
70
60
S32750
20
10
317L
316L
304
0
20
25
30
35
40
45
YUS170
304
corrosion cracking resistance
17.020.0
9.013.0
0.060.10
0.200.50
15min.
Alloy 825
40
50
S31260
400
YUS270
300
70
80
0
0.1
100
(980)
50
500
400
40
30
300
0.2% proof stress
200
20
10
R.T
100
200
300
400
500
600
700
10
102
Rupture time (h)
650C
Temperature(C)
550
600
650
700
750
(49)
800
test
10
700C
103
Rupture timeh
102
Varestraint
104
105
103
test result
20
TIG (200Ax15Vx15cm/min)
Crack
Additional strain = 2%
15
10
5
0
347AP
347
321
304
316
of aging condition on the SCC resistance of a weld joint (ASTM G35, U-bent specimen, 720 hrs immersion)
750
750
700
700
650
600
550
450
1
550C
600C
10
(98)
100
Allowable stress of 347/0.9
Allowable
stress of
347/0.83
50
(490)
600
Tensile strength
500
Alloy 625
60
Creep rupture property
60
Effect
304L
100
Gl [Cr]1.42[Ni]0.19[Mo]8.47[Cu]
14
1.00max.
Corrosion resistance of a GTAW weld joint without PWHT
316L
30
0.030max.
12t x 50w x 300l mm
200
20
0.045max.
R300mm
Temperature
Stress (MPa)
Corrosion rate (mm/y)
S31260
10
2.00max.
700
50
316L
30
Nb/C
No pitting corrosion
500
20Cr-1.5Mo-Nb-Ti
-10
Nb
70
600
-20
800
Varestraint
30
304
-10
-30
Ni
Test temperature
JIS G0576 42% MgCl2, Boiling143C
50
YUS270
Cr
Weldability (Hot weld cracking)
S31803
40
Stress
10.42% HCI, ph0.61, 50C, 6h
Si
Temperature
corrosion resistance (hydrochloric acid)
20
80
PI[Cr]3.3[Mo]16[N]
40
YUS270
S31254
S31260
50
-10
15
General
Mn
Tensile property

Specification
C
0.005
0.020
2
Stress:kgf/mm
MPa
Seawater heat exchanger tubes and seawater desalination plant pipes
0.2% proof stress, Tensile strengthkgf/mm2
Application
Varestraint total crack length

in weld metalmm
Features
Austenitic stainless steel pipes and tubes against polythionic acid stress corrosion cracking resistance
MPa
YUS270
104
No SCCSCC
650
600
550
500
10
30
100
300
1000
Retention time
347AP
3000
10000
450
10
30
100
300
Retention time
1000
Type321
15
NSSMC317CU
Austenitic stainless steel pipes and tubes with sulfuric acid dew point corrosion resistance
18Cr-18Ni-3.5Mo-4CuEquivalent steel gradesASTM S31730
YUSDX1
Duplex stainless steel pipes and tubes with high strength and high corrosion resistance
22Cr-5Ni-3Mo-0.13N-LCEquivalent steel gradesASTM S31803EN 1.4462JIS G3463 SUS329J3LTB
Superior corrsion resistance in sulfuric acid and hydrochloride acid than conventional austenitic stainless steels.
Features
Equivalent localized corrosion resistance to Type316L.
Features
Superior pitting corrosion resistance and crevice corrosion resistance to Type316 and Type317.
Application
Heat exchanger tubes for various chemical plants
About twice the yield strength at room temperature as Type304 and Type316.
Equivalent weldability to Type316L using commercially available Ni-based welding consumable.

Specification
Si
Mn
Ni
Cr
Mo
Cu
0.030max.
1.00max.
2.00max.
0.040max.
0.010max.
15.10
16.50
17.00
19.00
3.104.00
0.045max.
3.55.0

Specification
Si
Mn
Ni
Cr
Mo
0.030max.
1.00max.
2.00max.
0.030max.
0.020max.
4.506.50
21.00
23.00
2.503.50
0.080.20
Quality property
MPa
0.2% proof
stressMPa
Elongation
550
480min.
175min.
35min.
Typical example
520
225
50
450
Corrosion
resistance of weld joints
2
Corrosion rateg/m
h
100
10
82 alloy consumable
625 alloy consumable
276 alloy consumable
NSSMC317CU base material
NSSMC
317CU
0.2% proof stress, Tensile strengthMPa
Specification
500
Quality property
80
Tensile strength
60
400
Elongation
350
50
300
40
250
0.2% proof stress
200
30
150
20
100
Sulfuric
50H2SO4,70
C
70H2SO4,100
C
10
50H2SO4,70
C
70H2SO4,100
C
RT
100
200
300
400
500
600
Temperature
Hydrochloric
5 HCL, 40
acid corrosion resistance (base material)
40
80H2SO4,140
C
20
10
30
31
6L
82
5
NS
317 SMC
CU
Car
bon
CR steel
IA
31
6L
82
5
NS
317 SMC
CU
Car
bon
CR steel
IA
31
6L
82
5
NS
317 SMC
CU
Car
bon
CR steel
IA
MPa
Elongation
Specification
620min.
450min.
18min.
Typical example
767
552
34
20
10
Test
temperature
C
YUSDX1
316L
316LN
317L
25.0
22.5
20.0
17.5
100
15.0
75
12.5
10.0
7.5
5.0
2.5
Effect
of solution heat treatment temperature on

mechanical properties and ferrite content
50
YUSDX1
S31260
25
No crevice corrosionCrevice corrosion occurred
800
Tensile strength
700
Effect
0.2% proof stress
500
NSSMC
317CU
Carbon
steel
CRIA
316L
825
Brittle zone during

isothermal heating
vE23<50 J /cm2
1000
400
900
40
800
Cooling
rate
C /min100
700
600
20
0
950
of cooling rate after solution heat treatment on toughness
Heating1250 30sec
600
60
16
Tensile strength
Elongation%
2
Corrosion rateg/m
h
2
Corrosion rateg/m
h
1000
100
corrosion resistanceASTM G48 Method B

Test conditionTest solution100g FeCI36H 2O 900mlH 2O6%FeCl3
Test period72h
Crevice
0.2% proof
stressMPa
80H2SO4,140
C
acid corrosion resistance (base material)
property
70
50
0.1
Mechanical
TemperatureC
Tensile strength
tensile property
Ferrite content%
High-temperature
Tensile strength and 0.2% proof stress

at room temperatureMPa
property
Elongation%
Mechanical
E23J /cm2
170
50
177
1050
1100
1150
1200
Solution heat treatment temperatureC
1250
10
153
0.5
73
500
1000
20
45
1
10
Timemin
10
8
103
17
DP3W
DP28W
Super duplex stainless steel pipes and tubes
25Cr-7Ni-3.2Mo-2W-NEquivalent steel gradesASTM S39274ASME Code Case 2427NORSOK M-630/M-650
Duplex stainless steel pipes and tubes for urea plants
27.5Cr-7.7Ni-2.2W-Mo-NEquivalent steel gradesASTM S32808ASME Code Case 2496
Excellent resistance to localized corrosion.
Features
Excellent corrosion resistance in urea- carbamate
Features
High resistance to general corrosion (especially in a sour environment).
Microstructure
solution.
High resistance to SCC.
Excellent mechanical properties.
Very high mechanical strength.
Good weldability.
Ferrite
Good weldability.
Low sensitivity to sigma phase precipitation.
Austenite
Good formability.
25m

C
Si
Mn
0.030max.
0.80max.
1.00max.
0.030max. 0.020max.
Ni
Cr
Mo
6.08.0
24.026.0
2.53.5
Cu
0.240.32 0.200.80 1.502.50
Pitting corrosion resistance

between the PREW value and pitting
potential in various stainless steel types
Pitting potential [volts vs SCE]
Corrosion rate [g/m2/hr]
Relationship
6%FeCl3x24hrs
DP3W
S31260
0.5
0.4
0.3
0.2
0.1
0.0
50
60
70
80
90
1.2
0.8
Austenite
Duplex
0.6
0.4
0.2
0.0
100
Synthetic seawater
[ASTM D1141]
80C, 20mV/min
1.0
Temperature
304
10
316
20
Phase stability
Crevice
Hardness
corrosion potential for DP3W in synthetic

seawater
DP3W
[S39274]
N08925
N06625
N06975
S31254
S31260
N08028
N08904
N08320
N08825
S31803
N08020
S31500
30
40
80
0.8
0.2
0
DP3W
50
40
Corrosion potential
with rust
20
40
50
60
Ni
Cr
Mo
0.030max.
0.50max.
1.10max.
0.030max.
0.010max.
7.08.2
27.027.9
0.801.20
0.300.40
2.102.50
70
80
of a corrosion test in boiling 65% nitric acid
Result of a corrosion test in a synthetic urea-carbamate solution
Over three times higher than DP12
0.12
1.50
Base material
Weld joint*
0.08
0.04
DP28W
Sample1
DP28W
Sample2
DP12
Weld Base
metal material
(*)Welding conditions Non-filler
welding
Current: 70 A, voltage: 1012 V
Welding speed: 11 cm/min
1.00
0.50
0.00
DP28W
DP12
316L-UG
60
increase due to sigma phase precipitation
90
100
DP3W
25%Cr-4%Mo
25%Cr-3%Mo
27%Cr-3%Mo
Grade
Tensile strength (MPa)
0.2% proof stress (MPa)
Elongation (%)
Hardness (Hv)
DP28W
934
647
42
281
DP12
822
610
42
251
25-22-2(S31050)
676
352
50
173
316L
518
234
52
144
Weldability
Appearance
60
S31260
Temperature
18
Hv
[V vs SCE]
Crevice corrosion potential
Synthetic seawater [ASTM D1141]
0.6
Result
Hv = Hv after aging Hv as solution heat treated
0.4
Mn
Mechanical property (example)
Crevice corrosion resistance
Si
Equivalent corrosion rate
corrosion rate in an ASTM G48 solution

(6% FeCl3)
0.6
Pitting
0.7
Specification
Corrosion speedg/m2/h
Specification
Formability
of weld overlay by for ESW
Appearance
of U-bent tube
Matching filler metals

for GTAW and ESW
have been developed.
850
900
Aging temperature10min.
19
YUS190
Ferritic stainless steel pipes and tubes with high corrosion resistance
Austenitic stainless (high Ni) alloy pipes and tubes for ethylene plants
19Cr-2Mo-Ti-Nb-ULC-LNEquivalent steel gradesASTM TP444JIS G3463 SUS444TB
25Cr-38Ni-Mo-Si
Features
Features
This is a ferrite stainless steel pipe and tube that delivers superior performance regarding stress corrosion cracking,
which is the disadvantage of austenite stainless steel, and also has intergranular corrosion resistance, pitting
corrosion resistance, and crevice corrosion resistance that have been significantly enhanced.
Long unit length more than 13m with small
diameter.
Internal finned tubes are available.
Superior stress corrosion crack resistance and intergranular corrosion resistance.
Excellent elevated temperature strength and
Even or better pitting corrosion resistance and crevice corrosion resistance than TP304.
carburization resistance.
Good formability and weldability.
Excellent ductility.
Easy repair of welds.
Water heater steel pipes and seawater heater exchanger steel tubes

C
Si
Mn
Cr
Mo
Ti + Nb
Grade
Basic composition
Oxidation
Carburization
Creep strength
0.015max.
0.50max.
0.50max.
0.040max.
0.030max.
18.00
20.00
1.752.25
0.025max.
16C+N
min.
800H
0.08C-20Cr-30Ni
HK4M
0.2C-25Cr-25Ni-Ti, B
HPM
0.14C-25Cr-38Ni-Mo, Si
Quality property
property
Pitting
Tensile strength
MPa
0.2% proof
stressMPa
Elongation
Specification
410min.
245min.
20min.
Typical example
531
357
42
corrosion resistance5% FeCl3 + N/20 HCl test (48 h)
50.0
Corrosion rateg/m2/h
Mechanical
10.0
Specification
42%MgCl 2
Load stress
(MPa)
265
Anneal
YUS190
Sens
304
316
Anneal
Anneal
Mn
Ni
Cr
Mo
Ti
Zr
0.100.20
1.42.0
1.5max.
0.02max.
0.03max.
3740
2326
1.03.0
0.20.6
0.01max.
0.05max.
Steel grade
As Solution
TIG weld joint
Development philosophy of
Grade HPM
YUS190
1.0
430
0.5
316
304
30
40
TemperatureC
50
Eutectic carbide
(high C)
Coarse grain
Centrifugal
cast tube
High temperature chloride
Heat treatment conditionYUS190 1200C 5min AC

Type304 650C 2h AC
Type316 650C 2h AC
Heat treatment
Si
Pack
Rupture time
Not ruptured after
1,000 hrs
294
314
265
314
147
Ruptured in 3 hrs
196
Ruptured in 1 hr
147
Ruptured in 7 hrs
196
Ruptured in 4 hrs
Eutectic carbide
Break down
Undissolved carbide
remains in large amounts
Fine grain
High-temperature
strength drops.
Test condition: Pure water + NaClCl -: 30 to 600 ppmis used for

adjustment.
300C, 9.5MPa,300h
Test specimen: 1 mmt 15 mmw 100 mmL10R U-bent specimen
Grade
ClHeat
treatment concentration
Anneal
YUS190
Sens
Anneal
304
Sens
Anneal
316
Sens
Occurrence of crack
100h
200h
Decrease of C amount
(solubility limit for S.T.)
300h
30
600
Coarse grain
Wrought
tube
Undissolved carbides
carburization test
1100 192
Gas
Steel
Grade HPM
HK4M
HK40
HP
Low C-HP-Mo, W, Nb
HP-Mo, W, Nb
High Sj HP
3.5
Forging extrusion
solution treatment
corrosion crack resistance
Grade
5.0
20
Stress
Reference level Superior
3.0
2.5
2.0
1.5
1.0
Average increase of C contentmass%
Specification
Characteristics
Increase of C content%
Application
Grade HPM
carburization test
Alloy A ; 25Cr-35Ni-0.54Si Wrought
Alloy B ; 32Cr-43Ni-1.7Si Cast
Carburization in 15%CH4-3%CO2-82%H2
3
Alloy 800H
Alloy A
1
0
Grade HPM
Alloy B
1000Cx96h
1100Cx96h
1150Cx48h
are small in amount.
30
600
30
600
30
600
HK4M
Grade HPM
30
Good strength
Exellent strength
600
30
600
Addition of
strengthening elements
Ti, B
Ti, Mo, B, Zr
Si
Addition of
carburization
resistant
elements
0.5
0
0
1.0
1.5
2.0
2.5
3.0
Distance from surfacemm
0.5
No crack, Crack, Not tested
20
21
NSSMC696
Ni-based alloy pipes and tubes with excellent metal dusting resistance
30Cr-60Ni-2Cu-1.5SiEquivalent alloy gradesASTM B163 N06696ASME Code Case 2652
NSSMC 845
New Ni-based alloy with best-balanced performances
23Cr-47Ni-6Mo-3CuEquivalent alloy gradesASTM N06845ASME Code Case 2794
Excellent high-temperature corrosion resistance especially carburization and metal dusting.
Features
Features Excellent corrosion resistance for both oxidizing and reducing environment.
High strength at elevated temprature.
More cost-effective than conventional alloys.
Excellent thermal stability.
Good formability and weldability.
Good weldability.

Si
Mn
Cu
Ni
Cr
Mo
Ti
Fe
0.15max.
1.02.5
1.0max.
0.010max.
1.53.0
Remainder
28.032.0
1.03.0
1.0max.
2.06.0
Si
Mn
Cu
Ni
Cr
Mo
Ti
Fe
max.0.05
max.0.5
max.0.5
max.0.010
2.04.0
44.050.0
20.025.0
5.07.0
2.05.0
Remainder
Mechanism
Concept
Resistance
of new metal dusting prevention technology
Protective oxide scale
Cu
Cu
Cr, Si
Metal
5000
10000
15000
20000
25000
0.01
for 1000h
150
for 10000h
for 3000h
100
50
0
Before aging
500
650
800
Charpy impact valueJ/cm2
Charpy impact valueJ/cm2
Thermal stability
200
for 1000h
200
for 3000h
150
Field evaluation
Economy
Microstructure
Economic
of weldment after 1year immersion in

salfuric acid tank
EnvironmentH2SO4+NH42SO4, 110 deg.C
100
(Effect of phase precipitation)
50
0
Before aging
500
650
800
Aging temperaturedeg.C
Aging temperaturedeg.C
Charpy impact value of NSSMC696

after aging at 500, 650, and 800
Charpy impact value of Al-bearing Ni-based alloy

after aging at 500, 650, and 800
N10276
N06625
0.1
30000
Exposure timet/h
Exposure timet/h
NSSMC 845
A696 has no pits
evaluation 1/corrosion rate/unit price
80
60
40
20
Good economy
30000
A693
N08825
A602
200
S31254
25000
(a) Ground surface and

(b) electrolytic-polished surface
S31603
20000
01
A6
400
S31603
600
10
R50400Ti-Gr.2
800
N06022
15000
650 cyclic heating

Gas composition
60vol.CO-26H2
-11.5CO2-2.5H2O
N10276
10000
resistance to 40% NH4cl solution at 200
100
1000
0.1% HCl+ 5% H2SO4 2% HCl+ 10% H2SO4 2% HCl+ 10% HNO3

boil
boil
80 deg.C
Corrosion
(b)
1200
A696 has no pits

5000
to local corrosion
80% CH3COOH
boil
S40500
A690
40% HNO3
boil
N08825
60
A1
200
0
20% H2SO4
80 deg.C
K02702C-Steel
Maximum pit depthd/m
A696
800
400
3% HCl
60 deg.C
ASTM G48 Method A, 6% FeCl3 at 85 deg.C
1000
600
0.01
Resistance
A690
A80
Maximum pit depthd/m
(a)
1200
N08825
0.1
0.001
Metal dusting resistance
N06022
NSSMC 845
Metal
N10276
(c) Repair of protective oxide

scale at the defect sites
NSSMC 845
Corrosion rate (mm/year)
Barrier to reaction
between CO and metal
(b) Suppression of the

dissociation
by a solid-solution
Cu at defect sites
of the oxide scale
Corrosion rate (mm/year)
(a) Oxide scale

formation
to acid corrosion
10
CO molecule
22
Specification
Index of economic evaluation
Specification
3% HCl at 60 deg.C
20% H2SO4 at 80 deg. C
23
HRX19
Examples of Application
New stainless steel for high pressure gaseous Hydrogen environments
22Cr-13Ni-5Mn-2Mo-0.3NNippon Steel & Sumitomo Metal StandardAccording to ASME SA-312 TPXM-19
Features Highest level of resistance to hydrogen embrittlement in the world under high pressure gaseous hydrogen environment.
High strength over wide temperature range from room temperature to high temperature.
Good weldability with high strength and resistance to hydrogen embrittlement equal to base metal.

Specification
Si
Mn
Ni
Cr
Mo
Nb
0.0050.06
0.21.0
4.36.0
12.013.5
21.523.5
1.53.0
0.150.30
0.150.30
0.250.4
Mechanical property
SSRT
Slow
Mechanical
Strain Rate Test
property
1000
100
85MPa
85MPa
100MPa
Tensile strengthMPa
Relative elongation, reduction of area/

Elongation, reduction of area in H2/
elongation, reduction of area in air
Hydrogen embrittlement
80
Excellent hydrogen brittlement in

severe high pressure gasous hydrogen environment at -50, 100 MPa
60
80
40
40
80
Temperature/
120
900
800
700
SUS316L-Cold hardening
about 1.5 times of

strength of SUS316L
600
500
400
500
160
HRX19
SUS316L
0
50
100
150
200
Petroleum and chemical plant pipes
Seawater desalination plant pipes
250
Temperature/
Weldability
Appearance
of welded joint
Mechanical
property of welded joints
Tensile strengthMPa
900
800
Steel pipes and tubes for heating furnaces

(steel pipes and tubes for power generation boilers)
LNG ships and LNG unloading facility pipes
700
600
Manual GTAW
Automatic GTAW
5G position without filler 1G position with 309Mo filler
Heat exchanger tubes
24
25
Example of Packing
Example of Indications
ASTM
Bare packing
Resin-coated steel wire or PP rope
This is an example. Indication is based on cargo mark reports, in principle.
NSSMC ASTM A312-12A GR.TP316L COLD FIN N4S10S6000 36NLT12 E23456 MADE IN JAPAN
Manufacturer's band or
name
Standard abbreviation
Manufacturing method
JIS

Polyethylene sheet packing
NSSMC
JICQA SUS304TP SH 114.33.06000 SL 0613 36NDT12 E12345
(outside diameter
thickness length)
Inspection number
Heat number
Country of origin
JIS mark
Certification body code
Type code
Works abbreviation
Polyethylene sheet
Dimensions
(serial number)
(molten steel number)
Date of manufacture
(month/two low-order
digits for year)

Hollow plastic board packing
Requests during orders

When ordering or inquiring about our stainless steel pipes and tubes, you are requested to inform us about the following items.
Hollow plastic board
1. Steel pipe standard and type
6. Packing type
2. Dimensions (outside diameter, thickness, and length)
7. Number of copies of the inspection certificate
3. Quantity
8. With or without a witnessed inspection
4. Delivery date and destination
9. Other and specially requested items
5. Applications and usage condition

Open wood box packing
Resin-coated steel wire
or PP rope
Board
Polyethylene sheet
Closed wood box packing
Resin-coated steel wire

or PP rope
Board
Polyethylene sheet
26
27
memo
28

Seamless Pipes and Tubes For The Chemical Industry: (Stainless Steel and Ni-Based Alloys)

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Seamless Pipes and Tubes For The Chemical Industry: (Stainless Steel and Ni-Based Alloys)

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Pipe Products

NIPPON STEEL & SUMITOMO METAL

Seamless Pipes and Tubes

2-6-1 Marunouchi, Chiyoda-ku,Tokyo 100-8071 Japan

Seamless Pipes and Tubes for the Chemical Industry

Seamless Pipes and Tubes for

Stainless steel and Ni-based alloy pipes and tubes

Our stainless steel and Ni-based alloy pipes and

Consistent quality control

Abundant steel grades

Numerous acquired certifications

Substantial process control and service organization

Main production specifications

Seamless Ferritic Alloy-Steel Pipe for High-Temperature Service

Seamless Austenitic Steel Pipe for High-Temperature Central-Station Service

Wrought Austenitic Stainless Steel Piping Fittings

Seamless and Welded Ferritic/Austenitic Stainless Steel Pipes

Nickel Seamless Pipes and Tubes

Nicke-Chromium-Iron Alloys and Nickel-Chromium-Cobalt-Molybdenum Alloy Seamless Pipes and

Stainless steel pipes for machine and structural purposes

Stainless steel pipes

Stainless steel boiler and heat exchanger tubes

Steel tubes for fired heater

Seamless nickel-chromium-iron alloy heat exchanger tubes

Nickel and nickel alloy seamless pipes and tubes

Seamless steel pipes (Mannesmann process)

Seamless steel pipes (Mannesmann process)

Osaka Steel Works

Spiral steel pipes

Electric resistance-welded steel pipes

Electric arc furnace

Manufacturable size range

Super forging press

Vertical piercing press

Extrusion process (Ugine-Sejournet process)

Vertical expanding press

Horizontal extrusion press

(Mannessman and Mandrel mill processes)

Vacuum Arc Remelting (VAR)

Cold pilger mill

3-roller stretch reducer

Cold finished seamless

3-roller extracting sizer

Steel Making Facilities

Electric arc furnace, AOD (Argon Oxygen Decarburizing) equipment

Super forging press, Blooming mill

Hot Finished Pipe and Tube-Making Facilities

(Toe-angle piercing type tube making mill)

Cold Finished Pipe and Tube-Making Facilities

Hydraulic cold drawing bench, Oil hydraulic drawing bench

Heat Treatment Furnaces

Continuous type/Batch type/Barrel type, Atomsphere controlled type/Vacuum annealing type

Electric arc farnace

Horizontal push bench

Horizontal extrusion press

Cold pilger mill

Cold drawing bench

Heat treatment furnace

Available Size Range (typical examples)

Cold-finished seamless pipes and tubes

Wall Thickness (mm)

Wall Thickness (mm)

Wall Thickness (mm)