Perhitungan Ca Model dan Ca Percobaan pada Proses Kontinu

a Variabel 0,15N Etil Asetat Ca=Cb

-Neraca massa total

input output = akumulasi
dV
Fo - 0
= dt
dV = Fo.dt
V = Fo.t ............(1)
-Neraca massa komponen
akumulasi = input output laju konsumsi konversi
dVCa
= Fo.Cao 0 V.k.Ca2
dt
Ca. Fo+
Ca+

dCa
2
Fo. t =Fo .CaoFo. t . k . Ca
dt

dCa
2
.t=Caot . k .Ca .........(2)
dt

Persamaan (1) dan (2) diselesaikan dengan orde 4

( CaoCa )
k Ca2 t
k1 =
t

k2 =

k3 =

k4 =
Ca =

[
[
[

Cao(Ca+

k1
)
2

t +h/2
Cao(Ca+
t +h /2

k2
)
2

]
]

k (Ca+

k1 2
) t
2

k (Ca+

k2 2
) t
2

Cao(Ca+ k 3)
k (Ca+k 3)2 t
t +h
1
( k 1+2 k 2+2 k 3+ k 4 )
6

Ca model = Ca + Ca model sebelumnya

k= 0,1868 , Cao= 0,1

Ca

K1

K2

K3

K4

Ca

Ca model

VHC
l
6

0.12

0.12

0.003534

0.12

0.003784

4.5

6.1

0.12
2

0.004014

0
0.001411
5
0.002360
1
0.002976
1

0.15

0
0.003647
79
0.003757
75
0.003937
19

1.5

0
0.003652
17
0.003756
7
0.003934
35

b Variabel 0,2N Etil Asetat CaCb

-Neraca massa total

input output = akumulasi
dV
Fo - 0
= dt
dV = Fo.dt
V = Fo.t ............(1)
-Neraca massa komponen
akumulasi = input output laju konsumsi konversi
dVCa
= Fo.Cao 0 V.k.CaCb
dt
Ca. Fo+
Ca+

dCa
Fo. t=Fo .CaoFo. t . k . CaCb
dt

dCa
.t=Caot . k .CaCb .........(2)
dt

-Persamaan (1) dan (2) diselesaikan dengan orde 4

( CaoCa )
k CaCb t
k1 =
t

k2 =

k3 =

k4 =

[
[
[

Cao(Ca+

k1
)
2

t +h/2
Cao(Ca+
t +h /2

k2
)
2

]
]

k (CaCb+

k1
) t
2

k (CaCb+

k2
) t
2

Cao(Ca+ k 3)
k (CaCb+ k 3)2 t
t +h

0.009665
817
0.004653
302
0.001901
104

0.148588
5
0.146228
4
0.143252
25

1
( k 1+ 2k 2+2 k 3+ k 4)
6

Ca =

Ca model = Ca + Ca model sebelumnya

k = 0.228, Cao= 0,2
t

VHCl
0

Ca

7.5

1.
5

0.15

7.3 0.146

Cb

K1

0.3

0
0.00329
0
0.00170
3
0.00336
9

0.29
4

0.14

0.29

4.
5

0.14

0.29

0.138

0.29

6.9

K2

0.00351

K3

0
0.00430
42
0.00352
14
0.00420
58
0.00423
19

K4

Ca

0
0.004779
47
0.003204
26
0.004184
74
0.004666
89

0
0.004009
4
0.002992
7
0.004885
0
0.004798
7

K3

K4

Ca model
0
0.2
0.1957555
0.00424
2
4
0.1927309
0.00302
5
4
0.1885582
0.00417
8
2
0.1842067
0.00435
1
1

c. Variabel 0,25N Etil Asetat CaCb

k= 0.086, Cao=0,25
t

VHCl

Ca

Cb

K1

K2

8.5

0.17

0.25

1.5

8.2

0.16
4

0.24

0.01746

7.9

0.15
8

0.23

4.5

7.6

0.15
2

0.22

7.5

0.15

0.22

0.00290

7.5

7.5

0.15

0.22

0.00290
2

0.00722
0
0.00364
0

0
0.00574
2
0.00432
9
0.00294
4
0.00262
3
0.00266
5

0
0.00851
3
0.00491
1
0.00303
3
0.00262
3
-0.00290

Ca

Ca
model
0
0.25

0
0.007458
0.00890
1

0.24109
3

0.004377 0.00501

0.23608
0

0.002703
0.00305
5

0.23302
9

0.002902 0.00271

0.23031
2

0.002902

0.22748

-0.0022