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GCI/V/Privi-II/EIA/2013-2014/Nov/R02
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ALSO AT
BENGALURU
RUDRAPUR
NEW DELHI
HYDERABAD
PUNE
RAIPUR
OVERSEAS
AUSTRALIA
OMAN
KUWAIT
AFRICA
VIETNAM
KOLKATA
GOA
C/SCA/10311/2012
ORDER
Appearance:
DELETED for the Petitioner(s) No. 6
MR NILESH P SHAH, ADVOCATE for the Petitioner(s) No. 1 - 8
MS DHARA H ASLOT, ADVOCATE for the Petitioner(s) No. 1 - 8
MR ANSHIN H DESAI, ADVOCATE for the Respondent(s) No. 1
MR IH SYED, ADVOCATE for the Respondent(s) No. 1 - 2
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C/SCA/10311/2012
ORDER
(J.B.PARDIWALA, J.)
zgs
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10/16/2014
Case Detail
CCIN No : 001021201210311
Not Before
:
S.NO.
1
2
3
4
5
6
7
8
Advocate On Record
MR NILESH P SHAH for: Petitioner(s)
MS DHARA H ASLOT for: Petitioner(s)
DELETED for: Petitioner(s)
6
S.NO.
1
2
Advocate On Record
MR ANSHIN H DESAI for :Respondent(s)
1
1-2
MR IH SYED for :Respondent(s)
MR DEVANG VYAS for :Respondent(s)
1-2
2
MR MK VAKHARIA for :Respondent(s)
1-8
1-8
Presented On
: 19/07/2012
Registered On
: 26/07/2012
Bench Category
: DIVISION BENCH
District
: VADODARA
Case Originated From
: THROUGH ADVOCATE
Listed
: 67 times
StageName
: NOTICE & ADJOURNED MATTERS
DB - GREEN BENCH / POLUTION / ENVIRONMENT - POLLUTION - AIR (PREVENTION AND CONTROL OF
Classification
POLLUTION) ACT, 1981
Act
CONSTITUTION OF INDIA
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for PETITIONER(s)
1
MR PS CHAMPANERI ADVOCATE
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for RESPONDENT(s)
MR NILESH P SHAH ADVOCATE
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NOTICE SERVED BY DS
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Coram
2/13
ted EIA
-ucturin
d-402309
com
Rev.
No.
Reoson History
Dote
Prepored
&
Reviewed
compiled
By
Approved Volidoted
by
by
By
VB, NT,
02
17
/11
1201
PJ
Prodeep Joshi
RK
Ronjit Kolito
Vikosh Bhogot
Nidhi Trivedi
Poojo Vishnoi
VB
NT
PV
Gompiled &
Prepored by
Vikosh Bhogot
PJ
RK
PV
Nidhi Trivedi
Poojo Vishnoi
Signoture
Ronjit Kolito, Sr. Executive EIA &
EE
S. No.
I
2
3
4
sotvovqn
PJ
ACKNOWLEDGEMENT
DISCLAIMER
The consulting services conducted by Green Circle, Inc.(the Company) were performed
using generally accepted guidelines, standards, and/or practices, which the Company
considers reliable. Although the Company performed its consulting services pursuant to
reliable and generally accepted practices in the industry, the Company does not guarantee
or provide any representations or warranties with respect to Clients use, interpretation or
application of the findings, conclusions, and/or suggestions of the consulting services
provided by the Company. Moreover, the findings, conclusions, and the suggestions
resulting from the consulting service are based upon certain assumptions, information,
documents, and procedures provided by the Customer. AS SUCH, IN NO EVENT AND UNDER
NO CIRCUMSTANCE SHALL THE COMPANY BE LIABLE FOR SPECIAL, INDIRECT, PUNITIVE OR
CONSEQUENTIAL DAMAGES OF ANY NATURE WHATSOEVER, INCLUDING WITHOUT LIMITATION,
ANY LOST REVENUE OR PROFITS OF THE CUSTOMER OR ITS CUSTOMERS, AGENTS AND
DISTRIBUTORS, RESULTING FROM, ARISING OUT OF OR IN CONNECTION WITH, THE SERVICES
PROVIDED BY THE COMPANY. The Customer agrees that the Company shall have no liability
for damages, which may result from Clients use, interpretation or application of the
consulting services provided by the Company. Clients logo has been used for report
purpose only.
ABBREVIATIONS
AAQM : Ambient Air Quality Monitoring
BOD : Biochemical Oxygen Demand
COD : Chemical Oxygen Demand
CPCB : Central Pollution Control Board
DMP : Disaster Management Plan
EIA : Environmental Impact Assessment
EMP : Environmental Management Plan
ETP : Effluent Treatment Plan
IMD : Indian Meteorological Department
KVA : Kilo Volt Ampere
KLD : Kilo Litre per day
MoEF : Ministry of Environment & Forest
PM : Particulate Matter
PPE : Personal Protective Equipment
STP : Sewage Treatment Plant
TDS : Total Dissolved Solids
TABLE OF CONTENTS
CHAPTER
TITLE
PAGE NO.
NO.
Table of Contents
Abbreviations
Executive Summary
CHAPTER 1: INTRODUCTION
1.0
1.1
1.1
1.1
1.2
1.2
1.3
1.2
1.4
1.3
1.4.1
Plant Location
1.3
1.4.2
1.3
1.4.3
1.4
1.5
STATEMENT OF PRINCIPLES
1.4
1.6
FRAMEWORK OF ASSESSMENT
1.4
1.7
1.5
1.8
1.5
1.9
1.5
1.10
1.7
1.11
1.7
INTRODUCTION
2.1
2.1
TYPE OF PROJECT
2.1
2.2
CAPITAL INVESTMENT
2.1
2.3
2.1
2.4
PROJECT JUSTIFICATION
2.2
2.5
2.2
2.6
2.6
2.7
2.10
2.8
PRODUCT DETAILS
2.21
2.9
2.31
2.10
MANUFACTURING PROCESS
2.39
2.11
2.99
2.12
2.100
2.103
2.14
2.108
2.111
2.16
2.113
INTRODUCTION
3.1
3.1
3.3
3.2
3.5
3.2.1
3.5
Methodology
3.3
3.7
3.4
3.7
3.4.1
Regional Meteorology
3.7
3.4.1.1
3.8
3.5
3.8
3.6
AIR ENVIRONMENT
3.10
3.6.1
Reconnaissance
3.10
3.6.2
3.10
3.6.3
3.10
3.7
3.8
NOISE ENVIRONMENT
3.19
3.7.1
Reconnaissance
3.19
3.7.2
3.19
3.7.3
3.19
3.7.4
3.22
WATER ENVIRONMENT
3.23
3.8.1
Reconnaissance Survey
3.23
3.8.2
3.23
3.8.3
Sampling locations
3.24
ii
3.9
3.10
3.11
3.12
3.13
LAND ENVIRONMENT
3.29
3.9.1
3.30
3.9.2
Soil Characteristics
3.30
3.9.3
Sampling Locations
3.30
3.9.4
3.33
3.9.5
Seismicity
3.33
BIOLOGICAL ENVIRONMENT
3.33
3.10.1
Floral compositions
3.33
3.10.2
Fauna composition
3.35
3.41
3.11.1
Reconnaissance
3.41
3.11.2
Methodology
3.41
3.11.3
Socioeconomic assessment
3.41
3.11.4
Demography
3.43
3.11.5
Sex ratio
3.44
3.11.6
Social Structure
3.45
3.11.7
Literacy
3.46
3.11.8
Occupational Pattern
3.47
3.11.9
Infrastructure Availability
3.52
3.11.10
Economic Profile
3.52
TRAFFIC SURVEY
3.52
3.12.1
Reconnaissance
3.52
3.12.2
3.52
3.12.3
3.54
3.12.4
3.55
3.56
INTRODUCTION
4.1
4.2
4.1
4.2.1
4.1
4.2.2
4.2
4.2.3
4.2
4.2.4
Impact on drainage
4.3
iii
4.3
4.4
4.5
4.2.5
4.3
4.2.6
4.4
4.2.7
4.4
4.2.8
4.5
4.2.8.1
Traffic Volume
4.5
4.2.9
4.5
4.2.9.1
Hazardous waste
4.6
4.6
4.3.1
4.6
4.3.2
4.6
4.3.2.1
Air modeling
4.6
4.3.3
4.11
4.3.4
4.11
4.3.5
4.12
4.3.5.1
Terrestrial ecology
4.12
4.3.5.2
Aquatic ecology
4.12
4.3.6
4.12
4.3.7
Solid Waste
4.13
4.3.7.1
4.13
IMPACT ON CLIMATE
4.14
4.3.1
Construction phase
4.14
4.3.2
Operation Phase
4.14
4.15
INTRODUCTION
5.1
5.1
5.1
5.2
5.2
5.2.1
5.2
5.2.2
5.3
5.3
5.5
5.4
5.6
5.5
CARBON FOOTPRINT
5.6
5.6
5.6
6.1
iv
6.2
6.1
6.3
6.2
6.4
METEOROLOGICAL CONDITIONS
6.3
6.4.1
Atmospheric parameters
6.4
6.4.2
Weather category
6.4
6.5
6.5
6.5.1
6.5
6.5.1.1
Pool fire
6.5
6.5.1.2
Flash fire
6.6
6.5.1.3
Jet fire
6.6
6.5.1.4
6.6
6.5.2
6.6
6.5.3
6.7
6.6
CONSEQUENCE ANALYSIS
6.8
6.7
6.42
6.7
REFERENCES
6.46
OBJECTIVE
7.1
7.1
7.2
7.2
METHODOLOGY
7.2
7.3
INTRODUCTION
7.3
7.4
7.4
7.5
7.4
7.6
EMERGENCY ORGANIZATION
7.5
7.7
7.12
7.8
MEDICAL ARRANGEMENTS
7.13
7.9
7.14
7.10
7.14
DISASTER
7.11
OUTSIDE HELP
7.12
INFORMATION
7.14
ON
RISK
EVALUATION
PRELIMINARY
HAZARD
7.15
ANALYSIS
7.13
HAZARDS/FORESEEABLE SCENARIOS
7.15
7.14
7.18
7.15
7.18
7.16
7.19
7.17
7.22
7.18
7.23
7.19
7.25
7.20
7.25
7.21
7.26
7.22
7.27
7.23
7.27
7.24
HOSPITALS
7.28
7.25
FIRE
7.30
7.26
7.32
7.27
7.32
7.28
PUBLIC RELATIONS
7.33
7.29
7.33
7.30
7.33
7.31
7.33
7.32
7.34
7.33
EVACUATION PLAN
7.34
7.34
TRAFFIC CONTROL
7.34
7.35
OTHER ARRANGEMENTS
7.35
7.36
7.35
7.37
7.37
LIST OF ANNEXURE
7.40
INTRODUCTION
8.1
8.1
8.1
8.1.1
CSR activities
8.1
8.1.2
Budgetary cost
8.2
8.2
ECONOMIC DEVELOPMENT
8.2
8.3
EMPLOYMENT POTENTIAL
8.2
vi
9.0
INTRODUCTION
9.1
9.1
9.1
9.2
9.1
9.3
ENVIRONMENTAL OBJECTIVES
9.2
9.4
9.3
9.5
9.4
9.5.1
9.5
9.5.2
9.5
9.5.3
9.6
9.5.4
9.6
9.5.5
9.7
9.5.6
9.8
9.6
9.8
9.7
9.8
9.7.1
9.9
9.7.2
9.11
9.7.3
9.12
9.7.4
9.13
9.7.5
9.16
9.7.6
9.16
9.7.7
9.16
9.7.8
Management of Traffic
9.17
9.8
9.17
9.8.1
Water Conservation
9.17
9.8.2
Energy Conservation
9.18
9.8.3
9.19
9.8.4
9.19
9.8.5
9.19
9.8.6
9.22
9.8.7
9.23
Hazards
9.8.8
9.9
9.23
9.24
vii
9.10
9.28
9.10
FINDINGS
9.28
9.11
CONCLUSIONS
9.29
10.1
GENERAL INFORMATION
11.1
11.1
VISION
11.1
11.2
MISSION
11.1
11.3
11.1
11.4
ACTIVITIES
11.2
11.5
EIA TEAM
11.3
viii
LIST OF TABLES
TABLE
TITLE
NO.
PAGE
NO.
2.1
2.2
2.2
Area Details
2.6
2.3
2.10
2.4
Summary of products
2.21
2.5
2.23
2.6
2.29
2.7
2.31
2.8
2.101
2.9
2.101
2.10
Water Consumption and Waste water generation details for Dry Season
2.103
2.11
2.104
2.12
2.106
2.13
2.111
2.14
2.111
2.15
Details of Stack
2.112
2.16
2.113
2.17
Employment Details
2.113
2.18
2.114
2.19
Annual Runoff
2.116
3.1
3.3
3.2
3.5
3.3
Climatology of Alibag
3.7
3.4
3.8
3.5
3.11
ix
3.6
3.12
3.7
3.13
3.8
3.14
3.9
3.15
3.10
3.11
3.12
3.16
3.17
3.18
3.13
3.18
3.14
3.20
3.15
3.21
3.16
3.21
3.17
3.23
3.18
3.26
3.19
3.27
3.20
3.30
3.21
3.30
3.22
3.32
3.23
3.34
3.24
3.35
3.25
3.36
3.26
3.37
3.27
3.40
3.28
3.42
3.29
Demographic details
3.43
3.30
Social Structure
3.45
3.31
Literacy Rate
3.46
3.32
3.48
3.33
3.53
3.34
Level of Service
3.54
3.35
3.54
4.1
sources of noise
4.11
4.2
4.13
4.3
4.17
5.1
5.2
5.2
5.3
5.3
5.5
6.1
6.2
6.2
6.2
6.3
6.8
6.4
6.8
6.5
6.9
6.6
6.18
6.7
6.18
6.8
6.26
6.9
6.26
6.10
6.34
6.11
6.34
9.1
9.9
9.2
9.10
9.3
9.13
9.4
9.15
9.5
9.15
9.6
9.21
9.7
9.24
11.1
11.3
xi
LIST OF FIGURES
TABLE NO.
TITLE
PAGE
NO.
1.1
1.6
2.1
2.4
2.2
2.5
2.3
Map showing the distance of severely polluted area from project site.
2.5
2.4
2.8
2.4(a)
2.9
2.5
2.42
2.6
2.46
2.7
2.47
2.8
2.49
2.9
2.50
2.10
2.53
2.11
2.57
2.12
2.60
2.13
2.64
2.14
2.69
2.15
2.71
2.16
2.74
2.17
2.77
2.18
2.78
2.19
2.79
2.20
2.82
2.21
2.83
2.22
2.85
xii
2.23
2.90
2.24
2.91
2.25
2.93
2.26
2.95
2.27
2.99
2.28
2.102
2.29
2.105
2.30
2.106
2.31
2.107
2.32
2.110
3.1
3.2
3.2
3.2
3.3
3.9
3.4
3.12
3.5
3.13
3.6
3.14
3.7
3.15
3.8
3.16
3.9
3.17
3.10
3.17
3.11
3.20
3.12
3.22
3.13
3.22
3.14
3.24
3.15
3.29
3.16
3.31
3.17
3.42
3.18
3.50
xiii
3.19
3.50
3.20
3.51
3.21
3.51
3.22
Graph of Vehicular concentration at Peak hour & Lean hour for NH17
3.53
3.23
Graph of Vehicular concentration at Peak hour & Lean hour for MIDC
3.55
Internal road
6.1
6.4
6.2
6.11
6.3
6.12
6.4
6.13
6.5
6.14
6.6
6.15
6.7
6.16
6.8
6.17
6.9
6.19
6.10
6.20
6.11
6.21
6.12
6.22
6.13
6.23
6.14
6.24
6.15
6.25
6.16
6.27
6.17
6.28
6.18
6.29
6.19
6.30
6.20
6.31
6.21
6.32
6.22
6.33
xiv
6.23
6.35
6.24
6.36
6.25
6.37
6.26
6.38
6.27
6.39
6.28
6.40
6.29
6.41
9.1
9.4
xv
Executive Summary
1.0 PROJECT DESCRIPTION
1.1 Introduction
M/s Privi Organics Limited was promoted by Mr D. B. Rao (Executive Director) and
Mr.Mahesh.P.Babani (Managing Director) as a Private Limited Co. It was commissioned in 1999
and commercial production commenced in same year. The manufacturing plant is located at
plot no. C-3,4,5,6, 6/1, 7, 8, 9 and its utility service plot is at C-33/1, X-9, 10, 11 MIDC, Taluka:
Mahad, District: Raigad, Maharashtra. The unit Proposes for expansion of aroma chemicals. At
present 18 products are manufacturing while it is planned to manufacture 24 new products and
expansion of 5 existing products. Besides this it is also plan to install recovery plant for
concentrated sulfuric acid and 4MW captive power plant.
1.2 Type of Project
The proposed unit is Synthetic Organic Chemicals manufacturing unit covered under the
category A,
5(f) of EIA notification Synthetic organic chemicals industry (dyes & dye
intermediates; bulk drugs and intermediates excluding drug formulations; synthetic rubbers;
basic organic chemicals, other synthetic organic chemicals and chemical intermediates) of EIA
Notification 2006.
1.3 Location of Project Site
The proposed expansion of Industrial project is located at plot no. C-3,4,5,6, 6/1, 7, 8, 9 & C-33/1, X9, 10, 11 MIDC, Taluka: Mahad, District: Raigad, Maharashtra - 402309. The site is located on
1806.397N Latitude and 7329.321E Longitude. The site is well connected by national highway
(NH-66) around 2.5 Km, Veer railway station (18 km) and Pune Airport (130 km) and Birwadi town
(3 km).
1.4 Proposed Expansion production capacity
The proposed expansion of project is the manufacturing of aroma chemicals. The details of
products and by-products along with their capacity are given in Table: 1.1 and Table: 1.2
I
ExecutiveSummary
No
Product
Existing
Proposed
Total
Qty MTPM
Qty MTPM
Qty MTPM
Category
01
Aroma chemical
1.0
50.0
51.0
02
L-Carvone
Aroma chemical
50.0
50.0
03
Aroma chemical
12.0
12.0
04
D-Limonene
Aroma chemical
125.0
125.0
05
Myrcene
Aroma chemical
400.0
400.0
06
Alpha-Campholenic aldehyde
Aroma chemical
50.0
50.0
07
Floreol
Aroma chemical
80.0
80.0
08
D-Carvone
Aroma chemical
5.0
5.0
09
Dihydrocarvone
Aroma chemical
5.0
5.0
10
Carvomenthone
Aroma chemical
5.0
5.0
11
Nimberol
Aroma chemical
1.0
1.0
12
Dihydromyrcene
Aroma chemical
150.0
150.0
13
Aroma chemical
20.0
20.0
14
Sandal touch
Aroma chemical
5.0
5.0
15
Aroma chemical
30.0
30.0
16
Citronellal
Aroma chemical
20.0
20.0
II
ExecutiveSummary
17
mixture)
Aroma chemical
2.0
2.0
18
Aroma chemical
30.0
30.0
19
Citronellyl nitrile
Aroma chemical
30.0
30.0
20
Aroma chemical
666.66
945.0
1611.66
21
Aroma chemical
216.66
288.2
504.86
22
Aroma chemical
83.33
-42.01
41.32
Aroma chemical
744.0
744.0
Aroma chemical
679.15
679.15
Aroma chemical
537.0
537.0
25
Aroma chemical
334.0
334.0
26
Amberfleur
Aroma chemical
400.0
400.0
27
MI for soap
Aroma chemical
1.0
1.0
28
Violetone Coeur
Aroma chemical
2.0
2.0
29
Aroma chemical
2.0
3.0
5.0
297.0
297.0
Esters
Para Tertiary Butyl Cyclo Hexyl
30
Acetate
Ortho Tertiary Butyl Cyclo Hexyl
31
Acetate
Aroma chemical
Aroma chemical
III
ExecutiveSummary
32
Aroma chemical
33
Aroma chemical
34
Aroma chemical
35
Geranyl Acetate(GOLA)
Aroma chemical
36
Dimethyl Octonol A
Aroma chemical
37
Nerol A
Aroma chemical
38
Aroma chemical
39
Longifolene Acetate
Aroma chemical
Alcohols
40
Citronellol (Col)
Aroma chemical
41
Geraniol (Gol)
Aroma chemical
42
Damascone (DMO)
Aroma chemical
43
Nerol
Aroma chemical
44
Terpineol
Aroma chemical
45
Dihydromyrcenol
Aroma chemical
46
Rose Oxide
47
48
Gammanolene
445.0
445.0
Aroma chemical
3.0
3.0
Aroma chemical
10.0
10.0
Aroma chemical
50.0
50.0
49
Geraniol Formate
Aroma chemical
05.0
05.0
50
Citronellol Formate
Aroma chemical
05.0
05.0
IV
ExecutiveSummary
51
Camphene
Aroma chemical
01.0
01.0
52
Aroma chemical
01.0
01.0
53
Prionyl
Aroma chemical
1.0
1.0
54
Rosaxanol
Aroma chemical
10.0
10.0
55
Muganol
Aroma chemical
6.0
6.0
56
Aroma chemical
2.0
2.0
57
Hydrogen
15.0
15.0
1820.65
4961.34
6781.99
Total
Note: Mixed Terpenes/Terpene biofuel from CST is taken in addition while DDTO/Carene varities
60,90,98/ Terpene bio fuel is not included in addition because the same is the product of Mixed
Terpenes/Terpene biofuel after distillation.
Products
By-Products
Quantity
Utilization
(MT/M)
Aqueous fluoroboric acid
1.
(Fluoboric acid)
2.
43.34
Recovered Toluene
128.3
3.
Recovered catalyst
3.9
4.
Recovered IPA
22.1
Isobornyl
Cyclohexanol
V
ExecutiveSummary
5.
Recovered Methanol
5.0
6.
Column tops
34.9
7.
41.9
8.
Recovered cyclohexane
30.0
9.
Recovered D-Limonene
20.6
Spent Aq Layer
10.
(Aluminium Sulphate
94.6
+IPA)
L-Carvone
MEK+Butanol recovered
133.0
12.
Column tops
20.1
13.
22.8
2-Butanol (Separated
14
29.0
mixture)
15
Floreol
Recovered EDC
22.73
VI
ExecutiveSummary
registered Party
16
DHP
28.05
17
Column Tops
8.64
18
7.45
19
Recovered Toluene
110.3
20
Column tops
4.2
19.7
21
A-Campholenic
Aldehyde
22
(16-20%)
Sodium Sulphate
23
decahydrate
24
25
26
D-Carvone
8.2
25.5
Recovered cyclohexane
3.0
Recovered L-Limonene
2.1
Spent Aq.layer
9.5
(Aluminium sulphate
VII
ExecutiveSummary
+IPA)
registered party
Separate mixture and
27
MEK+Butanol rec
13.3
28
Column tops
2.0
29
3.1
2-Butanol (recovered
30
from MEK+Butanol
2.9
mixture)
31
Recovered cyclohexane
2.5
32
Recovered EDC
17.4
Column Tops
1.3
Dihydrocarvone
33
34
2.9
35
Catalyst recovered
0.05
IPA recovered
5.19
Carvomenthone
36
VIII
ExecutiveSummary
registered party
37
Recovered cyclohexane
13.88
38
Column Tops
4.14
39
2.69
1.80
40
Myrcene
41
Acid)
3.85
42
Recovered Toluene
3.44
43
0.48
44
60%)
3.79
Nimberol
45
Recovered MPK
2.51
46
recovered catalyst
0.01
47
Column Tops
0.61
48
0.48
IX
ExecutiveSummary
49
Column Tops
19.5
50
32.3
51
Recovered Cyclohexane
28.8
52
Recovered methanol
43.0
53
5.0
54
15.0
55
Column Tops
11.3
56
4.7
Dihydromyrcene
Recovered
57
MEK+Methanol
Spent Aq.Layer
58
59
(Pot.acetate)
Sandal Touch
45.7
6.5
Recovered Catalyst
0.2
60
Column Tops
2.2
61
1.4
X
ExecutiveSummary
party
62
Recovered 2 -butanol
3.4
63
Column Tops
5.9
1.8
65
Recovered catalyst
0.22
66
Aniline recovered
2.0
67
Recovered cyclohexane
30.6
64
68
Citronellal
Cyclocitral (A&B
Ammonium sulphate
Mixture)
solution (30-35 %)
47.3
69
Column Tops
0.5
70
0.9
71
Column Tops
1.77
1.24
Sodium
87.5
Isocitronellene &
Isomer
72
73
Citronellyl nitrile
sulphate/Ammonium
XI
ExecutiveSummary
74
Column Tops
1.3
75
1.6
76
8.1
77
Calcium Sulphate OR
181.56
78
Sodium Sulphate OR
189.57
CST DMS
85.44
CST DMS/DMDS OR
85.44
A-Pinene from
CST &B-Pinene
79
80
CST &
Mixed terpenes
from CST
OR
81
DDTO/Carene
250.8
sulphide solution
party
60/ 90/98
82
83
84
Heavy Fractions
105.93
336.43
A-Pinene & B-
Pinene (From
fuel
95.0
registered party
XII
ExecutiveSummary
85
GTO)
86
(Fluoboric acid)
Spent Phosphoric acid
87
88
Layer
Amberfleur
51.0
109.34
42.29
Recovered Toluene
111.51
89
Column Tops
128.68
90
86.5
91
Column Tops
0.31
92
0.34
93
Column Tops
1.20
2.32
Recovered MPK
11.04
party
Sale to PCB registered
party
Sale to PCB registered
party
Reuse or Sale to PCB
registered party
Sale to PCB registered
party
Sale to PCB registered
party
Sale to PCB registered
party
MI for Soap
Sale to PCB registered
party
Sale to PCB registered
party
Violetone couer
94
Timber
97
party
Reuse/Sale to PCB
95
96
Reuse/Sale to PCB
touch/Timber
forte
registered party
2.32
registered party
Barium hydroxide
1.0
Reuse/Sale to PCB
XIII
ExecutiveSummary
registered party
98
Reuse/Sale to PCB
Recovered Toluene
3.43
Column tops
1.51
99
100
101
registered party
party
Sale to PCB registered
1.64
Recovered Catalyst
0.04
party
Sale to PCB registered
party
Existing By products
S.No.
By-Products
Existing
Proposed
(MT/M)
(MT/M)
2.0
38.2
12.0
17.0
Utilization
Sale to PCB
registered party
Sale to PCB
registered party
XIV
ExecutiveSummary
Acetate(OTBCHA)
10.0
147.3
3.0
41.3
100.0
100.0
75.0
0.0
Sale to PCB
registered party
E. Terpinyl Acetate
F.Citronellol
G.Geraniol
H. Geranyl Acetate
I. Citronellyl Acetate
J.Timber Touch
ISO Longifolene
4.
product Longifolene Ketone
Spent Sulphuric Acid
5.
product Dihydromyrcenol
Sale to PCB
registered party
Sale to PCB
registered party
Calcium Sulphate
6.
Products-
Sale to PCB
registered party
A. Alpha Pinene
XV
ExecutiveSummary
B. Beta Pinene
C. Limonene
Heavy Fractions
products
7.
A. Alpha Pinene
116.66
116.66
0.0
75.0
0.0
20.0
0.0
90
0.0
165.0
0.0
16.0
0.0
200.0
Sale to PCB
registered party
B. Beta Pinene
C. Limonene
Spent Chromium Sulphate
8.
product Damascone
Potassium Sulphate
9.
product Damascone
10
MgCl2/Mg(OH)Cl/Mg SO4
solution
20%-30 % Ammonium Sulphate
11
product Damascone
Potassium Acetate
12
product GPMI
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
B. OTBCHA
XVI
ExecutiveSummary
Sodium Acetate
product
A. PTBCHA
B. OTBCHA
14
C. Geranyl Acetate
0.0
50.0
Sale to PCB
registered party
D. Citronellyl Acetate
E. Terpinyl Acetate
F. Isobornyl acetate
XVII
ExecutiveSummary
S.N
1.
Details
Boiler
Boiler
Capacity
Fuel/Fuel
Stack Ht.
Stack Dia(mm)
consumption
Stack gas
temp(C)
Exist.
Pro.
Exit.
Pro.
Exit.
Pro.
Exit.
Pro.
Exit.
Pro.
18 TPH &
30 TPH
42 m
46 m
90 TPD
120 TPD
1300
2000
136
160
8 TPH
(Coal)
(coal)
6 TPH
Coal
FO-
(coal)&
include
4.75
550
120
Exit.
Pro.
Exit.
Pro.
6 TPH
30 m
(FO)
in 90 TPD
KLPD or
FO-
biofuel
4.1KLPD
Exist
Pro.
Exit.
Pro.
Exit.
Pro.
12m &
125 L/hr
177.8
185
1100/50
93.5
1000,750
3.
DG set
380 KVA
10 m
&
80 L/hr &
45 L/hr
4.
Incinerator
Exist
75 Kg/hr
30 m
240
L/Day
XVIII
ExecutiveSummary
(Diesel)
Exist
Pros
Thermic
6 lac Kilo
6 lac
Fluid
Calorie/
Kilo
Hr
Calorie
5.
Heater
Exist
30.0
Pro.
30
FO/Biofu
Pro.
el
Coal
650
3.624
Exist
Pro.
Exit.
Pro.
250
550
158
158
L/Day
/Hr
1.11 Manpower requirement
During construction phase, around 60 laborers will be hired for construction activity. During
operation phase around 50 skilled and 13 unskilled nos. of people will work directly in the facility
other than sales and marketing team.
1.12 Green Belt Development
There are total of 2286 M2 areas has been taken for green cover / lawn development in the
existing facility. Suitable plant species of local varieties will be planted with adequate spacing
and density for their fast growth and survival.
1.13 Cost of Project
The expected cost for the proposed project will be around Rs 67.92 Crores. Out of which Rs 7.72
Crores shall be earmarked for development of EMS (Environment Management Systems).
XIX
ExecutiveSummary
XX
ExecutiveSummary
XXI
ExecutiveSummary
AREA (m2)
Area (ha)
Area (%)
Water
3016850
302
0.96
Agriculture land
4813200
481
1.53
Fallow land
97188841
9719
30.97
Degraded land
24574891
2457
7.83
Forest
62610950
6261
19.95
Degraded forest
121249800
12125
38.64
Settlements
146675
15
0.05
Road
198768
20
0.06
Area
313799975
31380
100.00
Soil: Soil samples from 7 locations were collected and analyzed to assess the soil quality
prevailing in the study area.
XXII
ExecutiveSummary
Total literate population is 33016 and average literacy rate is 72.9 % in study area.
Villages in study area have fairly good infrastructural, health, Drinking water, Electricity and
communication facilities.
3.0 ANTICIPATED ENVIRONMENTAL IMPACTS AND MITIGATION MEASURES
3.1 Ambient Air
In order to estimate the ground level concentrations due to the emission from the proposed
project, an EPA approved ISCST - 3 version 98356 (Industrial Source Complex Short Term
dispersion model) has been employed.
The predicted ground level concentrations of PM10, SO2, NOx are found to be 1.300 g/M3,
0.136 g/M3, 0.580 g/M3 respectively.
These predicted ground level concentrations when added to baseline scenario, the overall
scenario levels of PM10, SO2, NOx, are well within the permissible limits specified by CPCB.
VOCs and other NAQQS parameters are observed with below detectable limit, the detail
explanation is mentioned in Basline chapter-3.
Adequate mitigation measures will be proposed to control air pollution.
3.2 Noise
The major noise source includes various machines, pumps, motors, DG sets and vehicular traffic.
The noise levels were below the stipulated standards of CPCB for residential and industrial areas.
Every effort would be taken to minimize the noise levels including Periodic maintenance of
machinery, mandatory use of equipment with operable mufflers, oiling and lubrication, Noise
suppression measures such as enclosures, buffers, green belt development etc.
XXIII
ExecutiveSummary
XXIV
ExecutiveSummary
implementation, mitigation measures are phased as per the priority implementation. Air pollution
control measures will be installed as per CPCB norms. During construction phase monthly
monitoring will be carried out and during operation phase monitoring will be done on quarterly
basis or as per MPCB/CPCB guideline.
5.0 PROJECT BENEFITS
Growth in the industrial sector creates new opportunities for employment and can also help
diversify the economy.
5.1 Improvement in Social Infrastructure
From the very initial stage of the inception of the project, infrastructure development in and around
the project site has been kept into consideration. Infrastructure development will be done based
on actual requirement rolled out as part of companys CSR activity.
5.2 CSR Activities
1. Will create residential, medical, educational and recreational facilities for our employees.
2. Rural Development Programs for upliftment of people in the form of de-addiction, selfhelp, vocational training and guidance etc
3. Organise blood donation Camp.
4. Save girl child programm in rural areas
5. Food & Clothes distribution to Old age home.
6. Sponsoring / Providing Hobby workshop for ladies & children.
7. Sponsoring / Providing English Speaking classes.
8. Free medical check up for villagers.
9. Tree Plantation in rural areas.
10. Provision of sanitation (toilets) facility.
11. Training under privileged women housewives in hospitality, self-grooming, house-keeping
and laundry.
12. Total CSR activities by Privi group is budgeted around Rs. 34 Lakhs
XXV
ExecutiveSummary
Noise control
To adopt construction and operational methods that will limit environmental degradation.
To incorporate the views and perceptions of the local inhabitants in the project.
To establish a long term program to monitor effects of the project on the environment.
XXVI
ExecutiveSummary
8. Public Hearing
As per the EIA notification 2006 and OM dated 16th May 2014, Public Hearing was conducted by
MPCB for this project. Public views and opinions are incorporated in chapter 13 of the EIA report.
XXVII
ExecutiveSummary
CHAPTER 1
INTRODUCTION
1.0 PROMOTER & CREDENTIALS OF THE COMPANY
M/s Privi Organics Limited was promoted by Mr. D. B. Rao (Executive Director) and Mr.
Mahesh.P.Babani (Managing Director) as a Private Limited Company. It was commissioned in
1999 and commercial production commenced in same year. Currently Privi Organics is
manufacturing 18 Aroma products, and planned to manufacture 24 additional products and
expanding 5 existing products. Ever since the beginning, Privi has been gradually increasing
its manufacturing capacity and the range of products. Privi has entered in the Global market
in 1998 and today manufacturing site has grown to Global Standards. M/s Privi Organics Ltd.
have the bouquet of products consists of around 18 aroma chemicals such as Rose Oxide,
Prionyl, Rosaxanol, Alpha Pinene, etc. The present capacity of plant is 1820.65 MT per month.
The company which was once engaged in manufacturing of commodity products has
graduated
to
manufacturing
specialty
and
value
added
products
like
Isobornyl
Lalit Doshi Memorial Award (Year 2000) for its outstanding performance in year 2000(This prestigious award was instituted by Lalit Doshi Memorial Foundation and SICOM
Limited is annually presented to a SICOM assisted unit having outstanding performance.)
1.1
Flavor and fragrance demandincluding demand for flavor and fragrance blends, essential
oils and natural extracts, and aroma chemicalsis expected to rise 4.4% a year to reach
$26.5 billion in 2016. In 2011, total world aroma chemicals consumption was worth $ 3.37
billion.
Introduction
1.1
M/s Privi Organics limited supplies its aroma ingredients to Top ten fragrance houses in the
world, which accounts 66% of world total flavour and fragrance market share and known for
its consistent quality and competitive pricing. It is estimated that International houses (foreign
players) account for about 70% of the organized Indian market while domestic companies
cater to the rest. The Asia/Pacific region is expected to surpass Western Europe to become
the second largest regional consumer of flavors and fragrances, behind North America in
next few years.
Privi Organics Ltd aims to become the largest global supplier of competitive and quality
aroma chemicals. This project will enhance Indias potential of supplying aroma
chemicals/products to worldwide leading to step-up of Indias position in global market
sector and strengthening of Indian economy. This will also enable to meet rising demands of
such products in domestic market.
1.2 APPLICATIONS OF AROMA CHEMICALS
The products e.g., Isobornyl Cyclohexanol, D-Limonene & Orange oil, Myrcene, L-Carvone &
Alpha-Campholenic aldehyde etc which Privi Organics intend to manufacture are used as
fragrance agents and/or flavouring agents. Apart from use in flavorings/fragrances, the
products have other important and valuable applications.
For example, D-Limonene & Orange oil is also used as adhesive and stain removers. Oils
containing carvones are used in aromatherapy and alternative medicine.
1.3 PURPOSE AND NEED OF EIA
The proposed project falls within 5 Km radius from the boundary of Eco-Sensitive Areas (ESA) as
per Directions under Section 5 of the Environment (Protection) Act, 1986 by MoEF (F. No. 14/2012 - RE (Pt.) dated 13.11.2013 and as per EIA notification 2006 & subsequent amendments,
the proposed expansion project falls under the clause 5(f) category A. This requires obtaining
environmental clearance from MoEF & CC, Government of India.
M/s. Privi organics Ltd. has retained the services of Green Circle Inc, Vadodara to undertake
Environmental Impact Assessment (EIA) studies for assessing the impact of the proposed
expansion of manufacturing capacity on various environmental parameters in the study area
and prepare an Environment Management Plan for negating the adverse impacts of the
proposed project. Analysis of samples has been carried out by MoEF approved Environment
Laboratory of Green circle Inc, Vadodara, Gujarat.
Introduction
1.2
The Environmental (Protection) Act 1986 (EIA Notification, 2006) established the requirements
for preparing Environmental Impact Assessment (EIA) in India for certain category of projects.
The EIAs subsequently has been prepared, on an individual basis for this project. While the
project specific EIAs have been successful to varying extent in the incorporation of
environmental objectives in the project design, several experiments have been done to
address the issue of cumulative environmental impacts by carrying out Regional
Environmental Impact studies. This has given a basis for evaluating total environmental
impacts of the region and hence helped in planning at the regional level. Hence, EIA tool
has been improvised and used innovatively for assisting decision-makers in assessment of
environmental impacts and considering alternative mitigation measures in a variety of
situations.
Environmental Impact Assessment (EIA) is required to be carried out for certain categories of
projects and the criteria for screening have been provided. Thus, EIA is essentially made
applicable to industrial and developmental projects, which are more likely to have
significant environmental impacts. Indian regulation screens project category based on the
Scale of Impact, Sensitivity of Impact and Nature of locations as the primary criteria for
deciding on the requirement of EIA for approval.
1.4 BRIEF DESCRIPTION OF PROJECT
1.4.1 Plant Location
The proposed project is located at plot no. Plot No.C-3, 4, 5, 6, 6/1, 7, 8, 9 & C-33/1, X-9, 10, 11
Maharashtra Industrial Development Corporation (MIDC), Taluka: Mahad, District: Raigad,
Maharashtra. The proposed project at intersection of latitude 1806.397N and longitude
7329.321E. The total plot area of plant is 50675.0 m2 and 5081.0 m2 for plot nos. C-3, 4, 5, 6,
6/1, 7, 8, 9 & C-33/1, X-9, 10, 11 respectively. The Plant is situated near to National Highway 66
in the Northwest direction at a distance of 3 Km. The nearest railway station is located at
Veer is at distance of 18 Km in the Southeast direction. The nearest Airport is located at a
distance of 130 Km in the Northwest direction at Pune. There are no national parks and wild
life sanctuaries within the 10 Km radius of the project site. However Eco-Sensitive Areas
(ESA)like village Jite is present within 5 km radius of project site.
Introduction
1.3
To ensure that the industries consider the effect on the health, economy and culture of
the surrounding communities as well as its impacts on the air, land and water.
Construction phase
Operation phase
Introduction
1.4
Base line data generation and characterization of air, water, soil, noise and
vegetation in the ten kilometer radius area (impact zone) over a period of Three
months.
A thorough study of the process including provisions for pollution control, and
environmental management that includes prediction of impacts and relevant
mathematical modeling.
To study Baseline environmental conditions of the study area for air, water, soil, noise,
meteorology.
Develop an Environmental Management Plan and Disaster Management Plan for the
proposed project to mitigate the negative significant impacts that would arise from
the proposed project.
Introduction
1.5
The scope of the study would include a detailed characteristic of environment in the study
area associated with the development of Special Economic Zone for various environmental
components. For the purpose of environmental assessment, areas within 10 km radius of the
project have been studied and the following methodology will be adopted. Monitoring and
analysis done as per CPCB /APHA /MPCB guidelines /relevant IS.
PROJECT
INITIATION
PRELIMINARY SCAN
OF EXISTING
ENVIRONMENT
PRELIMINARY SCAN
OF PROPOSED
PROJECT
SELECT
ENVIRONMENTAL
INDICATORS
DESCRIBE
ENVIRONMENTAL
SETTING
FIELD
SURVEYS
AND
IMPACT
EVALUATION
(MODELLING)
ENVIRONMENTAL
IMPACT
ASSESSMENT
ENVIRONMENTAL
MANAGEMENT
PRELIMINARY
SCAN OF
EXISTING
ENVIRONMENT
Introduction
1.6
The Hazardous Waste (Management, Handling and Tran boundary Movement) Rules,
2008.
The MSIHC (Manufacture, Storage and Import of Hazardous Chemicals) rules 1989
and amendment in 2000
Noise Pollution (Regulation and Control) Rules, 2000 and its amendments
The Batteries (Management and Handling) Rules 2001 and amendment in 2010
Introduction
1.7
Chapter 1: Introduction
This chapter provides background information on need of project, need of EIA study and
brief of the project. It also covers the identification of project and project proponent, brief
description of nature, size, location of the project and its importance to the country and the
region.
Chapter 2: Project Description
This chapter deals with the project details of the proposed synthetic organic Plant, with type
of project, need for the project, location, size and magnitude of operation including
associated activities required by and for the project, proposed schedule for approval and
implementation, including technical details of raw material, quality and quantity etc.
Chapter 3: Baseline Environmental status
This chapter presents the existing environmental status of the study area of 10 km around the
proposed project including topography, drainage pattern, water environment, geological,
climate, transport system, land use, flora and fauna, socio-economic aspects, basic
amenities etc. Environmental assessment of the proposed project site in regard to its
capability to receive the proposed new development is also discussed in this Chapter.
Chapter 4: Anticipated Environmental Impacts and Mitigation Measures
This chapter describes the overall impacts of the proposed project activities and underscores
the areas of concern, which need mitigation measures. It predicts the overall impact of the
proposed project on different components of the environment viz. Air, Water, Land, Noise,
Biological, and Socio-Economic.
Chapter 5: Environmental Monitoring Program
This chapter describes technical aspects of monitoring the effectiveness of mitigation
measures (including measurement methodologies, frequency, location, and data analysis,
reporting schedules, emergency procedures, detailed budget and procurement schedules.
Environmental Monitoring Programme is implemented during construction and operation
phases of the project. The objective of environmental monitoring Programme is to assess the
adequacy of various environmental safeguards and to compare the predicted and actual
scenario during construction and operation phases. This enables suggestion of remedial
measures not foreseen during the planning stage but arising during these phases.
Introduction
1.8
Introduction
1.9
CHAPTER 2
PROJECT DESCRIPTION
2.0. INTRODUCTION
M/s. Privi Organics Ltd. has proposed to increase its manufacturing capacity of aroma chemicals
products at plot no. C-3, 4, 5, 6, 6/1, 7, 8, 9 MIDC, Mahad, Taluka: Mahad, District: Raigad,
Maharashtra. M/s Privi Organics Ltd was commissioned in 1999 and commercial production
commenced in the same year. Currently, 18 aroma products are manufactured in the plant. It
has been planned to manufacture additional 24 products in the plant and expansion of 5 existing
products. Whereas utility service and recovery plant for concentrated sulfuric acid is provided
from plot no. C33/1, X-9,10,11. It is also planned to install captive power plant for the generation of
4 MW power for in-house utilization.
2.1. TYPE OF PROJECT
The proposed unit is aroma Chemicals manufacturing unit covered under the category of 5(f) in
schedule Synthetic organic chemicals industry (dyes & dye intermediates; bulk drugs and
intermediates excluding drug formulations; synthetic rubbers; basic organic chemicals, other
synthetic organic chemicals and chemical intermediates) of EIA Notification-2006. This project
falls under category A as project falls within 5 Km radius from the boundary of Eco-Sensitive Areas
(ESA) as per Directions under Section 5 of the Environment (Protection) Act, 1986 by MoEF (F. No.
1-4/2012 - RE (Pt.) dated 13 .11.2013 and EIA notification amendment dated 25.06.2014.
2.2. CAPITAL INVESTMENT
The expected cost of the proposed project will be around Rs. 67.92 crores. Rs 7.72 crores shall be
earmarked for development of EMS (Environment Management Systems).
2.3. NEED OF THE PROJECT
M/s. Privi Organics Limited is a leading marketer of value-added products, Privi shall continue to
be a leader in the local aroma chemicals industry and keep on thriving and innovating for the
international market, thereby portraying Indias potential as a market leader in Aroma Chemicals.
Flavor and fragrance demand including demand for flavor and fragrance blends, essential oils
and natural extracts, and aroma chemicals is expected to rise 4.4% a year to reach $26.5 billion in
2016.
Project Description
2.1
aldehyde, Nimberol, Dihydromyrcene, Sandal fleur, Sandal touch etc. will start in existing plant at
MIDC, Mahad, Raigad. The site is well connected by metallic roads and close to national highway
(NH-66) railway station Veer (18 km) and Airport Pune (130 km). The raw material required for this
plant is easily available from and within local markets of Maharashtra. Man power required is
easily available and which in turn will generate employment. Products are primarily meant for
export for which import and export facilities are available in Maharashtra. Moreover this will result
in revenue generation and socio-economic upliftment through our CSR activities.
2.5 LOCATION OF PROJECT SITE
The proposed Industrial project is located at Plot no- C-3,4,5,6, 6/1,7, 8, 9 and C33/1, X-9, X-10, X-11
MIDC, Taluka: Mahad, District: Raigad, Maharashtra. The environmental setting around the
proposed site is given in Table-2.1. The location plan of project site is given in figure 2.1 & Google
map of project site is shown as figure 2.2 & figure 2.3.
Table 2.1: Environment setting of the proposed project
Sr. No.
Particulars
Details
Latitude
1806.397N
Longitude
7329.321E
Climatic Conditions
Nearest village
Jite (2 km, S)
Nearest Town/City
Birwadi (3 km)
Nearest Highway
10
Nearest Airport
11
12
Village Jite
13
Project Description
2.2
Sr. No.
14
Particulars
National Parks/Wild Life Sanctuary
Details
No National Parks/Wildlife Sanctuary is present
within 10 Km radius.
15
16
Seismic Zone
Zone IV
** Source: Report of Ministry of Water Resources Central Ground Water Board (2009)
Project Description
2.3
Project
Site
Project Site
2.4
Project Site
Figure: 2.3: Map showing the distance of severely polluted area from project site.
Project Description
2.5
Existing
Propose
Plant
4013.0
66.0
Storage
7167.20
468.50
RM/BSR/Store
2623.12
Utility
492.55
109.70
Boiler
313 .70
DG/ PCC/Transformer
680.0
Administrative Building
116.70
678.25
Approach roads
8329.20
3574.80
10
Parking
736.15
11
Security/Change room
153.84
12
Open Shed
851.18
13
Green belt
1920.0
14
Open space
11892.01
15
Office/R&D/Workshop
2438.90
Total
42406.0
4219.0
Grand Total
46625.0
Area Details (Plot no. C-7)
Storage
1197.54
2852.45
Grand Total
4050.0
Project Description
2.6
Description
Area (m2)
Remarks
3906
Existing
1175
Existing
Total
5081
Existing
Area Details
Area (m2)
Description
Existing
Propose
Plant
97.76
DM water plant
95.90
Storage
55.95
Boiler 8TPH
198.40
Boiler 18 TPH
418.80
Boiler 30 TPH
460.0
ESP
108.0
Turbine
80.0
Toilet Block
12.04
10
DG Room
81.47
11
Transformer area
69.0
12
Septic tank
3.13
13
Chimney
4.5
14
Coal Shed
180.0
15
81.75
16
HT breaker room
18.0
17
Scrap area
65.79
18
Security
9.0
19
Road area
976.0
20
Green belt
161.0
21
open space
1900.51
Total
4433.0
648.0
Project Description
2.7
Figure: 2.4: Plant Layout of proposed expansion project: Plot no- C-3, 4, 5, 6, 6/1, 7, 8, 9
Project Description
2.8
Figure: 2.4a: Layout Plan of proposed expansion project: Plot no C33/1, X-9, 10, 11
Project Description
2.9
Product
Raw Materials
Consumpti
on (MT /M)
Source
Transportation
Storage
Condition
Self
1
Camphene
made/Import/
52.71
Domestic
Road ways
Tank
Road ways
Tank
Road ways
Drum
Road ways
Drum/Bag
Road ways
Bag
Road ways
Bag
Road ways
Drum
Road ways
Box
Road ways
Cylinder
Road ways
Tank
Road ways
Tank
Road ways
Tank
market
2
Toluene
135.66
BF3 etherate
6.2
Isobornyl
cyclohexa
nol (IBCH)
Catechol /
Guiacol
Sodium
hydroxide
Salt
Isopropyl
alcohol
market
Import/
72.87
Domestic
market
Domestic
2.52
market
Domestic
23.64
market
Domestic
3.88
market
Domestic
Catalyst
1.94
Hydrogen
52.71
10
D-Limonene
107.09
Cyclohexane
32.13
12
L-Carvone
Hydrogen
peroxide 50%
market
Domestic
11
Domestic
54.62
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Project Description
2.10
13
PTC
4.28
14
Catalyst ST
3.21
Phosphoric
15
acid
Sodium
16
Hydroxide
17
CATALYST PBS
Sodium
18
Sulphite
Catalyst ZO
5.19
MEK
30 % Sulphuric
23
Acid
24
25
Orange oil
& D-
Domestic
market
Domestic
market
Domestic
market
Domestic
10.71
20
22
market
2.86
5.19
Isopropoxide
Domestic
1.07
AP catalyst
Aluminium
market
1.07
19
21
Domestic
market
Domestic
market
Import/Domesti
c market
Import/Domesti
22.32
c market
Import/Domesti
135.0
c market
Domestic
38.41
market
Domestic
Salt
2.0
Orange oil
138.12
market
Import/Domesti
c market
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Box
Road ways
Drum/Tank
Road ways
Drum/Tank
Road ways
Tank
Road ways
Bag
Road ways
Tank
Road ways
Tank
Road ways
Drum
Limonene
Self
26
Myrcene
Beta -Pinene
402.8
made/Import/
Domestic
market
27
Floreol
Isovaleraldeh
yde
59.81
Import/
Domestic
Project Description
2.11
market
28
Sulphuric acid
1.79
Domestic
market
Road ways
Tank
Road ways
Drum
Road ways
Drum/Tank
Road ways
Bag
Road ways
Tank
Road ways
Tank
Road ways
Drum
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Tank
Import/
29
Isoprenol
65.79
Domestic
market
Import/
30
EDC
23.93
Domestic
market
Sodium
31
hydroxide
2.33
Domestic
market
Self
alpha pinene
32
57.80
made/Import/
Domestic
market
Hydrogen
33
peroxide
38.61
(50%)
34
Catalyst ST
3.76
Phenyl
35
36
37
A-
phosphonic
Camphole
acid
nic
aldehyde
(ACA)
0.91
PTC
4.62
Catalyst PBS
1.40
Sodium
38
sulphate
1.45
anhydrous
39
Sodium
sulphite
0.29
40
Salt
113.7
41
Toluene
1.13
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Project Description
2.12
42
Zinc Bromide
0.91
Domestic
market
Road ways
Bag
Road ways
Tank
Road ways
Tank
Road ways
Tank
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Box
Road ways
Drum/Tank
Road ways
Drum/Tank
Road ways
Bag
Road ways
Tank
Self made /
43
L-Limonene
10.7
Domestic
market
44
Cyclohexane
Hydrogen
45
peroxide 50%
3.2
5.5
46
PTC
0.4
47
Catalyst ST
0.3
Phosphoric
48
acid
Sodium
49
50
Hydroxide
DCarvone
Catalyst PBS
Sodium
51
Sulphite
52
AP catalyst
0.1
0.1
0.3
1.1
0.5
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Import/
53
Catalyst ZO
0.5
Domestic
market
Aluminium
54
Isopropoxide
Methyl ethyl
55
ketone
30 % Sulphuric
56
Acid
57
58
Dihydro
2.2
13.5
3.8
Salt
0.2
D-Limonene
10.4
Import/Domesti
c market
Import/Domesti
c market
Domestic
market
Domestic
market
Self
Project Description
2.13
carvone
made/Import/
Domestic
market
59
Cyclohexane
Hydrogen
60
peroxide 50%
2.7
4.5
61
PTC
0.4
62
Catalyst ST
0.3
Phosphoric
63
acid
Sodium
64
Hydroxide
65
Catalyst PBS
Sodium
66
Sulphite
Perchloric
67
acid
0.1
0.2
0.2
0.9
0.01
68
EDC
18.3
69
Salt
0.1
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Road ways
Tank
Road ways
Tank
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Bag
Road ways
Tank
Road ways
Drum
Road ways
Drum
Road ways
Cylinder
Road ways
Tank
Self made/
Limonene
70
10.82
Domestic
market
Isopropyl
71
Carvomen
72
thone
alcohol
5.41
Catalyst
0.05
73
Hydrogen
0.16
74
Cyclohexane
1.39
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Project Description
2.14
Hydrogen
75
peroxide 50%
6.49
76
PTC
0.37
77
Catalyst ST
0.28
Phosphoric
78
acid
Sodium
79
Hydroxide
80
Catalyst PBS
Sodium
81
Sulphite
Perchloric
82
acid
83
Cyclohexane
Caustic
84
solution
85
Salt
0.09
0.1
0.19
0.19
0.08
14.24
0.2
0.03
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Road ways
Tank
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Drum
Road ways
Drum
Road ways
Bag
Road ways
Bag
Road ways
Drum
Road ways
Tank
Road ways
Drum
Road ways
Bag
Road ways
Tank
Road ways
Bag
Road ways
Bag
Self
86
Citronellal
1.81
made/Domesti
c market
Acetic
87
anhydride
88
89
Triethylamine
Nimberol
Sodium
acetate
2.39
1.18
0.18
90
Toluene
0.18
91
soda ash
0.05
92
Salt
0.25
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Project Description
2.15
Ortho
93
Phosphoric
0.45
acid
Domestic
market
Road ways
Tank
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Cylinder
Road ways
Bag
Road ways
Tank
Road ways
Tank
Road ways
Drum
Road ways
Drum
Road ways
Drum
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Drum
Import/
94
MPK
0.67
Domestic
market
Sodium
95
methoxide
Import/
0.13
Domestic
market
96
Acetic acid
0.13
97
Hydrogen
0.03
98
Catalyst
0.01
Domestic
market
Domestic
market
Domestic
market
Self
99
Alpha-Pinene
202.1
yrcene
101
Hydrogen
2.96
Catalyst
0.13
Campholenic
22.72
aldehyde
Butyraldehyd
103
Sandal
104
fleur &
market
Domestic
market
made/Import/
Domestic
market
Import/
15.76
Domestic
market
Cyclohexane
0.99
105
Catalyst A
2.98
106
Acetic acid
5.42
107
30 % HCl
2.39
derivative
Domestic
Self
A102
Domestic
market
Dihydrom
100
made/Import/
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Project Description
2.16
108
Soda ash
Sodium
109
borohydride
Sodium
110
hydroxide
111
Methanol
0.33
Campholenic
1.51
113
Touch
0.19
2.65
Bag
Domestic
Road ways
Bag
Domestic
market
Road ways
Bag
Domestic
market
Road ways
Tank
Road ways
Drum
Road ways
Tank
Road ways
Tank
Road ways
Bag
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Tank
Road ways
Tank
Self
6.70
made/Import/
Domestic
market
Import/
MEK
2.11
Domestic
market
114
Methanol
1.13
115
Soda ash
0.07
116
Salt
0.34
117
Acetic acid
1.61
Potassium
118
Road ways
market
aldehyde
Sandal
market
Import/
A112
Domestic
Hydroxide
1.34
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Self made/
119
2-butanol
0.20
Domestic
market
Copper
120
chromite
121
122
Hydrogen
Citral
extra pure
Import/
0.20
Domestic
market
0.16
Domestic
market
Import/
Citral
30.03
Domestic
market
Project Description
2.17
Import/
123
Citral
27.59
Domestic
Road ways
Tank
Road ways
Bag
Road ways
Cyclinder
Road ways
Tank
Road ways
Bag
Road ways
Tank
Road ways
Tank
Road ways
Drum
Road ways
Drum/Tank
Road ways
Bag
Road ways
Tank
market
124
Catalyst
0.22
Hydrogen
0.47
126
Methanol
0.19
127
soda ash
0.03
125
Citronellal
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Import/
Citral
128
3.39
Domestic
market
129
Domestic
Aniline
0.61
Cyclohexane
15.76
Sulphuric acid
11.9
132
soda ash
0.5
133
Liq Ammonia
17.5
DHMOL tops
15.46
Self made
Road ways
Tank
DHM tops
13.95
Self made
Road ways
Tank
24.45
Self made
Road ways
Drum
Road ways
Tank
Road ways
Bag
Road ways
Bag
130
131
134
135
136
Cyclocitra
l (A& B
mixture)
Isocitronell
-ylene &
Isomer
DHM bottom
mass
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Import/
137
Citral
39.13
Domestic
market
138
Citronellyl
nitrile
Hydroxyl
amine
22.83
sulphate
Soda
139
ash/Ammonia
solution
22.83
Domestic
market
Domestic
market
Project Description
2.18
Sodium
140
chloride
Domestic
1.47
141
Caustic Soda
0.65
142
White oil
2.77
market
Domestic
market
Domestic
market
Road ways
Bag
Road ways
Bag
Road ways
Drum
Road ways
Tank
Road ways
Bag
Road ways
Bag
Road ways
Bag
Road ways
Bag
Crude
Sulphate
143
turpentine
A-Pinene
144
145
146
147
148
hydroxide
terpenes
or
2.2
Hydrogen
60/90/98/
peroxide
150
151
Charcoal
ene
Caustic
solution
Nitrogen
A-Pinene
Gum
& B-
turpentine
Pinene
crude
market
111.12
2.2
50 %
biofuel
market /Import
Domestic
98.79
Silica
DDTO/Car
terpene
149
Lime
Sodium
Mixed
Domestic
(CST Crude)
3050.78
Domestic
market
Domestic
market /Import
Domestic
market
Domestic
67.18
market
Domestic
5.55
market
320 M3
Domestic
market
Road ways
Road ways
Road ways
Carbouy /
Tank
Tank
Cyclinder/
Tank
Import/
1032.6
Domestic
Road ways
Tank
Road ways
Tank
Road ways
Tank
Road ways
Drum
market
Self
152
Myrcene
367.5
153
Domestic
market
Amberfleu
r
made/Import/
Self made/
MPO
269
Domestic
market
154
Boron
trifluoride
23
Domestic
market
Project Description
2.19
etherate
Sodium
155
chloride (Salt)
3.9
156
Antioxidant
0.8
157
Toluene
115.9
Phosphoric
158
acid
159
Caustic soda
42
4.5
Methyl
160
Ionone for
161
core
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Road ways
Bag
Road ways
Bag
Road ways
Tank
Road ways
Tank
Road ways
Bag
Road ways
Drum
Road ways
Drum
Road ways
Tank
Road ways
Drum
Road ways
Bag
Road ways
Drum
Road ways
Bag
Road ways
Tank
Road ways
Tank
Road ways
Bag
Self made/
NMI crude
5.0
Soap
Violetone
Domestic
Domestic
market
Self made/
GMI crude
40.0
Domestic
market
Import/
Citral
162
5.76
Domestic
market
Import/
163
MPK
14.40
Domestic
market
Barium
164
Timber
165
touch or
Timber
hydroxide
Import/
0.69
market
Acetic acid
0.2
Salt
0.1
Forte
166
167
Orthophosph
oric acid
Domestic
2.27
168
Toluene
3.60
169
Soda ash
0.08
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Domestic
market
Project Description
2.20
Self made/
170
Hydrogen
0.17
Domestic
Road ways
Cyclider
Road ways
Box
market
Import/
171
Catalyst
0.04
Domestic
market
Proposed
Total
Qty MTPM
Qty MTPM
Qty MTPM
Aroma chemical
1.0
50.0
51.0
L-Carvone
Aroma chemical
50.0
50.0
03
Aroma chemical
12.0
12.0
04
D-Limonene
Aroma chemical
125.0
125.0
05
Myrcene
Aroma chemical
400.0
400.0
06
Alpha-Campholenic aldehyde
Aroma chemical
50.0
50.0
07
Floreol
Aroma chemical
80.0
80.0
08
D-Carvone
Aroma chemical
5.0
5.0
09
Dihydrocarvone
Aroma chemical
5.0
5.0
10
Carvomenthone
Aroma chemical
5.0
5.0
11
Nimberol
Aroma chemical
1.0
1.0
12
Dihydromyrcene
Aroma chemical
150.0
150.0
13
Aroma chemical
20.0
20.0
14
Sandal touch
Aroma chemical
5.0
5.0
15
Aroma chemical
30.0
30.0
16
Citronellal
Aroma chemical
20.0
20.0
Aroma chemical
2.0
2.0
No
Product
Category
01
02
17
18
Aroma chemical
30.0
30.0
19
Citronellyl nitrile
Aroma chemical
30.0
30.0
20
Aroma chemical
666.66
945.0
1611.66
21
Aroma chemical
216.66
288.2
504.86
22
Aroma chemical
83.33
-42.01
41.32
Project Description
2.21
from CST or
DDTO/Carene varities 60,90,98/
Terpene bio fuel
Aroma chemical
744.0
744.0
Aroma chemical
679.15
679.15
24
Aroma chemical
537.0
537.0
25
Aroma chemical
334.0
334.0
26
Amberfleur
Aroma chemical
400.0
400.0
27
MI for soap
Aroma chemical
1.0
1.0
28
Violetone Coeur
Aroma chemical
2.0
2.0
29
Aroma chemical
2.0
3.0
5.0
297.0
297.0
445.0
445.0
Esters
30
31
Aroma chemical
Aroma chemical
32
Aroma chemical
33
Aroma chemical
34
Aroma chemical
35
Geranyl Acetate(GOLA)
Aroma chemical
36
Dimethyl Octonol A
Aroma chemical
37
Nerol A
Aroma chemical
38
Aroma chemical
39
Longifolene Acetate
Aroma chemical
Alcohols
40
Citronellol (Col)
Aroma chemical
41
Geraniol (Gol)
Aroma chemical
42
Damascone (DMO)
Aroma chemical
43
Nerol
Aroma chemical
44
Terpineol
Aroma chemical
45
Dihydromyrcenol
Aroma chemical
46
Rose Oxide
Aroma chemical
3.0
3.0
47
Aroma chemical
10.0
10.0
Aroma chemical
50.0
50.0
48
Ionones - GMI,NMI,AI,BIGammanolene
49
Geraniol Formate
Aroma chemical
05.0
05.0
50
Citronellol Formate
Aroma chemical
05.0
05.0
51
Camphene
Aroma chemical
01.0
01.0
Project Description
2.22
52
Aroma chemical
1.0
1.0
53
Prionyl
Aroma chemical
1.0
1.0
54
Rosaxanol
Aroma chemical
10.0
10.0
55
Muganol
Aroma chemical
6.0
6.0
56
Aroma chemical
2.0
2.0
57
Hydrogen
15.0
15.0
1820.65
4961.34
6781.99
Total
Note: Mixed Terpenes/Terpene biofuel from CST is taken in addition while DDTO/Carene varities
60,90,98/ Terpene bio fuel is not included in addition because the same is the product of Mixed
Terpenes/Terpene biofuel after distillation.
Table 2.5: Product wise By-product details
Proposed
Sl.No.
Products
By-Products
Quantity
Utilization
(MT/M)
Aqueous fluoroboric acid
1.
(Fluoboric acid)
43.34
2.
Recovered Toluene
128.3
3.
Recovered catalyst
3.9
Recovered IPA
22.1
5.
Recovered Methanol
5.0
6.
Column tops
34.9
7.
41.9
8.
Recovered cyclohexane
30.0
Recovered D-Limonene
20.6
4.
9.
10.
Isobornyl
Cyclohexanol
L-Carvone
Spent Aq Layer
(Aluminium Sulphate
94.6
+IPA)
Project Description
2.23
MEK+Butanol recovered
133.0
12.
Column tops
20.1
13.
22.8
2-Butanol (Separated
14
29.0
mixture)
15
Recovered EDC
22.73
16
DHP
28.05
17
Column Tops
8.64
18
7.45
19
Recovered Toluene
110.3
20
Column tops
4.2
19.7
Floreol
21
A-Campholenic
Aldehyde
22
(16-20%)
Sodium Sulphate
23
decahydrate
24
25
26
D-Carvone
8.2
25.5
Recovered cyclohexane
3.0
Recovered L-Limonene
2.1
Spent Aq.layer
(Aluminium sulphate
9.5
Project Description
+IPA)
Separate mixture and
27
MEK+Butanol rec
13.3
28
Column tops
2.0
29
3.1
2-Butanol (recovered
30
from MEK+Butanol
2.9
mixture)
31
Recovered cyclohexane
2.5
32
Recovered EDC
17.4
Column Tops
1.3
33
Dihydrocarvone
34
2.9
35
Catalyst recovered
0.05
36
IPA recovered
5.19
Recovered cyclohexane
13.88
38
Column Tops
4.14
39
2.69
1.80
37
40
41
42
Carvomenthone
Myrcene
Acid)
Recovered Toluene
3.85
3.44
Project Description
registered party
43
44
60%)
0.48
3.79
45
Recovered MPK
2.51
46
recovered catalyst
0.01
47
Column Tops
0.61
48
0.48
49
Column Tops
19.5
50
32.3
51
Recovered Cyclohexane
28.8
52
Recovered methanol
43.0
53
5.0
15.0
55
Column Tops
11.3
56
4.7
Dihydromyrcene
54
Recovered
57
MEK+Methanol
Spent Aq.Layer
58
Sandal Touch
(Pot.acetate)
45.7
6.5
59
Recovered Catalyst
0.2
60
Column Tops
2.2
Project Description
61
1.4
62
Recovered 2 -butanol
3.4
63
Column Tops
5.9
1.8
65
Recovered catalyst
0.22
66
Aniline recovered
2.0
67
Recovered cyclohexane
30.6
64
68
Citronellal
Cyclocitral (A&B
Ammonium sulphate
Mixture)
solution (30-35 %)
47.3
69
Column Tops
0.5
70
0.9
71
Column Tops
1.77
1.24
72
Isocitronellene &
Isomer
Sodium
sulphate/Ammonium
73
87.5
%)
74
Column Tops
1.3
75
1.6
76
8.1
Calcium Sulphate OR
181.56
Sodium Sulphate OR
189.57
77
78
Citronellyl nitrile
A-Pinene from
CST &B-Pinene
from CST &
Project Description
party
Limonene from
CST &
79
Mixed terpenes
from CST
80
85.44
CST DMS/DMDS OR
85.44
OR
DDTO/Carene
60/ 90/98
81
CST DMS
Sodium Hydrogen
250.8
Heavy Fractions
105.93
83
336.43
Pinene (From
85
GTO)
fuel
Pine tar
(Fluoboric acid)
Spent Phosphoric acid
87
88
86
Layer
Amberfleur
95.0
51.0
109.34
42.29
Recovered Toluene
111.51
89
Column Tops
128.68
90
86.5
91
Column Tops
0.31
92
0.34
93
Column Tops
1.20
2.32
Recovered MPK
11.04
2.32
MI for Soap
Violetone couer
94
95
96
Timber
touch/Timber
forte
82
A-Pinene & B-
party
84
Project Description
registered party
97
Barium hydroxide
1.0
98
Recovered Toluene
3.43
99
Column tops
1.51
100
1.64
101
Recovered Catalyst
0.04
Reuse/Sale to PCB
registered party
Reuse/Sale to PCB
registered party
Sale to PCB registered
party
Sale to PCB registered
party
Sale to PCB registered
party
S.No.
1
2.
By-Products
Spent Phosphoric Acid
Product- Ionones
Tops and bottom
Product- Di hydro myrcenol
Existing
Proposed
(MT/M)
(MT/M)
2.0
38.2
12.0
17.0
10.0
147.3
3.0
41.3
100.0
100.0
Utilization
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
E. Terpinyl Acetate
F.Citronellol
G.Geraniol
H. Geranyl Acetate
I. Citronellyl Acetate
J.Timber Touch
4.
5.
ISO Longifolene
product Longifolene Ketone
Spent Sulphuric Acid
product Dihydromyrcenol
Project Description
Sale to PCB
registered party
Sale to PCB
registered party
2.29
Calcium Sulphate
Products6.
A. Alpha Pinene
75.0
0.0
116.66
116.66
0.0
75.0
0.0
20.0
0.0
90
0.0
165.0
0.0
16.0
0.0
200.0
0.0
50.0
B. Beta Pinene
Sale to PCB
registered party
C. Limonene
Heavy Fractions
products
7.
A. Alpha Pinene
B. Beta Pinene
Sale to PCB
registered party
C. Limonene
8.
9.
10
11
12
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
Sale to PCB
registered party
product
A. PTBCHA
Sale to PCB
registered party
B. OTBCHA
Sodium Acetate
product
A. PTBCHA
B. OTBCHA
14
C. Geranyl Acetate
D. Citronellyl Acetate
Sale to PCB
registered party
E. Terpinyl Acetate
F. Isobornyl acetate
Project Description
2.30
Sr. No
Name of equipment
Reactors- 10 KL
Reactors
Reactor
wash vessels
Distillation Reboiler
Distillation Reboiler
Distillation Reboiler
10
Pre-Heater
11
12
13
Condenser
16
14
Vent condenser
15
Product Cooler
16
17
Day Tank
18
Receivers
20
19
Centrifugal Pump
51
20
Vacuum Trap
21
Ejector
12
22
Blending vessel
23
PYROLYSER
24
BAROMETRIC CONDENSER
25
26
sparkler Filter
27
Pressure Filter
28
Cooling tower
29
Cooling tower
30
Project Description
Units
2.31
No. of
Sr. No
Name of equipment
31
Hot N2 system
32
Air Blower
33
34
Silica Column
35
36
Mixing Reactor
37
38
39
Graphite Condenser
40
41
42
43
44
45
Teflon TVR
46
Metering Pump
Units
BOILER
47
48
Boiler
49
Superheater
50
Transformer
51
Circuit breaker
52
Bus bar
53
54
De-aerator
55
56
57
Chimney
TURBINE
58
Turbine
59
Alternator
60
Exciter
61
Condenser
62
Cooling tower
63
Project Description
2.32
No. of
Sr. No
Name of equipment
64
65
66
Oil cooler
67
68
Mono rail
69
Oil tank
Units
Reboiler
71
72
Evaporator
73
Preheater
74
Main Condenser
75
Vent Condenser
76
Tertairy Condenser
77
78
79
80
Collection Receiver 3
81
Vacuum Trap
82
83
DVP
84
85
Feed Pump
86
Transfer Pump
88
89
Furnace
91
Expansion Tank
92
Coal Crusher
93
Bucket Elevator
94
Screw Feeder
95
Bunker
Project Description
2.33
No. of
Sr. No
Name of equipment
96
Economiser
97
FD Fan
98
99
Cyclon Separator
100
ID Fan
101
102
MS Underground Tank
Units
CARBON COLUMNS
103
104
105
12
106
107
108
Centrifugal pump
109
Metering pump
14
110
Compressor
111
Filter press
112
113
Evaporator
114
115
Main Condenser
116
Vent Condenser
117
Product cooler
118
Storage Tank
119
Feed pump
120
Circulation Pump
Reboiler
122
Column
123
Main Condenser
124
Vent Condenser
125
Product Cooler
126
Receiver
6.0 KL SS Reactor
Project Description
1
2.34
No. of
Sr. No
Name of equipment
128
10.0 KL SS Reactor
129
Metering Pump
130
Pump
131
Receiver
Units
Resin Column
133
Intermediate Receiver
134
Intermediate Receiver
135
Separator
136
137
138
139
140
141
142
143
144
145
DHMOL EXPANSION
146
SS Reactor 6.0 KL
147
148
Storage Tank
149
150
Pumps
151
SS Reactor 6.0 KL
153
154
12
155
156
157
Centrifugal Pump
158
Metering Pump
14
159
Compressor
Project Description
2.35
No. of
Sr. No
Name of equipment
160
Filter Press
161
162
Evaporator
163
164
Main Condenser
165
Vent Condenser
166
Product cooler
167
Storage Tank
168
Feed pump
169
Circulation Pump
170
Reactor - 6.0 KL
171
172
173
12
174
175
176
Centrifugal Pump
177
Metering Pump
14
178
Compressor
179
Filter Press
180
181
Evaporator
182
183
Main Condenser
184
Vent Condenser
185
Product cooler
186
Storage Tank
187
Feed pump
188
Circulation Pump
189
Reactor - 6.0 KL
Units
Stripper Column
191
192
Kettle
193
Primary Condenser
Project Description
2.36
No. of
Sr. No
Name of equipment
194
195
196
Preheater
197
Product Cooler
198
Feed Pump
199
200
Reflux Pump
201
202
Vacuum Pump
203
Vacuum Trap
204
Reflux Tank
205
Collection Tank
206
Units
Distillation Column
208
209
Kettle
210
Primary Condenser
211
212
213
Preheater
214
215
216
Feed Pump
217
218
Reflux Pump
219
220
221
Vacuum Pump
222
Vacuum Trap
223
224
Product receiver
225
226
227
Moisture Seperator
Project Description
2.37
No. of
Sr. No
Name of equipment
228
Distillation Column
229
230
Kettle
231
Primary Condenser
232
233
234
Preheater
235
236
237
Feed Pump
238
239
Reflux Pump
240
241
242
Vacuum Pump
243
Vacuum Trap
244
245
Product receiver
246
247
248
Moisture Seperator
249
Units
251
Centrifugal Pump
252
253
254
255
Reactor - 6.0KL
257
Settler
258
259
Pumps
2.38
No. of
Sr. No
Name of equipment
260
Thermal Oxidizer
261
Spray Dryer
262
Venturi
263
Scrubber
264
Chimney
265
Lime Tank
266
267
268
Pumps
269
Blowers
Units
271
Pumps
Description
Details
01
IUPAC NAME
3-(2,3,3-trimethyl-6-bicyclo[2.2.1]heptanyl)cyclohexan-1-ol
4-(1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl)cyclohexan-1-ol
4-(2,3,3-trimethyl-6-bicyclo[2.2.1]heptanyl)cyclohexan-1-ol
02
CAS NO
3407-42-9,660772-32-0,66068-84-6
03
MT/Month
51 MT
04
MT/Annum
612 MT
Chemical Reaction:
Stage 1:
Project Description
2.39
Stage 2:
Material Balance:
Stage 1:
S.No
Qty
Qty
Camphene
1054
acid)
867
02
Toluene
2713
Effluent
1554
03
BF3 etherate
124
Crude weight
5264
04
Catechol / Guiacol
1457
Total
7685
05
Sodium hydroxide
50
06
Water quenching
698
07
1589
Total
7685
Distillation:
S.No
01
Qty
Qty
Recovered Toluene
2566
Column Tops
643
Stage 1 Mains
1147
791
5264
Distillation Loss
117
5264
Total
Crude Stage 1
Total
5264
Stage 2
S. No
01
Stage 1 Mains
02
03
Qty
Qty
1147
IBCH Crude
1656
Isopropyl alcohol
473
Recovered catalyst
78
Catalyst
78
Hydrogen loss
Project Description
2.40
04
Hydrogen
39
Total
1737
Total
1737
Distillation:
S.No
01
Qty
Qty
Recovered IPA
442
Recovered Methanol
101
Column Tops
54
Product
1000
47
1656
Loss
12
1656
Total
1656
IBCH crude
Total
Manufacturing process:
Stage 1& 2
Camphene reacts Catechol or Guiacol in presence of Lewis acid gives Camguiol Crude, distilled
to give Intermediate (Camguiol) which on hydrogenation (Stage 2) in presence of catalyst gives
IBCH crude and Methanol and distilled to give IBCH product.
Project Description
2.41
Description
Details
01
IUPAC NAME
2-Methyl-5-(1-methylethenyl)-2-cyclohexenone
02
CAS No
6485-40-1
03
MT/Month
50 MT
04
MT/Annum
600 MT
Project Description
2.42
Chemical Reaction
Stage 1:
Stage 2:
Stage 3:
Material Balance:
Stage 1
S. No
Qty
Qty
01
D-Limonene
2142
Effluent
3790
02
Cyclohexane
643
3027
03
1092
Total
6817
04
PTC
86
05
Catalyst ST
64
06
Phosphoric acid
21
07
Sodium Hydroxide
21
08
Catalyst PBS
57
09
Sodium Sulphite
214
10
1292
Project Description
2.43
11
1185
Total
6817
Distillation:
S. No
Qty
Limonene epoxide
crude
3027
Total
Qty
Recovered cyclohexane
600
2210
164
Distillation Loss
53
Total
3027
3027
Stage 2
S. No
Qty
Qty
2142
D-Carveol crude
2350
AP Catalyst
104
Total
2350
Catalyst ZO
104
Total
2350
Distillation:
S. No
D-Carveol crude
Qty
2350
Total
Qty
Recovered D-Limonene
413
Column Tops
191
D-Carveol Mains
1349
349
Distillation Loss
48
Total
2350
2350
Stage 3
S.No
Qty
01
Qty
Spent Aq Layer
(Aluminium Sulphate
D-Carveol
1349
+IPA)
1893
02
Aluminium Isopropoxide
446
Effluent
1079
03
2699
MEK+Butanol rec
2664
Project Description
2.44
04
30 % Sulphuric Acid
768
L-Carvone crude
1349
05
675
Total
6985
06
1010
07
Salt
38
Total
6985
Distillation:
S. No
Qty
L-Carvone crude
Qty
Column Tops
211
L-Carvone Mains
1000
107
Distillation Loss
31
Total
1349
Total
1349
1349
Manufacturing Process
Stage1:
D-Limonene (Distilled from Orange oil) undergoes epoxidation with Hydrogen peroxide gives
Crude D-Limonene epoxide crude which subjected to Distillation gives D-Limonene epoxide
product
Stage 2:
D-Limonene epoxide undergoes rearrangement to D-Carveol crude which subjected to distillation
gives D-Carveol.
Stage 3:
D-Carveol undergoes Oxidation in presence of Aluminium Isopropoxide and Methyl Ethyl Ketone
gives L-Carvove crude, which subjected to distillation, gives L-Carvone Product
Project Description
2.45
Description
Details
IUPAC NAME
------
MT/Month
MT/Annum
Chemistry
Orange oil is a mixture of D-Limonene and Other aldehydes and alcohols. Major componenet is DLimonene and rest is aldehydes and traces of alcohols.
Distillation of Orange oil gives D-Limonene and rest fraction blending gives Orange oil folds.
Project Description
2.46
Material Balance
Distillation:
S. No
Orange oil
Total
Qty
1105
Qty
D-LIMONENE
1000
94
Distillation loss
11
Total
1105
1105
Figure 2.7: Process Flow diagram for Manufacturing of D-Limonene and Orange Oil Folds
Project Description
2.47
Description
Details
IUPAC NAME
7-Methyl-3-methylene-1,6-octadiene
CAS.No
123-35-3
MT/Month
400
MT/Annum
4800
Chemical Reaction
Material Balance
Distillation:
S.
Qty
Qty
Myrcene
1000
Bottom mass
4.5
Vapour loss
2.5
Total
1007
No
Beta Pinene
Total
1007
1007
Project Description
2.48
Manufacturing Process
Beta- Pinene undergoes rearrangement (By thermolysis) at high temperature gives Myrcene.
Description
Details
01
IUPAC NAME
2-Iso-butyl-4-hydroxy-4-methyltetrahydropyran
02
CAS No
63500-71-0
03
MT/Month
80 MT
04
MT/Annum
960MT
Chemical Reactions
Project Description
2.49
Material Balance:
S.No
Qty
Qty
Isovaleraldehyde
748
Effluent
126
Sulphuric acid
22
Floreol crude
1869
Isoprenol
822
Total
1995
EDC
299
Water
75
Sodium Hydroxide
29
Total
1995
Distillation:
S.No
Floreol crude
Total
Qty
1869
1869
Qty
EDC recovered
284
Column tops
108
DHP
351
Floreol product
1000
93
Loss
33
Total
1869
Manufacturing Process:
Cycloaddition of Isovaleraldehyde and Isoprenol in presence of acid gives Floreol crude which
subjected to distillation gives Floreol product.
2.50
Description
Details
IUPAC NAME
1-(2,2,3-trimethyl-1-cyclopent-3-enyl)ethanone
CAS No
4501-58-0 , 42370-35-4
MT/Month
50 MT
MT/Annum
600 MT
Chemical Reactions
Stage 1 & Stage 2
Material Balance:
Stage 1
S.No
Qty
Qty
01
alpha pinene
1156
Effluent
1419
02
772
1335
03
Catalyst ST
75
Total
2754
04
18
05
PTC
92
06
Catalyst PBS
28
07
29
08
Water quenching
116
09
462
10
Salt
Total
2754
Distillation:
S.No
A-Pinene epoxide
crude
Qty
1335
Qty
Recovered A-Pinene
66
1137
111
Loss
21
Total
1335
Project Description
2.51
Total
1335
Stage 2
S.No
Qty
Qty
A-Pinene epoxide
1137
3410
Toluene
2274
Effluent
341
Catalyst
22
Total
3751
Water
318
Total
3751
Qty
Qty
Recovered Toluene
2205
Column Tops
84
A-Campholenic Aldehyde
1000
86
Loss
35
Total
3410
Distillation
S.No
1
A-Campholenic
aldehyde crude
Total
3410
3410
Manufacturing Process:
Stage1:
Alpha- Pinene undergoes epoxidation with Hydrogen peroxide gives Crude A-Pinene epoxide
crude which subjected to Distillation gives A-Pinene epoxide product
Stage 2:
A-Pinene epoxide undergoes rearrangement to gives Alpha-Campholenic aldehyde crude which
subjected to distillation gives Alpha-Campholenic aldehyde.
Project Description
2.52
Description
Details
IUPAC NAME
5-Isopropenyl-2-methyl-2-cyclohexenone
CAS No
2244-16-8
MT/Month
5 MT
MT/Annum
60 MT
Project Description
2.53
Chemical Reactions
Stage 1
Stage 2
Stage 3
Material Balance:
Stage 1
S.No
Qty
Qty
L-Limonene
2142
Spent Aq.Layer
2345
Cyclohexane
643
Effluent
2038
1092
3027
PTC
86
Total
7410
Catalyst ST
64
Phosphoric acid
21
Sodium Hydroxide
14
Catalyst PBS
57
Sodium Sulphite
214
Project Description
2.54
10
1292
11
1785
12
Total
7410
Distillation:
S.No
L-Limonene epoxide
Qty
3027
crude
Total
Qty
Recovered cyclohexane
600
2210
164
Distillation Loss
53
Total
3027
3027
Stage 2
S.No
L-Limonene Epoxide
Mains
Qty
2142
AP catalyst
104
Catalyst ZO
104
Total
2350
Qty
L-Carveol crude
2350
Total
2350
Distillation:
S. no
L-Carveol crude
Qty
2350
Total
Qty
Recovered D-Limonene
413
Column Tops
191
L-Carveol Mains
1349
349
Distillation Loss
48
Total
2350
2350
Stage 3
S.No
1
L-Carveol
Qty
1349
Project Description
Qty
1907
2.55
Sulphate +IPA)
2
Aluminium Isopropoxide
446
Effluent
1443
MEK
2699
MEK+Butanol rec
2661
30 % Sulphuric Acid
768
D-Carvone crude
1349
675
Total
7360
1384
Salt
39
Total
7360
Distillation:
S.No
Qty
D-Carvone crude
Qty
Column Tops
211
D-Carvone Mains
1000
107
Distillation Loss
31
Total
1349
1349
Total
1349
Manufacturing Process:
Stage1:
L-Limonene undergoes epoxidation with Hydrogen peroxide gives Crude L-Limonene epoxide
crude which subjected to Distillation gives L- Limonene epoxide product
Stage 2:
L-Limonene epoxide undergoes rearrangement to gives L-Carveol crude which subjected to
distillation gives Carveol.
Stage 3:
Carveol undergoes Oxidation in presence of Aluminium Isopropoxide and Methyl Ethyl Ketone
gives D-Carvove crude, which subjected to distillation, gives D-Carvone Product.
Project Description
2.56
Description
Details
IUPAC NAME
2-Methyl-5-prop-1-en-yl cyclohexan-1-one
CAS No
7764-50-3
MT/Month
5 MT
MT/Annum
60 MT
Project Description
2.57
Chemical Reactions
Stage 1
Stage 2
Material Balance
Stage 1
S. No
D/L-Limonene
Qty
2071
Spent Aq.Layer
1944
Cyclohexane
533
Effluent
1837
905
2509
PTC
71
Total
6290
Catalyst ST
53
Phosphoric acid
18
Sodium Hydroxide
12
08
CATALYST PBS
47
09
Sodium Sulphite
178
10
1071
11
1331
Total
Qty
6290
Project Description
2.58
Distillation:
S. No
Limonene epoxide
Qty
2509
Crude
Total
Qty
Recovered cyclohexane
497
1831
136
Distillation Loss
44
Total
2509
2509
Stage 2
S.No
Qty
Qty
1831
Dihydrocarvone crude
5494
Perchloric acid
Effluent
933
3663
Total
6427
Caustic solution
21
Salt
21
888
Total
6427
Distillation:
S.No
Dihydrocarvone
Qty
5494
crude
Total
5494
Qty
Recovered EDC
3473
Column Tops
269
Dihydrocarvone Mains
1000
453
Distillation Loss
299
Total
5494
Manufacturing Process:
Stage1:
D/L-Limonene undergoes epoxidation with Hydrogen peroxide gives Crude D-Limonene epoxide
crude which subjected to Distillation gives Limonene epoxide product
Project Description
2.59
Stage 2:
Limonene epoxide undergoes rearrangement to Dihydrocarvone crude which subjected to
distillation gives Dihydrocarvone
Project Description
2.60
Description
Details
IUPAC NAME
2-Methyl-5-propan-2yl-cyclohexanone or 5-Isopropyl-2methylcyclohexanone
CAS No
MT/Month
5 MT
MT/Annum
60 MT
Chemical Reactions:
Stage 1
Stage 2
Stage 3
Project Description
2.61
Material Balance:
Stage 1
S. No
Qty
Qty
Limonene
2164
Recovered catalyst
3278
IPA
1082
1-p-Menthene Crude
11
Catalyst
11
Total
3289
Hydrogen
32
Total
3289
Distillation:
S.No
Qty
Qty
Recovered IPA
1039
Column tops
287
1-p-Menthene
1855
65
3278
Distillation loss
32
3278
Total
3278
1-p-Menthene
Crude
Total
Stage 2
S.No
1-p-menthene
Qty
Qty
1855
Spent Aq.Layer
2237
Cyclohexane
278
Effluent
1141
1299
2325
PTC
74
Total
5703
Catalyst ST
56
Phosphoric acid
19
Sodium Hydroxide
CATALYST PBS
37
Sodium Sulphite
37
10
928
11
1113
Total
5703
Project Description
2.62
Distillation:
S.No
p-Menthane epoxide
Crude
Total
Qty
2325
2325
Qty
Recovered cyclohexane
271
Column tops
232
1646
161
Distillation Loss
15
Total
2325
Stage 3
S.No
Qty
Qty
1646
Carvomenthone crude
4495
Perchloric acid
17
Effluent
961
Cyclohexane
2848
Total
5456
Caustic solution
11
Salt
928
Total
5456
Distillation:
S.No
Carvomenthone
crude
Total
Qty
4495
4495
Qty
Recovered Cyclohexane
2776
Column Tops
310
Carvomenthone
1000
312
Distillation Loss
97
Total
4495
Manufacturing Process:
Stage1:
Limonene undergoes hydrogenation in presence of catalyst to give 1-Para-Menthene crude,
which subjected to distillation gives 1-para-Menthene.
Project Description
2.63
Stage2:
1-P-Menthene undergoes epoxidation with Hydrogen peroxide to give Crude 1-P-Menthane
epoxide crude which subjected to Distillation gives 1-p-Menthane epoxide product
Stage 3:
1-p-menthane epoxide undergoes rearrangement to give Carvomenthone crude which
subjected to distillation gives Carvomenthone product.
Project Description
2.64
Description
Details
IUPAC NAME
1-(2,2,6-Trimethyl Cyclohexyl)-hexan-3-ol
CAS No
70788-30-6
MT/Month
01 MT
MT/Annum
12 MT
Chemical Reactions:
Stage 1A
Stage 1B
Stage 2
Stage 3
Project Description
2.65
Material Balance
Stage 1A
S.No
Qty
Qty
01
Citronellal
1806
3847
02
Acetic anhydride
2393
Effluent
1651
03
Triethylamine
1185
6605
04
Sodium acetate
181
Total
12103
05
Toluene
3612
06
soda ash
27
07
1445
08
1445
09
Salt
Total
12103
Stage 1B
S.No
Qty
Qty
01
6605
484
02
452
3794
03
Soda ash
27
DCC crude
5109
04
Sodium chloride
181
Effuent
948
05
2167
Total
10335
06
903
Total
10335
Distillation:
S.No
DCC crude
Total
Qty
5109
Qty
Recovered Toluene
3435
Column Tops
128
DCC Mains
1279
143
Distillation loss
124
Total
5109
5109
Project Description
2.66
Stage 2
S.No
Qty
Qty
01
DCC mains
1279
Recovered MPK
2507
02
MPK
3180
1621
03
Sodium methoxide
128
Effluent
752
04
Acetic acid
131
DNEI Crude
1833
05
Sodium chloride
57
Loss
29
06
1311
Total
6742
07
656
Total
6742
Distillation:
S.No
DNEI crude
Qty
1833
S
t
Total
Qty
Column Tops
348
DNEI Mains
1195
261
Distillation loss
29
Total
1833
1833
a
Stage 3
S.No
Qty
Qty
01
DNEI mains
1195
Recovered catalyst
11
02
Hydrogen
26
Nimberol Crude
1216
03
Catalyst
11
Hydrogen loss
Total
1232
Total
1232
Qty
Qty
Column Tops
134
Nimberol Mains
1000
74
Distillation loss
Total
1216
Distillation:
S.No
Nimberol crude
Total
1216
1216
Project Description
2.67
Manufacturing Process:
Stage1A:
Citronellal reacts with acetic anhydride in presence of Triethyl amine and Toluene as solvent gives
Citronellyl Diacetate crude
Stage1B:
Citronellyl diacetate undergoes cyclisation in presence of Phosphoric acid followed by hydrolysis
gives acetic acid and Dihydrocyclocitral crude which on distillation gives Dihydrocyclocitral
product
Stage 2:
Dihydrocyclocitral product undergoes condensation with MPK in presence of base catalyst gives
DNEI crude which subjected to distillation gives DNEI mains.
Stage 3;
Hydrogenation of DNEI gives Nimberol crude which subjected to distillation gives Niberol product
Project Description
2.68
Project Description
2.69
Description
Details
IUPAC NAME
3,7-dimethylocta-1,6-diene
CAS No
2436-90-0
MT/Month
150 MT
MT/Annum
1800 MT
Chemical Reactions:
Stage 1
Stage 2
Material Balance
Stage 1
S.No
Qty
Qty
01
Alpha-Pinene
1347
Recovered catalyst
02
Hydrogen
20
Cis-Pinane Crude
1367
03
Catalyst
Total
1368
Total
1368
Stage 2
S.No
01
Cis-Pinane
Qty
1367
Qty
DHM crude
1362
Loss
Project Description
2.70
Total
1367
Total
1367
Distillation:
S.No
DHM crude
Total
Qty
1362
Qty
Column Tops
130
DHM Mains
1000
215
Loss
17
Total
1362
1362
Manufacturing Process:
Alpha-Pinene undergoes hydrogenation in presence Hydrogen and catalyst to give Cis-Pinane.
Cis-Pinane undergoes rearrangement (by pyrolysis) at high temperature to Diydromyrcene(DHM)
crude which is subjected to distillation gives Dihydromyrcene (DHM) mains
Project Description
2.71
Description
Details
IUPAC NAME
CAS No
28219-61-6
MT/Month
20 MT
MT/Annum
240 MT
Chemical Reactions:
Stage 1
Stage 2
Material Balance
Stage 1
S.No
Qty
Qty
01
A-Campholenic aldehyde
1136
Recovered Cyclohexane
1441
02
Butyraldehyde
788
Spent Aq.Layer
672
03
Cyclohexane
1491
Effluent
706
04
Catalyst A
149
CABAL Crude
1824
05
Acetic acid
119
Loss
37
06
30 % HCl
119
Total
4680
07
Soda ash
26
08
284
09
568
Total
4680
Project Description
2.72
Distillation:
S.No
CABAL crude
Total
Qty
1824
Qty
Column Tops
497
Cabal Mains
1143
150
Distillation Loss
34
Total
1824
1824
Stage 2
S.No
Qty
Qty
01
Cabal mains
1143
Recovered methanol
2152
02
Sodium borohydride
76
Effluent
1790
03
Sodium hydroxide
10
1173
04
Acetic acid
152
Total
5115
05
Methanol
2286
06
Soda ash
19
07
Water quenching
381
08
1048
Total
5115
Distillation:
S.No
Total
Qty
1173
Qty
Column Tops
69
1000
84
Distillation Loss
20
Total
1173
1173
Project Description
2.73
Manufacturing Process:
A-Campholenic aldehyde undergoes aldol reaction with Butyraldehyde in presence of weak
base to and Cyclohexane as solvent gives CABAL crude which is subjected to distillation give
CABAL mains.
Reduction of CABAL mains by using Sodium Borohydride in presence of methanol and water gives
Sandal fleur crude which is subjected to distillation gives Sandal fleur Products.
Figure 2.16: Process Flow diagram for manufacturing of Sandal Fleur & Derivatives
Project Description
2.74
Description
Details
IUPAC NAME
5-2,2,3-Trimethyl-3-cyclopentenyl)-3-methylpentan-2-ol
CAS No
65113-99-7
MT/Month
05 MT
MT/Annum
60 MT
Chemical Reactions:
Stage 1
Stage 2:
Material Balance:
Stage 1
S.No
Qty
Qty
01
A-Campholenic aldehyde
1340
Recovered MEK+Methanol
9139
02
MEK
1005
1303
03
Methanol
8780
Effluent
2332
04
Soda ash
13
CAMEK Crude
1702
05
Salt
67
06
Acetic acid
322
Total
14476
07
Potassium Hydroxide
268
08
670
09
Water
2011
Total
14476
Project Description
2.75
Distillation:
S.No
CAMEK Crude
Total
Qty
1702
Qty
Column Tops
265
CAMEK Mains
1214
190
Distillation loss
33
Total
1702
1702
Stage 2
S.No
Qty
Qty
01
Camek
1214
40
02
2-butanol
729
Crude
1975.33
03
Copper chromite
40
Total
2015.33
04
Hydrogen
32
05
Methanol
0.3
06
soda ash
0.03
Total
2015.33
Distillation:
S.No
Total
Qty
1975.33
Qty
Recovered 2 -butanol
689
ColumnTops
166
1000
91.33
Distillation loss
29
Total
1975.33
1975.33
Manufacturing Process:
A-Campholenic aldehyde undergoes aldol condensation with MEK in presence of base and
Methanol as solvent to give CAMEK crude which is subjected to give CAMEK mains.
CAMEK mains undergoes hydrogenation in presence of catalyst and 2-Butanol as solvent to give
Sandal Touch crude which is subjected to distillation to give Sandal Touch product
Project Description
2.76
Description
Details
IUPAC NAME
3,7-DIMETHYL-2,6-OCTADIENAL
CAS No
5392-40-5
MT/Month
30 MT
MT/Annum
360 MT
Material Balance:
Stage 1
S.No
Qty
Qty
01
Citral
1000.1
1000
Loss
0.1
Total
1000
Total
1000.1
Project Description
2.77
Manufacturing Process:
Citral is purged with Nitrogen to improve the odour & filtered to get Citral extra pure .
Figure 2.18: Process Flow diagram for manufacturing of Citral extra Pure
2.10.15. Citronellal Capacity 20 MTPM
S. No
Description
Details
IUPAC NAME
3,7-DIMETHYL-2,6-OCTADIENAL
CAS No
106-23-0
MT/Month
20 MT
MT/Annum
240 MT
Chemical Reactions:
Project Description
2.78
Material Balance:
Stage 1
S No
Qty
Qty
01
Citral
1379
Catalyst recovered
11
02
Catalyst
11
CAL Crude
1414
03
Hydrogen
23
Total
1425
04
Methanol
10
05
soda ash
Total
1425
Distillation:
S.No
CAL Crude
Total
Qty
1414
Qty
Column Tops
294
Citronellal Product
1000
90
Distillation loss
30
Total
1414
1414
Manufacturing Process:
Citral undergoes hydrogenation gives Citronellal crude which is subjected to distillation gives
Citronellal products.
Project Description
2.79
Description
Details
IUPAC NAME
Cyclocitral
CAS No
432-25-7
MT/Month
02 MT
MT/Annum
24 MT
Chemical Reactions:
Stage 1
Stage 2
Aniline recovery:
Project Description
2.80
Material Balance
Stage 1
S.No
Qty
Qty
01
Citral
1694
Effluent
208
02
Aniline
1093
Anitral Crude
4765
03
Cyclohexane
2186
Total
4973
Total
4973
Stage 2
S. No
01
Anitral crude
Qty
Qty
4765
15885
solution)
02
Cyclohexane
13579
Effluent
3862
03
Sulphuric acid
5956
Cyclocitral crude
17175
04
8934
Total
36922
05
soda ash
273
06
3415
Total
36922
Distillation:
S.No
Qty
Cyclocitral crude
17175
Total
17175
Qty
Recovered cyclohexane
15290
Column Tops
251
Cyclocitral product
1000
454
Distillation loss
180
Total
17175
Qty
Qty
01
15885
Aniline recovered
984
02
Liq Ammonia
8743
23644
Total
24628
Total
24628
Project Description
2.81
Manufacturing Process:
Citral reacts with aniline forms adduct (Anitral), which undergoes cyclisation and hydrolysis gives
Cyclocitral (A & B) and Aniline sulphate.
Aniline sulphate neutralized with liquid ammonia gives Aniline and Ammonium sulphate.
Description
Details
IUPAC NAME
ISOCITRONELLENE;Einecs 285-035-1;(R)-5,7-dimethylocta1,6-diene;R(+)-5,7-DIMETHYL-1,6-OCTADIENE
CAS No
85006-04-8
MT/Month
30 MT
MT/Annum
360 MT
Project Description
2.82
Material Balance:
Stage 1
S. No
Qty
Qty
01
DHMOL tops
309
Mixture blend
1077
02
DHM tops
279
Total
1077
03
489
Total
1077
Distillation:
S.No
Mixture blend
Total
Qty
1077
Qty
Column Tops
35
1000
25
Distillation loss
17
Total
1077
1077
Manufacturing Process:
Isocitronellene Isomer is prepared from Blending of DHMOL tops (contains small qty of DHMOL,
other terpenes) and DHM tops & Bottom mass also contains Isocitronellene & other terpenes. The
bled is distilled to remove tops & other fractions are blended to get Isocitronellene Isomer.
Figure 2.21: Process Flow diagram for manufacturing of Isocitronellene & Isomer
Project Description
2.83
Description
Details
IUPAC NAME
3,7-Dimethyl-6-octenenitrile
CAS No
51566-62-2
MT/Month
30 MT
MT/Annum
360 MT
Chemical Reactions:
Stage 1
Stage 2
Material Balance:
Stage 1
S.No
Qty
Qty
01
Citronellal
1304
2915
02
761
Effluent
701
03
Soda ash
761
Carbon dioxide
158
04
Sodium chloride
49
1492
05
1739
06
652
Total
5266
Total
5266
Project Description
2.84
Stage 2
S. No
Qty
Qty
01
1492
CN rapid mains
1120
02
Caustic soda
22
293
03
white oil
92
151
Loss
42
Total
1607
Total
1607
Distillation:
S. No
CN rapid mains
Total
Qty
1120
Qty
Column Tops
43
1000
53
Distillation loss
24
Total
1120
1120
Manufacturing Process:
Citronellal reacts with Hydroxylamine sulphate in presence of Sodium carbonate gives CAL Oxime
crude. CAL oxime undergoes dehydration in presence of Sodim hydroxide at particular
temperature gives Citronellyl nitrile which is subjected to distillation gives Citronellyl nitrile.
2.85
2.10.19. A-Pinene & B-Pinene & Limonene & Mixed Terpenes or DDTO/Carene 60 / Carene
90/Carene98/ Terpene biofuel (From CST crude) 1611.66 & 504.86 &41.32 & 744 or 679.15
Capacity MTPM
S. No
Description
Details
IUPAC NAME
Mixture
CAS No
Mixture
Brief description:
CST is collected as by-product from pine wood based paper mills. Various paper mills collect the
separated oil during its pulp making and store in the tanks for disposal.
Depending on the season, nature and species of wood the composition of the oil varies quite a bit
in its Alpha & Beta Pinene & Other Terpenes content and also in its impurity levels. It contains very
small amount of dissolved & volatile sulfides like Dimethyl Sulfide and Dimethyl Disulfide etc.
CST contain different sulfurous impurities and it is essential to remove these impurities totally (as low
as 1 ppm) because the Alpha & Beta Pinene are further processed for hydrogenation and are
used to make perfumery ingredients.
Continuously sulphur compounds removed from Stripper column (C1) lower sulfides like Dimethyl
sulphide etc collected & sold as CST DMS or Stripper vapour passed to Incinerator followed by
scrubber which is burnt immediately and subsequent scrubbing after heat recovery of the gases.
The generated Sulphur dioxide gas absorbs in scrubber which contains Lime (Calcium
hydroxide)/Sodium hydroxide solution to form Calcium sulphate / Sodium sulphate .
The stripped CST called TCST is cooled & treated with Sodium hydroxide solution & Stored in
storage tank for further processing.
TCST crude is feed to C2 Column (A-Pinene) from top A-Pinene collected & from bottom Beta -450
collected (B-Pinene, Carene, limonene etc) & stored in tank for further purification.
Beta-450 is feed to C3 column from top B-Pinene collected & from bottom Limonene 350
collected ( Carenes ,limonene & other terpenes) & stored in tank for further processing.
Mixed Terpenes is feed to distillation column & to get DDTO (Mixture of Carene, limonene & other
terpenes), further purification to get Carene 60/Carene90
Treatment
A-Pinene treatment to remove sulphur below 1PPM,1st process A-Pinene treated with Zinc chloride
, cooled washed with caustic solution & feed to Silica column followed by charcoal column &
stored for further processing.
B-Pinene & Mixed Terpenes
cooled, washed & crude feed to distillation column to get Beta-Pinene product & DDTO/Carene
60 / Carene 90 /98/Terpene biofuel product.
Project Description
2.86
Material Balance:
CSTCRUDEPROCESSING
CSTDMS
OR
118.67 Kg/hr Tops
CSTCrude
Incinerator
Scrubber
SprayDryer
Alkaliwashing
10.45
Kg/hr Columntops
4118.53 Kg/hr
Column
Causticsolution
Water
BPinenecrude
Distillation
72.18
333.25
16946.06
Kg
Kg
Neutralisation
Distillation
16946.06
Kg
BPinenecrude
1236.70
Kg
Aq.layerusedforScrubber
45.01
16828.69
67.08
5.28
Kg
Kg
Kg
Kg
ColumnTops
BPinene
Columnbottommass
DistillationLoss
Project Description
2.87
APineneTreatment(Sulphurreduction)
APinene(32PPM) 53755.97
ZnCl2
213.26
Kg
Kg
20%Causticsoltion
Kg
721.00
Sulphur
reduction
Reactor
Neutralisation
Silicacolumn
Charcoal
column
53755.71
934.52
Kg
Kg
APinene
ZincHydroxidesolution
RegenerationofSilica&CharcoalColumnbyUsingNitrogen
Nitrogen
320 m3/M
Silica/Charcoal
Column
Project Description
2.88
MixedTerpenesTreatment(Sulphurreduction)
MixedTerpenes
H2O2
24801.15
1407.83
Kg
Kg
Causticsolution
112.62
Kg
Water
623.95
Kg
24801.15
Kg
MixedTerpenescrude
Sulphur
reduction
Reactor
Neutralisation
Distillation
24801.15 Kg MixedTerpenescrude
2144.41 Kg Aq.layerusedforScrubber
22638.34
DDTO/Carene60/90/98
1377.20 Kg Limonene
742.11 Kg ColumnBottommass
43.38 Kg DistillationLoss
Description
Details
IUPAC NAME
2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene &
BICYCLO[3.1.1]HEPTANE; 6,6-DIMETHYL-2-METHYLENE
CAS No
MT/Month
MT/Annum
Material Balance:
Stage 1
S.No
01
Qty
1033
1033
Project Description
2.89
Distillation:
S.No
GTO
Total
Qty
1033.0
1033.0
Qty
A-Pinene
537
B-Pinene
334
Dipentene
95
Pine tar
51
Distillation Loss
16
Total
1033
Manufacturing Process:
Gum turpentine oil is a mixture of alpha-Pinene, beta-Pinene and mixture of Dipentene (mixture of
Limonene, Terpinolene, other Terpenes) subjected to distillation gives Alpha-Pinene, and Betapinene and Dipentene and Pine tar.
Figure 2.23: Process Flow diagram for manufacturing of A-Pinene & B-Pinene
2.10.21. Methyl Ionone (MI) FOR SOAP Capacity 01 MTPM
S. No
Description
Details
IUPAC NAME
1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one
CAS No
1335-46-2
MT/Month
01MT
MT/Annum
12 MT
Project Description
2.90
Material Balance:
Stage 1
S. No
Qty
01
NMI crude
2513
Total
2513
Distillation:
S.No
NMI crude
Total
Qty
2513
2513
Qty
Column Tops
156
NMI
1131
1000
171
Distillation loss
55
Total
2513
Manufacturing Process:
NMI crude or MI crude subjected to distillation gives NMI product / MI product along with Methyl
Ionone for soap (MI for Soap) product.
Figure 2.24: Process Flow diagram for manufacturing of Methyl Ionone (MI)
Project Description
2.91
Description
Details
IUPAC NAME
4-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-3-buten-2-one
CAS No
127-51-5
MT/Month
02 MT
MT/Annum
24 MT
Material Balance:
Stage 1
S. No
Qty
01
GMI crude
20000
Total
20000
Distillation:
S. No
GMI crude
Total
Qty
20000
20000
Qty
Column Tops
600
Violetene couer
1000
GMI mains
16800
1160
Distillation loss
440
Total
20000
Manufacturing Process:
GMI crude subjected to distillation gives GMI product along with Viletone couer product (High
Gamma methyl Ionone percentage)
Project Description
2.92
Description
Details
IUPAC NAME
(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2naphthalenyl)-ethan-1-one
CAS No
54464-57-2
MT/Month
400 MT
MT/Annum
4800 MT
Chemical Reaction:
Manufacturing Process:
Stage1:
Myrcene undergoes Diels-Alder reaction with MPO gives PCM crude which subjected to Distillation
gives PCM product (Intermediate)
Project Description
2.93
Stage 2:
PCM product undergoes cyclisation in presence of acid catalyst gives Amberfleur crude which
subjected to distillation gives Amberfluer.
Note;
Amber fleur product is manufactured at Unit 1, blending, packing and sale (dispatch) from uint -2.
So no production activity of Amberfleur on plot no. C-3/4/5/6, 6/1, 8, 9 and C33/1, X-9, X-10, X-11
hence no water input / effluent is generated.
Material Balance:
Stage 1
S. No
01
Qty
Qty
919
(Fluoboric acid)
02
MPO
672
Effluent
1350
03
PCM crude
1571
04
Salt
05
Antioxidant
06
07
1308
Total
3194
57
273
Total
3194
230
Distillation:
S. No
Qty
PCM Crude
1571
Total
Qty
PCM Tops
283
PCM Mains
1099
Column Bottom
161
Distillation loss
28
Total
1571
1571
Stage 2
S.No
Qty
Qty
01
PCM Mains
1099
Amberfleur crude
1388
02
Toluene
290
106
03
Phosphoric acid
105
Effluent
1004
04
Water
989
Total
2498
Project Description
2.94
05
Caustic soda
11
06
Salt
Total
2498
Distillation:
S. No
AF crude
Total
Qty
1388
Qty
Recovered Toluene
279
Column Tops
39
Amberfleur
1000
Column Bottom
56
Loss
14
Total
1388
1388
Project Description
2.95
Description
Details
IUPAC NAME
1-(2,2,6-Trimethyl Cyclohexyl)-hexan-3-ol
CAS No
70788-30-6
MT/Month
05 MT
MT/Annum
60 MT
Chemical Reactions:
Stage 1
Stage 2
Stage 3
Material Balance
Stage 1
S.No
Qty
Qty
01
Citral
1152
Recovered MPK
2209
02
MPK
2879
Effluent
1243
03
Barium Hydroxide
138
NPEI crude
1659
Project Description
2.96
04
Acetic acid
40
Loss
21
05
water
921
Total
5132
06
Sodium chloride
07
Total
5132
Distillation:
S.No
Qty
NPEI crude
1659
Total
Qty
Column Tops
160
NPEI Mains
1288
178
Distillation loss
33
Total
1659
1659
Stage 2
S.No
Qty
Qty
01
NPEI
1288
463
02
Phosphoric acid
454
NEI crude
2009
03
Toluene
719
Effluent
892
04
Soda ash
17
Total
3364
05
Water
884
06
Salt
Total
3364
Distillation:
S.No
NEI crude
Total
Qty
2009
2009
Qty
Recovered toluene
687
Column Tops
73
NEI Mains
1158
53
Distillation loss
38
Total
2009
Project Description
2.97
Stage 3
S.No
Qty
Qty
01
NEI mains
1158
Recovered catalyst
7.4
02
Hydrogen
03
33
Catalyst
Hydrogen loss
Total
1198
Total
1189
1.6
1187
Distillation:
S.No
Total
Qty
1189
Qty
Column Tops
70
1000
97
Distillation loss
22
Total
1189
1189
Manufacturing Process:
Stage1A:
Citral reacts with MPK in presence of base gives NPEI crude which on distillation gives NPEI mains
Stage1B:
NPEI undergoes cyclisation in presence of Phosphoric acid gives NEI crude which on distillation
gives NEI mains
Stage 3;
Hydrogenation of NEI gives Timber touch / Timber forte crude which subjected to distillation gives
Timber touch / Timber forte product
Project Description
2.98
Figure 2.27: Process Flow diagram for manufacturing of Timber touch / Timber forte
to
63.13
m3/day.
As
per
Existing
Consent
Alcohol
group
products
are
Project Description
2.99
Material Balance:
Stage1
S. No
Qty
Qty
01
Dihydromyrcene
1152
1385
02
Sulphuric acid 70 %
03
Ferrous Sulphate
DHMOL crude
1192
04
Emulifier
Total
3018
05
730
06
230
07
691
Effluent
441
211
3018
Distillation:
S. No
Qty
DHMOL Crude
1192
Total
Qty
Column Tops
118
DHMOL Mains
1000
Column Bottom
58
Distillation loss
16
Total
1192
1192
Note:
1).Spent Sulfuric acid will send for in-house concentration process (discussed in 2.13) .
2). Water wash & Neutralized resin column effluent will send to Effluent treatment.
2.12 BRIEF PROCESS DESCRIPTION: RECOVERY OF CONCENTRATED SULFURIC ACID AT PLOT NO.
C33/1, X-9, 10, 11
Spent Sulfuric acid (27%) will be utilize to generate 70% concentrated sulfuric acid through multiple
effect evaporation system. 27% Spent Sulfuric acid will be generate from DHMOL process plant.
This spent acid is taken to the day tank of capacity 50 KL. The spent acid is already contains some
impurities, which is removed by passing it from the resin columns. The resin is regenerated by
methanol which is further distillate for recovery and reuse. The recovered methanol will be store in
a tank of capacity 05KL for reuse.
The recovered colorless dilute acid will be store in polish tank of capacity 15 KL and further transfer
to the feed tank (50 KL). The dilute acid then goes to the multiple effect evaporation system
Project Description
2.100
where water gets evaporated and collected into a tank (50KL) for recycling in DHMOL process
plant and 70% concentrated sulfuric acid collected in a tank of capacity 50 KL and transfer to
DHMOL plant for hydration system. During the whole process no effluent is generated, the water
separated from dilute sulfuric acid is recycle back to the process utilization.
Table 2.8 Details and Quantity of Sulfuric acid
S.no.
Description
Quantity (Kg/day)
1.
36250
2.
9788
3.
26463
4.
13594
5.
3806
6.
22656
Parameters
Standards
Unit
1.
2000
LPH
2.
Steam Inlet
4.0
Kg/cm2
3.
System Vacuum
700
mm of Hg
4.
750
LPH
5.
1250
LPH
6.
1200 (each)
LPH
7.
Cooling Tower
200
TR
Project Description
2.101
Project Description
2.102
Sr.
No.
1
*2
Domestic
Industrial
Processing
Existing as
Current
per consent
Actual
40
Proposed
Total
40
190
190
468
Proposed
Total
28
35
83.0
75
84.0
686.2
24.0
18
21
11
0#
240.2
927.2
135.0
121
19
140
consent
actual
49
28
192
468
218.2
24
24
722
722
Industrial
3
Cooling
& Boiler
Feed
Agricultural
/
gardening
Total
Note:
* No major increase in water consumption and effluent generation of industrial processing though
new addition of products as we are going to use resin technology in process instead of water
wash.
@ Boiler & cooling tower effluent generation reduced due to the use of demineralization plant
which have better feed quality which results low effluent discharge in compare to existing softener
and incorporation of online filters which removes foreign particles and decreases the effluent
quantity and also increases the performance of cooling tower.
Project Description
2.103
Details
Existing
as per
consent
Current
Actual
Proposed
water
Proposed
Total
consumption
in wet season
Existing
as per
consent
Current
actual
Proposed
Total
Domestic
40
40
49
28
28
35
Industrial
Processing
190
190
192
83.0
75
84.0
Industrial
Cooling &
Boiler Feed
468
468
218.2
190.2
658.2 24.0
18
21
Agricultural 24
/gardening
24
11
Total
722
240.2
201.2
899.2 135.0
121
19
140
722
Note: Avg rain water harvesting is 28-29 m3/day will be used for cooling tower and RO water will
be recycled for gardening purpose.
Write up on Effluent Treatment Plan
A. Source of Effluent water:
The effluent is generated from sources:
i)
ii)
iii)
Domestic Purpose
iv)
Process
Project Description
2.104
The equalized effluent is taken in to Aeration Tank where the same is subjected to
aeration.
The Effluent from Aeration Tank is taken in to clarifier from which the de-cantate is
taken to collection tank.
2. MEE
The effluent from the receiving tank is subjected to triple effect evaporation.
Project Description
2.105
Parameters
Effluent
After Treatment
pH
6.5 -8.5
100
BOD (mg/l)
100
Project Description
2.106
Project Description
2.107
2.14 BRIEF DESCRIPTION: 4 MW THERMAL POWER PLANT AT (PLOT NO. C-33/1, X-9, 10, 11)
A Captive power plant of capacity 4MW is proposed to install, to save the energy demand. The
thermal power plant will be coal based which is mainly divided into four parts.
1. Coal Handling Plant
2. Boiler with ESP and ash handling system
3. Turbine
4. Generator
S.no.
Description
Requirement
Unit
1.
Coal
120
MT/day
2.
Steam
30
3.
Boiler
30
Note: About 3 MW energy will be saved and 1 MW power used for auxiliary consumption.
1. Coal Handling Plant: The capacity of coal handling plant is 20 MT/hr. As the coal consumption
is about 120 MT/day, the coal handling plant should be simple, reliable and low maintenance.
Coal is feeded on coal conveyer belt through vibrating feeder. Feeders are of electromagnetic
type and controls the rate of feeding required for bunkering (150 MT). By the various combinations
of conveyor belts, coal is conveyed to the surge hopper of a crusher house. Before the coal
comes to the crusher house, the ferrous material which comes along with the coal is taken out
with the help of suspended and rotating type magnetic separators. Non-ferrous materials like
stones. Shells, wood etc. are removed manually. Here coal is crushed to the size of 6 to 8 mm.
This size of coal is then sent to coal bunkers through various belts and finally coal trippers and
stored for further processing of coal for combustion in boiler furnace. This cycle is known as
bunkering cycle.
2. Boiler: Boiler is used for generation of steam for power generation. In thermal power plant water
tube boilers are used. Type of a boiler: Natural circulation, natural draft, tangentially fired, radiant,
reheat type, dry bottom and pulverized fuel fired. A 30 TPH boiler will be use from which 30 MT/hr
@67 kg/cm2 of steam will generate to produce power. The consumption of imported coal is about
120 MT/day.
ESP: Electrostatic precipitator will be used to control the flue gas. Three field high voltage
transformer with rectifier, emitting and collecting electrodes with inbuilt rapping and draining
arrangement. The capacity of ESP is 70 NM3/hr, having the inlet velocity is about 10 M/sec and
outlet (inside ESP) velocity is 0.5 M/sec.
Project Description
2.108
Ash Handling: Ash handling will be done with the help of ash cello of capacity 90M3 having
pneumatic handling system and having automatic drop down system in vehicles. The bottom ash
quantity is approximately 1.44 MT (on basis of 120 MT/day) falls in the bottom hopper and after
crushing it is transferred to ash handling plant .Fly ash approximately 5.76 MT (on basis of 120
MT/day) along with the flue gases goes through ESP where fine ash is taken out by ionization with
help of high voltage transformer /rectifier and send to the ash handling plant for further processing
to the ash bunds.
3. Turbine: A 4 MW turbine is used, which is three cylinder, horizontal, disc and diaphragm type
with nozzle governing and regenerating feed water heating. Live steam from boiler enters two
emergency stop valves (ESV) of high-pressure turbine (HPT) Excess exhaust steam after fulfillment
of plant demand condenses in the surface condenser which welded directly to the exhaust part
of turbine. The turbine is equipped with barring gear which rotates the rotors of turbine at a speed
nearly 3.4 rpm for providing uniform heating during starting and uniform cooling during shut down.
4. Generator: The steam enters in steam turbine and due to the heat energy of steam, turbine
rotates at about 7000 to 8000 rpm. The turbine is coupled to the generator rotor through gear box
by reduction in RPM up to 3000 RPM and Electricity is generated as per the Faradays Law in
generator. Electricity produced in the stator is then passed through bus ducts to the generator
transformer. GT increases the voltage level from 22kv. This transformer is connected to 22 KV buses
in switchyard through isolators and a circuit breaker. Various 22 KV lines are connected to this bus
through isolators and breakers.
Project Description
2.109
Project Description
2.110
: 30KVA
: 1x 1000KVA
1x 750 KVA
1x 380 KVA
Operation Phase:
Table 2.13: Details of Power Consumption
S.No.
Particulars
Source
Proposed
Total
Administration
MSEDCL
100
50
150
Plant
MSEDCL
1600
1545
3145
Total
1700
1595
3295
Particulars
Name of
Quantity required
Quantity required
fuel
(existing)
(proposed)
1.
Remark
For Existing-
DG set
Diesel
250 Lt/hrs
2.
Boiler
Coal
90 TPD
120 TPD
3.
Boiler
FO/ Bio-Fuel
FO = 4.1 KLPD
KLPD/5.9 KLPD
4
Thermo
FO/ Bio-
FO-0.3 KLD/
pack
Fuel/Coal
Project Description
2.111
S.N
1.
Details
Boiler
Capacity
Exist.
18 TPH
&
8 TPH
Boiler
6 TPH
(coal)&
6 TPH
(FO)
3.
DG set
4.
Incinerat
or
5.
Thermic
Fluid
Heater
Fuel/Fuel
consumption
Stack Ht.
Pro.
30
TPH
Exit.
42 m
Pro.
46
m
Stack Dia(mm)
Exit.
90 TPD
(Coal)
Pro.
120
TPD
(coal)
Coal
include
in 90
TPD
FO4.1KLPD
FO4.75
KLPD
or
biofuel
-5.9
KLPD
Pro.
Stack gas
temp(C)
Exit.
1300
Pro.
2000
Exit.
136
Pro.
160
550
120
Exit.
Pro.
Exit.
Pro.
30 m
Exist
1000,75
0
380 KVA
Pro.
Exit.
Pro.
Exit.
12m &
10 m
177.8
185
Exist
75
Kg/hr
30 m
125 L/hr
&
80 L/hr
& 45
L/hr
240
L/Day
(Diesel)
1100/500
93.5
Exist
6 lac
Kilo
Calorie
/Hr
Pros
6 lac
Kilo
Calori
e/Hr
Exist
Pro.
Pro.
Exit.
Pro.
30
Pro.
Coal
3.624
Exist
30.0
FO/Biof
uel
650
L/Day
250
550
158
158
2.15.3 Action plan for disposal of Fly ash generated from Boiler
Coal will be used for boiler and generated fly ash shall be collected and sold to nearest brick
manufacturer and land filling. Details are shown in Table 2.16
Project Description
2.112
Fuel/Fuel
Sr.
Details
No.
Capacity(TPH)
consumption
(TPD)
1.
Boiler
pack
Disposal option
(MT/M)
Exit.
Prop.
Exit.
Prop.
Exit.
Prop.
Exit.
Prop.
18, 8 &
30
90
120
85.5
288.0
Sale to brick
Sale to brick
manufacture/
manufacture/
land filling
land filling
Thermo
2.
generation
6.0
-
Lacs
Sale to brick
-
3.624
5.5
manufacture/
Kcal
land filling
Descriptions
Approx. Numbers
Skilled
50
Un-skilled
13
63
395
458
Project Description
2.113
Operation Phase
Various facilities and systems are presently in use within plant premises for management of excreta
and waste water. The main methods of excreta management practiced in the settlement are
through:
1. Individual pit latrines (both traditional and VIP)
2. Public communal latrines
3. Septic tanks and sewer connections
4. Open defecation.
2.17 SOLID WASTE MANAGEMENT
2.17.1 Construction Phase:
Waste generated during the construction will be properly handled, stored and disposed off in
accordance with relevant Waste Management Rules (Municipal Waste Management Rules,
Hazardous Waste Management & Handling Rules etc.) enacted by the government of India. Total
Waste generated during construction phase will be about 4000 kg/day. The Construction waste
like, debris, excavated soil will be used for land filling on same site and other unused construction
materials and construction equipment will be removed from the site after the construction. Used
plastics, LDPE, HDPE, gunny bags/cement bags will be collected, stored and disposed of properly.
Plastics and similar material will not be allowed to dispose outside the plant boundary.
2.17.2 Operation Phase:
Total domestic waste will be generated during the operation phase is about 65.1kg/day. The
generated waste that is bio degradable waste (35.1 kg/day) and Non bio degradable waste (30
kg/day) will be hand over to authorize vendors.
2.18. HAZARDOUS WASTE DETAILS
Details of Hazardous Waste generation, storage and disposal facility are shown in Table 2.18.
Table 2.18: Hazardous Waste Handling and Disposal Details
S.
Category
No.
No.
Particulars
Existing
Proposed
Total Qty
Disposal
Chemical Sludge
1
34.3
8.0 MT/M
32.0 MT/M
40 MT/M
CHWTSDF
Treatment
Spent oil
2
5.1
Sale to
0.4 MT/M
0.1 MT/M
0.5 MT/M
Authorised
recyclers
Project Description
2.114
Discarded
33.3
Containers
83 nos/M
118 nos/M
201 nos/M
MS / HDPE Drums
0 nos/M
25 nos/M
25 nos/M
IBCs
0 nos/M
50 nos/M
50 nos/M
Carboys
36.1
Concentration
Techniques (MEE)
Authorised
recyclers
CHWTSDF/Sal
Sludge from
4
Sale to
Nil
20.4 MT/M
20.4 MT/M
e to
Authorised
recyclers
Batteries
5
Rules,
Sale to
Lead Acid Batteries
Nil
30 Nos /A
30 Nos /A
2002
6
15.2
Authorised
recyclers
Discarded Asbestos
8.3 kg/M
8.3 kg/M
CHWTSDF
Sale to
35.2
Spent Catalyst
0.2 MT/M
0.3MT/M
0.5 MT/M
Authorised
recyclers
Waste or residue
8
5.2
Nil
150 kg/M
150 kg/M
CHWTSDF
Rules,
Sale to
e-Waste
Nil
57 kg/M
57 kg/M
2011
10
35.3
Authorised
recyclers
Carbon/Charcoal
Nil
2.2 MT/M
2.2 MT/M
Incineration
in boiler
Sale to
11
Silica
Nil
2.2 MT/M
2.2 MT/M
authorize
party/Land
filling
12
Resin
Nil
0.1 MT/M
0.1 MT/M
CHWTSDF
2.115
Area (M2)
Coefficient runoff
Rainfall (m)
Quantity of
rain
water (M3)
Roof top area
Green Area
Total
2686.00
0.9
3.413
8250.5
18.00
0.3
3.413
18.4
2704.00
8268.9
Harvested water will be collected in underground tanks of 350 KL and 150 KL. The stored water
shall be used for firefighting as well process.
2.21 Storm Water-Collection and Disposal
Storm water drains is constructed according to municipal regulations. Storm water from the entire
plot will be collected through network of storm drains. Storm water from plot area will be collected
in the rainwater harvesting pits provided for this purpose. The overflow from these pits, if any, will
be then discharged in the proposed drains. The dimension of the drain is 10.5 x 15.0 x 2.25 M.
2.22 Air Pollution Control Measures
Air pollution control measures include adequate stack height, installation of cyclone, dust
collectors and incinerator.
Project Description
2.116
ETP Facility
Aeration tank
MEE
RO Plant
Greenbelt
Greenbelt
Project Description
2.117
CHAPTER 3
BASELINE ENVIRONMENTAL STATUS
3.0 INTRODUCTION
The baseline environmental qualities of various environmental components like air, noise,
water, land, flora and fauna and socio-economic form an important and integral part of any
environmental study. The baseline data forms the basis for predicting/assessing the
environmental impacts of the proposed project. The baseline environmental quality is assessed
through field surveys within the impact zone as well as secondary data for various components
of the environment, viz. air, noise, water, land and socio-economic.
The proposed Project is located on the land falling under MIDC area, Mahad, District Raigad,
Maharashtra. The coordinates of the site is 1806.397N, 7329.321E at an altitude of around
56 m above MSL.
The present report presents the data collected during the sampling period of three months
during summer Season from March 2013 to May 2013. Various environmental components
were monitored and samples were analyzed.
The baseline quality of various components of the environment, viz. air, noise, water, and land,
biology, meteorological and socio-economic is assessed within the impact zone of about 10 km
around the proposed site. Secondary data has also been incorporated from authentic sources
viz. Government/Non-Governmental Agencies, Universities, Indian Meteorological Department
(IMD), Ground Water Board etc. Various environmental components were monitored and
samples analyzed. The is Google image showing project site shown in figure 3.1 and 10 km radius
map from Project site is shown in Fig. 3.2.
3.1
3.2
Feature
Details
Coordinates
1806.397N, 7329.321E
Altitude
56 MSL
MIDC land
Ambient Temperature
Relative humidity:
Average 94%
Annual Rainfall
1.25 m/s
Reserve Forests
10
11
Nearest village
12
Nearest Town/City
13
14
Nearest Hospital
15
16
Nearest Highway
NH - 66 (2.5 KM)
17
Nearest Airport
18
19
Not present
20
21
3.3
S. No.
Feature
Details
22
23
24
Seismic Zone
Zone IV
Source: Field survey & secondary information, Report of Ministry of Water Resources Central
Ground Water Board (2009).
Fig. 3.2 (a) Map showing villages in the study area
3.4
Parameters
No. of
Sampling
Locations
Meteorology
Wind
speed
&
direction,
temperature, relative humidity,
rainfall, cloud cover and solar
radiation.
Project Site
Ambient air
quality
10
Noise levels
Biological
environment
Surface
water quality
Physical,
chemical
and
bacteriological
parameters
including
pH,
temperature,
turbidity, magnesium hardness,
total alkalinity, chloride, sulphate,
nitrate,
fluoride,
sodium,
potassium, salinity, Total nitrogen,
total phosphorus, DO, BOD, COD,
Heavy metals, Total coliforms,
faecal coliforms, Phyto-plankton.
Sr.
No.
Study Area
Once in a season.
Frequency of
Monitoring / Data
Collection
Data collected from
IMD,
and
by
installing
meteorological
station for hourly site
specific data.
24 hourly samples
twice a week. CO
and O3 8 hourly
samples twice a
week.
At least one day in
a season for day
time and night time
on a working &
nonworking day.
3.5
Sr.
No.
Attribute
Parameters
No. of
Sampling
Locations
Groundwater
quality
Soil
characteristi
cs
Land use /
Land Cover
Socioeconomic
Environment
Socio-economic characteristics,
labour force characteristics,
population statistics existing
amenities in the study area and
quality of life.
Once in a season.
Once in season
Study Area
Study Area
Based
on
field
survey and data
collected
from
Census of India
Frequency of
Monitoring / Data
Collection
3.6
: December to February
: March to May
Monsoon season
: June to September
: October to November
Maximum
Minimum
Temperature Temperature
31.6
31.6
33.3
35.6
37.0
36.8
32.6
31.9
32.7
35.2
13.4
11.2
18.0
20.2
24.6
23.2
23.6
23.3
22.7
20.8
42
51
58
54
61
62
79
69
66
48
-----25.3
21.9
13.5
13.5
--
8.08
9.05
10.0
11.5
13.1
24.3
24.4
19.2
13.7
9.2
19.3
19.1
20.8
21.2
24.3
26.2
34.1
45.6
31.2
19.8
3.7
November
December
36.1
18.0
91
40
--
6.8
17.7
35.2
16.4
90
52
--
7.0
20.8
Mar-13
Apr-13
May-13
--
Temp C
Relative
Humidity
%
Wind
Speed
m/s
Wind
Direction
Rainfall
mm
Visibility
Min
12
N.A
Max
37
92
16.8
337.5
N.A
10
Average
25.8
31.7
2.8
100.1
N.A
6.5
Min
17
N.A
Max
41
85
18.6
315
N.A
10
Average
29.0
32.5
4.1
171.9
N.A
Min
22
Max
40
78
20.7
315
N.A
N.A
6.9
4
Average
29.8
41.4
6.8
248.6
N.A
10
6.9
The maximum temperature is in the month of April (41C) (and minimum temperature is in the
month of March (12C). Maximum wind speed recorded is 20.7 m/s in the month of May.
3.8
3.9
3.10
S. No.
1
A1
---
Temgarh
A2
2 Km, NW
Kusgaon
A3
6 km, NNW
Sakadi
A4
5 Km, NW
Jite
A5
Asanpoi
A6
Aklae
A7
2 Km, SW
Birwadi
A8
1 Km, ESE)
Nadgaon
A9
6 Km, W
10
Deshmukh
A10
5 Km, NW
3.11
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
Minimum
169
332
226
301
270
208
135
248
413
140
Maximum
175
348
234
311
280
214
147
256
425
150
Average
172
340
230
306
275
211
141
252
419
145
90th Percentile
175
346
233.7
309
279
214
146
256
423
149
95th Percentile
175
347
234
310
280
214
147
256
424
150
98th Percentile
175
348
234
310.54
280
214
147
256
425
150
CPCB
Standard
100 g/m3
3.12
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
Minimum
73
75
71
76
50
49
34
62
69
40
Maximum
78
81
79
86
65
55
46
74
81
48
Average
75
78
75
82
58
52
40
68
75
44
90th Percentile
78
81
79
85
63
55
45
73
79
48
95th
Percentile
78
81
79
86
64
55
45
74
80
48
98th Percentile
78
81
79
86
65
55
46
74
81
48
Sampling
3.13
of
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
Minimum
15
16
13.6
11.3
15
16.4
14
16
21
14
Maximum
21
22
23.5
20.2
26
24.4
26
27
28
21
Average
18
19
19.5
16.8
20
20.4
20
22
24
19
90th Percentile
20
22
23.2
19.1
23
23
24
25
27
21
95th Percentile
21
23
23.5
19
23
24
25
26
27
21
98th
21
23
23.5
19.878
25
24.4
26
27
27
21
Sampling
Percentile
CPCB
Standard
80 g/m3
3.14
of
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
Minimum
34
43
31.2
32
35
29
31
32
33
30
Maximum
42
48
39.2
45
45
37
40
40
40
41
Average
38
45
35.2
39
39
33
34
36
36
35
90th Percentile
41
47
37.9
41
43
36
39
39
39
39
95th Percentile
42
48
38.2
43
44
36
39
39
39
40
98th Percentile
CPCB
Standard
42
48
38.74
44
45
37
39
39
39
40
80 g/m3
3.15
of
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
Minimum
0.22
0.35
0.22
0.29
0.24
0.23
0.23
0.23
0.26
0.25
Maximum
0.68
0.58
0.55
0.51
0.56
0.51
0.58
0.53
0.48
0.54
Average
0.39
0.45
0.40
0.41
0.38
0.35
0.36
0.41
0.39
0.40
90th Percentile
0.54
0.53
0.49
0.50
0.52
0.48
0.44
0.52
0.47
0.51
95th Percentile
0.60
0.55
0.51
0.51
0.53
0.49
0.48
0.53
0.48
0.52
98th Percentile
0.64
0.57
CPCB
2 mg/m3
Standard
0.53
0.51
0.55
0.50
0.53
0.53
0.48
0.53
3.16
of
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
Minimum
2.50
6.20
5.29
2.30
2.30
3.20
3.40
4.80
2.90
3.50
Maximum
7.20
8.70
7.65
9.30
9.50
10.00
7.40
9.60
10.00
10.20
Average
5.12
7.48
6.9
5.00
5.88
7.02
6.08
8.37
5.91
6.17
90th Percentile
6.72
8.40
7.4
7.27
8.69
8.81
7.37
9.60
8.54
7.88
95th Percentile
6.89
8.57
7.485
8.92
9.07
9.50
7.40
9.60
8.96
8.43
98th Percentile
CPCB
Standard
7.07
8.65
7.581
9.25
9.32
9.82
7.40
9.60
9.58
9.42
100 g/m3
3.17
Observation:
Ozone observed during the base line monitoring was in the average range of 5.00 to 8.37
g/m3. Thus 8 hourly Ozone found in the given locations are found well within CPCB standard
of 100 g/m3.
Table 3.12: Ambient Air Quality Monitoring For VOCs, HC, Lead, Arsenic, Nickel, &
Benzopyrene at Sampling Locations
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
CPCB
Standard
VOCs
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
HC
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
Lead
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
1.0 g/m3
Arsenic
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
6.0 ng/m3
Nickel
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
20.0 ng/m3
Benzopyrene
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
1.0 ng/m3
Locations
Sampling
of
Observation:
VOCs, HC, Lead, Arsenic, Nickel, & Benzopyrene were monitored at all 10 locations and it
was found BDL.
Table 3.13: National Ambient Air Quality Standards and Methods of Measurement
National Ambient Air Quality Standards
S.
No.
Pollutants
Time
Weighted
Average
Industrial,
Residential,
Rural and other
area
Ecologically
Sensitive
Area
SO2 (g/m3)
24 hours
80
80
NOx (g/m3)
24 hours
80
80
PM10 (g/m3)
24 hours
100
100
PM2.5 (g/m3)
24 hours
60
60
CO (mg/m3)
8 hours
24 hours
400
400
8 hours
100
100
6
7
Ammonia
(g/m3)
Ozone
(g/m3)
Methods of
measurement
Improved West and
Gaeke method.
Modified Jacob &
Hochheiser
(Sodium
Arsenite).
Gravimetric
Gravimetric
Non Dispersive Infra
Red Spectroscopy
Indophenol
Blue
Method
UV Photometric
Chemical Method
3.18
Lead (g/m3)
24 hours
1.0
1.0
AAS
Arsenic (ng/m3)
Annual
6.0
6.0
AAS
10
Nickel (ng/m3)
Annual
20.0
20.0
AAS
11
Benzene (g/m3)
Benzopyrene
(ng/m3)
Annual
05
05
Annual
1.0
1.0
11
Gas Chromatography
Gas Chromatography
3.19
Sampling locations
Sample ID
Project Site
N1
---
Birwadi Market
N2
1 Km, ENE
MMA Hospital,MIDC,
Mahad
N3
4 Km, W
N4
WNW 3 Km
Dr.Babasaheb
ambedkar college,
NH-66
N5
(WSW, 7 Km)
Represents
residential
area in the western part
of the study area.
N6
5 Km,W
Represents nearest
habitation to the Project
Site.
Type of Area
Represents Project site.
Represents nearest
habitation to the Project
Site.
Represents the residential
area close to the main
access road to the
Project site.
Represents
residential
area in the western part
of the study area.
3.20
Result
CPCB
Permissible
Limit
Result
CPCB
Permissible
Limit
Industrial
79
75
68
70
Location name
Zone
1.
Project Site
2.
Birwadi Market
Commercial
area
68
65
59
55
3.
MMA Hospital,
MIDC, Mahad
Industrial
68
75
60
70
4.
Silence zone
53
50
42
40
Silence zone
55
50
43
40
Industrial
69
75
62
70
5.
6.
Dr.Babasaheb
ambedkar
college, NH-66
MIDC, residential
area
Category of Area
Night Time
Industrial area
75
70
Commercial area
65
55
Residential area
55
45
Silence zone
50
40
3.21
Figure 3.12: Graphical Representation of Day time Noise Level in the study area
Figure 3.13: Graphical Representation of Night time Noise Level in the study area
3.7.4 Observed Noise Level in the Study Area
The noise levels varied in the study area during daytime from 53 dB (A) Leq to 69 dB (A) Leq
and at the project site (industrial area) noise observed was 79 dB (A) Leq. The day time noise
level in the study area is higher than the permissible noise standards. The night time noise
level in the study area is in the range of 42 dB (A) Leq to 62 dB (A) Leq whereas on industrial
site, it was 68 dB (A) Leq. The night time noise was also within stipulated standards of CPCB
Though we are considering the proposed project site in Industrial area, residential areas and
Silence zones are located nearby.
3.22
3.8
WATER ENVIRONMENT
Parameters
Physico-chemical test
Colour
Temperature
Turbidity
pH at 25C
Conductivity
Total Hardness as CaCO3
Iron as Fe
Chlorides as Cl
Dissolved solids
Magnesium hardness
Copper as Cu
Sulphate as SO4
Nitrate as NO3
Total Nitrogen
Total Phosphorus
Fluoride as F
Sodium as Na
Potassium as K
Phenolic compounds as Phenol
Mercury as Hg
Cadmium as Cd
Selenium as Se
Arsenic as As
Protocol
APHA 21st edition, 2120 B
IS 3025 (Part 9) 1984 Reaffirmed: 2002
APHA 21st edition, 2130 B
APHA 21st edition, 4500 H+
APHA 21st edition, 2510 B
APHA 21st edition, 2340 C
APHA 21st edition, 3500 Fe
APHA 21st edition, 4500 Cl
APHA 21st edition, 2540 C
APHA 21st edition, 3500 Mg B
APHA 21st edition, 3111 B
APHA 21st edition, 4500 SO4
APHA 21st edition, 4500 NO3 E
APHA 21st edition, 4500 NO3 B
APHA 21st edition, 4500 P D
APHA 21st edition, 4500 F
APHA 21st edition, 3500 Na B
APHA 21st edition, 3500 K B
APHA 21st edition, 5530 C
APHA 21st edition, 3112B
APHA 21st edition, 3111B
APHA 21st edition, 3114B
APHA 21st edition, 3550 As B
3.23
S.No
24
25
26
27
28
29
30
31
32
33
B
34
35
36
37
Parameters
Lead as Pb
Zinc as Zn
Chromium as Cr+6
Total Chromium
Alkalinity as CaCO3
Total Suspended solids
Salinity (parts per thousand
Dissolved Oxygen
Chemical Oxygen demand
Biochemical Oxygen demand (at 20V
for 5 days)
Biological tests
Total Coliform
Faecal coliform
E.Coli
Zooplankton
Protocol
APHA 21st edition, 3111 B
APHA 21st edition, 3111 B
APHA 21st edition, 3500 Cr
APHA 21st edition, 3500 Cr
APHA 21st edition, 2320 B
APHA 21st edition, 2540 D
APHA 21st edition, 2520
APHA 21st edition, 4500 O-C
APHA 21st edition, 5220 B
IS 3025 (Part 44) 1993
3.24
Geo- Hydrology
1.
The Mahad region is part of Konkan Coastal Belt from Raigarh district of
Maharashtra.
2.
3.
The major tributaries of Savitri are Kal River, Gandari River, Ghod
Negeshri nadi.
4.
The Konkan Coastal Belt (KCB) is narrow and elongated strip of land
average width is about 40 km.
5.
6.
whose
Trap of upper
3.25
Sampling locations
Sample
Id
1.
Birwadi (well)
GW 1
3.2 Km, SE
2.
Jite (well)
GW 2
2 Km, NE
3.
Sakadi(borewell)
GW 3
5.4 Km, NW
4.
Nadgaon (Well)
GW4
5 Km, NW
5.
Kal river
SW 1
2.5, SW
6.
Savitri river
SW 2
5 Km, W
7.
Nala
SW 3
1.5 Km, NW
8.
Chaudha tale,
lake Mahad city
SW 4
5 Km, NW
3.26
Table 3.19: Analysis Result of Ground Water and Surface Water Samples
Date of sampling: 22- 23/04/2013
S.
No.
Parameter
Units
Permissible Limit
Result
as Per
Sample Identification
GW1
GW2
GW3
GW4
SW1
SW2
SW3
SW4
IS 10500:1991
---
7.63
7.74
8.58
7.98
8.83
8.24
8.83
8.38
6.5-8.5
APHA 4500 H+
S/cm
256
707
687
343
214
352
7428
425
APHA 2510
NTU
10
15
15
15
10
APHA 2130
BDL
BDL
BDL
BDL
25
APHA 2120
APHA 2150
1.
pH
2.
Conductivity
3.
Turbidity
4.
Color
Hazen
5.
Odor
Unobje
ctiona
ble
6.
7.
mg/l
mg/l
Solid
8.
Sulphate
9.
Chloride
10.
Total Hardness
11.
Calcium as Ca
12.
Magnesium Mg
13.
Alkalinity
14.
Copper
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
Unobj
Unobject Unobject Unobject Unobject Unobject Unobject Unobject
ection
-ionable -ionable -ionable -ionable -ionable -ionable -ionable
able
182
2
482
<2
462
8
242
<2
152
248
4925
292
2000
APHA 2540 C
10
APHA 2540 B
12.5
25
132.5
6.75
8.5
925
9.25
400
APHA 4500SO42-
29.99
89.97
79.97
19.99
29.99
32
2489
48
1000
150
340
170
130
130
142
2750
156
600
APHA 2340
29.66
92.18
60.92
44.08
26.45
34.4
713.4
39.2
200
APHA -3500 Ca
18.47
26.73
4.37
4.86
15.55
13.6
235.71
14.1
NS
APHA 3500-Mg
10
12
10
10
30
26
40
35
600
APHA 2320
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
1.5
APHA 3500-Cu
Reference
Method
3.27
mg/l
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
APHA 3500-Zn
1.0
APHA 3500-Fe
<0.01
0.05
APHA 3500-Pb
<0.1
<0.1
APHA 3500-Ni
<0.003
<0.003
<0.003
0.01
APHA 3500-C
Absent
Absent
Absent
BDL
APHA 9221 B
Absent
Absent
Absent
Absent
Absent
APHA 9221 E
Absent
Absent
Absent
Absent
Absent
Absent
APHA 9221 F
Zinc
16.
Iron
17.
Lead
mg/L
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
18.
Nickel
mg/L
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
19.
Cadmium
mg/L
<0.003
<0.003
<0.003
<0.003
<0.003
20.
Total Coliform
Absent
Absent
Absent
Absent
21.
Faecal Coliform
Absent
Absent
Absent
22.
E. Coli
Absent
Absent
mg/l
MPN/
100 mL
MPN/
100 mL
MPN/
100 mL
<0.1
<0.1
<0.5
15
15.
<0.1
<0.1
0.08
<0.1
0.18
<0.1
mg/L
74
230
152
110
66
86
1780
Absent
APHA 3500-Ca
24.
Calcium Hardness as
CaCO3
Magnesium
Hardness as CaCO3
mg/L
76
110
18
20
64
56
970
98
APHA 3500-Mg
25.
Phenol
mg/L
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
58
APHA 5530
26.
Fluoride
mg/L
0.028
0.18
1.26
0.039
1.27
1.4
1.25
BDL
1.5
APHA 5400-F-
27.
Salinity
mg/L
54
161.95
143.95
35.98
53.98
57.6
4480
1.25
APHA 2520 B
28.
Dissolved Oxygen
mg/L
3.1
2.5
3.0
2.2
6.2
6.5
4.6
6.2
APHA 4500-O
29.
Pesticides
P/A
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Gas
Chromatograph
y
Chemical Oxygen
Demand
Biochemical Oxygen
Demand
mg/l
35
29
185
38
APHA 5220
mg/l
26
APHA 5210
23.
30.
31.
3.28
Observation: From the Table above, it can be observed that ground water qualities in terms
of various essential and desirable characteristics are found within the limits specified by IS
10500:1991.
The surface water quality of the study area is good excluding Nala water which is much
higher than the permissible standard.
3.9 LAND ENVIRONMENT
Environmental baseline status keeping in view of the study of physical and chemical
properties of soil in the study area, sampling locations for soil were identified for existing soil
quality assessment in the study area. The baseline status of land environment has been
assessed through reconnaissance in project area characterization of soil through field
studies, study of the land use pattern and cropping pattern corresponding to project area.
3.9.1 Land use Pattern of the Study Area
The development of project leads to change in land use pattern in the form of permanent or
temporary changes in land use pattern.
Fig: 3.15 Land use/Land cover Map of the study area (10 km)
3.29
AREA (m2)
Area (ha)
Area (%)
Water
3016850
302
0.96
Agriculture land
4813200
481
1.53
Fallow land
97188841
9719
30.97
Degraded land
24574891
2457
7.83
Forest
62610950
6261
19.95
Degraded forest
121249800
12125
38.64
Settlements
146675
15
0.05
Road
198768
20
0.06
Area
313799975
31380
100.00
The land use land cover has been prepared for study area of 10 km radius comprising 31380
ha. From the above table, settlement area is least (15 ha) and fallow land is highest (32.47
ha). Water body comprises of 302 ha agricultural land, degraded land (2457 ha), Forest (6261
ha), Degraded forest (12125 ha), Roads (20 ha).
3.9.2.1 Soil characteristics
Keeping in view the study of physio-chemical properties of soil in the study area, sampling
locations were identified in the study area. The impacts of any major projects on land
environment generally depend on type of proposed development.
3.9.2.2 Methodology:
Soil samples were collected using auger from different depths and then mixed. The samples
were collected randomly from agricultural land and open land considering proximity of 10
km from the proposed Project site. Samples were then sent to laboratory for analysis.
3.9.3 Sampling Locations
Soil samples from 7 locations were collected to assess the soil quality prevailing in the study
area. Various physical and chemical parameters were analyzed. Soil monitoring locations are
tabulated in Table 3.21 and shown in Fig.: 3.16.
Table 3.21: Details of Soil Sampling Locations
S.
Sampling
No.
locations
Sample id
Project Site
S1
--
Kusgaon
S2
12 Km, WNW
3.30
Sakadi
S3
5 Km, NNW
Aklae
S4
2 Km, WSW
Asanpoi
S5
2 Km,W
Birwadi
S6
1 KM, NE
Sheltoli
S7
2 Km, NNW
3.31
S. No
Parameters
Units
Project Site
Kusgaon
Sakadi
Aklae
Asanpoi
Birwadi
Sheltoli
---
7.8
7.1
7.6
7.5
7.1
7.8
7.4
S/cm
529
619
648
451
495
431
428
1.
pH
2.
Conductivity
3.
Organic Carbon
0.30
0.42
0.51
0.86
0.78
0.74
0.78
4.
Organic Matter
1.03
1.05
1.02
1.58
1.45
1.31
1.35
5.
Phosphorus as P
mg/Kg
BDL
BDL
BDL
BDL
BDL
BDL
BDL
6.
0.06
0.05
0.07
0.16
0.10
0.09
0.07
7.
Sodium as Na
mg/Kg
59
55
61
87
84
79
80
8.
Potassium as P
mg/Kg
91
97
95
95
91
98
96
9.
Calcium Hardness
14.50
15.41
15.70
16.18
15.76
16.10
15.84
10.
Magnesium Hardness
2.67
2.70
2.71
2.89
2.31
2.51
2.88
11.
Chloride as Cl
1.19
1.21
1.29
1.21
1.13
1.20
1.25
12.
Copper as Cu
0.0012
0.016
0.011
0.010
0.004
0.007
0.008
13.
Zinc as Zn
BDL
BDL
BDL
BDL
BDL
BDL
BDL
14.
Iron as Fe
0.018
0.015
0.019
0.016
0.015
0.016
0.019
15.
Lead as Pb
0.007
0.005
0.008
0.006
0.010
0.008
0.009
16.
Nickel as Ni
0.002
0.005
0.006
0.009
0.006
0.007
0.008
17.
Cadmium as Cd
BDL
BDL
BDL
BDL
BDL
BDL
BDL
3.32
from
various
Government
agencies
like
Forest
Department,
Agriculture
3.33
grassland. Most of the study area is under human settlement and agricultural practice. The
grasses were found growing on open places, agricultural area and near human settlements.
The most common grasses Aristida sp., Brachiara sp., Digitaria sp., Heteropogon sp.,
Themeda sp., Sporobolus sp., Cenchrus barbatus, Lasiurus hirsutus and Cymbopogon
jwarancusa are found to grow in this region. These grasses are useful as fodder and also
check the soil erosion in the area.
The agricultural practice is mainly depending on monsoon water. The main crops cultivated
in the region are Rice, lab lab bean, cowpea, black gram, horse gram, finger millet,
prosomillet and groundnut. Some irrigated part of the area has vegetables like okra, brinjal
and leafy vegetables. The floral composition of the study area is mostly tropical deciduous
type. The various terrestrial plants available in the study area are reported in Table 3.23.
Heavy rainfall, moderate and humid climatic condition favors the richness of flora in study
area.
Table 3.23: List of Flora in the Study Area
Scientific name
Mangifera indica
Annona squamosa L.
Polyalthia longifolia
Alstonia scholaris
Nerium indicum
Cocos nucifera
Tridax procumbens
Jacaranda mimosefolia
Bombax ceiba
Cassia fistula
Cassia javanica
Cassia siamea
Cassia tora
Delonix regia
Tamarindus indica
Casuarina equisetifolia
Cyperus spp.
Dalbergia sisso
Pongamia pinnata
Lawsonia inermis
Melia azedarach
Albizia lebbeck
Ficus glomerata
Ficus religiosa
Ficus benghalensis
Eugenia jambolana
Bouganvillea spectabilis
Andropogan contortus
Andropogon martinii
Mimusops elengi
Ailanthus excelsa
Common name
Amba
Sitaphal
Ashok
Saptaparni
Kaner
Coconut
Dagadipala
Neel Gulmohor
Shalmali
Bahava
Cassia
Cassia
Takla
Gulmohar
Chinch
Suru
Motha
Shisham
Karanj
Mehndi
Bakan neem
Kala shirish
Umbar
Pimpal
Vad
Jambhul
Boganvel
Surwal
Rohis
Bakul
Rukhdo
Family
Anacardiaceae
Annonaceae
Annonaceae
Apocynaceae
Apocynaceae
Arecaceae
Asteraceae
Bignoniaceae
Bombacaceae
Caesalpiniaceae
Caesalpiniaceae
Caesalpiniaceae
Caesalpiniaceae
Caesalpiniaceae
Caesalpiniaceae
Casuarinaceae
Cyperaceae
Fabaceae
Fabaceae
Lythraceae
Meliaceae
Mimosaceae
Moraceae
Moraceae
Moraceae
Myrtaceae
Nyctaginaceae
Poaceae
Poaceae
Sapotaceae
Simaroubaceae
3.34
Typha angustata
Emblica officinalis
Syzygium cumini
Pankanis
Amla
Jamun
Typhaceae
Euphorbiaceae
Myrtaceae
Scientific Name
Schedule
Category
Jackal
Canis aureus
II
Striped Hyena
Hyanea hyaena
Jungle cat
Felis chous
II
Striped squirrel
Funambulus spp.
IV
Herpestes edwardii
II
Common hare
Lepus nigricollis
IV
Rhesus macaque
Macaca mulata
II
Bonnet monkey
Macaca radiata
II
Field Mouse
Mus booduga
House mouse
Mus musculus
Common languor
Presbytis entellus
II
Ratufa indica
Pteropus giganteus
House rat
Rattus rattus
Bat
Rousettus spp.
House Shrew
Suncus murinus
(B) Fish:
Savitri river originate from Mahabaleshwar and flows through Raigad district and eventually
meets Arabian sea. Its major tributary is Kal river. Savitri river and tributaries have good
diversity of fishes, which is given in Table no. 3.25.
3.35
Table 3.25: Fishes in the study area (Savitri River and its tributaries)
Scientific name
Notopterus notopterus
Anguilla bengalensis
Tenualosa ilisha
Catla catla
Cirrhinus cirrhosus
Cirrhinus mrigala
Crossocheilus latius
Eleotris fusca
Ctenopharyngodon idella
Cyprinus carpio
Devario aequipinnatus
Devario fraseri
Esomus danrica
Garra gotyla stenorhynchus
Garra mullya
Labeo calbasu
Labeo rohita
Laubuca laubuca
Puntius sarana subnasutus
Puntius sophore
Puntius ticto
Rasbora daniconius
Indoreonectes evezardi
Lepidocephalichthys thermalis
Mystus bleekeri
Arius sona
Hexanematichthys sagor
Gambusia affinis
Lutjanus johni
Otolithoides biauritus
Scatophagus argus
Etroplus maculatus
Boleophthalmus dussumieri
Glossogobius giuris
Channa punctata
Channa gachua
Lates calcarifer
Nemachilichthys rueppelli
Mystus bleekeri
Common name
Kanduli
Indian longfin eel
Hilsa Shad
Katla
Mirga
Ray finned fish
Kala bata
Dusky Sleeper
Hullu
Soneri masha
Balooki
Gayroonjee
Dendu
Shingacha mallaya
Mullya
Kanas
Rohu
Dendula
Darai
Khavli
Kaoli
Dandai
Chikli
Mura
Singhala
Shingala
Sona-tengra
Gambusia
Chavri-tamb
Koth
Vadda
Thikree
Nivti
Kharbi
Maral
Dhok
Fitadar
Chikl
Katirna
Family
Notopteridae
Anguillidae
Clupeidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Eleotridae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Cyprinidae
Nemacheilidae
Cobitidae
Bagridae
Arius
Ariidae
Poeciliidae
Lutjanidae
Sciaenidae
Scatophagidae
Cichlidae
Gobiidae
Gobiidae
Channidae
Channidae
Latidae
Nemacheilidae
Bagridae
(C) Avifauna:
During the field survey and with the help of secondary data various bird species were
recorded in the study region is given in Table no.3.26.
3.36
Scientific Name
IUCN Status
Black-shouldered Kite
Elanus caeruleus
Least concerned
Brahminy Kite
Haliastur Indus
Least concerned
Black Kite
Milvus migrans
Least concerned
Shikra
Accipiter badius
Least concerned
Bonellis Eagle
Hieraaetus fasciatus
Least concerned
Booted Eagle
Hieraaetus pennatus
Least concerned
Rufous-bellied Eagle
Hieraaetus kienerii
Least concerned
Steppe Eagle
Aquila nipalensis
Least concerned
Eurasian Hobby
Falco subbuteo
Least concerned
Common Kestrel
Falco tinnunculus
Least concerned
Painted Francolin
Francolinus pictus
Least concerned
Common Quail
Coturnix coturnix
Least concerned
Rain Quail
Coturnix coromandelica
Least concerned
Perdicula asiatica
Least concerned
Perdicula argoondah
Least concerned
Perdicula erythrorhyncha
Red Spurfowl
Galloperdix spadicea
Least concerned
Painted Spurfowl
Galloperdix lunulata
Least concerned
Red Junglefowl
Gallus gallus
Least concerned
Grey Junglefowl
Gallus sonneratii
Least concerned
Indian Peafowl
Pavo cristatus
Least concerned
White-breasted Waterhen
Amaurornis phoenicurus
Least concerned
Watercock
Gallicrex cinerea
Least concerned
Common Moorhen
Gallinula chloropus
Least concerned
Common Coot
Fulica atra
Least concerned
Black-winged Stilt
Himantopus himantopus
Least concerned
Yellow-wattled Lapwing
Vanellus malabaricus
Least concerned
Charadrius dubius
Least concerned
Kentish Plover
Charadrius alexandrines
Least concerned
Treron pompadora
Least concerned
Treron phoenicoptera
Least concerned
Rock Pigeon
Columba livia
Least concerned
Spotted Dove
Streptopelia chinensis
Least concerned
Alexandrine Parakeet
Psittacula eupatria
Least concerned
Plum-headed Parakeet
Psittacula cyanocephala
Least concerned
Indian Cuckoo
Cuculus micropterus
Least concerned
Eurasian Cuckoo
Cuculus canorus
Lesser Cuckoo
Cuculus poliocephalus
Least concerned
Asian Koel
Eudynamys scolopacea
Least concerned
Greater Coucal
Centropus sinensis
Least concerned
Barn Owl
Tyto alba
Least concerned
3.37
Ketupa zeylonensis
Least concerned
Jungle Owlet
Glaucidium radiatum
Least concerned
Ninox scutulata
Least concerned
Indian Nightjar
Caprimulgus asiaticus
Least concerned
Indian Swiftlet
Collocalia unicolor
Least concerned
Brown-backed Needletail
Hirundapus giganteus
Least concerned
Cypsiurus balasiensis
Least concerned
Common Kingfisher
Alcedo atthis
Least concerned
White-throated Kingfisher
Halcyon smyrnensis
Least concerned
Green Bee-eater
Merops orientalis
Least concerned
Indian Roller
Coracias benghalensis
Least concerned
Common Hoopoe
Upupa epops
Brown-headed Barbet
Megalaima zeylanica
Least concerned
White-cheeked Barbet
Megalaima viridis
Least concerned
Crimson-fronted Barbet
Megalaima rubricapilla
Least concerned
Coppersmith Barbet
Megalaima haemacephala
Least concerned
Rufous Woodpecker
Celeus brachyurus
Least concerned
Rufous-tailed Lark
Ammomanes phoenicurus
Least concerned
Sykess Lark
Galerida deva
Malabar Lark
Galerida malabarica
Wire-tailed Swallow
Hirundo smithii
Streak-throated Swallow
Hirundo fluvicola
Least concerned
Red-rumped Swallow
Hirundo daurica
Least concerned
Bay-backed Shrike
Lanius vittatus
Least concerned
Rufous-tailed Shrike
Lanius isabellinus
Least concerned
Black-naped Oriole
Oriolus chinensis
Least concerned
Black Drongo
Dicrurus macrocercus
Least concerned
Ashy Drongo
Dicrurus leucophaeus
Least concerned
Bronzed Drongo
Dicrurus aeneus
Least concerned
Dicrurus paradiseus
Least concerned
Ashy Woodswallow
Least concerned
Chestnut-tailed Starling
Artamus fuscus
Sturnus malabaricus
malabaricus
Brahminy Starling
Sturnus pagodarum
Least concerned
Common Myna
Acridotheres tristis
Least concerned
Bank Myna
Acridotheres ginginianus
Least concerned
Jungle Myna
Acridotheres fuscus
Least concerned
House Crow
Corvus splendens
Least concerned
Large-billed Crow
Corvus macrorhynchos
Least concerned
Bar-winged Flycatcher-shrike
Hemipus picatus
Least concerned
Common Woodshrike
Tephrodornis pondicerianus
Least concerned
Large Cuckooshrike
Coracina macei
Least concerned
Black-winged Cuckooshrike
Coracina melaschistos
Least concerned
Black-headed Cuckooshrike
Coracina melanoptera
Least concerned
Least concerned
Least concerned
3.38
Scarlet Minivet
Pericrocotus flammeus
Least concerned
Common Iora
Aegithina tiphia
Least concerned
Red-whiskered Bulbul
Pycnonotus jocosus
Least concerned
Red-vented Bulbul
Pycnonotus cafer
Least concerned
Puff-throated Babbler
Pellorneum ruficeps
Least concerned
Common Babbler
Turdoides caudatus
Least concerned
Rufous Babbler
Turdoides subrufus
Jungle Babbler
Turdoides striatus
Least concerned
Culicicapa ceylonensis
Least concerned
White-browed Fantail
Least concerned
White-throated Fantail
Rhipidura aureola
Rhipidura albicollis
albogularis
Grey-breasted Prinia
Prinia hodgsonii
Least concerned
Rufous-fronted Prinia
Prinia buchanani
Least concerned
Plain Prinia
Prinia inornata
Least concerned
Ashy Prinia
Prinia socialis
Least concerned
Jungle Prinia
Prinia sylvatica
Least concerned
Common Tailorbird
Orthotomus sutorius
Least concerned
Thick-billed Warbler
Acrocephalus aedon
Least concerned
Paddyfield Warbler
Acrocephalus Agricola
Least concerned
Orphean Warbler
Sylvia hortensis
Sylvia althaea
Phylloscopus tytleri
Least concerned
Dusky Warbler
Phylloscopus fuscatus
Least concerned
Phylloscopus magnirostris
Least concerned
Phylloscopus occipitalis
Least concerned
Luscinia brunnea
Least concerned
Copsychus saularis
Least concerned
White-rumped Shama
Copsychus malabaricus
Least concerned
Pied Bushchat
Saxicola caprata
Least concerned
Blue Rock-thrush
Monticola solitaries
Least concerned
Myophonus horsfieldii
Least concerned
Orange-headed Thrush
Zoothera citrine
Least concerned
Tickells Thrush
Turdus unicolor
Eurasian Blackbird
Great Tit
Parus major
Chestnut-bellied Nuthatch
Sitta castanea
Least concerned
Velvet-fronted Nuthatch
Sitta frontalis
Least concerned
Tree Pipit
Anthus trivialis
Least concerned
Forest Wagtail
Dendronanthus indicus
Least concerned
Citrine Wagtail
Motacilla citreola
Least concerned
Grey Wagtail
Motacilla cinerea
Least concerned
White-browed Wagtail
Motacilla maderaspatensis
Least concerned
Thick-billed Flowerpecker
Dicaeum agile
Least concerned
Least concerned
Least concerned
3.39
Pale-billed Flowerpecker
Dicaeum erythrorynchos
Least concerned
Plain Flowerpecker
Dicaeum concolor
Least concerned
Purple-rumped Sunbird
Nectarinia zeylonica
Crimson-backed Sunbird
Nectarinia minima
Least concerned
Least concerned /
Endemic
Oriental White-eye
Zosterops palpebrosus
Least concerned
House Sparrow
Passer domesticus
Least concerned
Chestnut-shouldered Petronia
Petronia xanthocollis
Least concerned
Baya Weaver
Ploceus philippinus
Least concerned
Common Rosefinch
Carpodacus erythrinus
Least concerned
House Bunting
Emberiza striolata
Least concerned
Crested Bunting
Melophus lathami
Least concerned
(D) Reptiles:
Due to close proximity with Western Ghats, rivers and agricultural area the region has various
reptilian fauna is given in table no. 3.27.
Table 3.27: Reptilian fauna in the study area
Common Name
Scientific Name
Schedule Category
Checkered Keelback
Xernochrophis piscator
II
Cobra
Naja naja
II
Rock Gecko
Hemidactylus maculatus
Garden lizard
Calotes versicolor
Giant Gecko
Hemidactylus giganticus
Krait
Bungarus coeruleus
IV
Monitor lizard
Varanus benghalensis
Rat snake
Ptyas mucosus
II
Russell's viper
Vipera russeli
II
Wall lizard
Hemidactylus brooki
Wolf snake
Oligodon venustus
IV
Saw-scaled viper
Echis carinatus
IV
Pond Tortoise
Geomyda trijuga
IV
3.40
(E) Amphibians
Amphibians are probably the best indicators of environmental health of all vertebrates being
extremely sensitive to temperature and humidity (Daniels, 1991). The common amphibian
species reported from the site are Hoplobatrachus tigerinus, Duttaphrynus melanostictus,
Euphlyctus cyanophlyctus, Fejervarya syhadrensis.
(F) Aquatic insects and molluscs
The aquatic insects and molluscs were studied from Savitri river and and its main tributary Kal
river. In the molluscs, viviparidae, lymnaedae and thiaroidae were found dominant. Aquatic
insects and molluscs are highly sensitive to water quality. The study indicates that certain
groups of aquatic macro-invertebrates are highly specific for their microhabitats, as substrate
type influences the distribution of most of the forms of aquatic insects and molluscs. The
distribution of various forms of aquatic macro-invertebrates is highly diverse at various
localities. The presence of chironomid larvae in most of the localities.
3.11 SOCIO-ECONOMIC PROFILE OF STUDY AREA (As per Census India 2011)
3.11.1 Reconnaissance
Reconnaissance has been done to assess socio-economic status in the study area. The study
area is rural however basic amenities were observed.
3.11.2 Methodology
Detailed socio-economic data was collected within 10 km radius of the proposed Project
site. Preliminary information was collected during field investigation followed by secondary
data from the census of India 2011.
3.11.3 Socioeconomic Assessment
Socio economic status of the population is the indicator of the change in the life style due to
the developmental activities taking place in the region. The villages which appears within the
10 km radius from the centre of the proposed Project site are considered for socioeconomic
study.
3.41
1.
2.
3.
4.
5.
6.
7.
8.
9.
Mandle
Tetghar
Kachale
Kinjaloli Bk
Ghurupacha Kond
Kinjaloli Kh
Bhalekar kond
Gondala
Ladvali
10.
Walan Kh
11.
Adrai
12.
Waki bk
13.
Zolicha Kond
14.
Solamond
15.
Dahivad
3.42
16.
Padavi
17.
Warandh
18.
Mazeri
19.
Barasgaon
20.
Gavadi
21.
Amshet
22.
Dhamane
23.
Jite
24.
Sheltoli
25.
Kalij
26.
Bhave
27.
Taliye
28.
Kiye
29.
Pimpalwadi
30.
Rupavali
31.
Mohat
32.
Katiwade
33.
Kharivali
34.
35.
Borgaon
36.
Mahad
37.
38.
Chochinde Kond
39.
Chochinde
40.
Birwadi (CT)
S.No.
Village
Total
Population
Male
Female
No. of
Household
Sex Ratio
(females/males)*1000
1
2
3
4
5
Mandle
Tetghar
Kachale
Kinjaloli Bk
Ghurupacha
799
367
472
912
441
361
176
240
441
211
438
191
232
471
230
223
93
104
178
106
1213.29
1085.22
966.66
1068.02
1090.04
3.43
S.No.
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
Village
Kond
Kinjaloli Kh
Bhalekar kond
Gondala
Ladvali
Walan Kh
Adrai
Waki bk
Zolicha Kond
Solamkond
Dahivad
Padavi
Warandh
Mazeri
Barasgaon
Gavadi
Amshet
Dhamane
Jite
Sheltoli
Kalij
Bhave
Taliye
Kiye
Pimpalwadi
Rupavali
Mohot
Katiwade
Kharivali
Khair Tarf
birwadi
Borgaon
Mahad
Kamble tarf
Mahad
Chochinde
Kond
Chochinde
Birwadi (CT)
Total
Population
Male
Female
No. of
Household
Sex Ratio
(females/males)*1000
575
327
1689
1508
600
235
1109
289
273
780
751
2547
314
875
182
504
1297
1310
595
2410
1870
673
577
608
812
550
328
2782
297
150
826
748
274
110
520
136
131
382
344
1251
161
425
88
257
648
658
305
1287
946
321
272
299
406
274
162
1443
278
177
863
760
326
125
589
153
142
398
407
1296
153
450
94
247
649
652
290
1123
924
352
305
309
406
276
166
1339
139
76
372
313
158
68
314
83
62
191
197
600
75
198
44
113
264
268
132
605
429
173
155
167
195
117
75
676
936.02
1180.00
1044.79
1016.04
1189.78
1136.36
1132.69
1125.00
1083.96
1041.88
1183.13
1035.97
950.31
1058.82
1068.18
961.08
1001.54
990.88
950.81
872.57
976.74
1096.57
1121.32
1033.44
1000.00
1007.29
1024.69
927.92
405
213
192
93
901.40
433
2430
218
1267
215
1163
84
542
986.23
917.91
1718
864
854
341
988.42
699
344
355
147
1031.97
1366
8829
683
4692
683
4137
289
2149
1000.00
881.71
3.44
S.No.
Village
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
Mandle
Tetghar
Kachale
Kinjaloli Bk
Ghurupacha Kond
Kinjaloli Kh
Bhalekar kond
Gondala
Ladvali
Walan Kh
Adrai
Waki bk
Zolicha Kond
Solamond
Dahivad
Padavi
Warandh
Mazeri
Barasgaon
Gavadi
Amshet
Dhamane
Jite
Sheltoli
Kalij
Bhave
Taliye
Kiye
Pimpalwadi
Rupavali
Mohat
Katiwade
Kharivali
Total
Population
799
367
472
912
441
575
327
1689
1508
600
235
1109
289
273
780
751
2547
314
875
182
504
1297
1310
595
2410
1870
673
577
608
812
550
328
2782
SC
Population
45
0
0
12
1
126
0
124
157
15
12
102
0
8
5
15
17
0
41
0
22
0
30
104
155
42
19
43
55
139
4
0
292
% SC
5.63
0
0
1.31
0.22
21.9
0
7.34
10.41
2.5
5.1
9.19
0
2.9
0.64
1.99
0.66
0
4.68
0
4.36
0
2.29
17.4
6.43
2.24
2.82
7.45
9.04
17.11
0.72
0
10.4
ST
Population
8
1
0
20
0
15
0
148
3
86
28
299
1
0
276
14
227
0
0
0
0
0
4
147
226
90
0
3
0
80
0
0
13
% ST
1.0
0.2
0
2.19
0
2.6
0
8.7
0.19
14.3
11.9
26.96
0.34
0
35.3
1.86
8.91
0
0
0
0
0
0.30
24.7
9.37
4.81
0
0.51
0
9.8
0
0
0.46
3.45
S.No.
Village
34
35
36
37
38
39
40
Total
Population
405
433
2430
1718
699
1366
8829
SC
Population
95
0
65
80
0
18
273
45241
2116
23.4
0
2.67
4.65
0
1.31
3.09
ST
Population
0
8
116
72
0
27
96
4.67
2008
% SC
% ST
0
1.84
4.77
4.19
0
1.97
1.08
4.43
Sr. No.
Village
1
2
Male
% Literacy
Mandle
Tetghar
292
164
36.5
44.6
266
165
33.2
44.9
Kachale
42.1
Kinjaloli Bk
Ghurupacha Kond
Kinjaloli Kh
Bhalekar kond
Gondala
Ladvali
Walan Kh
Adrai
Waki bk
Zolicha Kond
Solamond
Dahivad
Padavi
Warandh
Mazeri
Barasgaon
Gavadi
Amshet
Dhamane
Jite
Sheltoli
Kalij
168
362
118
185
101
505
570
209
57
245
91
104
182
266
896
100
278
66
165
422
450
206
779
35.5
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
199
371
166
237
117
613
606
217
77
297
113
102
258
276
1016
144
342
73
219
541
551
265
968
40.6
37.6
41.2
35.7
36.2
40.1
36.1
32.7
26.7
39.1
37.3
33.0
36.7
39.8
45.8
39.0
40.1
43.4
41.7
42.0
44.5
40.1
Female
Literates
% Literacy
Literates
39.6
26.7
32.1
30.8
29.8
37.7
34.8
24.2
22.0
31.4
38.0
23.3
35.4
35.1
31.8
31.7
36.2
32.7
32.5
34.3
34.6
32.3
3.46
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
Bhave
Taliye
Kiye
Pimpalwadi
Rupavali
Mohat
Katiwade
Kharivali
Khair Tarf birwadi
Borgaon
Mahad
Kamble tarf Mahad
Chochinde Kond
Chochinde
Birwadi (CT)
710
215
194
207
300
230
133
1161
172
166
1005
712
257
576
3862
37.9
31.9
33.6
34.0
36.9
41.8
40.5
41.7
42.4
38.3
41.3
41.4
36.7
42.1
43.7
538
182
132
125
204
187
107
989
152
150
782
617
201
465
3105
28.7
27.0
22.8
20.5
25.1
34.0
32.6
35.5
37.5
34.6
32.1
35.9
28.7
34.0
35.1
3.47
186
118
77
341
Agri-cultural
Labourers
33
17
4
150
Workers in household
industries
9
0
0
5
Other
workers
42
48
62
25
Total
workers
278
186
152
537
Main
workers
270
183
143
521
Marginal
workers
8
3
9
16
Non
workers
521
181
320
375
1
90
66
184
143
201
66
207
33
34
6
379
275
164
229
27
22
402
97
28
16
292
315
0
0
5
112
73
11
13
55
3
7
1
2
150
3
129
2
3
4
23
7
4
237
7
0
0
0
32
12
3
6
38
1
4
5
1
98
0
3
1
3
11
12
3
7
3
10
63
41
55
248
311
20
19
130
30
45
60
31
292
41
97
22
120
237
198
176
638
387
21
249
272
128
886
598
262
112
532
149
92
295
413
935
211
493
57
159
688
443
217
827
965
434
64
131
126
576
539
235
104
430
67
90
72
413
815
208
458
52
148
654
330
214
665
919
353
185
141
2
310
59
27
8
102
82
2
223
0
120
3
35
5
11
34
113
3
162
46
81
192
303
199
803
910
338
123
577
140
181
485
338
1612
103
382
125
345
609
867
378
1583
905
239
S.No.
Village
Cultivators
1
2
3
4
Mandle
Tetghar
Kachale
Kinjaloli Bk
Ghurupacha
Kond
Kinjaloli Kh
Bhalekar kond
Gondala
Ladvali
Walan Kh
Adrai
Waki bk
Zolicha Kond
Solamond
Dahivad
Padavi
Warandh
Mazeri
Barasgaon
Gavadi
Amshet
Dhamane
Jite
Sheltoli
Kalij
Bhave
Taliye
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
3.48
28
29
30
31
32
33
34
35
36
37
38
39
40
Kiye
Pimpalwadi
Rupavali
Mohat
Katiwade
Kharivali
Khair Tarf
birwadi
Borgaon
Mahad
Kamble tarf
Mahad
Chochinde
Kond
Chochinde
Birwadi (CT)
389
60
343
107
86
60
7
257
10
64
15
18
1
0
1
0
4
50
7
16
17
48
74
689
411
344
489
294
207
903
404
333
371
219
179
817
7
11
118
75
28
86
166
264
323
256
121
1879
29
44
185
49
14
24
2
3
10
94
58
456
185
259
939
174
119
675
11
140
264
220
174
1491
129
30
19
422
689
600
89
1029
80
46
131
7
18
54
16
8
27
111
262
2847
270
554
3275
214
334
3059
56
220
216
429
812
5554
3.49
Fig. 3.18: Total population vs. total workers in the study area
3.50
Fig. 3.20: Total population vs. social profile in the study area
3.51
School
Health Centre
Roads
Post Office
Bus Stand
3.52
S.
No.
1
2
3
4
5
6
7
Vehicle
Type
%During
Lean
Hrs
No.of
vehicles in
PCU During
peak Hrs
574
33.82
430.5
438
40.86
328.5
143
8.43
171.6
144
13.43
288.0
698
41.13
698
260
24.25
260.0
95
5.60
209
81
7.56
178.2
121
7.13
266.2
96
8.96
211.2
66
3.89
264
53
4.94
212.0
0.00
0.00
0.0
1697
100
2039.3
1072
100
1477.9
Two
Wheelers
Three
Wheelers
Cars/Sumos
Buses/Mini
Buses
Trucks/Lorrie
s
Other Heavy
vehicles
Slow moving
vehicles
(Cycle)
Total
No. of
vehicles
in PCU
During
Lean Hrs
During
peak Hrs
(No. of
vehicles/hr)
During Lean
%During
Hrs (No. of
Lean Hrs
vehicles/hr)
Lean Hrs: Before 8 hrs (morning), 1 to 5 hrs afternoon & after 9 hrs (evening).
Peak Hrs: After 8 hrs & 5 to 9 hrs in the evening.
PCU: Passenger Car Units
Figure 3.22: Graph of Vehicular concentration at Peak hour & Lean hour for NH66 MumbaiGoa
3.53
= 2000 PCUs/hr
= 1697
=1697/2000 =0.84
=1072
=1072/2000 (=0.53)
Level of Services
0.0 to 0.2
A (Excellent)
0.2 to 0.4
B (Very Good)
0.4 to 0.6
C (Good)
0.6 to 0.8
D (Fair)
0.8 to 1.0
E (Poor)
Vehicle
Type
Two
Wheelers
Three
Wheelers
During peak
Hrs (No. of
vehicles/hr)
%During
Lean Hrs
No. of
vehicles in
PCU During
peak Hrs
158
42.47
118.5
98
35.90
73.5
72
19.35
144
29
10.62
58
No. of
During Lean
%During vehicles in
Hrs (No. of
Lean Hrs PCU During
vehicles/hr)
Lean Hrs
Cars
81
21.77
81
61
22.34
61
Buses
30
8.06
66
3.30
19.8
17
4.57
37.4
60
21.98
222
14
3.76
56
16
5.86
64
372
100
502.9
273
100
498.3
5
6.
Trucks /
Lorries
Slow
moving
vehicles
Total
3.54
Figure 3.23: Graph of Vehicular concentration at Peak hour & Lean hour for MIDC Internal
road
3.12.4 Existing Traffic Scenario and Level of Services
The road from MIDC Internal road is 4 meter wide with Single lane without divider. All types of
vehicles move on the road.
= 1000 PCUs/hr
= 372
=372/1000 =0.37
=273
=273/1000 =0.27
Results:
The above traffic survey for NH-66 Mumbai- Goa (Double lane road of 8 meter wide) mention
the LOS (Level of Service) as D which is poor during peak hour. However, traffic survey for
MIDC Internal road (Single lane road of 8 meter wide) mention the LOS (Level of Service) as
B which is very Good during peak hour. Since there will be very insignificant permanent
increase in the traffic after the Construction of the project. The condition of the road even
after the project is envisaged to be very good.
3.55
3.13
Air Monitoring
3.56
CHAPTER 4
ANTICIPATED ENVIRONMENTAL IMPACTS AND
MITIGATION MEASURES
4.1 INTRODUCTION
Prediction of environmental impacts is an important part of impact assessment study as it
provides quantitative as well as qualitative information related to projection of possible
environmental consequences from the proposed project well in advance. Several
mathematical / statistical techniques and methodologies are available for prediction &
evaluation of impacts due to proposed projects on physical, chemical, biological and socioeconomic components of environment. The results obtained from the predictions are to be
superimposed over the baseline (pre-project) status of environmental quality to derive the
ultimate (post-project) scenario of environmental quality within the impact zone (10 km
radius) around site. This chapter presents identification and appraisal of the likely impacts
due to the proposed expansion & addition of Aroma Chemical Production Capacity of M/s
Privi Organics Ltd, MIDC Area, Mahad, Dist. Raigad. The construction and operational phase
of the proposed project comprises various activities each of which may have an impact on
environmental parameters. Various impacts during the construction and operation phase on
the environment have been studied to estimate the impact on the environmental attributes
and are discussed in the subsequent section. The probable impacts of each of these
activities on various sectors of environment have been mentioned below in two headings:
Construction Phase
Operation Phase
4.1
existing land use pattern by proposed project as it shall be set up in Notified Industrial Area,
MIDC-Mahad. Construction shall be done in an area of 5416.54.0 m2 (Plot no.C-3, 4, 5, 6, 6/1,
7, 8, 9) and 648.0 m2 (Plot no.C-33/1, X-9, 10, 11)
Mitigation Measures:
As a part of afforestation drive 350 nos. of trees saplings have been already planted, while
500 nos. of trees saplings were propose to plant. Further plantation and thick green belt
development will mitigate soil erosion and enhance the visual aesthetics of the area.
4.2.2 Impact on Air Environment
The main source of emission during the construction phase is the movement of equipment
and vehicles at site. Equipment deployed during the construction phase is also likely to result
in marginal increase in the levels of SO2, NOX, and PM and fugitive emissions. The impact is
reversible, marginal and temporary in nature. The construction activities at site will be
restricted to civil and structural fabrication. The main sources of air Pollution are:
Fugitive dust emissions from digging, filling, material handling, transportation and use of
construction machinery etc.
Emissions from operation of DG sets for construction purpose in case of power supply
failure.
Most of the gaseous emissions would be in the form of carbon dioxide (CO2), although
smaller quantities of other gasses, such as oxides of nitrogen (NOx) and sulphur dioxide (SO2)
would also be generated. Adequate mitigation measures will be planned to minimise
adverse impacts.
Mitigation Measures:
Water sprinkling will be regularly carried in order to arrest the fugitive dust to the maximum
extent possible. All construction equipment will be maintained properly. Only PUC certified
vehicles of contractor will be deployed at site. The existing green belt will reduce fugitive
emissions in the environment.
4.2.3 Impact on Noise Environment
The project site is likely to have increase noise level upto 85-90 dB(A) due to the
constructional activity, the movement of heavy motor vehicles, loading and unloading,
fabrication and handling of equipments and materials, construction equipments like dozer,
4.2
scrapers, concrete mixer, crane, generators pumps and compressor, rock drills, Pneumatic
tools, vibrators, etc. Vibration will be developed in addition to noise.
During Construction Phase, potential noise emissions will be mainly from:
Vehicular Noise: 85 dB(A) (at the edge from the centerline of the road)
Mitigation Measures:
To minimize the impact, construction schedules would be optimized to day time working and
the night activities will be scaled down. Extensive earthmoving and movement of heavy
equipments would be conducted only during the regular working hours in day time. Noise
and vibration impacts at construction sites will be minimized by:
Green belt has been and will be developed around the periphery of project site.
Overall, the impact of generated noise on the environment during construction period is
likely to be insignificant, reversible and localized in nature and mainly confined to the day
hours.
4.2.4 Impact on Drainage
Only surface runoffs are likely in Monsoon which will be channelized to natural streams.
Natural drainage pattern will not be affected as construction activity will be done inside the
existing project periphery. Thus there will be no impact on drainage pattern.
4.2.5 Impact on Water Environment
Approximately 65.5 m3/day of freshwater will be sourced from MIDC out of which 5.5 m3/day
will be used for domestic purpose and 60 m3/day will be used for construction activity. Waste
water will be generated from construction areas, sewage from workers etc. which may
cause surface water contamination. The resulting wastewater could potentially carry
inorganic solids above applicable discharge standards.
4.3
Mitigation Measures:
Generated sewage will be disposed off through septic tank and soak pit. Construction
activity will be stopped during rainy season to check soil erosion & contamination of nearby
water bodies. Solid waste will be disposed off through authorize vendors. The potential
negative impact is considered minor and has no long-term impact. Alkaline wash water
containing excessive amounts of cement will be made settle down and neutralized before
discharge. The overall impact on water environment during construction phase due to the
proposed project would be short term duration and insignificant.
4.2.6 Impact on Soil Environment
Construction activities like excavation would result into permanent loss of topsoil of the
construction area. Estimated excavation quantity would be around 4000 kg/day of soil.
Potential risk of contamination of soil can be due to handling of lube oil, diesel and paints/
solvents onsite.
Mitigation Measures:
The impacts envisaged will be mitigated with suitable measures:
To prevent contamination of soil, lube oil and diesel will be stored separately on
impervious surface provided with sheds. Paints and related solvents will be stored in a
well ventilated room provided at a location away from other construction and
flammable materials.
The excavated soil would be used within the premises for filling, leveling etc. and
excavated rocks would be used of construction of boundary wall and internal roads.
4.4
There will be direct & indirect employment opportunities to the local population.
Growth of services (like retail shops, automobile workshops, etc.) and increase in
employment and trade opportunities in service sector.
Increase in per capita income and overall economic upliftment of the area.
PPEs like Safety belts, safety shoes, goggles etc will be provided to construction
workers. Adequate sanitation and hygiene facilities will be maintained onsite at all
times.
Most of the negative impacts will be of short term and limited to the construction period only.
4.2.8.1 Traffic Volume
There will be slight increase in road traffic. The site has good road connectivity. Traffic volume
on nearby roads will increase due to movement of medium and heavy vehicles Considering
the overall size and nature of the Project, the increase in traffic will not have any significant
effect. A traffic management plan for the area will be developed to ease the situation. The
following arrangement would be made to ease the situation.
Mitigation Measures:
Transport of construction materials and machineries will be carried out during lean
traffic period of the day or during night.
4.5
4.6
quality standards (NAAQS). GLCs of individual pollutant are predicted at 20000 m X 20000 m
Cartesian Square Grid Receptors in the impact zone covering 10 km radial distance.
Data used for Modeling
The hourly site specific meteorological data, stack details, emission rate have been used for
AQM. Stack details given in below.
Plant Section
Stack
& units
No.
Internal Diameter
Emission
Temp. of Exhaust
(Top)(m)
Rate
Gases
SPM:
SO2:
NOx:
Boiler
1
42.0
136
1.3
CO:
18 TPH
Others
5510 m3/hr
SPM:
SO2:
NOx:
Boiler
2
42.0
136
1.3
CO:
8 TPH
Others
5510 m3 /hr
SPM:
SO2:
NOx:
Boiler
3
6TPH
30.0
152
0.55
CO:
Others
5598 m3 /hr
4.7
SPM:
SO2:
NOx:
Boiler
4
30.0
152
0.55
CO:
6 TPH
Others
5598 m3 /hr
SPM:
SO2:
NOx:
DG set
6
12.0
185
0.1778
CO:
1000KVA
Others
618 m3/hr
SPM:
SO2:
NOx:
DG set
7
12.0
185
0.1778
CO:
750KVA
Others
625 m3/hr
SPM:
SO2:
NOx:
DG set
8
380KVA
10.0
141
0.1778
CO:
Others
6223 m3/hr
4.8
SPM:
SO2:
NOx:
Incinerator
9
30
93.5
0.25
CO:
75 Kg/h
Others
3914 m3/hr
SPM:
SO2:
Thermic Fluid
Heater
NOx:
10
30
158
0.25
CO:
Others
965 m3/hr
The predicted concentrations of PM10, SO2 & NOX in the study area are shown below.
Season
Incremental GLCs
Stack
(g/m3)
distance
in m
Summer
PM10
SO2
NOx
Min.
Max.
Avg.
Min.
Max.
Avg.
Min.
Max.
Avg.
200
1.225
1.300
1.245
0.115
0.136
0.124
0.565
0.580
0.570
500
1.198
1.277
1.219
0.104
0.121
0.110
0.517
0.556
0.529
4.9
4.10
4.11
Noise level at 1
meter distance
Diesel Generators
< 85 dB (A)
< 85 dB (A)
< 85 dB (A)
< 85 dB (A)
Condensate Pumps
< 85 dB (A)
11
Compressors
< 85 dB (A)
12
Vacuum Pumps
< 85 dB (A)
14
Vehicular Noise
85 dB (A)
Mitigation Measures:
Adopting modern building design and the use of sound absorbing materials will minimize
noise and vibration. Noise shields will be provided around noise generating sources. Workers
will be provided with PPEs like ear plugs, ear mufflers etc. Anti vibrating pads will also be
provided.
4.3.4 Impact on Water Resources
The water requirement for the proposed plant will be met from MIDC. There will be no drawl
of ground water. Hence, no impact on ground water is envisaged. Effluents that are likely to
cause water contamination will be treated in Effluent Treatment Plant (ETP). The total effluent
generation is 140.0 m3/day, from which 98.0 m3/day will be transferred to CETP after aerobic
treatment and rest of the treated effluent (42.0 m3/day) sent to RO (Capacity-300 m3/day)
and MEE (Capacity-72 m3/day) for further treatment.
4.12
Increase in employment due to large flow of financial and material resources through
increased business, trade commerce and service sector.
Negative impacts like increment in noise, air pollution, water pollution will be checked
by implementing effective pollution control measures.
Impact on health, if any, will be primarily due to emissions of PM, NOX and SO2, and noise
generation. Adequate air and noise pollution control measures will be provided to conform
to regulatory standards. Employees working in high noise work place would be provided with
protective devices like ear plugs/ ear muffs for ensuring minimum impact on human health.
Further, the medical facilities envisaged for the project employees will also be extended to
the nearby villages.
4.3.7 Solid waste
In construction phase, Small quantity of Solid wastes generated from the temporary campsites and other wastes like plastics, paper, cardboard etc. shall be properly collected,
segregated and disposed off suitably as per norms. Construction debris about 40 ton per day
shall be generated during construction phase, which shall be used for leveling of low-lying
areas or base course preparation of approach roads.
No demolition involved.
During operation phase, solid waste generated shall be around 1.227 MT/day, which shall be
segregated as organic (5.0 Kg/day) and inorganic (1222.0 Kg/day) and handed over
authorized vendor for disposal.
4.13
Categor
y No.
Particulars
Existing
Proposed
Total Qty
Disposal
34.3
Chemical Sludge
from Waste Water
Treatment
8.0 MT/M
32.0 MT/M
40 MT/M
CHWTSDF
5.1
Spent oil
0.4
MT/M
0.1 MT/M
0.5 MT/M
Sale to
Authorised
recyclers
33.3
Discarded
Containers
MS / HDPE Drums
IBCs
Carboys
83 nos/M
0 nos/M
0 nos/M
118 nos/M
25 nos/M
50 nos/M
201 nos/M
25 nos/M
50 nos/M
Nil
20.4 MT/M
20.4 MT/M
CHWTSDF/S
ale to
Authorised
recyclers
36.1
Sludge from
Concentration
Techniques (MEE)
Batteries
Rules,
2002
Lead Acid
Batteries
Nil
30 Nos /A
30 Nos /A
Sale to
Authorised
recyclers
15.2
Discarded
Asbestos
8.3 kg/M
8.3 kg/M
CHWTSDF
35.2
Spent Catalyst
0.2 MT/M
0.3MT/M
0.5 MT/M
Sale to
Authorised
recyclers
5.2
Waste or residue
containing oil (Oil
soaked gaskets
and cotton
waste)
Nil
150 kg/M
150 kg/M
CHWTSDF
E- waste
Rules,
2011
e-Waste
Nil
57 kg/M
57 kg/M
Sale to
Authorised
recyclers
10
35.3
Carbon/Charcoal
Nil
2.2 MT/M
2.2 MT/M
Incineration
in boiler
2.2 MT/M
Sale to
Authorised
party /Land
filling
11
Silica
2.2 MT/M
Sale to
Authorised
recyclers
4.14
12
Resin
Nil
0.1 MT/M
0.1 MT/M
CHWTSDF
As per action plan, 350 nos of trees have been already planted and another 500 nos of
sapling will plant in and around project site.
4.15
4.16
Biological
S.
Project
No.
activities
Air
Surface
Ground
Soil
Soil
Quality
Water
Water
Stability
Quality
Noise
Socio
Use (Water
Health
economic
Flora &
supply
(Individual/
(Population,
Fauna
and use,
Community ,
Community
visual
Occupational)
Infrastructure,
features)
A.
Employment)
Construction Phase
Site
excavation
and
foundation
ST, -ve,
RE
ST, -ve,
RE
ST, -ve
ST, -ve
work
Material
2
storage,
transportation
ST, -ve
ST, -ve
ST, -ve
ST, -ve
ST, -ve
ST, -ve
ST, -ve
and handling
3
4
Movement of
vehicles
Sewage
generation
4.17
Physical
Biological
S.
Project
No.
activities
Air
Surface
Ground
Soil
Soil
Quality
Water
Water
Stability
Quality
Noise
Socio
Use (Water
Health
economic
Flora &
supply
(Individual/
(Population,
Fauna
and use,
Community ,
Community
visual
Occupational)
Infrastructure,
features)
5
6
7
Solid waste
generation
Construction
activities
Operation of
DG set
ST, -ve
ST, -ve
ST, -ve
+ve
ST, -ve
ST, -ve
B.
1
2
Employment)
Operation Phase
Production
activities
Operation of
DG set
RE, ST,
RE, -ve,
-ve, LT
-ve
-ve
ST, -ve
ST, -ve
..
..
ST, -ve
ST, +ve
+ve
LT,
Material
3
storage,
transportation
and handling
4.18
Physical
Biological
S.
Project
No.
activities
Air
Surface
Ground
Soil
Soil
Quality
Water
Water
Stability
Quality
Noise
Socio
Use (Water
Health
economic
Flora &
supply
(Individual/
(Population,
Fauna
and use,
Community ,
Community
visual
Occupational)
Infrastructure,
features)
4
5
6
7
Movement of
vehicles
Effluent
generation
Ground water
withdrawl
Green belt
Development
ST, -ve
_
ST, -ve
-ve
-ve
..
+ve
+ve
+ve
+ve
+ve
+ve
+ve
+ve
RE Reversible
IR Irreversible
Employment)
4.19
CHAPTER 5
ENVIRONMENTAL MONITORING PROGRAM
5.0 INTRODUCTION
It is imperative that the Project Authorities set up regular monitoring stations to assess the
ambient levels in relevant areas of environment after the commissioning of the project. An
environmental monitoring plan provides a delivery mechanism to address the adverse
environmental impacts of a project during its execution, to enhance project benefits and to
introduce standards of good practice to be adopted for all project works. An environmental
monitoring program is important as it provides useful information and helps to:
5.1
No. of
Attribute
Parameters
Sampling
Locations
Frequency of Monitoring /
Data Collection
Period
Meteorology
1 hourly
Temperature,
Relative
Study Area
humidity, Cloud
observatio
by installing meteorological
ns from
continuous
cover and
records
Rainfall.
PM10, PM2.5, SO2,
2
Ambient
air quality
Quarterly
metals etc.
Stack
3
Emissions
(DG sets)
Surface
water
quality
Groundwa
ter quality
Quarterly
Each stack
for flue gas
Quarterly
emissions
As per the
CPCB
guidelines
Physical,
chemical and
bacteriological
Quarterly
Quarterly
parameters.
Physical &
chemical
parameters.
Through field visit during the
Ecology
Study area
Annually
secondary sources.
7
Noise
Noise levels in
levels
dB(A) Leq
10
Quarterly
5.2
No. of
S.
No.
Attribute
Parameters
Sampling
Locations
Frequency of Monitoring /
Data Collection
Period
Physical,
chemical and
biological
Soil
8
characteris
tics
parameters to
assess
Quarterly
agricultural and
a forestation
potential.
As per
All relevant
Health
Monthly
parameters
nt
Plant site
10
Hazardous
All relevant
and
waste
parameters
adjoining
Half yearly
Once during the study period
area
11
Biological
Environme
(Terrestrial &
nt
aquatic)
requireme
and as per
requireme
nt
Study area
Quartely
Study area
Half yearly
Demographic,
12
Socio-
infrastructure,
economy
economic
growth etc.
Attributes
Parameters
No. of
Sampling
Locations
Frequency of Monitoring
/ Data Collection
Period
Ambient air
including
quality
NMHC, VOCs,
Quarterly
O3, heavy
metals etc
2.
Stack Emissions
Each
H2 S
stack for
Quarterly
Quarterly
As per the
5.3
flue gas
CPCB
emissions
guidelines
Quarterly
3.
Process
Emissions
VOCs
Each
Quarterly
stack
As per the
CPCB
guidelines
Physical,
4.
Surface water
chemical and
quality
bacteriological
Quarterly
parameters
5.
6.
Groundwater
quality
Noise levels
Physical &
chemical
parameters
Noise levels in
dB(A) Leq
Quarterly
Quarterly
season
Physical,
chemical and
biological
7.
Soil
parameters to
characteristics
assess
Quarterly
agricultural and
a forestation
potential
8.
Health
All relevant
Study
parameters
area
Half yearly
Plant site
9.
Hazardous
All relevant
and
waste
parameters
adjoining
period
Half yearly
area
5.4
0.5
2.0
1.0
Environment Monitoring
0.25
S.
No.
1
2
3
4
4.95
Operation Phase
Recurring Cost
Pollution Control Measures
per annum Rs.
(Lakhs)
Capital
Cost Rs. (Lakhs)
18.8
242
540.55
478
0.5
0.0
2.05
0.0
0.5
6.0
Environment Monitoring
and Management
Occupational Health
39.69
Green Belt
8.82
1.5
1.5
32.0
Other (CSR)
0.0
10.0
5.5
Total
612.41
778.5
5.6
CHAPTER 8
PROJECT BENEFIT
8.0 INTRODUCTION
Growth in the industrial sector creates new opportunities for employment and can also help
diversify the economy. This is especially important given the high level of urbanization, and
growing levels of unemployment and poverty in many cities. Unemployment is particularly
high and an important factor in continued levels of low human well-being and slow growth.
Synergistic growth in the chemical industries could have positive spin-offs for the socioeconomic development. The use of chemical further leads to development in field of
Research and development. This chapter describes about benefits of the project on
improvements in the physical infrastructure, social infrastructure, Employment potential in the
region.
8.1 IMPROVEMENT IN THE SOCIAL INFRASTRUCTURE
From the very initial stage of the inception of the project, infrastructure development in and
around the project site has kept in consideration. Infrastructure development will be done
based on actual requirement socio-economic development of the region. The infrastructure
development will be rolled out as part of companys CSR activity.
8.1.1 CSR Activities
M/s. Privi Organics Ltd. has plans to institutionalise the Corporate Social Responsibility (CSR)
activities so that the CSR transforms itself into personal Social Responsibility for the personnel
manning the factory.
1. Will create residential, medical, educational and recreational facilities for our employees.
2. Rural Development Programs for upliftment of people in the form of de-addiction, selfhelp, vocational training and guidance etc
3. Organise blood donation Camp.
4. Save girl child programm in rural areas
5. Food & Clothes distribution to Old age home.
6. Sponsoring / Providing Hobby workshop for ladies & children.
7. Sponsoring / Providing English Speaking classes.
8. Free medical check up for villagers.
9. Tree Plantation in rural areas.
10. Provision of sanitation (toilets) facility.
Project Benefit
8.1
This project will increase the economic activities around the area, creating avenues for
direct/ indirect employment during construction and operation phase of the project. There
would be a wider economic impact in terms of generating opportunities for other business
like workshops, marketing, repair and maintenance tasks etc.
The continuous inflow of people will require local transport systems like autos, taxis etc which
would help economic boost.
During construction phase of the project, this project will provide temporary employment to
many unskilled and semi-skilled labours in nearby villages. This project will also help in
generation of indirect employment to those people who render their services for the
personnel directly working in the project.
Project Benefit
8.2
Project Benefit
8.3
CHAPTER 9
ENVIRONMENTAL MANAGEMENT PLAN
9.0 INTRODUCTION
Environmental Management Plan (EMP) consists of implementation of various pollution
abatement measures for project. The EMP lists out all these measures for the construction and
operational phase of the project. The EMP is prepared keeping in view all possible strategies
oriented towards impact minimization. The EMP for the proposed project is divided into two
phases i.e. Construction and Operational phase. The detailed EMP for Plant area is also given
in below mentioned sections. The component-wise environmental impact statement is
summarized below and tabulated in Table 9.7.
9.1 ENVIRONMENT, HEALTH AND SAFETY (EHS)
It is of utmost concern for a company to conduct its business in a manner that will
promote the protection of the occupational Health & Safety; Welfare of its employees
and others involved in or affected by its business operations and address the
environmental concerns regarding sustainable development.
As an integral part of the companys business performance, the company will declare full
commitment to achieve high levels of performance in Health, Safety and Environment.
Continual improvements in Safety, Health and Environment will be recognized as essential
for the future success of the company.
9.2 ENVIRONMENTAL MANAGEMENT PLAN
An Environmental Management Plan (EMP) is prepared to mitigate and manage various
environmental impacts identified. The EMP presents the project specific guidelines on:
Environmental management strategies
Specialized engineering construction procedures in relation to environmental guidelines of
the country
Spill prevention and control
Management of wastes and hazardous chemicals
Air, water and soil quality protection
Noise control
Soil erosion control and slope stabilization
Vegetation, wildlife and habitat protection
Socio-economic and welfare considerations
9.1
9.2
project
facilities
including
statutory
compliance,
pollution
prevention,
environmental monitoring, etc. The flow diagram for Organogram for EHS is shown in Refer Fig
9.1.
The Project Proponent will be responsible for providing all the necessary funding and
administrative support to the EMP and be ultimately responsible for carrying out this
project with total commitment to environmental matters.
The General Manager (Quality Systems), working on behalf of the project proponent, will
be responsible for coordinating the activities of a technical staff, responsible for
monitoring and managing compliance of the EMP. The responsibilities include technical,
community and administrative matters related to the EMP, including liaison with the
general public in the project area, other parties and regulatory bodies on environmental
issues related to the project. This person will also keep the local communities informed of
the environmental compliance of the project and properly address any issues of their
concern.
There will be EHS (Deputy Manager) for overseeing all environment and safety responses
to ensure the implementation of EMP mentioned during construction and operation
phase including findings / recommendations of third party audits and monitoring results
as mentioned in the EMP.
The EHS (Assistant Manager) with the help of the technical staff, will be responsible for
monitoring the compliance of the EMP (for which they will be given adequate training)
and must report to General Manager.
The EHS (Executive) will be responsible for ensuring full compliance with environmental
matters related to construction activities, as laid down in the EMP. The EHS (Supervisor)
will ensure that all his workers are properly briefed in environmental matters in terms of
Dos and Donts while they work on the project. The cost towards implementation of EMP
is the part of the bidding document so that the related costs are included in the
contract.
9.3
monitoring will be employed by company and will directly report to the GM (Quality
Systems) of the organizations operations.
VP
Operations
Technology
GM
QUALITY SYSTEMS
EHS
EHS
DEPUTY MANAGER
DEPUTY MANAGER
EHS
ASSISTANT MANAGER
EHS
EXECUTIVE
EHS
SUPERVISOR
EHS
Office/Chem
Figure 9.1: Organogram for EHS
The proposed project would create impacts on the environment in two distinct phases:
Phase 1: During the construction phase which may be regarded as temporary or short term.
Phase 2: During the operation phase which will have marginal impact.
9.5 EMP FOR CONSTRUCTION PHASE
The overall impact of the pollution on the environment during construction phase is localized
in nature and is for a short period. In order to develop effective mitigation plan, it is important
to conceive the specific activities during construction phase causing environmental impact.
The various activities during construction phase have been identified and listed in Chapter 4
along with their impacts. The following subsections describe the mitigation measures planned
9.4
It will be ensured that all the vehicles deployed for the project possess Pollution under
Control (PUC) Certificate.
A schedule for the operation of vehicles will be established to minimize to the extent
practicable, the time of operation of emission sources.
Water will be sprayed by high pressure water hoses during dust generating construction
activities e.g. excavation, crushing/demolishing, concrete mixing, material handling etc.
to suppress dust.
9.5
As far as possible unleaded and Sulphur free petrol will be used for petrol driven vehicles.
Approach road side plantation will further act as sink to gaseous emission
Construction equipment requiring minimum water for cooling and operation for optimum
effectiveness will be chosen.
High pressure hose will be used for cleaning and dust suppression purpose.
Drip and sprinkler system will be provided for spraying water in green belt.
a. Surface water quality
Rainy season will be avoided for cutting and filling of earth work.
Soil binding and fast growing plants will be grown around the construction site before
commencement of construction activity to reduce soil erosion.
Temporary drainage channels will be provided for collection of water and facilitating rain
water harvesting.
Water used in washing and flushing pipelines will be discharged into storm water drains or
natural drains after settling.
Rain water harvesting will be done to control water logging and surface runoff.
b. Ground water quality
9.6
Ear plugs and/muffs will be provided to construction workers working near the noise
generating activities / machines / equipment.
Vehicles and construction equipment with internal combustion engines without proper
silencer will not be allowed to operate.
Construction equipment meeting the norms specified by EP Act, 1986 will only be used.
Noise control equipment and baffling will be employed on generators especially when
they are operated near the residential and sensitive areas.
Noise levels will be reduced by the use of adequate mufflers on all motorized
equipment.
Heavy and noisy construction work will be avoided during night time.
Earth/Construction Debris
Excavated earth will be backfilled in the trench after foundation work and top soil will be
restored for the agricultural purpose. The remaining excavated material will be disposed
off or spread out in low laying area.
The natural gradient of the area will be maintained after reinstatement to avoid water
logging.
The construction debris as well as debris from demolition work will be utilized within the site
for levelling purpose and base course preparation of internal roads.
The materials like steel and other recyclable material will be segregated and reused or
sold to authorize vendors for reuse.
Topsoil Segregation
Existing topsoil which is removed during construction will be stockpiled temporarily for
replacement whenever required.
Topsoil and sub-soil will be segregated during trenching and stockpiled separately.
9.7
Topsoil will not be used for padding, backfill or trench breakers, under any circumstances.
9.8
Fire / Explosion
During the design stage of the Plant strict adherence to the pollution prevention and
Control measures will be made, the environmental impacts will be moderated to the
Minimum possible levels during the operation phase. In general, the environmental
management plan during operational phase of the plant will be directed to the following:
It will be ensured that all the pollution control / environment management systems are
commissioned before the commencement of operation of the project.
Wherever possible, the control systems will be interlinked with the operational units, so that
failure of the control system will shut down the respective operational unit.
Regular performance evaluation of the control systems will be undertaken to ensure their
optimum performance.
Preventive maintenance schedule of the control systems will be matching with that of the
respective operational unit.
Regular monitoring for various components of environment will be undertaken to ensure
effective functioning of pollution control measures as well as to safe guard against any
unforeseen changes in environment.
9.7.1 Management of Hazardous Raw materials
During the, Hazardous raw materials will be handled with every care and precautions. SOP
will be followed for handling the chemicals. The list of raw materials and storage is given
below in the Table.
Table 9.1: List of Hazardous raw materials and storage
S.no
1
2
3
4
5
6
7
8
Chemicals
Phase of Chemical
Storage Condition
Type of Storage
Capacity
Acetic acid
Liquid
Above ground
Phosphoric acid
Liquid
Above ground
Acetic anhydride
Liquid
Above ground
Methanol
Liquid
Above ground
Toluene
Liquid
Above ground
Sulfuric acid
Liquid
Above ground
OTBP
Liquid
Above ground
Aniline
Liquid
Above ground
9.9
&
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
Camphene
Liquid/Solid
Above ground
Limonene
Liquid
Above ground
B-pinene
Liquid
Above ground
Cyclohexane
Liquid
Above ground
EDC
Liquid
Above ground
Petroleum Ether
Liquid
Above ground
Acetone
Liquid
Above ground
Boron trifluoride
Liquid
Above ground
Sodium hydroxide
Solid
Above ground
Isopropyl alcohol
Liquid
Above ground
Hydrogen
Gas
Above ground
Hydrogen Peroxide
Liquid
Above ground
Perchloric acid
Liquid
Above ground
1Drum [180kg]
Triethylamine
Liquid
Above ground
Solid
Above ground
Potassium hydroxide
24
Copper Chromite
Solid
Above ground
25
Ammonia
Liquid
Above ground
28 Drum [200kg ]
26
Hydroxyl
sulphate
Solid
Above ground
amine
Handling procedure
The chemical will be
received by
authorized personal
& name of the item,
date of receipt to be
recorded.
A log book will be
maintained with
date, quantity used
& the purpose.
Responsibility &
Accountability
Safety Measures
Quality control
chemist &
Manager
quality control
9.10
OTBP
Aniline
Camphene
Limonene
B-pinene
Cyclohexane
EDC
Petroleum Ether
Acetone
Boron trifluoride
Sodium hydroxide
Isopropyl alcohol
Hydrogen
Hydrogen Peroxide
Perchloric acid
Triethylamine
Potassium hydroxide
Copper Chromite
Ammonia
Hydroxyl amine sulphate
Entire process is carried out in the closed reactors with proper maintenance of pressure
and temperature.
9.11
The unit will also provide adequate stack monitoring facilities for the periodic
monitoring of the stack to verify the compliance of the stipulated norms.
Adequate stack heights as per the CPCB estimation will be provides at all locations to
reduce GLCs of pollutants.
The air quality surveillance program will be undertaken for proposed and the program
may be strengthened properly keeping in view the combined maximum impacts from
post-project activities particularly in critical downwind directions.
Periodic maintenance of machinery and vehicles will be undertaken to reduce the noise
impact.
Noise suppression measures such as enclosures, buffers and / or protective measures will
be provided (wherever noise level is more than 75 dB (A)).
Employees will be provided with Personal Protective Equipments like earplugs or earmuffs,
wherever required.
Extensive oiling, lubrication and preventive maintenance will be carried out or the
machineries and equipments to reduce noise generation.
The green belt area will be developed within industrial premises and around the
periphery to prevent the noise pollution in surrounding area.
Noise monitoring will be carried out to check the efficacy of maintenance schedules
undertaken to reduce noise levels and noise protection measures.
Good quality digital sound level meter will be in place to monitor noise level.
9.12
Details
Existing as
per
consent
*2
Domestic
Industrial
Processing
Current
Actual
Proposed
Total
Existing as
Current
per consent
actual
Proposed
Total
40
40
49
28
28
35
190
190
192
83.0
75
84.0
468
468
218.2
686.2
24.0
18
21
Industrial
3
Cooling
& Boiler
Feed
9.13
Agricultur
4
al/
24
24
11
0#
722
722
240.2
927.2
135.0
121
19
140
gardening
Total
Note:
* No major increase in water consumption and effluent generation of industrial processing
though new addition of products as we are going to use resin technology in process instead
of water wash.
@ Boiler & cooling tower effluent generation reduced due to the use of demineralization
plant which have better feed quality which results low effluent discharge in compare to
existing softener and incorporation of online filters which removes foreign particles and
decreases the effluent quantity and also increases the performance of cooling tower.
# recycling/ reused of effluent will be used for gardening after treatment.
9.14
Sr.
Parameters
No.
Effluent
After Treatment
pH
6.5 -8.5
100
BOD (mg/l)
100
No. of
Name of Unit
Units
Capacity
Equalization Tank
45 M3
Primary Clarifier
45 M3
Secondary Clarifier
45 M3
Aeration Tank
540 M3
Sand Filter
02 M3
02 M3
Reverse Osmosis
300 M3/day
72 M3/day
The mitigation measures for minimizing the impacts on water environment in general includes
following:
Use of high-pressure hoses for cleaning the floor to reduce the amount of wastewater
generated.
9.15
of processing units.
Unit proposed to recharge ground water during the monsoon to balance the water
table to make a recharge sump in own premises.
Advance controls and instrumentation for operations and control and leak detection
techniques will be implemented for this project.
9.7.5
The management plan for this component of environment lays emphasis on development of
greenbelt comprising of appropriately selected species of shrubs and trees. It is recommended
that plantation will be made on sites, road sides, around waste treatment units and on
adjacent degraded forest and barren land. Such a development of greenbelt and plantation
of shrubs and trees will not only significantly reduce or mitigate adverse impacts due to
aerosols and gaseous pollutants, noise, odour and nuisance etc, but also, serve as shelter belts
for avifauna, stabilize and improve soil permeability and aesthetic environment.
9.7.6 Management of Hazardous Waste
Hazardous wastes like ETP waste and MEE waste will be handled as per Hazardous Wastes
Handling rules, 2008. Hazardous materials required at the site during construction activities will
be stored as per accepted industrial safety norms. ETP Sludge generated will be sent to TSDF
site along with MEE waste for final disposal. Discarded Containers and spent oil will be sold to
authorize party or reused within plant premises. Discarded Asbestos and Spent catalyst will
be sold to authorize party.
Hazarous waste will be managed as per the following guidelines.
Hazardous waste will be stored in proper storage room and handed over to authorized
vendor for final disposal.
The collection, treatment and disposal of hazardous waste will be as per Hazardous
waste (Management and Handling) Rules 2008, and hence no adverse impact on land
environment is envisaged.
9.16
Some basic amenities, viz. education, regular medical checkup in the villages may be
taken up.
Formal and informal training to be provided to the employees of the effected villages due
to the project will be taken up on priority basis. Job oriented skill training, courses may be
organized.
Personal protective facilities like helmets, safety (gas) mask / safety dress, shoes etc. are
ensured for all workers, engaged in operation.
9.7.8 Management of Traffic
Two gates, one for entry and the other for exit, will be provided with 9 m wide approach
roads.
Traffic Signals will be exhibited at all appropriate locations.
Convex mirror placed along all critical points for visibility.
Adequate Ramp Feeds will be provided.
Flow of traffic is eased out by providing adequate entries and exits space.
Zebra crossings will be provided on the existing road for pedestrian access.
Entry and exit will be managed by security personnel who will also regulate traffic.
Thus the traffic management will be easily and smoothly monitored without any
hindrances to the regular flow of traffic on the main road.
9.8 ADDITIONAL MITIGATION MEASURES
In addition to the above suggested measures for management of air, water, soil, traffic etc
following additional measures will be provided.
9.8.1 Water Conservation
Water conservation will be practiced to the extent possible by use of reclaimed water for all
non potable application like gardening, lawns an, car washing, flushing toilets etc.
a. Minimizing Water Consumption
A combination of water saving appliances and water management measures will be
planned in the plant. The message of water conservation will be spread to all occupiers on
site by way of awareness campaigns and circulars. Specific measures that will be
implemented include the following:
b. Management Measures
Reduce toilet cistern volume in single flush models.
Promote awareness on water conservation and reducing water wastage.
9.17
9.18
selected.
Gravity flow will be preferred wherever possible to save pumping energy.
9.8.3 Storm Water Management
Rainfall intensity of 100 mm/hr is considered for the design calculations. The size of the drain
dimension is 10.5 x 15.0 x 2.25 M.
Rational Formula for calculating the runoff =Q=(C*I*A)
Q= Run off in m3/hr
I=Intensity of rainfall in mm/ hr
A=Catchments area in hectares
C=Runoff co-efficient
Annual average rainfall
Land use type
Area (M2)
Coefficient runoff
Rainfall (m)
Quantity of
rain
water (M3)
Roof top area
Green Area
Total
2686.00
0.9
3.413
8250.5
18.00
0.3
3.413
18.4
2704.00
8268.9
Harvested water will be collected in underground tanks of 350 KL and 150 KL. The stored
water shall be used for firefighting as well process.
9.8.4 Vehicle Parking & Management Plan
Parking space for vehicles will be provided for loading and unloading products. The
attached Master layout plan shows the parking plan. Adequate roads to cater to two way
traffic and to meet the fire regulations are planned in the complex.
9.8.5 Green Belt Development
An ideal green belt always imparts scenic beauty besides providing roosting/perching place
for birds and ground surface for naturally available reptiles, other flora and fauna species, to
make the area more natural and hazard free.
Most of the existing trees will be retained at site so as to minimize adverse impact on flora
and fauna. It is proposed to plant local fast growing species for landscaping. Development
of green belt with carefully selected native plant species is of prime importance due to their
capacity to reduce noise and air pollution impacts by attenuation / assimilation and for
providing food and habitat for local macro and micro fauna. This not only overcomes the
9.19
problem but also enhances the beauty of area that will attract bird and insect species and
by this way ecology of the area will maintain to a great extent. For developing the greenbelt
in and around proposed project sites care need to be taken to plant the evergreen species.
The planting of evergreen species may have certain advantages that may reduce the
environmental pollution.
Preparation of Greenbelt Plan
The proposed greenbelt development will be of a suitable width along the periphery of
project site area including unit complex, space between the units located within the project,
along the roads, storage areas, loading / unloading areas of products etc.
9.20
Botanical Name
Common Name
Type
Quantity (No.)
1.
Hyophorbe lagenicaulis
Bottle Palm
Flowering Plant
63
2.
Areca catechu
Areca Palm
Tree
50
3.
Saraca asoka
Ashok
Tree
45
4.
Mangifera indica
Mango
Tree
15
5.
Azadirachta indica
Neem
Tree
04
6.
Rosa
Rose
Shurb
57
7.
Cycas revoluta
Cycus
Shurb
18
8.
Delonix regia
Gulmohor
Tree
08
9.
Cassia fistula
Bahava
Tree
09
10.
Mimusops elengi
Bakul
Tree
04
11.
Nyctanthes arbor-tristis
Parijatak
Tree
12
12.
Bauhinia racemosa
Apta
Tree
17
13.
Bombax ceiba
Kate sawar
Tree
10
14.
Anthocephallus cadamba
Kadamb
Tree
06
15.
Alstonia scholaris
Satwin
Tree
15
16.
Citrus sp
Lemon
Tree
06
17.
Ziziphus mauritiana
Ber
Tree
09
18.
Erythrina indica
Pangara
Tree
10
19.
Ficus retusa
Nandruk,
Tree
21
20.
Putranjiva roxburghii
Putranjiva
Tree
07
21.
Albizia lebbeck
Shirish
02
22.
Bambusea
Golden Bamboo
Tree
Grass
23.
Cordia myxa
Cordia
Flowering Plant
18
24
Alstonia macrophylla
Alstonia
Tree
11
25
Michelia champaca
Son chafa
Tree
17
26
Plumbago zeylanica
White plumbago
Shurb
16
27
Adhatoda vasica
Adulasa
Shurb
13
28
Bougainvillea spectabilis
Bougainvillea
Flowering Plant
14
Total
23
500
b) Roadside Plantation
Roadside plantation plays a very important role for greening the area, increasing the shady
area, increasing aesthetic value and for eco-development of the area. The approach roads
to project site will be planted with flowering trees. Trees will be planted to increase aesthetic
value as well as shady area along the roads.
9.21
Each plant shows different air pollution tolerance level depending upon number of factors.
The trees will be tolerant to air pollutants present in the area & will be able to grow and thrive
on soil of the area, be evergreen, inhabitant, having minimum of leaf fall. The trees will be tall
in peripheral curtain plantation and with large and spreading canopy in primary and
secondary attenuation zone. It is also recommended to plant few trees, which are sensitive
to air pollution as air pollution indicator.
9.8.6 Odour Management Plan
Causes of odour can be bad sanitation, bacterial growth in the interconnecting pipes &
unattended drains etc.
Remedial Measures
Regular use of bleaching powder in the drains to avoid growth of sulphur decomposing
micro-organisms to control H2S generation.
Green belt development in the buffer zone may help at least partially to mitigate /
obfuscate the odour.
If still the odour persists spraying of ultra-fine particles of water or chemicals can be used
along the boundary lines of area sources to suppress odour.
All process vents will be with brime chilling followed by BV+ FA.
Electrical equipments will be properly earthed & lock out/tag out, electrical isolation
method will be developed & displayed at required locations.
Proper training will be given to all the employees at regular time period to bring
awareness among the employees.
Employees will be provided with Personal Protective Equipments like earplugs or earmuffs,
shoes, gloves wherever required.
9.22
Special Health awareness camp and medical camps for primary check up will be arranged
at least once in a year in nearby villages for health check-ups.
During the construction and operation phase villagers will be directly or indirectly employed.
Funds will be provided to arrange extracurricular activities for nearby school and colleges.
9.23
Environmental
Potential Impacts
Impact Evaluation
Water
Construction Phase
No
contamination
impact
No
impact
No
Component
1.
Water
adverse
workers
Surface runoff from site.
Operation phase
Domestic waste water
Surface runoff from site
adverse
adverse
impact
At present Rain water harvesting is done to
Positive impact
of
industrial
waste water
No
impact
adverse
Air Quality
Dust Emission
Construction Phase
Temporary
Construction activities
exposure of dust.
minor impact
&
9.24
S. No.
Environmental
Potential Impacts
Impact Evaluation
Periodic
Construction
insignificant
impact
Component
Particulate
gaseous
i.e.
&
emissions
equipments
of
construction
Temporary
&
certificate.
SO2, NOx
Emission
maintenance
from
DG
Operation of DG set
No
of emissions.
impact
significant
&
emissions
Emissions
from
vehicular
traffic.
No
significant
impact
3.
Noise
Increase
level
in
noise
Construction Phase
No
Operation of construction
silencers.
impact.
movement.
equipment
significant
9.25
S. No.
Environmental
Potential Impacts
Impact Evaluation
Operation Phase
No
Vehicles movement
impact
Component
significant
Generators
with
inbuilt
mufflers
will
be
No
significant
impact.
Land
Land contamination
Construction Phase
No
by
Disposal
impact.
No
debris
waste
construction
and
solid
of
construction
significant
significant
impact.
Metallic waste
No
Impact.
significant
No
facility is proposed.
impact
paper,
plastic
significant
garbage
9.26
S. No.
Environmental
Potential Impacts
Impact Evaluation
etc.
Positive impact
Component
around
waste
treatment
units
and
on
No impact
Construction Phase
5.
Biodiversity
Fauna
construction activities
Operational Phase
Green
belt
will
be
developed
as
per
Positive impact
boundary.
Construction Phase
vehicular
Heavy
movements
movement at site
Increase
6.
Traffic Pattern
of
Vehicular
Operational Phase
Traffic due to commercial
once the site is operational
7.
Socio-
Increase
in
Economic
opportunities
Job
Minor impact
Minor impact
Construction Phase
Positive impact
9.27
Remedial Measures
Regular use of bleaching powder in the drains to avoid growth of sulphur decomposing
micro-organism to control H2S generation.
Green belt development in the buffer zone may help at least partially to mitigate/
obfuscate the odour
If still the odour persists spraying of ultrafine particles of water or chemicals can be used
along the boundary lines of area sources to suppress odour.
9.11 FINDINGS
From the foregoing sections it is clear that environmental considerations are foremost during
development of the project, at all the following levels:
Project sitting
Project construction
The Project will have no significant environmental impacts during construction and
operations.
Project risks will be minimized through rigorous enforcement of international design and
operational standards.
The environmental and safety aspects of the Project are straightforward and well
understood.
9.28
A detailed environmental impact study is carried out. No further studies are required to
elaborate these subjects.
The EMP also provides for establishing, and maintaining a system of environmental monitoring
and auditing to ensure strict compliance of all the measures identified in the EMP, and
minimize adverse environmental and social impacts. Suitable provisions related to
environmental management will also be made in the construction contract agreement.
9.12 CONCLUSIONS
The project can cause minor impacts due to the various activities involved during
construction and operational phase. However, strict adherence to the various mitigation
measures as identified under the EMP, strengthened by adequate environmental monitoring
using best available technology (BAT) and auditing and good construction practices,
including the special construction methods as prescribed, will go a long way in effectively
reducing the impacts as to negligible levels.
During operation phase of the project, none of the routine activities will cause any
noticeable impact on any component of the environment, including the socio-economic
component. Provision of green belt and rain water harvesting, storm water management
and energy conservation will further facilitate in overall scenario management of
Environment.
Thus, it can be concluded on a positive note that after the implementation of the mitigation
measures and Environmental Management Plan, the proposed project will have negligible
impact on environment and will benefit the local people and economy.
9.29
CHAPTER 10
CONCLUSION
The project proponents and developer M/s. Privi Organics Ltd. (Unit-II) seems to be safety
conscious and aware about impacts industrial projects and is environment friendly.
We may conclude as under:
The project proponent will follow all the statutory norms and guidelines as per EPA, 1986
to safeguard environment.
Wastewater generated from the proposed project will be treated in to ETP followed by
R.O and MEE provided in the premises.
Ambient Air Quality of the project site are concerned viz. SPM (PM10 & PM2.5), SO2 and
NOx, their concentrations in the ambient air at the proposed site were observed to be
exceed SPM and SO2 and NOx well within the prescribed limits
No significant impact is seen on flora and fauna as no reserve forest and eco-sensitive
zones are present within 10 km. However Eco-Sensitive Areas (ESA) are present within 5
km radius of project site.
The project will generate employment opportunities during construction stage and also
at operational stage. The standard of living of local people due to employment is likely
to be better, so we may say that it is positive socio-economic impact. The region will
get economic boost.
Overall the project will have positive impact for socio-economic and cultural
development.
Conclusion
10.1
CHAPTER 11
DISCLOSURE OF THE CONSULTANT
11.0 GENERAL INFORMATION
Name of organization
Address
Telephone Nos
+91-265-2371269
+91-265-2371028
+91-9998036028
Fax
+91-265-2371269
info@greencircleinc.com , gccipl@rediffmail.com
11.1 VISION
We shall ensure quality, reliability and continuous technology up gradation thereby enhancing the
value of stakeholders. We should inspire others to create pollution free world in order to achieve
sustainable growth.
11.2 MISSION
Our mission is to become one stop consultancy for all kind of services in the field of environment,
health, Safety and risk by providing optimal solutions and to strengthen our position by adopting
and evolving best practices and principles. We strive to give our customer highest level of
satisfaction based upon a commitment to serve, an understanding of their needs and goals, and a
demonstrated ability to produce results.
11.3 APPROVALS & ACCREDATATIONS
MoEF (Ministry of Environment & Forest) Recognized & Gazetted Laboratory with Field
Monitoring Facility.
Recognized by Ministry of Environment & Forest, New Delhi under EPA 1986
11.1
ISO 9001:2008, 14001: 2004 & OHSAS 18001 Certified organization. Currently NABL, ISO 17025
& BIS system implementation &certification process is in progress.
Gujarat High court Stay order for NABET - No. C/SCA/10311/2012 dated 04/02/2014
11.4 ACTIVITIES
11.2
Person Name
Qualification
Team leader
2
3
4
5
6
7
8
9
10
11
Water Expert
Report finalization
Ecologist
Report preparation
Report Preparation
Laboratory analysis
Air and Noise Monitoring
Report Preparation
Report Preparation
Report Preparation
30+
8
7
6
6
5
6
5
3.1
3.6
12
13
14
15
16
Experience
(Years)
29+
Report preparation
Report preparation
Report preparation
Report preparation
Field monitoring
3.6
3.5
0.5
1
3.0
11.3
CHAPTER 12
COMPLIANCE OF TOR
Compliance
S.
ToR Points
No.
1.
(Reference in
EIA report)
It is enclosed in EIA
Report
XXVII
Project description:
2.
3.
4.
5.
6.
7.
balance).
EIA Report
premises
8.
9.
ToR COMPLIANCE
12.1
Compliance
S.
ToR Points
No.
(Reference in
EIA report)
10.
11.
12.
EIA Report
14.
measures
Report.
15.
16.
17.
Management
plan
for
solid/hazardous
waste
including
2.114-2.115 of the
EIA Report.
ToR COMPLIANCE
12.2
Compliance
S.
ToR Points
No.
19.
20.
(Reference in
EIA report)
operation phase.
EIA Report
Enclosed as
Annexure-IX
Not Applicable
23.
24.
25.
50000 scale).
report.
report.
area.
26.
27.
28.
report.
ToR COMPLIANCE
12.3
Compliance
S.
ToR Points
No.
(Reference in
EIA report)
area
29.
report.
toxicity
factor*,
Nitrate*
(as
N),
Arsenic*,
Chromium*,
EIA report.
32.
report.
33.
34.
Site-specific
micro-meteorological
data
including
mixing
height.
35.
36.
EIA report.
ToR COMPLIANCE
12.4
Compliance
S.
ToR Points
No.
37.
(Reference in
EIA report)
report.
ground water
prime
lands,
pastures,
migratory
corridors, etc.
38.
report.
ToR COMPLIANCE
12.5
Compliance
S.
ToR Points
No.
(Reference in
EIA report)
resources
management
shall
be
studied
Not Applicable
and
presented.
40.
Not Applicable
material
and
coastal
fisheries.
Anticipated
42.
project.
environmental impacts.
43.
report.
ToR COMPLIANCE
12.6
Compliance
S.
ToR Points
No.
(Reference in
EIA report)
45.
46.
published guidelines.
Not Applicable
48.
Not Applicable
50.
52.
Monitoring
pollutants
at
receiving
environment
ToR COMPLIANCE
for
the
12.7
Compliance
S.
ToR Points
No.
(Reference in
EIA report)
of workers
54.
55.
measures.
report.
gaseous emissions.
56.
57.
----
Additional studies:
59.
no. 6.9-
6.10,6.15,6.43-6.44 of
the EIA report.
60.
61.
62.
report.
report.
Not Applicable
ToR COMPLIANCE
12.8
Compliance
S.
ToR Points
No.
(Reference in
EIA report)
EIA report.
no. 8.1
mitigation measures.
66.
be
provided
along
with
item-wise
cost
of
its
Allocation
of
resources
and
responsibilities
for
plan
implementation
68.
ToR COMPLIANCE
12.9
2.
3.
4.
5.
6.
MOM Point
Compliance
Refer Chap 2 page no.2.392.99 of EIA Report.
Refer Chap 9 page no 9.4 of
the EIA Report
Enclosed as Annexure- XV &
XVI
Refer Chap 2 page no.2.103
of EIA Report
Annexure-XII
Annexure-XI
7.
Annexure-X
8.
Annexure-IX
9.
Enclosed as Annexure-XIII
10.
ToR COMPLIANCE
12.10
CHAPTER 13
PUBLIC HEARING
13.0 INTRODUCTION
As per the EIA Notification 2006 and amendment 2009, public consultation is mandatory to seek
the opinion of the people regarding the proposed project through public hearing organized by
the State Pollution Control Board.
Public hearing has been made mandatory for projects located in notified industrial estates or
parks which have not obtained prior environmental clearance under EIA notification, 2006 as
per MoEF OM No. J-11013/36/2014-IA-I dated 16th May 2014.
The environmental public hearing for the proposed expansion of Aroma Chemicals production
by Privi Organics Limited Unit-2 (plot no. C-3,4,5,6,6/1,7,8,9,C-33/1,X-9,10,11, MIDC Mahad),
District Raigad, Maharashtra conducted on 16/9/2014 between 4.27 pm to 4.40 pm at
Karamnuk Kendra, MIDC colony, MIDC, Mahad, District Raigad, Maharashtra under the
chairmanship of Shri Satish Bagal, Additional district Magistrate, Raigad, Maharashtra.
Shri Satish Bagal, Additional District Magistrate, Raigad, Chairman
Shri S. V. Auti, Sub-Regional Officer-MPCB, Mahad was the convener and member of the Public
hearing.
Shri Dilip Khedkar, Regional Officer, MPCB, Raigad &
Shri Sandeep Kadam, Tahsildar, Mahad Taluka were present for the Public hearing.
Total 172 residents participated in public hearing.
To begin with Shri Dilip Khedkar RO-MPCB Raigad explained the public about the purpose of
conducting the public hearing as per the EIA notification 2006. He also informed the present
public that the advertisement regarding today public hearing was published in local news
papers, daily Sagar in Marathi and in the daily The Indian Express in English and appeal public in
large to submit their suggestions, suggestions, views, comments and objections about proposed
expansion of the said projects of Privi Organics Limited to MPCB within 30 days from the date of
Public Notice. He also appeal to present public to come forward and submit their suggestions,
views, comments and objections verbally as well as in writing.
Thereafter, Shri Satish Bagal, Additional District Magistrate Raigad district spoke about purpose
of the public hearing & assured the public present that any questions, objections regarding the
project will be noted & addressed to in a free & fair atmosphere & the same will be video
recorded.
Public Consultation
13.1
Thereafter, Mr S. B. Pathare, Senior Vice President Privi Organics Limited gave information about
the company to the audience, its products & the need for expansion of the plants. He also
informed that the application for EC for all the 3 units was done on 28/2/2013 & the presentation
before the SEAC-1 was done on 31/5/2014. Thereafter the expert technical committee of the
SEAC-1 visited the 3 project sites on 14/6/14 & second presentation before the SEAC was done
on 21/6/14 for remaining compliance. In that meeting it was told to the project proponent that
as per the notification of Ministry of Environment & Forests a Public hearing was required to be
conducted. Accordingly the application was submitted to MPCB to conduct public Hearing &
accordingly advertisement was published in news papers on 15/8/2014 (daily sagar) &
16/8/2014 (The Indian Express). The copies of Draft EIA / EMP & Executive summaries in English &
Marathi were kept to all concerned Government offices for the study of proposed projects.
Mr Pradeep Joshi (Green Circle inc.) on behalf of the Project Proponent gave presentation to
the public in local language regarding the proposed expansion plan for Privi Organics Limited,
Unit-2 (plot no. C-3,4,5,6,6/1,7,8,9,C-33/1,X-9,10,11, MIDC Mahad).
Thereafter the Regional Officer appeal the present public to come forward to submit their
suggestions, comments, objections if any regarding the proposed project and accordingly
following persons has submitted their comments.
Shri Anant Deshmukh (Ex Sarpanch Kamble) informed the public hearing committee that for the
Unit-2 the questions are same which are raised for Unit-1. Hence the project proponent should
abide by the actions it has promised. He thanked all the public hearing committee members as
well as the public for the peaceful conduct & active participation in the public hearing process
& on behalf of all the public informed that they have no objection for the proposed expansion
of unit-2 of Privi Organics Limited.
The details of the questions raised during the public hearing and their answers given by the
project proponent are given below.
Thereafter Shri Satish Bagal, Additional District Magistrate, Raigad thanked the public for
participating in the public hearing process conducted for the proposed expansion of Unit-2 of
Privi organics limited in peaceful manner. He directed the project proponent to execute the
CSR activities as mentioned in the presentation in consultation & coordination with the Gram
Panchayat members of the respective villages.
ensure there is no increase in pollution for the proposed expansion project & also directed the
MPCB authorities to monitor the same.
concluded.
Public Consultation
13.2
PublicHearingPhotos
LIST OF ANNEXURE
Sr. No.
Annexure Number
Name of Annexure
Annexure I
Industry License
Annexure II
EC Letter
Annexure III
Consent to Establish
Annexure IV
Consent to Operate
Annexure V
Annexure VI
River Certificate
Annexure VII
MSEB NOC
Annexure VIII
Annexure IX
EC Compliance
10
Annexure X
11
Annexure XI
12
Annexure XII
13
Annexure XIII
Accident Statistics
14
Annexure XIV
PH Documents
15
Annexure XV
MSDS Products
16
Annexure XVI
MSDS RM
17
Annexure XVII
Site Photographs
Annexure I
Industry License
Annexure II
EC Letter
Annexure III
Consent to Establish
Annexure IV
Consent to Operate
Annexure V
Registration certificate CHW-TSDF,
Taloja
Annexure VI
River Certificate
Annexure VII
MSEB NOC
Annexure VIII
Steam Line Underground NOC
Annexure IX
EC Compliance
Ref.No:POL/U-II/EC/13-14/220
Date : 02.01.2014
To,
Dr. A. Mehrotra,
Director (S) Ministry of Environment &
Forests,
Regional Office, W estern Region, Kendriya
Paryavaran Bhavan
Link Road No.3, E-5, Ravi Shankar Nagar
BHOPAL- 462016 (MP)
H.M.RAFIQ
General Manager- QEHS Systems
Copy to: 1. Shri.P.M.A.Hakeem, IAS (Retd), Chairman, SEIAA.
2. Shri. Dr.S.Devotta, Chairman, SEAC.
3. Member Secretary, MPCB.
4. Secretary, Environment Department & MS.
5. Regional Office, MPCB-Raigad
6. Collector, Raigad.
7. IA-Division, Monitoring Cell, MoEF, Paryavaran Bhavan
8. Director (TC-1), Dy.Secretary (TC-2), Scientist-1, Environment Department
9. Sub Regional Officer, MPCB-Mahad-Raigad
Annexure-A
Compliance Report
SEAC 2010/CR.824/TC-2
Dated 2nd Nov 2011
Manufacture of alpha Pinene, Beta Pinene, Limonene and byproducts by way of backward
integration at MIDC, Mahad by M/s Privi Organics Ltd.- Environmental Clearance Regarding
Point
No
I
ii
iii
iv
vi
SPECIFIC CONDITIONS
COMPLIANCE STATUS
No land development
work/construction work preliminary or
otherwise relating to the project shall
be taken up without obtaining due
clearance from respective authorities.
No additional land shall be used /
acquired for any activity of project
without obtaining proper permission.
For controlling fugitive natural dust
regular sprinkling of water and wind
shields at appropriate distances in
vulnerable areas of the plant shall be
ensured.
Regular monitoring of air quality,
including SPM and SO2 level both in
work zone and ambient air shall be
carried out in and around the power
vii
viii
ix
xi
xii
xiii
xiv
xv
xvi
xvii
xviii
xix
Being complied
xx
xxi
xxii
xxiii
xxiv
xxv
Not Applicable
xxvii
xxviii
xxix
xxx
Will be complied.
xxxi
Annexure X
Fly Ash Disposal
UNIT-II
ANNEXURE X: DETAILS OF FLY ASH GENERATION & DISPOSAL
Ash Generation Data-Year-2012-13
Month
Apr
May
Jun
Jul
Aug
Sep
Oct
Nov
Dec
Jan
Feb
Mar
Total
Total Ash
57.93
51.48
54.45
57.62
57.11
58.98
55.37
38.53
58.09
57.85
59.05
73.70
680.16
Unit II
Proposed
Coal
Ash Limit
Consumption
MT/Day
MT/Day
Coal
Quality
Sulpher
%
90
2.85
120
Imported
Indonesian
9.6
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
47
16.06.2012
Bhalekar
Coal Ash
18130
51
21.06.2012
Bhalekar
Coal Ash
19050
52
22.06.2012
Bhalekar
Coal Ash
20230
55
29.06.2012
Bhalekar
Coal Ash
20970
59
04.07.2012
Bhalekar
Coal Ash
20190
66
11.07.2012
Bhalekar
Coal Ash
16600
78
24.07.2012
Bhalekar
Coal Ash
21150
86
04.08.2012
Bhalekar
Coal Ash
21370
92
09.08.2012
Bhalekar
Coal Ash
20480
10
96
16.08.2012
Bhalekar
Coal Ash
19440
11
99
23.08.2012
Bhalekar
Coal Ash
19230
12
103
30.08.2012
Bhalekar
Coal Ash
21890
Vech. No.
MH12
WZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
Remarks
Weighment Slip no 13404
Weighment Slip no 13463
Weighment Slip no 13480
Weighment Slip no 13588
Weighment Slip no 13658
Weighment Slip no 13758
Weighment Slip no 13937
Weighment Slip no 14120
Weighment Slip no 14189
Weighment Slip no 14272
Weighment Slip no 14398
Weighment Slip no 14541
Sr.
No.
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
13
106
07.09.2012
Bhalekar
Coal Ash
20550
14
116
12.09.2012
Bhalekar
Coal Ash
18770
15
121
18.09.2012
Bhalekar
Coal Ash
18170
16
127
25.09.2012
Bhalekar
Coal Ash
16320
17
128
30.09.2012
Bhalekar
Coal Ash
9590
18
130
06.10.2012
Bhalekar
Coal Ash
12640
19
134
10.10.2012
Bhalekar
Coal Ash
17390
20
140
26.10.2012
Bhalekar
Coal Ash
13470
21
142
26.10.2012
Bhalekar
Coal Ash
18070
22
175
17.12.2012
Bhalekar
Coal Ash
10860
23
176
17.12.2012
Bhalekar
Coal Ash
9780
24
177
20.12.2012
Bhalekar
Coal Ash
14260
25
178
21.12.2012
Bhalekar
Coal Ash
10910
26
221
01.02.2013
R.N.Deshmukh
Coal Ash
13090
27
227
08.02.2013
R.N.Deshmukh
Coal Ash
10420
Vech. No.
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ3738
MH12
FZ4885
MH16 AE
8979
MH12
FZ3738
MH16
AE8979
MH12
FZ3738
MH 12 FZ
4885
MH 12 CH
5503
MH 12 FZ
3738
MH 12 FZ
4885
MH 12 DG
297
MH 12 AU
6399
Remarks
Weighment Slip no 14719
Weighment Slip no 14831
Weighment Slip no 14951
Weighment Slip no 15045
Weighment Slip no 15112
Weighment Slip no 15192
Weighment Slip no 15243
Weighment Slip no 15478
Weighment Slip no 15492
Weighment Slip no 16258
Weighment Slip no 16260
Weighment Slip no 16307
Weighment Slip no 16331
Weighment Slip no 17346
Weighment Slip no 17513
Sr.
No.
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
28
230
12.02.2013
R.N.Deshmukh
FLY ASH
5350
29
30
231
235
12.02.2013
14.02.2013
R.N.Deshmukh
R.N.Deshmukh
FLY ASH
FLY ASH
6260
8290
31
236
14.02.2013
R.N.Deshmukh
FLY ASH
7800
32
237
15.02.2013
R.N.Deshmukh
Coal Ash
9420
33
239
18.02.2013
R.N.Deshmukh
Coal Ash
11190
34
241
19.02.2013
R.N.Deshmukh
Coal Ash
11090
35
245
23.02.2013
R.N.Deshmukh
Coal Ash
9290
36
247
25.02.2013
R.N.Deshmukh
FLY ASH
7110
37
248
25.02.2013
R.N.Deshmukh
Coal Ash
10850
38
252
28.02.2013
R.N.Deshmukh
Coal Ash
9560
39
259
04.03.2013
R.N.Deshmukh
Coal Ash
9590
40
260
04.03.2013
R.N.Deshmukh
FLY ASH
6290
41
261
04.03.2013
R.N.Deshmukh
FLY ASH
4940
42
269
06.03.2013
R.N.Deshmukh
FLY ASH
3970
43
274
08.03.2013
R.N.Deshmukh
Coal Ash
8770
44
275
12.03.2013
R.N.Deshmukh
Coal Ash
9830
45
276
12.03.2013
R.N.Deshmukh
FLY ASH
5990
Vech. No.
MH 06 AQ
9587
MH 06 9565
MH 06 9565
MH 06 AQ
9587
MH 43 E
7670
MH 14 4640
MH 12 AU
6399
MH 14 4640
MH 06 AQ
9587
MH 14 4640
MH12
AU6399
MH 12 AU
6399
MH 06 9565
MH 06 AQ
9587
MH 06 9565
MH 43 E
7670
MH 12 UA
6765
MH 06 AQ
9587
Remarks
Weighment Slip no 17639
Weighment Slip no 17638
Weighment Slip no 17697
Weighment Slip no 17696
Weighment Slip no 17728
Weighment Slip no 17806
Weighment Slip no 17839
Weighment Slip no 17947
Weighment Slip no 18018
Weighment Slip no 18016
Weighment Slip no 18106
Weighment Slip no 18212
Weighment Slip no 18205
Weighment Slip no 18206
Weighment Slip no 18258
Weighment Slip no 18291
Weighment Slip no 18390
Weighment Slip no 18393
Sr.
No.
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
46
47
279
281
14.03.2013
15.03.2013
R.N.Deshmukh
R.N.Deshmukh
Coal Ash
Coal Ash
9550
8010
48
286
20.03.2013
R.N.Deshmukh
Coal Ash
8420
49
287
20.03.2013
R.N.Deshmukh
Coal Ash
7750
50
288
20.03.2013
R.N.Deshmukh
FLY ASH
6860
51
291
25.03.2013
R.N.Deshmukh
Coal Ash
9870
52
295
30.03.2013
R.N.Deshmukh
Coal Ash
7360
Total
Vech. No.
Remarks
MH 14 4640
MH 11 6285
MH 11 M
3844
MH 43 E
7670
MH 06 AQ
9587
MH 11 M
4505
MH 43 E
7670
656430
U-II
Total coal
1683.0
1718.0
1990.0
1820.0
1707.0
1549.0
Bottom Ash
52.57
48.01
58.01
55.38
58.28
52.59
Fly Ash
28.39
30.94
25.98
29.14
25.96
23.55
Total Ash
80.96
78.95
84.00
84.52
84.24
76.15
Oct
Nov
Dec
Jan
Feb
Mar
Total
1737.0
1968.8
1965.1
2051.6
1808.6
1972.4
21970.5
59.69
59.35
53.12
51.77
49.81
48.69
647.28
25.02
23.66
29.97
33.24
33.21
35.80
344.86
84.71
83.01
83.09
85.00
83.02
84.49
992.14
Unit II
Proposed
Coal
Ash Limit
Consumption
MT/Day
MT/Day
2.85
120
9.6
Coal
Quality
Sulpher
%
Imported
Indonesian
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
Vech. No.
Remarks
1
2
3
4
5
6
6
7
9
11
19
20
10.04.2013
10.04.2013
13.04.2013
17.04.2013
22.04.2013
22.04.2013
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
Fly Ash
Fly Ash
Coal Ash
Coal Ash
Fly Ash
Fly Ash
5420
5960
8320
8740
7230
6550
MH06 AQ9587
MH06 9565
MH11 M 3822
MH12 HB 3867
MH06 9565
MH06 AQ
Sr.
No.
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
Vech. No.
Remarks
9587
7
8
9
10
25
26
31
33
24.04.2013
24.04.2013
30.04.2013
01.05.2013
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
Coal Ash
Coal Ash
Fly Ash
Fly Ash
9670
7690
9240
6040
11
34
01.05.2013
R N Deshmukh
Fly Ash
6390
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
50
56
64
72
73
76
77
81
85
88
89
95
108
112
115
117
123
131
136
22.05.2013
31.05.2013
08.06.2013
14.06.2013
18.06.2013
21.06.2013
21.06.2013
26.06.2013
28.06.2013
29.06.2013
02.07.2013
05.07.2013
17.07.2013
19.07.2013
23.07.2013
25.07.2013
30.07.2013
02.08.2013
07.08.2013
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
B.P.Bhalekar
R N Deshmukh
R N Deshmukh
B.P.Bhalekar
B.P.Bhalekar
B.P.Bhalekar
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Fly Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
17340
6430
9720
9970
9690
8750
9610
10180
9390
9350
9800
10250
7600
9110
10170
10050
10090
9900
9310
MH11 M 4505
MH12 RA 8512
MH11 M 3844
MH06 9565
MH06 AQ
9587
MH04 EY 6699
MH12 R 9533
MH11 F 4306
MH11 F 4306
MH12 UA 6765
MH11 F 4306
MH12 UA 6765
MH11 J 4306
MH12 UA 6765
MH 11 F 4306
MH 11 F 4306
MH 11 F 4306
MH06 9565
MH12 UA6763
MH08 H0821
MH08 H0821
MH12 UA6765
MH12 UA6765
MH11 F4306
Sr.
No.
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
141
142
158
164
171
172
175
181
182
190
194
195
200
203
215
216
10.08.2013
12.08.2013
27.08.2013
30.08.2013
06.09.2013
07.09.2013
11.09.2013
19.09.2013
20.09.2013
27.09.2013
30.09.2013
30.09.2013
04.10.2013
09.10.2013
16.10.2013
17.10.2013
B.P.Bhalekar
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
B.P.Bhalekar
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Fly Ash
Coal Ash
Fly Ash
Coal Ash
Coal Ash
Coal Ash
Fly Ash
Coal Ash
9100
10700
9450
10250
11710
10650
11580
10980
23960
11630
23500
11850
9410
8910
18660
9760
47
222
23.10.2013
R N Deshmukh
Coal Ash
9880
48
49
50
229
238
240
R N Deshmukh
R N Deshmukh
R N Deshmukh
Fly Ash
Coal Ash
Coal Ash
51
242
R N Deshmukh
52
53
54
253
257
259
24.10.2013
28.10.2013
29.10.2013
30 10 201
3
11.11.2013
12.11.2013
14.11.2013
55
266
19.11.2013
Vech. No.
Remarks
weighment Slip No. 22184
weighment Slip No. 22211
weighment Slip No. 22594
weighment Slip No. 22692
weighment Slip No. 22845
weighment Slip No. 22856
weighment Slip No. 22883
weighment Slip No. 23021
weighment Slip No. 23037
weighment Slip No. 23165
weighment Slip No. 23233
weighment Slip No. 23242
weighment Slip No. 23313
weighment Slip No. 23417
weighment Slip No. 23542
weighment Slip No. 23552
21290
10040
8760
MH11 F4306
MH08 H 0821
MH08 H 0821
MH08 H 0821
MH08 H 0821
MH08 H 0821
MH08 H 0821
MH08 H 0821
MH10 Z 3243
MH08 H 0821
MH10 Z 2343
MH12 CT 5850
MH08 H 0821
MH08 H 0821
MH10 Z 2343
MH08 H 0821
MH12 CH
9911
MH10 Z 2343
MH08 H 0821
MH08 H 0821
Coal Ash
8950
MH08 H 0821
R N Deshmukh
R N Deshmukh
R N Deshmukh
Coal Ash
Coal Ash
Fly Ash
11030
10250
14180
R N Deshmukh
Coal Ash
8100
MH08 H 0821
MH08 H 0821
MH10 Z 2343
MH12 AQ
5153
Sr.
No.
G .P.
No.
Date
Party Name
Description
Qty. in kgs. /
Nos.
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
267
269
273
275
276
279
281
286
295
296
299
301
306
311
312
315
316
320
321
322
325
22.11.2013
25.11.2013
28.11.2013
03.12.2013
04.12.2013
06.12.2013
09.12.2013
16.12.2013
20.12.2013
21.12.2013
23.12.2013
24.12.2013
27.12.2013
30.12.2013
30.12.2013
03.01.2014
03.01.2014
07.01.2014
07.01.2014
07.01.2014
11.01.2014
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
B.P.Bhalekar
R N Deshmukh
R N Deshmukh
B.P.Bhalekar
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Fly Ash
Fly Ash
Coal Ash
Coal Ash
Coal Ash
Coal Ash
Fly Ash
Coal Ash
Fly Ash
Fly Ash
Coal Ash
Fly Ash
Fly Ash
Coal Ash
Fly Ash
10030
10030
8040
8070
9820
9090
17880
14740
8080
9300
9160
9900
6290
9190
5980
7220
8890
7180
6490
9370
7020
77
334
16.01.2014
B.P.Bhalekar
Fly Ash
7370
78
79
80
81
341
344
347
350
21.01.2014
24.01.2014
27.01.2014
29.01.2014
B.P.Bhalekar
R N Deshmukh
R N Deshmukh
R N Deshmukh
Fly Ash
Coal Ash
Coal Ash
Coal Ash
6360
9280
9800
9310
Vech. No.
Remarks
MH08 H 0821
MH08 H 0821
MH12 HD 4530
MH09 A 9818
MH08 H 0821
MH12 HD 4530
MH10 Z 2343
MH10 Z 2343
MH11 M 4505
MH50 631
MH11 AL 961
MH08 H 0821
MH06 7783
MH43 E 7670
MMK 459
MH06 7783
MH04 AL5029
MH06 9565
MH06 7292
MH09 Q5534
MH06 9565
MH06 AQ
9587
MH06 AQ9587
MH08 H0821
MH08 H0821
MH08 H0821
Sr.
No.
G .P.
No.
Date
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
354
355
359
360
365
372
381
382
386
394
397
408
412
413
419
425
426
434
440
444
447
448
452
463
30.01.2014
30.01.2014
03.02.2014
03.02.2014
04.02.2014
06.02.2014
10.02.2014
10.02.2014
11.02.2014
13.02.2014
17.02.2014
20.02.2014
24.02.2014
24.02.2014
27.02.2014
03.03.2014
03.03.2014
08.03.2014
12.03.2014
17.03.2014
20.03.2014
20.03.2014
25.03.2014
31.03.2014
Party Name
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
B.P.Bhalekar
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
R N Deshmukh
Total
Description
Fly Ash
Coal Ash
Fly Ash
Fly Ash
Fly Ash
Coal Ash
Coal Ash
Fly Ash
Fly Ash
Fly Ash
Fly Ash
Coal Ash
Fly Ash
Coal Ash
Fly Ash
Fly Ash
Coal Ash
Fly Ash
Coal Ash
Coal Ash
Coal Ash
Fly Ash
Fly Ash
Fly Ash
Qty. in kgs. /
Nos.
7340
9580
6430
7950
5000
9500
9950
6830
7180
8270
6550
9530
8150
9170
8350
6660
9320
5650
8690
7260
7630
7280
8780
6200
960,770.00
Vech. No.
Remarks
MH06 9565
MH08 H0821
MH06 AQ9587
MH06 9565
MH06 AQ9587
MH08 H0821
MH08 H0821
MH06 AQ9587
MH06 9565
MH06 9565
MH06 9565
MH08 H0821
MH06 9565
MH08 H0821
MH067783
MH06 9565
MH08 H0821
MH06 AQ9587
MH08 H0821
MH08 H0821
MH43 E7670
MH06 7783
MH06 7292
MH06 AQ9587
Annexure XI
Details of By Product Sold
UNIT-II
ANNEXURE-XI- CHRONOLOGICAL DETAILS OF BY-PRODUCTS DISPOSED / SOLD FOR LAST TWO YEARS
By products sale - 2012 -13
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped
Qty. in
kgs.
DTA/12-13/2000309
30-APR-2012
10860
DTA/12-13/2001853
25-AUG-2012
11960
DTA/12-13/2003719
30-JAN-2013
12300
Total in Kgs
35120
Disposed Qty
Consented
Qty
35.120 MT/ A
24 MT/A
Disposed Qty
Consented
Qty
151.740 MT/A
120 MT/A
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped Qty.
in kgs.
DTA/12-13/2000237
25-APR-2012
Dihydromyrcenol Tops
7425
DTA/12-13/2000238
25-APR-2012
Dihydromyrcenol Tops
7425
DTA/12-13/2000475
16-MAY-2012
Dihydromyrcenol Tops
1815
DTA/12-13/2000728
31-MAY-2012
Dihydromyrcenol Tops
2805
DTA/12-13/2000729
31-MAY-2012
Dihydromyrcenol Residue
4900
DTA/12-13/2000320
31-MAY-2013
Dihydromyrcenol Residue
1485
DTA/12-13/2000838
09-JUN-2012
Dihydromyrcenol Tops
1485
DTA/12-13/2001114
30-JUN-2012
Dihydromyrcenol Tops
4060
DTA/12-13/2001208
07-JUL-2012
Dihydromyrcenol Tops
2475
DTA/12-13/2001367
19-JUL-2012
Dihydromyrcenol Tops
7920
DTA/12-13/2001558
04-AUG-2012
Dihydromyrcenol Tops
7425
DTA/12-13/2001651
10-AUG-2012
Dihydromyrcenol Tops
2970
DTA/12-13/2001971
05-SEP-2012
Dihydromyrcenol Tops
7425
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped Qty.
in kgs.
DTA/12-13/2002031
08-SEP-2012
Dihydromyrcenol Tops
2475
DTA/12-13/2002224
27-SEP-2012
Dihydromyrcenol Tops
165
DTA/12-13/2002494
15-OCT-2012
Dihydromyrcenol Tops
165
DTA/12-13/2002530
16-OCT-2012
Dihydromyrcenol Tops
7425
DTA/12-13/2002567
19-OCT-2012
Dihydromyrcenol Tops
4125
DTA/12-13/2002790
12-NOV-2012
Dihydromyrcenol Tops
7425
DTA/12-13/2003208
19-DEC-2012
Dihydromyrcenol Tops
7425
DTA/12-13/2003240
22-DEC-2012
Dihydromyrcenol Tops
5280
DTA/12-13/2003406
07-JAN-2013
Dihydromyrcenol Tops
7425
DTA/12-13/2003407
07-JAN-2013
Dihydromyrcenol Tops
7425
DTA/12-13/2003410
08-JAN-2013
Dihydromyrcenol Tops
3850
DTA/12-13/2003506
15-JAN-2013
Dihydromyrcenol Tops
7425
DTA/12-13/2003801
04-FEB-2013
Dihydromyrcenol Tops
4125
DTA/12-13/2003844
07-FEB-2013
Dihydromyrcenol Tops
660
DTA/12-13/2003891
11-FEB-2013
Dihydromyrcenol Tops
7425
DTA/12-13/2004098
23-FEB-2013
Dihydromyrcenol Tops
4455
DTA/12-13/2004232
05-MAR-2013
Dihydromyrcenol Tops
7425
DTA/12-13/2004511
25-MAR-2013
Dihydromyrcenol Tops
6600
DTA/12-13/2004511
25-MAR-2013
Dihydromyrcenol Tops
825
Total in Kgs
151740
Disposed Qty
Consented
Qty
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped
Qty. in kgs.
DTA/12-13/2004517
26-MAR-2013
DIPENTENE
7875
DTA/12-13/2004464
21-MAR-2013
DIPENTENE
6300
DTA/12-13/2004386
16-Mar-13
DIPENTENE
7875
DTA/12-13/2004385
16-Mar-13
DIPENTENE
7875
DTA/12-13/2004384
16-Mar-13
DIPENTENE
7875
DTA/12-13/2004380
15-Mar-13
DIPENTENE
7875
DTA/12-13/2004379
14-Mar-13
DIPENTENE
7875
DTA/12-13/2004097
23-FEB-2013
DIPENTENE
3150
DTA/12-13/2004074
23-FEB-2013
DIPENTENE
7875
DTA/12-13/2004037
20-FEB-2013
DIPENTENE
7875
DTA/12-13/2003958
16-FEB-2013
DIPENTENE
7875
DTA/12-13/2003957
16-FEB-2013
DIPENTENE
7875
DTA/12-13/2003956
16-FEB-2013
DIPENTENE
7875
DTA/12-13/2003955
16-FEB-2013
DIPENTENE
7875
DTA/12-13/2003066
7-Dec-12
DIPENTENE
7756
DTA/12-13/2003065
07-DEC-2012
DIPENTENE
7888
Total in Kgs
119594
Disposed Qty
Consented
Qty
119.594 MT/A
1424 MT / A
Invoice Date
Customer Name
Description
Shipped Qty.
in kgs.
DTA/13-14/2000253
23-APR-2013
10000
DTA/13-14/2000577
14-MAY-2013
11830
DTA/13-14/2004524
22-JAN-2014
15510
Disposal
Qty MT/A
Consented
QTY MT/A
34.340 MT
24 MT / A
37340
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped Qty.
in kgs.
DTA/13-14/2000353
30-APR-2013
Dihydromyrcenol Tops
6930
DTA/13-14/2000674
18-MAY-2013
Dihydromyrcenol Tops
7425
DTA/13-14/2000940
07-JUN-2013
Dihydromyrcenol Residue
8100
DTA/13-14/2001656
18-JUL-2013
Dihydromyrcenol Tops
7425
DTA/13-14/2002077
17-AUG-2013
Dihydromyrcenol Tops
7425
DTA/13-14/2002680
21-SEP-2013
Dihydromyrcenol Residue
8100
DTA/13-14/2002871
06-OCT-2013
Dihydromyrcenol Tops
14620
DTA/13-14/2003099
23-OCT-2013
Dihydromyrcenol Tops
7095
DTA/13-14/2003100
23-OCT-2013
Dihydromyrcenol Tops
7425
Disposal
Qty MT/A
Consented
QTY MT/A
168.070
MT/A
120 MT/A
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped Qty.
in kgs.
DTA/13-14/2003955
20-DEC-2013
Dihydromyrcenol Residue
8100
DTA/13-14/2004300
10-JAN-2014
Dihydromyrcenol Tops
7425
DTA/13-14/2004290
07-JAN-2014
Dihydromyrcenol Tops
7425
DTA/13-14/2004640
28-JAN-2014
Dihydromyrcenol Tops
7425
DTA/13-14/2005144
25-FEB-2014
Dihydromyrcenol Tops
18460
DTA/13-14/2005400
13-MAR-2014
Dihydromyrcenol Tops
14990
DTA/13-14/2005495
21-MAR-2014
Dihydromyrcenol Tops
7425
DTA/13-14/2005496
21-MAR-2014
Dihydromyrcenol Tops
7425
DTA/13-14/2005587
26-MAR-2014
Dihydromyrcenol Tops
7425
DTA/13-14/2005694
31-MAR-2014
Dihydromyrcenol Tops
7425
168070
Disposal
Qty MT/A
Consented
QTY MT/A
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped
Qty. in kgs.
DTA/13-14/2002858
04-OCT-2013
AAS MOHAMMAD
TRADING CO
2800
DTA/13-14/2002910
10-OCT-2013
AAS MOHAMMAD
TRADING CO
180
DTA/13-14/2004261
07-JAN-2014
AAS MOHAMMAD
TRADING CO
2450
DTA/13-14/2005035
19-FEB-2014
AAS MOHAMMAD
TRADING CO
2100
DTA/13-14/2005035
19-FEB-2014
AAS MOHAMMAD
TRADING CO
2800
DTA/13-14/2004945
12-FEB-2014
AAS MOHAMMAD
TRADING CO
DTA/13-14/2004945
12-FEB-2014
AAS MOHAMMAD
TRADING CO
1260
DTA/13-14/2004945
12-Feb-14
AAS MOHAMMAD
TRADING CO
1080
DTA/13-14/2005031
19-FEB-2014
AAS MOHAMMAD
TRADING CO
1080
DTA/13-14/2005450
17-Feb-14
AAS MOHAMMAD
TRADING CO
Rosaxanol Tops
4900
720
Disposal
Qty MT/A
Consented
QTY MT/A
22.355
MT/ A
120 MT / A
Excise Invoice No
Invoice Date
Customer Name
Description
Shipped
Qty. in kgs.
DTA/13-14/2005450
17-Feb-14
AAS MOHAMMAD
TRADING CO
825
DTA/13-14/2005450
17-Mar-14
AAS MOHAMMAD
TRADING CO
2160
Disposal
Qty MT/A
Consented
QTY MT/A
Annexure XII
Hazardous Waste Disposal
Apr-13
HW Gen
Qty/Month
Disposal
Qty,
MT/M
53.85
53.85
MWML - Taloja
II
9.27
9.27
MWML - Taloja
53.04
53.04
MWML - Taloja
II
24.96
8.110
24.96
8.110
MWML - Taloja
41.89
8.430
41.89
8.430
MWML - Taloja
NIL
NIL
NA
NIL
NIL
NA
34.35
35.35
NIL
NIL
NA
NIL
NIL
NA
Unit
Consent No
Consented
Qty/Month
I
II
I
II
I
II
I
Unit I - Consent
no.
BO/PAMS/R/EIC
No. RD - 238012/CC - 158 dt
30.12.2012
Unit I - 9.8 MT /
M. ( 117.6
MT/A)
II
I
Disposal to
MWML - Taloja
MWML - Taloja
MWML - Taloja
7.09
7.09
MWML - Taloja
16.97
16.97
MWML - Taloja
18.98
18.98
MWML - Taloja
15.93
15.93
MWML - Taloja
32.63
16.605
32.63
16.605
MWML - Taloja
29.87
18.600
MWML - Taloja
II
29.87
18.600
19.420
19.420
MWML - Taloja
II
17.53
16.750
17.53
16.750
MWML - Taloja
34.05
MWML - Taloja
Unit - I - Total
34.05
248.17 MT/ A
Unit - II - Total
230.16 MT / A
Unit I - 9.8 MT /
9.960
9.960
MWML - Taloja
II
I
II
I
II
Unit II - Consent
No. : -BO / RO Raigad / AS (T) /
EIC - RD -1665 10/R/CC-221
dt.04.11.2011
Unit II - 8 MT /
M ( 96 MT/A)
I
II
Unit I --
MWML - Taloja
MWML - Taloja
MWML - Taloja
Month
May-13
Jun-13
Jul-13
Aug-13
Sep-13
Oct-13
Nov-13
Dec-13
Jan-14
Feb-14
Mar-14
Unit
Consent No
II
BO/AST/EIC.No.RD-256313/A/Gen-5927
dated.12.07.2013
HW Gen
Qty/Month
Disposal
Qty,
MT/M
M. ( 117.6
MT/A)
19.01
19.01
Disposal to
MWML - Taloja
76.01
76.01
MWML - Taloja
25.89
25.89
MWML - Taloja
15.73
15.73
MWML - Taloja
18.57
18.57
MWML - Taloja
15.69
15.69
MWML - Taloja
NIL
NIL
16.76
16.76
MWML - Taloja
17.04
17.04
MWML - Taloja
8.15
8.15
MWML - Taloja
NIL
NIL
NA
41.06
41.06
MWML - Taloja
II
16.31
16.31
MWML - Taloja
54.136
54.136
MWML - Taloja
II
29.27
29.27
MWML - Taloja
8.41
8.41
MWML - Taloja
II
8.22
8.22
MWML - Taloja
II
I
II
I
II
I
II
I
II
Unit II -- Consent
No. : -BO / RO Raigad / AS (T) /
EIC - RD -1665 10/R/CC-221
dt.04.11.2011
Unit II - 8 MT /
M ( 96 MT/A)
NA
33.75
33.75
MWML - Taloja
II
38.51
38.51
MWML - Taloja
18.37
18.37
MWML - Taloja
II
17.55
17.55
MWML - Taloja
44.05
44.05
MWML - Taloja
II
28.77
20.77
MWML - Taloja
Consented
Qty/Month
Annexure XIII
Accident Statistics
2010-2011
2011-2012
2012-2013
2013-2014
Error of Judgment
Unsafe condition
Inattention
poor maintenance
Poor Housekeeping
Lack of supervision.
Poor communication
Design failure/Inadequate
system.
Unsafe act
Total
38
33
28
27
Annexure XIV
PH Documents
Annexure XXI
Public Hearing Documents
Annexure XV
MSDS Products
Version: EN/01
Revision No.: 00
Alpha damascone
Version: EN/01
C10610004
SLOVAKIA (Bratislava) + 421 2 54 774 166; SLOVENIA (Ljubljana) + 386 41 635 500; SPAIN (Madrid) + 34 156
20420; AUSTRIA (Vienna) + 43 1 406 43 43; BELGIUM (Brussels) + 32 70 245 245; BULGARIA (Sofia) + 359 2
9154 378/+359 887 435 325; CZECH REPUBLIC (Prague) + 420 22 49 192 93; DENMARK (Copenhagen) + 45
82 12 12 12; FINLAND (Helsinki ) + 358 9 471 977; FRANCE (Paris) + 33 1 40 05 48 48; GERMANY (Berlin) + 49
30 192 40; GREECE (Athens) + 30 21 07 79 37 77; HUNGARY (Budapest) +36 80 20 11 99; ICELAND
(Reykjavik) + 354 543 22 22; IRELAND (Dublin) +353 1 837 9964 (medical professionals) +353 1 809 2166
(public); ITALY (Rome) +39 06 305 4343; LATVIA (Riga) +371 704 2468; LITHUANIA (Vilnius) + 370 5 236 20
52/+370 687 533 78; NETHERLANDS (Utrecht) + 31 30 274 88 88; NORWAY (Oslo) + 47 22 59 13 00; POLAND
(Gdansk) + 48 58 682 04 04; PORTUGAL (Lisbon) 808 250 143; ROMANIA (Bucharest) + 402 212 106 282;
SWEDEN (Stockholm) + 46 8 33 12 31 / 112; UNITED KINGDOM (London) 0870 243 2241.
Reference: http://www.who.int/pcs/poisons/centre/directory/euro/en/
SECTION 2: Hazards identification
2.1. Classification of the substance
Classification according to Regulation (EC) No 1272/2008 (CLP):
Acute Oral Toxicity: Category 4; H302
Skin sensitizer: Category 1B; H317
Additional Information:
For full text of H and R-phrases: see sub-section 2.2 and 16 respectively
2.2. Label elements
Labeling according to Regulation (EC) No 1272/2008 (CLP/GHS):
Hazard pictogram:
Signal word:
Warning!
Hazard statements:
H302: Harmful if swallowed
H317: May cause an allergic skin reaction.
Precautionary statements:
P270: Do not eat, drink or smoke when using this product.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Page 2 of 8
Alpha damascone
Version: EN/01
C10610004
Identifier
number
24720-09-0
Identification
name
(E)-1-(2,6,6-trimethyl-2cyclohexen-1-yl)-2buten-1-one
Weight %
content
(or range)
EC Number
92 95 %
w/w
246-430-4
Alpha damascone
Version: EN/01
C10610004
Alpha damascone
C10610004
Provide exhaust ventilation or other engineering controls. Ensure that eyewash stations and safety showers
are proximal to the work-station location.
Individual protection measures:
Eye/face protection:
Tightly fitting safety goggles Safety glasses with side-shields
Skin/Hand protection:
Impervious butyl rubber gloves Glove thickness: 0.5 mm. For Skin and body protection: Rubber apron
Respiratory protection:
No personal respiratory protective equipment normally required. In the case of vapor formation use a
respirator with an approved filter.
Thermal Hazards:
No information available
Environmental exposure controls:
Do not allow run-off from fire fighting to enter drains or water courses
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Flash point
Vapour pressure
0.1 kPa
Relative Density at 25 C
0.928 0.943
Solubility
Appearance
Alpha damascone
Version: EN/01
C10610004
Alpha damascone
Version: EN/01
C10610004
N/A
N/A
ICAOTI/IATA-DGR
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
IMDG Code
14.1. UN Number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precaution for
users
14.7.
Transport
in
bulk
according to Annex II of
MARPOL73/78 and the IBC code
Hazard Label
N/A
Alpha damascone
Version: EN/01
C10610004
Page 8 of 8
Annexure XVI
MSDS RM
SIGMA-ALDRICH
sigma-aldrich.com
1.2
Product identifiers
Product name
2-Butanol
Product Number
Brand
Index-No.
REACH No.
:
:
:
:
CAS-No.
W510254
Aldrich
603-127-00-5
A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
78-92-2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
1.3
1.4
Telephone
Fax
:
:
+91-9880711432
2.2
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word
Warning
Hazard statement(s)
H226
Aldrich - W510254
Page 1 of 7
H319
H335 + H336
Precautionary statement(s)
P261
P305 + P351 + P338
Supplemental Hazard
Statements
2.3
none
Substances
Synonyms
sec-Butyl alcohol
()-2-Butanol
Formula
Molecular Weight
CAS-No.
EC-No.
Index-No.
:
:
:
:
:
C4H10O C4H10O
74,12 g/mol
78-92-2
201-158-5
603-127-00-5
Concentration
Butan-2-ol
Flam. Liq. 3; Eye Irrit. 2; STOT
SE 3; H226, H319, H335,
H336
Hazardous ingredients according to Directive 1999/45/EC
Component
Classification
Concentration
Butan-2-ol
Xi, R10 - R36/37 - R67
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16
SECTION 4: First aid measures
4.1
4.2
4.3
Aldrich - W510254
Page 2 of 7
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
5.3
5.4
Further information
Use water spray to cool unopened containers.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3
6.4
7.2
7.3
Control parameters
Components with workplace control parameters
8.2
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Aldrich - W510254
Page 3 of 7
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 480 min
Material tested:Camatril (KCL 730 / Aldrich Z677442, Size M)
Splash contact
Material: Nature latex/chloroprene
Minimum layer thickness: 0,6 mm
Break through time: 30 min
Material tested:Lapren (KCL 706 / Aldrich Z677558, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de,
test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
contact the supplier of the CE approved gloves. This recommendation is advisory only and must
be evaluated by an industrial hygienist and safety officer familiar with the specific situation of
anticipated use by our customers. It should not be construed as offering an approval for any
specific use scenario.
Body Protection
impervious clothing, Flame retardant antistatic protective clothing, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1
Appearance
Form: liquid
b)
Odour
no data available
c)
Odour Threshold
no data available
d)
pH
no data available
e)
Melting point/freezing
point
f)
98 C - lit.
g)
Flash point
27 C - closed cup
h)
Evapouration rate
no data available
i)
j)
Upper/lower
flammability or
Aldrich - W510254
explosive limits
9.2
k)
Vapour pressure
15,3 hPa at 20 C
24,4 hPa at 25 C
l)
Vapour density
m) Relative density
0,808 g/cm3 at 25 C
n)
Water solubility
soluble
o)
p)
Auto-ignition
temperature
no data available
q)
Decomposition
temperature
no data available
r)
Viscosity
no data available
s)
Explosive properties
no data available
t)
Oxidizing properties
no data available
23 mN/m at 20 C
Reactivity
no data available
10.2
Chemical stability
Stable under recommended storage conditions.
10.3
10.4
Conditions to avoid
Heat, flames and sparks.
10.5
Incompatible materials
acids, Acid chlorides, Acid anhydrides, Oxidizing agents, Halogens, Peroxides
10.6
Aldrich - W510254
Page 5 of 7
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Reproductive toxicity - rat - Inhalation
Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of
implants). Effects on Embryo or Fetus: Fetal death. Specific Developmental Abnormalities: Musculoskeletal
system.
Developmental Toxicity - rat - Inhalation
Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).
Specific target organ toxicity - single exposure
May cause respiratory irritation.
May cause drowsiness or dizziness.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: EO1750000
Nausea, Dizziness, Headache, To the best of our knowledge, the chemical, physical, and toxicological
properties have not been thoroughly investigated.
SECTION 12: Ecological information
12.1
Toxicity
Toxicity to fish
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
12.6
Aldrich - W510254
Page 6 of 7
Contaminated packaging
Dispose of as unused product.
SECTION 14: Transport information
14.1
UN number
ADR/RID: 1120
14.2
14.3
IMDG: 1120
IATA: 1120
IMDG: 3
IATA: 3
14.4
Packaging group
ADR/RID: III
IMDG: III
IATA: III
14.5
Environmental hazards
ADR/RID: no
IATA: no
14.6
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2
Eye irritation
Flammable liquids
Flammable liquid and vapour.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Specific target organ toxicity - single exposure
Irritant
Flammable.
Irritating to eyes and respiratory system.
Vapours may cause drowsiness and dizziness.
Further information
Copyright 2013 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.
Aldrich - W510254
Page 7 of 7
Annexure XVII
Site Photographs
UNIT-II
ANNEXURE- XVII: PHOTOGRAPHS OF EXISTING WATER/AIR POLLUTION CONTROL SYSTEM IN
OPERATION
ETPFACILITYOVERVIEW
Equalization Tank
Preliminary ETP pits - Plant wise for removal of oil & Neutralization