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Karbala International Journal of Modern Science 1 (2015) 9e14
http://www.journals.elsevier.com/karbala-international-journal-of-modern-science/
a
Department of Civil Engineering, National Institute of Technology Raipur, Chhattisgarh, India
Department of Applied Physics, Bhilai Institute of Technology (Seth Balkrishan Memorial), Near Bhilai House, Durg, C.G. Pin-491001, India
Abstract
Rapid industrialisation and resulting industrial solid waste from power plants and integrated iron and steel industries, have
imposed an enormous environmental pressure on water resources of Chhattisgarh, a state in Central India. Rural population living
nearby the study area is mainly depended on the available surface water in the form of lakes or pond in their vicinity. Therefore it is
necessary to look after the surface water through leachate pollution caused by dumping and disposal of industrial solid waste. In the
present study, ten surface water samples each for pre monsoon and post monsoon were collected for analysis from the surrounding
areas of a major industrial region of Chhattisgarh. The AAS analysis of the surface water samples shows higher concentration of
certain heavy metals above the permissible limits. In the pre monsoon samples the metals Mn and Cr resulted higher concentration
and at the same time metals; Cu, Fe and Pb resulted in lower concentrations. Similarly, for the post monsoon samples, Mn, Cr and Fe
found with higher concentration, while Cu and Pb resulted with lower concentration. The high amount of heavy metals were found
in the analyzed samples shows that there is a real risk for population living in the nearby areas of the industrial region of
Chhattisgarh. Therefore a huge amount of industrial wastes produced needs a proper disposal. Unscientific and poorly-managed
disposal of industrial solid wastes containing heavy metals needs remediation before discharging into the environment.
2015 The Authors. Production and hosting by Elsevier B.V. on behalf of University of Kerbala. This is an open access article
under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Keywords: Industrial solid waste; Heavy metals; Leachate; Surface water; Water pollution
1. Introduction
Coal based thermal power plants, contributing to the
61.5 percent of total installed power capacity, are the
major source of electricity generation in India [3].
Most of industries are using pulverized coal as the fuel,
producing enormous quantities of coal fly ash every
* Corresponding author.
E-mail addresses: raunak.ruby@gmail.com, nitr.mkt@gmail.com
(R.K. Tamrakar).
Peer review under responsibility of University of Kerbala.
http://dx.doi.org/10.1016/j.kijoms.2015.08.001
2405-609X/ 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of University of Kerbala. This is an open access article under
the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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M.K. Tiwari et al. / Karbala International Journal of Modern Science 1 (2015) 9e14
M.K. Tiwari et al. / Karbala International Journal of Modern Science 1 (2015) 9e14
11
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M.K. Tiwari et al. / Karbala International Journal of Modern Science 1 (2015) 9e14
Table 1
Standard operating procedure (SOP) of AAS.
Instrument condition
Chromium
Copper
Iron
Lead
Manganese
Zinc
Lamp
Chromium Hollow
Cathode
3
358.3 nm
Acetylene
Air
Reducing
(slightly yellow)
Copper Hollow
Cathode
4
324.7 nm
Acetylene
Air
Oxidizing
Iron Hollow
Cathode
3
248.3 nm
Acetylene
Air
Oxidizing
Lead Hollow
Cathode
4
283.3 nm
Acetylene
Air
Oxidizing
Manganese Hollow
Cathode
4
279.8 nm
Acetylene
Air
Oxidizing
Zinc Hollow
Cathode
4
670.8 nm
Acetylene
Air
Oxidizing
Slit
Wavelength
Fuel
Oxidant
Type of flame
Reference: [17].
M.K. Tiwari et al. / Karbala International Journal of Modern Science 1 (2015) 9e14
13
Table 2
Pre-monsoon sample analysis results.
Sample no Distance from Concentration (mg/L)
dump site
Cr
Cu
Fe
Pb
Mn
Zn
1
2
3
4
5
6
7
8
9
10
0
2.557
0.088
0.057
2.931
0.233
0.209
0.155
0.341
0.343
0.0533
0.0246
0.0377
0.0095
0.0891
0.3967
0.1112
0.1068
0.0631
0.062
120
546
964
39
600
1000
350
650
1250
1490
m
m
m
m
m
m
m
m
m
m
0.326
0.642
0.811
0.498
0.3
1.832
2.398
3.298
3.192
1.879
0.002
0
0.005
0.003
0.014
0.012
0.033
0.005
0.006
BDLa
0.822
1.368
0.76
0.366
3.505
2.192
0.755
1.541
0.697
0.697
0.26
0.22
0.2
0.17
0.2
0.15
0.21
0.2
0.21
0.26
Table 3
Post-monsoon sample analysis results.
Sample no Distance from Concentration (mg/L)
dump site
Cr
Cu
Fe
Pb
1
2
3
4
5
6
7
8
9
10
a
120
546
964
39
600
1000
350
650
1250
1490
m
m
m
m
m
m
m
m
m
m
1.45
1.648
2.16
2.013
1.853
2.085
1.929
2.185
2.316
2.149
0.007
0.007
0.008
0.007
0.008
0.008
0.008
0.008
0.009
0.009
BDLa
0.199
0.731
BDLa
0.019
0.408
0.263
0.269
0.353
0.352
0.08
0.12
0.09
0.09
0.08
0.08
0.07
0.1
0.07
0.07
Mn
Zn
0.088
1.272
0.559
0.046
0.327
0.066
0.087
0.097
0.166
0.656
0.161
0.1584
0.204
0.127
0.1532
0.204
0.1085
0.1782
0.3411
0.2191
Table 4
Surface water quality characterization.
Sample Colour
Odour
pH EC
TDS Alkalinity Chloride
Turbidity
Calcium
Magnesium Hardness
(mS/m) (mg/L) (mg/L as (mg/L of Cl) (mg/L of Ca) (Mg/Lof mg) (mg/L of CaCO3) (NTU)
CaCO3)
1
2
2
4
5
6
7
8
9
10
Normal
Objectionable
Normal
Objectionable
Objectionable
Objectionable
Objectionable
Objectionable
Normal
Odourless
7.1
7.1
7.7
6.9
7.4
7.3
7.5
7.4
7.8
7.1
Clear
Clear
Yellowish
Turbid
Yellowish/Turbid
Turbid
Turbid
Clear
Transparent Yellow
Clear
471.6
413.9
422.4
880
1135
818.2
1146
664.5
731.4
177.0
275.8
242.4
258.5
512.8
677.5
480.5
675.7
381.4
417.4
102.2
180
200
180
100
160
240
240
200
180
100
70.01
60.07
70.01
150.2
280.3
480.5
210.2
100.1
140.2
40
400
600
550
700
1100
650
350
650
550
500
250
150
350
750
0
350
950
300
250
0
650
750
800
1450
1100
1000
1300
950
800
500
17
7
9
14
22
14
11
4
8
2
14
M.K. Tiwari et al. / Karbala International Journal of Modern Science 1 (2015) 9e14
6. Conclusions
The huge production of industrial solid waste in
Chhattisgarh and its inappropriate disposal management in the form of heap piled outside the industrial
area produces leachate. Heavy metals that leached out
from these disposal points and may contaminate the
ground water as well as surface water resources nearby
area could affect the health and livelihood of local
population. The introduction and implementation of a
proper industrial solid waste disposal management
should be implemented and preventive leachate
contamination measures like the use of multiple lining
layers, leachate collection system, waste cover, etc.
should also be adopted to increase effectiveness of
solid waste management practices.
Acknowledgement
The authors are thankful to CGCOST Raipur for
their support in metal analysis by AAS of all surface
water samples.
References
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Contamination of drinking water due to coal based thermal
power plants in India, Environ. Forensics (2011) 92e97.
[2] A. Baba, Leaching characteristics of wastes from Kemerkoy,
Glob. Nest Int. J. 2 (1) (2000) 51e57.
[3] CEA, Government of India, Ministry of Power, Central Electricity Authority, New Delhi, Executive Summary on Power
Sector, April 2015, 2015. http://www.cea.nic.in/reports/monthly/
executive_rep/apr15.pdf, 23 May 2015.
[4] C.L. Carlson, D.C. Adriano, Environmental impacts of coal
combustion residues, J. Environ. Qual. 22 (1993) 227e247.
[5] Environment Agency, Guidance on Monitoring of Landfill
Leachate, Groundwater and Surface Water.
[6] EPA e 1, Sampling and Analysis of Waters, Wastewaters, Soils
and Wastes, 22 May 2015. http://www.epa.vic.gov.au/~/media/
Publications/IWRG701.pdf.