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Article history:
Received 10 December 2014
Received in revised form
13 July 2015
Accepted 27 July 2015
Available online 1 August 2015
Renewable energy plays a predominant role in solving the current energy requirement problems and
biodiesel is a promising alternative fuel to tide over the energy crisis and conserve fossil fuels. The
present work investigates an eco-friendly substitute for the replacement of fossil fuels and the experiments are designed to determine the effects of a catalyst in the biodiesel production processes. Pongamia
pinnata oil was utilized to produce the biodiesel by using catalysts namely KOH and NaOH and the
properties of the fuel were found by using Carbon Hydrogen Nitrogen Sulfur (CHNS) elemental analysis,
Fourier Transform Infrared (FTIR) Spectroscopy, Gas Chromatography & Mass Spectrometry (GCMS), and
Proton Nuclear Magnetic Resonance (1H NMR) Spectroscopy and the thermophysical properties were
compared with those of neat diesel. In continuation, the working characteristics of the biodiesel and
biodieselwater emulsions were accomplished in a four stroke compression ignition engine and the
results were compared to those of neat diesel. It was found that the exhaust emission characteristics like
brake specic carbon monoxide (BSCO), brake specic hydrocarbons (BSHC) and smoke opacity were
better for neat biodiesel (except brake specic nitric oxide BSNO) than those of neat diesel.
& 2015 Elsevier Inc. All rights reserved.
Keywords:
Biodiesel
Transesterication
Diesel engine
Emission characteristics
1. Introduction
In the present global scenario, a rise in energy utilization and
ecological deprivation due to the rapid growth in technology, industrialization, population, automobiles and power plants affect
the health of living beings, deplete the ozone layer and lead to
global warming. The available energy resources are very limited
and are diminishing at a faster rate. In this perspective, various
non-edible vegetable oils are considered as the potential candidates to serve as a substitute fuel in diesel engines. However, the
vegetable oils and their methyl esters (biodiesel) have their own
limitations when they are used in diesel engines. Recovering the
energy resources from the environmental waste products and
throw away oils from the industry are an economically viable solution. In addition, the disposal of waste organic and inorganic
materials causes pollution of ground and surface water, obnoxious
odor and health hazards. For better environmental safety and the
implementation of strict regulations on emission norms over the
internal combustion engines, the biodiesel is a potential solution
for the replacement of fossil fuels in spite of its poor performance
characteristics in engines. Biodiesel is a chemical combination of
fatty acid methyl esters, non-toxic, biodegradable, sulfur free,
n
Corresponding author.
E-mail address: srinivasaraomuthe@gmail.com (M. Srinivasa Rao).
http://dx.doi.org/10.1016/j.ecoenv.2015.07.031
0147-6513/& 2015 Elsevier Inc. All rights reserved.
M. Srinivasa Rao, R.B. Anand / Ecotoxicology and Environmental Safety 121 (2015) 1621
BSHC
brake specic hydrocarbons (g/kWh)
BSNO
brake specic nitric oxide (g/kWh)
FTIR
Fourier Transform Infrared Spectroscopy
GCMS Gas Chromatography & Mass Spectrometry
1
H NMR Proton Nuclear Magnetic Resonance Spectroscopy
PBD
Pongamia biodiesel
PBD2S5W 93% biodiesel 2% surfactant 5% water
PBD2S10W 88% biodiesel 2% surfactant 10% water
Nomenclature
ASTM
BSFC
BTE
bmep
bTDC
CA
BSCO
Pongamia
Raw oil
Determination of Free
Fatty Acids (FFA)
No
FFA
>1
Base
Transesterification
Yes
Pre Treatment or
Acid Esterification
Base/Alkaline Catalyst
Acid Catalyst
Reactor Unit
Phase Separation
Methanol + KOH /
NaOH
Reactor Unit
Methanol +
H2SO4
Glycerin
Phase Separation
Water
Extra Glycerin
Distillation Process
Extra Methanol
Heating at 120 oC
Filtering
17
Soap
Determination of FFA
No
Yes
FFA
>1
Removal of Moisture
18
M. Srinivasa Rao, R.B. Anand / Ecotoxicology and Environmental Safety 121 (2015) 1621
ethanol to form ethyl ester in the presence of KOH catalyst. Subsequently the Soybean ethyl ester was subjected under FTIR analysis and they have found the ester peak at around 1730 cm 1 and
at 9001500 cm 1, which conrmed the ester functional groups
availability. Aliske et al. (2007) carried out FTIR analysis on soybean oil methyl ester and compared it with neat diesel and reported that the ester peak for soybean biodiesel was found at an
absorbance peak of 17001800 cm 1.
India is a tropical country and has a suitable climate for the
development of Pongamia tree. Pongamia trees are found in forests, waste lands and road sides and India has potential for the
growth of these trees. The growth of Pongamia trees in waste
lands also eliminates soil erosion and leads to increase of rain fall.
The seeds obtained from Pongamia tree are crushed in an expeller
to obtain the oil. In these conditions, non-edible oil such as Pongamia raw oil is considered as a major renewable fuel for sustainable economic development. The present investigation is carried out to describe complete production process, thermophysical
properties and working characteristics of Pongamia biodiesel in a
four stroke compression ignition engine.
M. Srinivasa Rao, R.B. Anand / Ecotoxicology and Environmental Safety 121 (2015) 1621
19
% Transmittance
100
90
723
80
1438
70
2853
1168
1741
Pongamia biodiesel
2923
60
90
722
1377
80
1457
2954
70
2854
60
2922
400
800
1200
1600
2000
2400
2800
3200
3600
50
Wave number cm -1
Neat diesel
4000
% Transmittance
50
100
20
M. Srinivasa Rao, R.B. Anand / Ecotoxicology and Environmental Safety 121 (2015) 1621
Neat Diesel
PBD
PBD2S5W
PBD2S10W
1.2
30
0.9
20
0.6
10
0.3
0
0
0.3
bmep (MPa)
Fig. 6. Variation in BSFC and BTE with respect to bmep.
BTE (%)
BSFC (kg/kWh)
ratio as 6:1.
M. Srinivasa Rao, R.B. Anand / Ecotoxicology and Environmental Safety 121 (2015) 1621
Neat Diesel
PBD
PBD2S5W
PBD2S10W
BSNO (g/kWh)
10
4. Conclusions
4
2
0
60
40
20
biodiesel production.
BSHC (g/kWh)
0.20
0.15
0.10
0.05
0.00
BSCO (g/kWh)
21
20
10
0.15
0.23
0.3
0.38
0.45
0.53
bmep (MPa)
Fig. 7. Variation in BSCO, BSHC, Smoke opacity and BSNO with respect to bmep.
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