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FUNDAMENTALS
(CH.E-301)
Lecture 1
COURSE CONTENTS
LIST OF BOOKS
EVALUATION CRITERIA
Assignments (5 marks)
INTRODUCTION
Thermodynamics:
DEFINITIONS
Heat
CONDUCTION
Conduction is the process whereby heat is transferred
directly through a material, any bulk motion of the
material playing no role in the transfer.
HEAT TRANSFER
Conduction when two objects are in physical
contact.
T
Q kA
t
L
k = thermal conductivity
Q = heat transferred
A = cross sectional area
t = duration of heat transfer
L = length
T = temperature difference
between two ends
THERMAL CONDUCTIVITIES
Metals have high thermal
conductivity, most electrical
insulators also have low
thermal conductivity.
Air is a great insulator,
except that large air spaces
allow
heat
flow
by
convection.
Substance
Thermal
Conductivity: k
W / (m K)
Gold
291
Glass
0.84
Water
0.60
Wood
0.10
Air
0.023
CONDUCTION
Stir your hot soup with a metal spoon
Pretty soon you need a pot holder because the end of
the spoon you are holding gets hot
This is heat transfer by conduction
Energy travels up the spoon from the end in the hot
soup to the end in your hand
CONDUCTION
We sense the movement of energy by the
increasing temperature
This means the atoms and molecules have higher
average kinetic energy
Primarily occurs by the movement of electrons in
the material
The more easily the electrons can move, the
better the conduction
CONDUCTION
Metals have some electrons that are very loosely bound
to the atoms in the material
These electrons can move easily and can rapidly pick
up additional kinetic energy
Metals are good conductors
Wood and plastic dont have loosely bound electrons, so
they are poor conductors
Heat Conduction
Steel: k = 14 J/s-m-C
How much energy is
conducted in 40
seconds?
--------------------------
Heat Conduction
Steel: k = 14 J/s-m-C
How much energy is
conducted in 40
seconds?
-------------------------H= kA (T2 - T1)/L
H= 14 (2)(475)/10
= 1330 J/s
Q= Ht = 1330 (40)
= 5.32 x 104 J
Substance
Thermal
Conductivity
k [J/(s-m-C)]
Substance
Thermal
Conductivity
k [J/(s-m-C)]
Styrofoam
0.010
Glass
0.80
Air
0.026
Concrete
1.1
Wool
0.040
Iron
79
Wood
0.15
Aluminum
240
Body fat
0.20
Silver
420
Water
0.60
Diamond
2450
(3)
(4)
(5)
(6)
(7)
(8)
CONVECTION
Convection is the process in which heat is carried from place to place by
the bulk movement of a fluid.
VOLCANIC ERUPTION
CONVECTION
Q: In the living room, the heating unit is placed in the floor but the
refrigerator has a top-mounted cooling coil. Why?
A: Air warmed by the baseboard heating unit is pushed to the top of the
room by the cooler and denser air. Air cooled by the cooling coil sinks to the
bottom of the refrigerator.
RADIATION
Radiation is the process in which energy is transferred by means of
electromagnetic waves.
Heat transfer by radiation can take place through vacuum. This is because
electromagnetic waves (e.g., light, microwaves, radio waves, X-rays etc.)
are involved in radiation and they can propagate through empty space.
SUMMER CLOTHING
Q: People are uncomfortable wearing dark clothes during the
summer. Why?
WHY IS THE
MOTHER
SHIELDING HER
CUB?
Q
4
P eAT .
t
The factor e is called the emissivity, which is a number between 0 and 1.
Perfect radiators have a value of 1 for e. A is the surface area and T is the
temperature of the radiator in Kelvin.
Example
How much energy is radiated
by this object in ten minutes?
-----------------------------------------
H = eAT4
Example
How much energy is radiated
by this object in ten minutes?
----------------------------------------t = 10 x 60 seconds = 600 s
Q = radiant energy = H t
H = eA T4
Q = (0.8)(5.67x10-8)(5)(500)4 x
(600)
= 8.5 x 106 J
H = eAT4
THERMOS BOTTLE
A thermos bottle minimizes energy transfer due
to convection, conduction, and radiation.
Stopper- minimize conduction.
Double-walled glass vessel with the space
between the walls is evacuated to minimize
energy losses due to conduction and convection.
The silvered surfaces reflect most of the radiant
energy that would otherwise enter or leave the
liquid in the thermos.
HALOGEN COOKTOP