60

4
N2

H2

NH3

C0

3x

2x

1-x

3-3x

0+2x

/
5
-1-


2013 7 X(g)Y(g)

2Z(g) H0

A.

B.Z

C. c(X)X

D.Y

2013 12. NaHSO3 KIO3 NaHSO3

I2 I2 NaHSO3
0.020molL-1NaHSO
10.0mlKIO
40.0ml 10~55
3
3
55

A40 40
B bc NaHSO3
C a NaHSO3 5.0 10-5molL-1s-1
D 40
2013 6. X Y 0.16 mol 10 L
Xg+ Yg

2Zg H < 0

t / min

n(Y)/mol

0.12

0.11

0.10

0.10

A. 2min v(Z)=2.010-5 mol/Lmin

B v()v()
C K=1.44
D 0.2 mol Z X
(2012 9)

SO2(g)+2CO(g)

2CO2(g)+S(l) H0

A
B
C SO2
D
(2012 8)

CO(g)H2O(g)== CO2(g)H2(g)

H<0

CO
A

C CO

-2-

2013 228.14
1.0 L 0.10molA(g)
1

H=+85.1kJmol

A(g)=== B(g)C(g)

(t)(p)
t/h

16

20

25

30

p/100kPa

4.91

5.58

6.32

7.31

8.54

9.50

9.52

9.53

9.53

:
(1) A

(2) P P0 A (A)

(3) p p0 n A nA

n =

molnA=

mol

A a=

t/h

16

cA
/ molL-1

0.10

0.026

0.0065

cA t

12h cA

molL-1

2013 10 PM2.5
2.5um PM2.5SO2
NOx
1 PM2.5

K+
Na+
NH4+
SO42NO3Cl
-6
-6
-5
-5
-5
6 1 0
2 1 0
4 1 0
3 1 0
2 1 0 - 5

4 1 0
/ mo l . L
PM2.5 _________ PH ____________
2 SO2

H2(g)+1/2O2(g)=H2O(g) H= 241.8kJ/mol

C(s)+1/2O2(g)=CO(g)

H= 110.5kJ/mol

__________________________
SO2 ________________________________
a.Ca(OH)2

b.Na2CO3

c.CaCl2

d.NaHSO3

(3) NOx CO
NO
-3-

N2(g)+O2(g)

2NO(g)

H0

1mol 0.8molN2 0.2molO2,1300 NO

810-4mol K= ___________
NO ______________
CO CO
2CO(g)=2C(s)+O2(g) H 0
_____________________________
CO NO
__________
2013 29
15
1 TaS2
TaS2s+2I2g

TaI4g+S2g H0

I K

K1 1mol

I2g TaS2s
I2g

2I T2
TaS2 I2g
T1 TaS2 T1

T2

3 I2 H2SO3
I2

425H2SO3

HSO3-+H+ Ka110-2mol/L NaHSO3

Kh=

mol/L NaHSO3 I2

c(H2SO3)

c(HSO3)

(2012 15) A(g) + B(g)

/

C(g) + D(g)
700

800

-4-

830

1000

1200

1.7

1.1

1.0

0.6

0.4

:
H=

(1) K=

0(<>=)

(2) 830 5L 0.20 mol A 0.80mol B

6s A v(A) = 0.003 molL 1s 1 6s c(A) =

C

molL 1

mol A

1mol A

(3)
a

()

b
d C A

cc(A)
(4) 1200 C(g)+D(g)

A(g)+B(g)

2013 15.CO(g)H2O(g)

CO2(g)H2(g)

2L () IIIIII I 1molCO
1molH2O II 1molCO2 1mol H2 III 2molCO 2molH2O700

A. III
B. IIII
C. I CO II
D. I CO II CO2 1
2013 11. MgO:MgSO3(s) +
MgO(s) + CO2(g) +SO2(g) H0

CO(g)

x
y x

CO

CO2 CO

SO2

MgSO4 CO

2013 15
9
A(g)

B(g) +C(g) 1.0L A

-5-

 0.050mol/L T1 T2 A
1 T1

T2 K(T1)

K(T2)

2 T2 5min A 70%

K=

0~5min v(A)=

(2012 14) T
2.0L 1.0 molPCl5 PCl5(g)

PCl3(g)

Cl2(g)
t/s

50

150

250

350

n(PCl3)/ mol

0.16

0.19

0.20

0.20

A. 50 s v(PCl3)=0.0032 molL 1s

B.c(PCl3)=0.11 molL 1, H0
C. 1.0molPCl50.20molPCl3 0.20molCl2
v()v()
D. 2.0molPCl32.0molCl2PCl3
80%
(2012 12)
TiO2 R

A 050min pH=2 pH=7 R

BR
CR
D 2025min pH=10 R 0.04 molL1min1
1g N2 1g H2
2g N2 2g H2
-6-

CH2

D H2

(2011 15)700
2L CO H2O,CO(g)
H2O(g)

CO2H2(g) ( t1t2):
/min

n(CO)/mol

H2O/ mol

1.20

0.60

t1

0.80

t2

0.20

A t1min v(H2)0.40/t1 molL 1min

B 0.60molCO 1.20 molH2O

n(CO2)0.40 mol
C 0.20molH2O
CO H2O
D 800 0.64

(2011 12)25 Pb2 Sn2 (Sn)

Sn(s)Pb2 (aq)

Sn2 (aq)Pb(s) c(Pb2 ) c(Sn2 )

Ac(Pb2 )

B Sn(NO3)2 c(Pb2 )

C c(Pb2 ) H>0
D25 K2.2
(2011 6) SO2 NO2
SO2(g)+NO2(g)

SO3(g)+NO(g)

A c
Ba b
C
D t1= t2 SO2 a~b b~c

(2011 10) 10

-7-

T1
T2

P1
P2

(T)

(P)
10

ACO2(g)2NH3(g)

H0

CO(NH2)2(s)H2O(g)
H0

BCO2(g)H2(g)

CO(g)H2O(g)

CCH3CH2OH (g)

CH2=CH2(g)H2O(g)

D2C6H5CH2CH3(g)O2(g)

H0
H0

2 C6H5CH=CH2(g)2H2O(g)

(2010 6)

A 25 0.1 molL

20 mL 0.1 molL

NaOH

pH
B 2SO2(g) + O2(g)

2SO3(g)H < 0

K
1

C 10 mL 0.01 molL

KMnO4 0.1 molL

H2C2O4

n(Mn2+)
D ab CH2CH2 (g) + H2(g)

CH3CH3(g)H< 0

(09 I13) X(g)

4Y(g)Z(g) H0 X

A 6min
BX 85%
CX 85%
Dv v

(2011 27)(NH2COONH4)

-8-


(1)(
)NH2COONH4(s)

2NH3(g)CO2(g)

()

15.0

20.0

25.0

30.0

35.0

(kPa)

5.7

8.3

12.0

17.1

24.0

2.4

3.4

4.8

6.8

9.4

(10 3mol/L)

___________
A

2 (NH3 ) (CO2 )

B
C
D
25.0__________________________
25
______()
H____0 S___0()
(2)NH2COONH42H2O

NH4HCO3NH3H2O

c(NH2COO )

c(NH2COO-)(mol/L)

15

25

t(min)

2506min ___________________________
_______________________

(2011 28) NO2SO2 CO

-9-

(1)NO2

6NO2

8NH3

7N512 H2O NO2 1.2mol NO2

L

(2)2SO2(g)+O2(g)

2SO3(g)

2NO(g)+O2(g)
NO2(g)+SO2(g)

H=196.6 kJmol-1
H=113.0 kJmol-1

2NO2(g)

SO3(g)+NO(g) H=

kJmol-1

NO2 SO2 1:2

a
b
cSO3 NO
d 1 mol SO3 1 molNO2
NO2 SO2 1:6 K
(3)CO CO(g)+2H2(g)
H
4

2501.310 kPa

CH3OH(g)CO
0(> <)

2mol NO2
2NO2(g)

N2O4 NO2 x% 1mol N2O4

NO2 y% x y

Axy

Bxy

Cxy

- 10 -