AIOT (JEE ADVANCE) - 1

TEST DATE :02-02-2014

TARGET DATE :

Paper-2 (AIOT-1 JEE ADVAN C E)

S.No. Subje ct Na ture of Que stions No. of Que stions Ma rks Ne ga tive Tota l
1 to 5 MCQ 5 4 0 20
6 to 11 Ma ths Comprehension (2 Comp. x 3 Q.) Single Choic e 6 2 0 12
12 to 21 Subjective double digit 10 4 –1 40
22 to 26 MCQ 5 4 0 20
27 to 32 Physics Comprehension (2 Comp. x 3 Q.) Single Choic e 6 2 0 12
33 to 42 Subjective double digit 10 4 –1 40
43 to 47 MCQ 5 4 0 20
48 to 53 Che m istry Comprehension (2 Comp. x 3 Q.) Single Choic e 6 2 0 12
54 to 63 Subjective double digit 10 4 –1 40
Tota l 63 Tota l 216

MCQ
x
3t
1. Let f(x) =  1 t 2
dt , x > 0 then [DIDF]
1

x
3t
ekuk fd f(x) =  1 t 2
dt , x > 0 rc
1

(A*) for 0 <  < , f() < f()

(B) for 0 <  < , f() > f()

(C) there exist  > 0 such that  x  (, ), f(x) + < tan–1x
4

(D*) there exist  > 0 such that  x  (, ), f(x) + > tan–1x
4

(A*) 0 <  < d sfy ,, f() < f()

(B) 0 <  < d sfy ,, f() > f()

(C)  > 0 bl izd kj fo|eku gSfd  x  (, ), f(x) + < tan–1x
4

(D*)  > 0 bl izd kj fo|eku gSfd  x  (, ), f(x) + > tan–1x
4
3x
Sol. f (x) =  f (x) > 0 ( x > 0) hence f(x) is 
1 x2
 0 <  <   f() < f()
x
3t
f (x) =  1 t 2
dt
1

x
1
 f(x) >  1 t 2
dt  t  (1, x)
1

Page - 1
 x
–1
 f(x) > tan t
1


 f(x) > tan–1x –
4

 f(x) + > tan–1x
4

2. Let O be centre, S, S be foci of hyperbola. If tangent at any point P on hyperbola cuts asymptotes at M and
N then OM + ON = [SBSF]
ekuk O d sUnzrFkk, S, S,d vfrijoy ; d h ukfHk;k¡gSA ;fn vfrijoy ; ij fLFkr fcUnqP ij [khph xbZLi'kZ
js[k mld h vuUrLif'kZ;ksad ksM rFkk N ij izfrPNsn d jrh gSrksOM + ON =
(A) |SP – SP| (B*) SP + SP (C) SS (D) distance between vertices

Sol.

x2 y2
2
– 1
a b2
Tangent at P(asec, btan)
x y
sec   tan   1 ........(1)
a b
Asmptotes are
b
y= x ..........(2)
a
b
y=– x .......(3)
a
M  [a(sec – tan), b(sec – tan) ]
and N  [a(sec + tan), b(sec + tan) ]
 ON = a 2  b 2 (sec + tan) = ae(sec + tan)
 OM + ON = ae(2sec) = 2ae(sec)
a a
SP + SP = e(asec – ) + e(asec + ) = 2aesec
e e

3. Let f(x) = x3 + px2 + qx + r, where p,q and r are integers, f(0) and f(–1) are odd integers. Which of the
following is/are CORRECT ? [QETE]
(A) f(1) is an even integer (B*) f(1) is an odd integer
(C) f(x) = 0 has three distinct integer roots (D*) f(x) = 0 cannot have three integer roots.
ekukf(x) = x + px + qx + r t gk¡p,q rFkkr iw.kk±d gS, f(0) rFkkf(–1) fo"ke iw.kk±d gSA fuEufy f[kr esalsd kSulk/
3 2

d kSulslR; gS?
(A) f(1) ,d leiw .kkZd gSA (B*) f(1) ,d fo"ke iw.kk±d gSA
(C) f(x) = 0 d srhu fHkUu-fHkUu iw
.kk±d ewy gSA (D*) f(x) = 0 d srhu iw.kk±d ewy ugh gksld rsA

Page - 2
Sol. f(0) = r is odd. Let r = 2n + 1, n  I.
f(0) = r ,d fo"ke gS A ekuk r = 2n + 1, n  I.
f(–1) = –1 + p – q + 2n + 1 = p – q + 2n is odd fo"ke gS
 exactly one of p, q is odd
 p, q es
alsBhd ,d fo"ke gS
f(1) = 1 + p + q + 2n + 1 = p + q + 2n + 2 is odd fo"ke gS
If possible suppose , I be zeros of f(x).
;fn lEHko gksrkseku y srsgSfd , I, f(x) 'kwU; gS
 x3 + px2 + qx + r = x3 – (+ + )x2 + (+ + )x – 
 r = –  are odd integers fo"ke iw.kkZad gS
 p = – (+ + ) is odd iw
.kkZad
gS
and rFkkq = + + is also odd. Hkh iw
.kkZad gS
It is a contradiction. Hence f(x) = 0
cannot have three integer roots.
t ksfojks/kkHkkl gSA vr%f(x) = 0 d srhu iw.kkZad ewy ughagksld rsA

4. A rod of length 2 units whose one end is (1, 0, –1) and other end touches the plane x – 2y + 2z + 4 = 0, is
rotated on this plane, then [TDPP]
(A*) the rod sweeps a solid structure whose volume is  cubic units
(B) the area of the region which the rod traces on the plane is 2
(C*) the length of projection of the rod on the plane is 3 units
2 2 5
(D*) the centre of the region which the rod traces on the plane is  , , 
3 3 3 
,d 2 bZd kbZy EckbZd h ,d NM+ft ld k ,d fljk (1, 0, –1) gSrFkk nwl jk fljk lery x – 2y + 2z + 4 = 0 d ks
Li'kZd jrk gSrFkk bl lery ij ?kw.kZu d jrk gS&
(A) NM+,d Bks l lajpuk cukrh gSft ld k vk;ru  ?ku bZd kbZgSA
(B) {ks
=k d k {ks=kQ y 2lsgksxk t ksNM+lery ij cukrh gSA
(C) NM+d h lery es aiz{ksi d h y EckbZ 3 gSA
2 2 5
(D) NM+}kjk lery ij cuk;sx, {ks=k d k d sUnz 3 , 3 , 3  gSA
 

Sol.

The rod sweeps out the figure which is a cone.

1 1 2  4 |
The distance of point (A(1, 0, – 1) from the plane is  1 unit.
9
The slant height l of the cone is 2 units.
Then the radius of the base of the cone is l2  1  4  1  3

Hence, the volume of the cone is ( 3 )2 .1   cubic units.
3

Page - 3
 Area of the circle on the plane which the rod traces is 3.
x  1 y  0 z  1  (1  0  2  4)
Also, the centre of the circle is Q(x, y, z). Then    2 , or
1 2 2 1  ( 2)2  22

2 2 5
Q( x, y, z )   , , .
3 3 3 
Hindi. (a, c, d)

fp=k esaNM+d ks.k cukrh gSA

1 1 2  4 |
fcUnq(A(1, 0, – 1) d hlery  1 unit lsnw
jh
9
'kad qd h fr;Zd Å ¡p kbZl 2 units gSA
rc 'kad qd svk/kkj d h f=kT;k l 2  1  4  1  3 gSA

vr%'kad qd k vk;ru ( 3 )2 .1   ?ku bZd kbZgSA
3
lery esaNM+}kjk cuk;k x;k oÙ̀k d k {ks=kQ y 3gSA
x  1 y  0 z  1  (1  0  2  4) 2 2 5
oÙ̀k d k d sUnzQ(x, y, z) rc    2 2 2
, ;k Q( x, y, z )   , , .
1 2 2 1  ( 2)  2 3 3 3 

5. If a is an integer and m 1, m 2, m 3 are the slopes of all three straight lines represented by equation
y3 + (2a + 5) xy2 – 6x2y – 2ax3 = 0 which are also integers, then which of the following can holds good?
[SLSA]
;fn a ,d iw.kkZd gSvkSj lehd j.k y + (2a + 5) xy – 6x y – 2ax = 0 lsfu: fir lHkh rhu ljy js[kkvksad h
3 2 2 3

izo.krk,sam1, m2, m3 Hkh iw.kkZd gSrc fuEu esalsd kSulslgh gS?

3 3 3 3

(A*) a +  mi = – 1 (B*) a +  mi = – 5 (C*) a +  mi = 0 (D) a +  m = 32i

i 1 i 1 i 1 i 1

Sol. m3 + (2a + 5)m2 – 6m – 2a = 0

m1 + m2 + m3 = – (2a + 5)
m 1 m 2 + m 2 m 3 + m 3 m 1= – 6
m1 m2 m3 = 2a
For (A)
3

a+ m
i 1
i =–1

 a – 2a – 5 = – 1  a = – 4  m1 m2 m3 = –8
 m1 = 1, m2 = –2, m3 = 4  m1 m2 m3 = – 8
for (B)
a – 2a – 5 = – 5  a = 0  m1 m2 m3 = 0
 m1 = 1, m2 = 0, m3 = –6

Page - 4
 3

 a+ m
i 1
i = 0 + 0 = 0 (C is correct)

for (D)
a + 2a = 32 not possible
Hence (D) is incorrect.

Comprehension # 1

1 2 0
 
2 1 0
There exists a matrix Q such that PQPT = N, where P =  . [MTST]
0 0 1
Given N is a diagonal matrix of form N = diag.(n1, n2, n3) where n1, n2, n3 are three values of n satisfying the
equation det.(P – nI) = 0, n1< n2< n3.
[Note : I is an identity matrix of order 3×3]

1 2 0
 
2 1 0
Hindi d ksbZvkO;wg Q bl izd kj gSfd PQPT = N t gk¡P =  .
0 0 1

fn;k gSfd N ,dfod .kZvkO;wg N = diag.(n1, n2, n3) : i oky h vkO;wg gSt gk¡n1, n2, n3 lehd j.k det.(P – nI)
= 0, n1< n2< n3 d kslarq"B d jusoky sn d srhu eku gSA
[Note : I, 3×3 Ø e d k bd kbZvkO;w g gS]
6. The value of det.(adjN) is equal to
[Note : adj M denotes the adjoint of a square matrix M.]
det.(adjN) d keku gksxk&
V : adj M oxZvkO;wg M d k lg[k.Mt
[uks vkO;wg gS

1 1
(A) 4 (B) (C) (D*) 9
4 9
Sol. 6 As det. t S
l kfd (P – nI) = 0
1– n 2 0
 2 1– n 0 =0  (1 – n)(n – 3)(n + 1) = 0 n = –1,1,3
0 0 1– n

–1 0 0
 
0 1 0
So vr%, N = 
 0 0 3
 det.(N) = – 3  det.(adj N) = (detN)2 = (–3)2 = 9 Ans.

7. If QT = Q + , then the value of  is equal to

;fn QT = Q + rc  d k eku gS&
–1
(A) –1 (B*) 0 (C) 1 (D)
3

Page - 5
 T
Sol. Given PQPT = N  P 
–1
P Q P (P T ) –1 = P–1N (PT)–1

 Q = P–1N(P–1)T [As (PT)–1] = (P–1)T]

–1 2  –1 2  1 
 0  0  0
0
3 3  3 3  3 
  –1 0 0    
 
 0 1 0
 –1 
 Q=  2
 2 –1   –1 
0  0 0 0
3 3   0 0 3 3 3   3 
     
0 0 1  0
  0 1  0
 0 3

 QT = Q + 
  = 0 Ans.

8. The trace of matrix P2012 is equal to

vkO;wg P2012 d k vuqjs[k (trace) d k eku gS&
(A) 32011 + 2 (B) 32012 (C*) 32012 + 2 (D) 32011

1 2 0
 
2 1 0
Sol.. Given fn;k gS P = 
0 0 1

 1 2 0   1 2 0  5 4 0 
     
2 1 0  2 1 0   4 5 0 
So vr%, P2 = PP =  =
0 0 1 0 0 1 0 0 1

5 4 0  1 2 0  13 14 0
     
4 5 0 2 1 0  14 13 0
Now vc, P3 = P2P =  =
0 0 1 0 0 1  0 0 1

13 14 0  1 2 0   41 40 0
     
14 13 0 2 1 0  40 41 0
P4 = P3P =  = 
 0 0 1 0 0 1  0 0 1

 41 40 0  1 2 0  121 122 0 
     
40 41 0 2 1 0  122 121 0 
Also iqu%, P5 = P4P =  = 
 0 0 1 0 0 1  0 0 1
 Tr.(P) = 3, Tr. (P3) = 27 = 33
Tr.(P5) = 243 = 35  Tr. (P2011) = 32011
Also iq
u%, Tr.(P2) = 11 = 32 + 2
Tr.(P4) = 34 + 2
Tr.(P ) = 32012 + 2 Ans.
2012

Comprehension # 2
Let M be the maximum value of c2 for which O(0, 0) and A(1, 1) does not lie on opposite side of the straight
line (a + b)2x – (ab + bc + ca + 1)y + 2 = 0 for all a,b  R.
Also lx + my + n = 0 be a variable line, where l, m,n are 1st, 3rd and 7th terms of an arithmetic progression and
the variable straight line always passes through a fixed point P(,). [CRCT]
ekuk c d k vf/kd re eku M gSt cfd ewy fcUnqO(0, 0) vkSj A(1, 1) ljy js[kk (a + b) x – (ab + bc + ca + 1)y
2 2

+ 2 = 0, lHkha,b  R d sfy , foifjr vksj fLFkr ughagSA rFkklx + my + n = 0 ,d pj js[kkgSt gk¡l, m,n lekUrj
Js.kh d sØ e'k%izFke in , rhljk in vkSj 7 ok¡in gSvkSj pj ljy js[kklnSo ,d fLFkj fcUnqP(,) lsxqt jrh
gSA

Page - 6
9. If the circles x2 + y2 = M + 1 and x2 + y2 – 24x – 10y + 2 = 0 have exactly two common tangents, then the
number of possible integral values of , is
;fn oÙ̀kksx2 + y2 = M + 1 rFkk x2 + y2 – 24x – 10y + 2 = 0 d sfy ;sBhd nksmHk;fu"B Li'kZjs[kk,sfo|eku gks
rks, d slHkh lEHko iw.kkZad ekukasd h la[;k gS-
(A) 11 (B*) 13 (C) 12 (D) 10

Sol.
Sol. Given fn;k gS, (a + b)2 x – (ab + bc + ca + 1) y + 2 = 0
Now vc lehd j.k , (a + b)2 – (ab + bc + ca) + 1  0 for all a,b  R
 a2 + b2 + ab – bc – ca + 1  0  a2 + (b – c) a + (b2 – bc + 1)  0 a R
2 2
 (b – c) – 4(b – bc + 1)  0  3b2 – 2bc + (4 – c2)  0 b R
2 2
 4c – 12(4 – c )  0  c2 – 12 + 3c2  0  c2  3
 M=3
Also, lx + my + n = 0 (l, m, n are 1st, 3rd and 7th terms of an arithmetic progression)
iqu% , lx + my + n = 0 (l, m, n ,d l-Js-Ø e'k%izFke]rr̀h; ,oalkrosin gSA )
 lx + (l + 2d)y + (l + 6d) = 0 ('d' be their common difference ) 'd' bld klkoZ
v Urj gS
 l (x + y + 1) + d(2y + 6) = 0  x + y + 1 = 0, 2y + 6 = 0  x = 2, y = – 3
Hence vr%,  = 2,  = –3x2 + y2 = 4 ; x2 + y2 – 24x – 10y + 2 = 0
c1(0, 0) ; c2 = (12, 5)
r1 = 2 ; r2 = 169 –  2

169 – 2 > 0 
   – 48 , 48 
Since  is integer
 = 0, ±1, ±2,....,2 ±6
 Number of possible integral values of  is 13 Ans.
  d slHkh lEHkkfor iw .kkZad ekuksd h la[;k 13 gS
10. If the point (2, k) lies outside the circles x2 + y2 + x – 2y – 14 = 0 and x2 + y2 = 2 +  2 , then the true set of
values of k, is [CRPC]
;fn fcUnq(2, k) oÙ̀k x + y + x – 2y – 14 = 0 rFkk x + y =  +  d sckgj fLFkr gksrksk d sekuksd k leqPp;
2 2 2 2 2 2

gksxk
(A) k  (–3, –2)  (3, 4) (B) k  (–3, 4)
(C*) k  (–, –3)  (4, ) (D) k  (–, –2)  (3, )
Sol. (2,k) lies outside the circle x2 + y2 + x – 2y – 14 = 0, so
(2,k) oÙ̀k x2 + y2 + x – 2y – 14 = 0 d sckgj fLFkr gS A vr%
4 + k2 + 2 – 2k – 14 > 0  k2 – 2k – 8 > 0  (k – 4)(k + 2) > 0
 k  (–, –2)  (4, ) .......(1)
Also the point (2, k) lies outside the circle x2 + y2 = 2 +  2 = 13
iqu% fcUnq(2, k) oÙ̀k x2 + y2 = 2 + 2 = 13 d sckgj fLFkr gS
4 + k2 – 13 > 0  k2 – 9 > 0  (k – 3)(k + 3) > 0
 k  (–, –3)  (3, ) .......(2)
 From (1) and (2)
 (1) o (2) ls
 k  (–, –3)  (4, ) Ans.

11. The tangent of the circle x2 + y2 = M + 2 at the point ( – 1,  + 1) also touches the circle
x2 + y2 – 4x – 2y + 20 = 0 then its point of contact is [CRTN]
oÙ̀k x2 + y2 = M + 2 ij fLFkr fcUnq( – 1,  + 1) ij [khph xbZLi'kZjs[kk]oÙ̀k x2 + y2 – 4x – 2y + 20 = 0 d k
Li'kZd jrh gSrksLi'kZfcUnqd sfunsZ'kkad gksxsa-
(A*) (3, – 1) (B) (–3,0) (C) (–1, – 1) (D) (–2, 1)

Page - 7
Sol 11. x2 + y2 = M + 2 = 3 + 2 = 5
tangent at ij Li'kZjs[kk (1, – 2)

x – 2y – 5 = 0 .......(1)
This line touches the circle x2 + y2 – 8x + 6y + 20 = 0
;g js[kk oÙ̀k x2 + y2 – 8x + 6y + 20 = 0 d ksLi'kZd jrh gSA
2x  y  5 
Solving  x  3, – 1
x – 2y  5
Hence point of contact (3, – 1) Ans.
vr%Li'kZfcUnq(3, – 1) Ans.

Subjective (double digit)

2
 AB – BC  CA 
12. In a triangle ABC if BAC = 60º and r is inradius then   = [STRA]
 r 
2
 AB – BC  CA 
fd lh f=kHkqt ABC es
a;fn BAC = 60º rFkk r vUr%f=kT;k gSrc 
r
 =
 
Ans. 12
A
Sol. r = tan   (s – a)
2

1  AB  BC  CA 
r=  – BC 
3  2 

1 AB – BC  CA
r=
3 2
AB – BC  CA
2 3
r
S.B.S.
2
 AB – BC  CA 
  = 12
 r 

13. If x,y,z are non-negative integers such that 2(x3 + y3 + z3) = 3(x + y + z)2 then maximum value of x + y + z
is [SSIG]
;fn rhu v_ .kkRed iw.kkZad x,y,z bl izd kj gSfd 2(x + y + z ) = 3(x + y + z)2 rc x + y + z d k vf/kd re eku
3 3 3

gS
Ans. 12

Page - 8
Sol. Let f(t) = t3, u = f(t)
A(x, x3), B(y, y3), C(z, z3)

Centroid G lies inside ABC

GL  ML

x3  y3  z3 xyz
 f 
3  3 

x3  y3  z3 ( x  y  z )3
 .......(1)
3 27

( x  y  z )2 x3  y3  z3
Given = ......(2)
2 3

( x  y  z )2 ( x  y  z )3 27
  (x + y + z) 
2 27 2
If x + y + z = 13, x,y,z will not satisfy (2)
If x + y + z = 12, x = 3,y = 4, z = 5 will not satisfy (2)
Hence maximum value is 12.
Alternate :
a   b   c abc  
    
3  3   3 

x3  y3  z3 xyz  x 2  y 2  z2 
     .....(1)
3  3   3 

x 2  y 2  z2 xyz xyz
    .......(2)
3  3  3 
3
x 3  y 3  z3  x  y  z 
    ...........(3)
3  3 

(x  y  z)2 x3  y3  z3
Given = ...........(4)
2 3
27
(3), (4)  x + y + z 
2
If x + y + z = 13, x,y,z will not satisfy (4)
If x + y + z = 12, then/ x = 3,y = 4, z = 5 will not satisfy (4)
Hence maximum value is 12.

3n 2  1

9
14. If S =  (n
n2
2
– 1) 3 then
S
= [SSTN]

3n 2  1

9
;fn S=  (n 2
– 1) 3 rc S
=
n2
Ans. 16

Page - 9
Sol. (n3 – 1)3 = (n + 1)3(n – 1)3
(n + 1)3 – (n – 1)3 = 6n2 + 2

3n 2  1 2
1 6n  2 1  (n  1)3 – (n – 1)3 
2 3 = =  3 3

(n – 1) 2 (n 2 – 1)3 2  (n  1) (n – 1) 

1  1 1 
 
=  (n – 1)3 – (n  1)3 
2  

1  1 – 1    1 – 1    1 – 1    1 – 1   ...
S=  3 
2  1 3 3   23 4 3   3 3 5 3   43 63  

1 1  1  9 9
=  =  16S = 9 16 =
2  8  16 S

15. Let f : N  [0, ) be a function satisfying the following conditions : [FNFR]

(a) f(100) = 10,
1 1 1 1
(b) + + +......+ = f(n +1), for all non-negative integers n. Find
f (0)  f (1) f (1)  f (2) f (2)  f (3) f (n)  f (n  1)
the value of f(9801).
ekuk f : N  [0, ) ,d Q y u gSt ksfuEu izfrcU/kksad kslUrq"V d jrk gS
(a) f(100) = 10,
1 1 1 1
(b) + +
f (0)  f (1) f (1)  f (2) f (2)  f (3)
+......+
f (n)  f (n  1)
= f(n +1), lHkh v_ .kkRed iw.kk±d n d sfy ,A
f(9801) d keku Kkr d hft ,A
Ans.99
Sol. Replace n by n – 1
1 1 1
+ +......+ = f(n)
f (0)  f (1) f (1)  f (2) f (n – 1)  f (n)
put in (b)
1
f(n) + = f(n +1)
f (n)  f (n  1)
 1 = f2(n + 1) – f2(n)
 1 = f2(1) – f2(0)
 1 = f2(2) – f2(1)

1 = f2(100) – f2(99)
Adding
100 = f2(100) – f2(0)  f(0) = 0
Also n = f2(n) – f2(0)  f(n) = n
f(9801) = 99

1
3n
 Cn  n A
16. If lim  2n  = , where A & B are relatively prime numbers, then A+B is equal to- [LTIL]
n
 Cn  B

1
3n
 Cn  n A
;fn lim  2n  = t gk¡A ,oaB lgvHkkT; la[;k,¡gSrc A+B cjkcj gS-
n
 Cn  B
Ans. 43

Page - 10
 1/n
A  (2n  1)(2n  2)(2n  3).......(2n  n) 
Sol. = nlim  
B 
 (n  1)(n  2)(n  3).........(n  n) 

 r 
1 n  2 n 
lim  ln  
ln (A/B) = n n r 1 1 r / n 
 
 
1
 (2  x)  27
 ln   dx =
0  (1  x)  16
 A = 27 & B = 16

sin 2x a  b cos x
17. If  (3  4 cos x) 3
dx   e where a, b, c, d are positive integers and e is arbitrary constant
c(3  4 cos x )d
then minimum value of a + b + c + d equal to [IITR]
sin 2x a  b cos x
;fn  (3  4 cos x) 3
dx  e t gk¡a, b, c, d /kukRed iw.kkZad gSrFkk e LoSPN vpj gSrc a+
c(3  4 cos x )d
b + c + d d k U;w
ure eku gS
Ans. 29
Sol. 3 + 4 cos x = t  – 4 sin x dx = dt
1 t3
I  dt
8 t3
1 1 3
  dt
8 t2 t3
11 3 
   e
8  t 2t 2 
2t  3 8 cos x  3
  e
16 t 2 16(3  4 cos x )2
 a = 3, b = 8, c = 16, d = 2

 z2  
18. Complex number z satisfies arg (z  (3 + 3i)) =  and arg   then range of  such that no z
 z  2i  11
exists is [a ,b], then find the value of [ 10 |a+b|] where [.] represents the greatest integer function and arg
means principal value of argument.
[CNAG]

 z2  
lfEeJ la[;k z, d ks.kkad (z  (3 + 3i)) =  vkSj d ks.kkad   d kslarq"B d jrk gSrc  d sekuksad k
 z  2i  11
ifjlj [a ,b] gS]t cfd d ksbZz fo|eku ughagSrc [ 10 |a+b|] d k eku Kkr d hft , t gk¡[.] egÙke iw.kkZad Q y u
d ksO;Drd jrk gSrFkk d ks.kkad ]d ks.kkad d seq[; eku d ksfu: fir d jrk gS&
Ans. 47

Page - 11
Sol. First note that (3, 3) is in the interior of the arc, as

 3  3i  2   1  3i 
arg   = arg  
 3  3i  2i   3i  (3, 3)

1 (0, 2)
= tan13 tan1 3

 3 1/ 3  (2, 0)
= tan1  
 2 

= tan1  8 
6
 
4 
= tan1 3  11

Now : From the figure it is clear that if rays don’t intersect the circle.

 1 1 
then      tan ,   tan1 3
 3 
1 1 1
 | a + b | = 2  tan 3  tan
3

= 2 
2
3
=
2
 10 | a + b | = 15 
 [ 10 | a + b | ] = [ 15 ] = 47
19. The numbers 2,3,4,5,6,7,8 are to be placed, one per square, in the diagram shown so that the sum of the four
numbers in the horizontal row equals 21 and the sum of the four numbers in the vertical column also equals
21. In how many different ways can this be done ? [PCGR]
la[;k,¡2,3,4,5,6,7,8 n'kkZ;sx;sfp=kkuql kj izR;sd oxZesa,d bl izd kj j[khgS]d h{kSfrt iafDr esapkj la[;kvksa
d k ;ksx Q y 21 d scjkcj gSvkSj m/okZ/kj LrEHk esapkj la[;kvksad k ;ksxQ y Hkh 21 d scjkcj gSrksbl izd kj
d sfd rusfofHkUu rjhd sgksxsa?

Ans. 72

Sol.

(a1 + a2 + a3 + a4) = 21,

a5 + a3 + a6 + a7 = 21,
a1 + a2 + a3 + a4 + a5 + a6 + a7 = 35
 a3 = 7, a1 + a2 + a4 = 14, a5 + a6 + a7 = 14
a1, a2 , a4  {2,4,8}, a5 , a6 , a7  {3,5,6}
or
a1, a2 , a4  {3,5,6}, a5 , a6 , a7  {2,4,8}
Required number of ways vHkh"V Ø e'k%= (3! × 3!) + (3! × 3!) = 72

Page - 12
20. If polygons with 4 vertices, 8 vertices, 16 vertices, ..., 2n+1 vertices are inscribed in circles with radii
1, 2, 4, ..., 2n–1 and length of sides are a1, a2, a3, ... an respectively, then [TRSP]
2 22 23 2n   
1+ a + + + .... + = cot  n  . Find the value of .
1 a2 a3 an 2 

;fn f=kT;kvksa1, 2, 4, ..., 2n–1 d soÙ̀kksd svUrxZr Ø e'k% 4 'kh"kksZ, 8 'kh"kksZ, 16 'kh"kksZ, ..., 2n+1 'kh"kksZd scgqHkqt gS
2 22 23 2n   
ft ud h Hkqt kvksad h y EckbZ;k¡Ø e'k% a1, a2, a3, ... an gSrc 1+ a +
a
+
a
+ .... +
a
= cot  n  gSA
1 2 3 n 2 
d k eku Kkr d hft ,A
Ans. 02

Sol.

   ak ak
sin  k 1  = 2r = k
2  k 2

2 22 23 2n         
1+ a + + + ... + = 1 + cosec  2  + cosec  3  + ... + cosec  n 1 
1 a2 a3 an 2  2  2 

    
sin  sin  –  sin  cos – cos  sin
2
   2  2 2
cosec = = =
  
sin  sin  sin  sin  sin sin 
2
  2
  2


= cot   – cot
2

2 22 23 2n           
1 + a + + + ... + = 1 +  cot 3 – cot  +  cot 4 – cot 3  + ... +  cot n 2 – cot n1 
1 a2 a3 an  2 4  2 2   2 2 

  
= cot  n2 .
2 

21. Eccentricity of an ellipse of minimum area, circumscribing two circles, of equal radius, touching externally,
22
is . Find the value of µ. [ELTN]
µ

22
leku f=kT;kd snksoÙ̀kksd kscká Li'kZd jusoky sifjxr U;wure {ks=kQ y d snh?koZ̀Ùkd hmRd sUnzrk µ
gSA µd k
eku Kkr d hft ,A

Page - 13
Ans. 33
Sol. (x – r)2 + y2 = r2

x2 y2
 =1
a2 b2
P(acos, bsin)  (acos – r)2 + (bsin)2 = r2 ..........(1)

Normal passes through (r, 0)

vfHky Ec (r, 0) lsxqt jrk gS
a.r b.0 r
– = a2 – b2  cos =
cos  sin  ae2

r2 r
put in (1) b2 = 2  b=
e e

r2 r
lehd j.k (1) esaj[kusij b2 = 2  b=
e
e

 b2 r 2
Area {ks
=kQ y = ab = = differentiable w.r.t. e (e d slkis
{k vod y u)
1– e2 e2 1 – e2

2
e =
3

Page - 14
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 1

Test Date : 02-02-2014

Test Type : AIOT (JEE ADVANCED PATTERN)

Target Date : 16-01-2014 Time Duration : 3 Hrs.

Test Syllabus : FULL XII&XIII SYLLABUS

Test Pattern :

Paper-2 (AIOT-1 JEE ADVANCE)

S.No. Subject Nature of Questions No. of Questions Marks Negative Total
1 to 5 MCQ 5 4 0 20
6 to 11 Maths Comprehension (2 Comp. x 3 Q.) Single Choice 6 2 0 12
12 to 21 Subjective double digit 10 4 –1 40
22 to 26 MCQ 5 4 0 20
27 to 32 Physics Comprehension (2 Comp. x 3 Q.) Single Choice 6 2 0 12
33 to 42 Subjective double digit 10 4 –1 40
43 to 47 MCQ 5 4 0 20
48 to 53 Chemistry Comprehension (2 Comp. x 3 Q.) Single Choice 6 2 0 12
54 to 63 Subjective double digit 10 4 –1 40
Total 63 Total 216
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 2

PAPER-2
SECTION-1 : (One or more option correct type)
[k.M –1 : (,d ;k v f/kd l gh fod Yi çd kj)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE or MORE are correct.
bl [k.M esa5 cgqfod Yi ç'u gSA çR;sd ç'u esapkj fod Yi (A), (B), (C) v kSj (D) gS] ft uesal sd soy ,d
;k v f/kd l gh gSA

22. A 100 cm long cylindrical flask with inner and outer radius r1 = 2 cm and r2 = 4 cm respectively, is completely
filled with ice at 0ºC as shown in the figure. The constant temperature outside (surrounding) the flask is 40ºC.
Assume heat exchange occurs only through the curved surface of the flask. (Thermal conductivity of the
flask is 0.693 W.mºC, Lice = 80 cal/gm and 1 cal = 4200 J). [HT_CL]
,d 100 cm y Eck csy ukd kj ik=k ft ld h vkUrfjd rFkk ckg~; f=kT;kØ e'k%r1 = 2 cm rFkk r2 = 4 cm gS, 0ºC ij
cQ Zd slkFk fp=kkuql kj iw.kZr;k Hkjkgqv k gSA ik=k d sckgj (okrkoj.k) d krki 40ºC fu;r gSA ;g ekusfd d soy
ik=k d h oØ h; lrg lsÅ "ek d k vknku iznku gksrk gSA (ik=k d h Å "eh; pky d rk 0.693 W.mºC, Lice = 80 cal/
gm rFkk 1 cal = 4200 J gS ).

r1
ice

r2

(A*) Rate of heat flow from surrounding to the flask is 80 J/s.

(B*) The rate at which ice melts is Kg/s.
4200
(C) The rate at which ice melts is 100 Kg/s.
(D) Rate of heat flow from surrounding to the flask is 40 J/s.
(A*) okrkoj.k lsik=k d ksizokfgr Å "ek d h nj 80 J/s gSA

(B*) cQ Zd sfi?ky usd h nj Kg/s gS
A
4200
(C) cQ Zd sfi?ky usd h nj 100 Kg/s gS
A
(D) okrkoj.k lsik=k d ksiz
okfgr Å "ek d h nj 40 J/s gSA
KAd d
Sol. H= = K (2rL)
dr dr
r2
dr
 H r = 2 KL( 2 – 1 ) = 80
r1

dm
 L = 80
dt
dm 8 80 
 = = = Kg/second.
dt L 80  4200 4200
23. A point object of mass m is slipping down on a smooth hemispherical body of mass M and radius R. The
point object is tied to a wall by an ideal string as shown. At a certain instant shown in figure, speed of the
hemisphere is v and its acceleration is a. Then speed vP and acceleration aP of the point object is. (Assume
all the surfaces in contact are frictionless). [CM_VT]
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 3

m nz
O;eku d h,d fcUnqoLrqM nzO;eku rFkkR f=kT;kd h,d ?k"kZ.kjfgr v) Zxksy h; oLrqij uhpsd hvksj fQ ly
jgh gSA fcUnqoLrqnhokj lsvkn'kZMksjh }kjk fp=kkuql kj t qM+h gqbZgSA fd lh fuf'pr {k.k ij v) Zxksy sd h pky v
gSrFkk bld k Roj.k a gSA rc fcUnqoLrqd h pky vP rFkk Roj.k aP gksxk (;g ekfu,safd lHkh lEifd Zr lrg
?k"kZ.kjfgr gS)

2
 a 3 v 2   a 2
(A) vP = v sin 60º (B*) vP = v (C) aP = a (D*) aP =     
 2 R   2 

Sol. x + R = constant fu;rka

d
dx Rd
 =0
dt dt
v
d v R
  = =
dt R
 = d/dt = a/R x
At = 60º,
2
 a 3 v 2   a 2
 vP = v and rFkkaP =     
 2 R   2 

24. A trinary star system has time period T = 3 year, while the distance between its components is 2 astronomical
unit. If mass of the sun is represented by MS, then the total mass of this multiple star system will be :
[GR_SK]
Note: (1) System of three star, orbiting around centre of mass of system, is called trinary star
system, for simplicity assume all three components to be identical.
(2) 1 astronomical unit = distance between earth and sun.
(3) 1 year = time period of earth to complete one full revolution around sun
,d f=krkjsfud k; d kvkorZd ky T = 3 o"kZgSt cfd bld s?kVd ksad se/; nwjh2 [kxksfy ; bd kbZgSA ;fn lw;Zd k
nzO;eku MS lsiznf'kZr fd ;k t k, rc cgqrkjsfud k; d k d qy nzO;eku gksxkA
uksV :
(1) fud k; d snzO;eku d sUnzd spkjksavksj d {kh; xfr d jrsgq, rhuksarkjksad k fud k; f=krkjk fud k; d gy krk gSA
ljy : i esalHkh rhuksa?kVd ksad ks,d leku eku ld rsgSA
(2) ,d [kxks y h; bd kbZ= iF̀oh rFkk lw;Zd se/; nwjh
(3) 1 o"kZ= iF̀oh d k lw
;Zd spkjksavksj ,d iw.kZifjØ ek d k vkorZd ky
7 8
(A) 3 MS (B) 2 MS (C) M (D*) M
9 S 9 S
Sol. For earth and sun system iF̀oh rFkk lw
;Zfud k; d sfy ,
4 2 3
T 02 = R ..............(i)
GMs
For trinary star system f=krkjk fud k; d sfy ,
Gm2 3 2 a 3Gm
2 = m  2 =
a 2 2 3 a3

42 42 3
T2 = = a ..............(ii)
2 3Gm
Given fn;k x;k gS
, T = 3T0 a = 2R

42
9T02 = 8R3
3Gm
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 4

4 2 3 2
8MS
 9 R = 8 4 R 3  m=
GMS 3 Gm 27

8
Total mass d q
y æO;eku = 3m = M .
9 S
25. The point S is monochromatic source of light emitting light of wavelength . At the point P at a distance x
from the mirror as shown in the figure, interference takes place between two light rays one directly coming
from source S and another after reflection from the mirror such that a maxima is formed. The value of x may
be : [YE_YE]
fcUnqS ,d o.khZ; izd k'k L=kksr gSt ksrjaxnS/;Zd k izd k'k mRlft Zr d j jgk gSA niZ.k lsx nwjh ij fcUnqP
fp=kkuql kj iznf'kZr gSA nksizd k'kfd j.ksaft ues
als,d lh/ksghiz
d k'kL=kks
r lsvkjghgSrFkknw
l jhniZ
.klsijkorZ
u
d si'pkr~vk jgh gS]d se/; O;frd j.k d sQ y Lo: i mfPp"V curk gSA x d k eku gksld rk gSA

(A) 120  (B) 125  (C*) 62.5  (D*) 187.5 

Sol. x = (SA + AP) – SP

= (SA + AB) – SP
= SB – SP
= (500 x )2  (3 x )2  (500 x )2  x 2

 9 1 
= 500x  1  5002 – 1  5002 
 

 9   1 
= 500x  1  2 
– 1  2 
 2  500   2  500  

500 x  3
= 2 [8] = , ....
2  500 2 2
x= 62.5187.5

26. An electron in H-atom in first case jumps from second excited state to first excited state and then in second
case from first excited to ground state. Let the ratio of wavelength, momentum and energy of photons
emitted in first case to second case be a, b and c respectively, then [MP_TR]
izFke fLFkfr esagkbMªkst u ijek.kqesa,d bysDVª kWu f}rh; mRrs
ft r voLFkklsaizFke mÙks
ft r voLFkkesalaØ e.kd jrk
gSrFkkfQ j f}rh; fLFkfr esaizFke mÙksft r voLFkklsewy voLFkkesalaØ e.kd jrkgSA ekukizFke fLFkfr lsf}rh;
fLFkfr esamRlft Zr Q ksVkWu d h rjaxnS/;Z]laosx rFkk Å t kZd svuqikr Ø e'k%a, b rFkk c gS]rc
27 5 b
(A*) a = (B*) b= (C*) 1 (D*) a × c = 1
5 27 c

1  1 1 h hc
Sol. As pw
afd = R  n 2 – n 2  and rFkk P = . Also rFkk, E =
  1 2   

SECTION – 2 : (Paragraph Type)

[k.M – 2 : (v uqPN sn çd kj)
This section contains 2 paragraphs each describing theory, experiment, data etc. Six questions related to
two paragraphs with three questions on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D).
bl [k.M esafl) karksa]ç;ksxksavkSj vk¡d M+ksavkfn d ksn'kkZusoky s2 v uqPN sn gSA nksuksavuqPNsnksalslacaf/kr N % ç'u
gSa]ft uesalsgj vuqPNsn ij rhu ç'u gSaA fd lh Hkh vuqPNsn esagj ç'u d spkj fod Yi (A), (B), (C) vkSj (D) gSa]
ft uesalsd soy ,d gh l gh gSA
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 5

Paragraph for Questions 27 and 29

iz'u 27 v kSj 29 d sfy , v uqPN sn
Two fixed and horizontal cylinders A and B having pistons (both massless) of cross sectional area 100 cm2
and 200 cm2 respectively, are connected by massless rod. The piston can move freely without friction. The
cylinder A contains 100 gms of an ideal gas ( = 1.5) at pressure 105N/m2 and temperature T0. The cylinder
B contains identical gas at same temperature T0 but has different mass. The piston are held at the state such
that volume of gas in cylinder A and cylinder B are same and is equal to 10–2m3. The walls and piston of
cylinder A are thermally insulated where as gas in cylinder B is maintained at constant temperature T0. The
whole system is in vacuum. Now the pistons are slowly released and they move towards left and mechanical
equilibrium is reached at the state when the volume of gas in cylinder A becomes 25 × 10–4 m3.
nksfLFkj rFkk{kSfrt csy u A rFkkB ft ud sfiLVu (nksuks
anzO;ekughu) d svuqiz
LFkd kV {ks
=kQ y Ø e'k%100 cm2 rFkk
200 cm2 gS
, ,d nzO;ekughu NM+}kjk t qM+sgq, gSA fiLVu fcuk ?k"kZ.k d sLora=krkiwoZd xfr d j ld rk gSA csy u
A esaT0 rki rFkk105N/m2 nkc ij 100 gms d h,d vkn'kZxSl ( = 1.5) HkjhgqbZgSA csy u B esaHkhleku rki T0
ij ,d leku fd UrqfHkUu nzO;eku d h vkn'kZxSl Hkjh gqbZgSA fiLVu bl izd kj y xsgq, gSafd csy u A rFkk B esa
xSl d kvk;ru leku gSrFkk10–2m3 d scjkcj gS A cs
a y u A d hnhokjsrFkkfiLVu Å "ekd sd q pkyd gSt cfd csy u
B esaxSl fu;r rki T0 ij cuk;sj[krh gSA lEiw.kZfud k; fuokZr esagSA vc fiLVu d ks/khjslsNksM+k t krkgSrFkk
;scka;h vksj xfr d jrsgSrFkk t c ;kaf=kd lkE;koLFkk esaigq¡p rsgSrc csy u A esaxSl d k vk;ru 25 × 10–4 m3
gkst krk gSA [TH_AD]

A B

27. The mass of gas in cylinder B is

csy u B esaxSl d k nzO;eku gksxk
(A) 200 gms (B) 600 gms (C) 500 gms (D*) 1 kg
28. The change in internal energy of gas in cylinder A is :
csy u A esaxSl d h vkUrfjd Å t kZesaifjorZu gksxk
(A*) 2000 J (B) 1000 J (C) 500 J (D) 3000 J
29. The compressive force in the connecting rod at equilibrium is :
lkE;koLFkk ij la;ksft r NM+ksaesalEihM+u cy gksxk
(A) 2000 N (B) 4000 N (C*) 8000 N (D) 10000 N
Sol. Let the initial temperature, pressure and volume of gas in ‘A’ be T0, P0, V0 and the area of the position A and
B be a, 2a.
Now gas in chamber ‘A’ undergoes adiabatic compression whereas gas in chamber ‘B’ undergoes
isothermal expansion.
Now solving for gas in ‘A’
P1A V1A

= P2A V2A

 P0 V0 = P2A (0.25V0 )  P2A = 8P0
Solving for gas is chambers ‘B’
P1BV1B = P2BV2B  P1BV0 = P2B x 2.5V0  P2B = 0.4 P1B
Also
(P2A x a) = (P2B x 2a) for gas in ‘B’
 8P0a = P2 x 2a  P2 = 4P0
 0.4 P1 = 4P0  P1 = 10P0
Now comparing the moles of gas in A and B
P0 V0 10P0 V0
nA  , nB  = 10nA
RT0 RT0
mB  10 mA = 10 x 100gm = 1kg.
Again for gas is A, Q = U + W
 0 = U + W
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 6

 V0 
 P0 V0  8P0  4 
 0 = U +  
 (   1) 
 
 U = 2P0V0
= 2 x 105 x 102 = 2000J
5
F = 8P0a = 8 x 10 x 10 = 8000 N
2

Sol. ekuk ‘A’ easaxSl d k izkjfEHkd rki]nkc rFkk xSl d k vk;ru T0, P0, V0 gSrFkk fLFkfr A rFkk B es
a{ks=kQ y a, 2a
gSA .
vc d {k ‘A’ esaxSl : ) ks"e laihMu d svarxZr gSt cfd d {k ‘B’ esaxSl lerkih; izl kj d svarxZr gSA
vc ‘A’ esaxSl d sfy ;sgy d jusij
P1A V1A

= P2A V2A

 P0 V0 = P2A (0.25V0 )  P2A = 8P0
d {k ‘B’ esaxSl d sfy , gy d jusij
P1BV1B = P2BV2B  P1BV0 = P2B x 2.5V0  P2B = 0.4 P1B
rFkk
(P2A x a) = (P2B x 2a) ‘B’ es
axSl d sfy ,
 8P0a = P2 x 2a  P2 = 4P0
 0.4 P1 = 4P0  P1 = 10P0
vc A rFkkB esaxSl d seksy ksad h rqy uk d jusij
P0 V0 10P0 V0
nA  , nB  = 10nA
RT0 RT0
mB  10 mA = 10 x 100gm = 1kg.
A es
axSl d sfy , iqu% , Q = U + W
 0 = U + W

 V0 
 P0 V0  8P0  
 0 = U +  4

 (   1) 
 
 U = 2P0V0
= 2 x 105 x 102 = 2000J
F = 8P0a = 8 x 105 x 102 = 8000 N

Paragraph for Questions 30 and 32

iz'u 30 v kSj 32 d sfy , v uqPN sn
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 7

A thin superconducting (zero resistance) ring is held above a vertical long solenoid, as shown in the figure.
The axis of symmetry of the ring is same to that of the solenoid. The cylindrically symmetric magnetic field
around the ring can be described approximately in terms of the vertical and radial component of the magnetic
field vector as Bz = B0(1 – z) and Br = B0r, where B0,  and  are positive constants, and z & r are vertical
and radial position coordinates, respectively. Initially plane of the ring is horizontal, has no current flowing in
it. When released, it starts to move downwards with its axis still vertical. Initial coordinates of the centre of
the ring ‘O’ is z = 0 and r = 0.
In the given diagram point O is on the axis and slightly above the solenoid having vertical and radial position
coordinates as (0, 0). Ring has mass m, radius r0 and self inductance L. Assume the acceleration due to
gravity as g. [EM_FQ]
,d iry h vfr pky d ('kwU; izfrjks/k) d h ,d oy ; Å /okZ/kj y Ech ifjukfy d k d sÅ ij fp=kkuql kj j[kh gqbZgSA
oy ; d hlefer v{kcsy u d hv{kd sleku gSA oy ; d spkjksavksj csy ukd kj lefer pqEcd h; {ks=kd kspqEcd h;
{ks=klfn'kd sÅ /okZ/kj rFkkf=kT;h; ?kVd d sinksaesaBz = B0(1 – z) rFkkBr = B0r d svuql kj n'kkZ;kt kld rk
gS, t gk¡B0,  rFkk /kukRed fu;rkad gSrFkkz o r Ø e'k%Å /okZ/kj rFkkf=kT;h; fLFkfr;ksad sfunsZ'kkad gSaA izkjEHk
esaoy ; d kry {kSfrt gSrFkkblesad ksbZ/kkjkizokfgr ughagSA t c blsNksM+kt krkgSarks;g bld hÅ /okZ/kj v{k
d svuqfn'k uhpsd h vksj xfr izkjEHk d jrh gSA oy ; d sd sUnz‘O’ d k izkjfEHkd funsZ'kkad z = 0 rFkk r = 0 gSA
fn;sx;sfp=k esafcUnqO v{k ij fLFkr gSarFkk ;g ifjukfy d k d sFkksM+k lk Å ij gSA ‘O’ d sÅ /okZ/kj rFkk f=kT;h;
fLFkfr funsZ'kkad (0, 0) gS] oy ; d k nzO;eku m, f=k
zT;k r0 rFkk Loiz
sjd Ro L gSA xq: Roh; Roj.k g ekusaA

B O B

30. Find the magnitude of current in the ring at a vertical position z.

Å /okZ/kj fLFkfr z ij oy ; esa/kkjk d k ifjek.k Kkr d hft ,A
1 1 1
(A*) B0 r02 z (B) B0 r02 z (C) B0r02 z (D) None of these bues
alsd ksbZugha
L L 2L

31. Find the vertical coordinates z for equilibrium position of the ring.
oy ; d h lkE;koLFkk d h fLFkfr d sfy , Å /okZ/kj funsZ'kkad z Kkr d hft ,
mgL mgL
(A) (B*)  2B2 2r 4 (C) zero 'kw
U; (D) None of these bues
alsd ksbZugh
2B 02  2r04 0 0

32. Find the time period of SHM (for small displacement along z–axis) of the ring.
oy ; d sSHM (z-v{k d svuqfn'k vYi foLFkkiu d sfy ,) d k vkorZd ky Kkr d hft ,A
1 2mL 1 2mL
(A*) (B)
B0r02  2B0r02 

1 mL
(C) (D) ring will not perform SHM oy ; SHM ughad jrh
B0r02 3
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 8

Sol. Total magnetic flux at any position   Bz r02  L

Since, R = 0, so   B0 (1  z)r02 – L = constant
From initial condition (z = 0, I = 0), the value of constant is   B0 r02

1
Using the above equation the current in the ring I = B0 r02 z
L
The lorentz force acting on the ring (which can only be vertical,
because of the symmetry of the assembly) can be expressed as
2B20 2r04 z
Fz  Br (z)2r0    kz
L
Equation of motion of the ring is maz = Fz – mg = –kz – mg
Equilibrium position z0 = –mg/k
k
0 
m
Sol. fd lh fLFkfr ij d qy pqEcd h; ¶y Dl   Bz r02  L
pwafd , R = 0, vr%  B0 (1  z)r02 – L = fu;rkad
izkjfEHkd 'krZls(z = 0, I = 0), fu;rkad d k eku   B0 r02
1
oy ; esa/kkjk d h mijksDr lehd j.k d smi;ksx lsI = B0 r02 z
L
oy ; ij d k;Zjr y ksjsat cy (t ksleferh d sd kj.k d soy Å /okZ/kj gksld rk gS)
d ksfuEu izd kj iznf'kZr d j ld rsgSa
2B20 2r04 z
Fz  Br (z)2r0    kz
L
oy ; d h xfr d slehd j.k lsmaz = Fz – mg = –kz – mg
lkE;koLFkk fLFkfr z0 = –mg/k
k
0 
m

SECTION-3 : (Integer value correct Type)

[k.M –3 : (iw.kkZad eku l gh çd kj)
This section contains 10 questions. The answer to each question is a double digit integer, ranging from
00 to 99 (both inclusive)

33. A thin convex lens having focal length 20 cm is cut into two parts (A and B) 10 mm above the principle axis.
The lower part ‘A’ is placed with its optical centre at origin and upper part ‘B’ at (90 cm, 0) as shown in the
figure. A point object ‘P’ is placed at (– 30 cm, 0). If the distance of final image from x-axis is N mm, then find
the value of N. (Assuming paraxial ray approximation to remain valid) [GO_LE]
20 cm Q ksd l nwjhd s,d irysmÙky ySUl d kseq [; v{klsÅ ij 10 mm nwjhij nksHkkxks a(A rFkkB) esafp=kkuq
l kj
d kVkt krkgSA fupy kHkkx A bld sizd kf'kr d sUnzd slkFkewy fcUnqO ij fLFkr gS]t cfd Å ijhHkkx B (90 cm,
0) ij fp=kkuq
l kj fLFkr gSA ,d fcUnqoLrqP (– 30 cm, 0) ij fLFkr gSA ;fn x v{klsvfUre izfrfcEc d hnwjhN
mm gS , rksN d k eku Kkr d hft ,A (fd j.kks
ad kslekf{k; ekusarFkk fud Vre eku ekU; gSA)
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 9

Ans. 30
Sol. y

10 mm
x
(–30, 0) (0, 0) 10 mm (90, 0)
90cm Optical axis
20mm
150cm

For first lens

1 1 1
– =
v u f
1 1 1 1
 = – 
v 20 30 60
 v= 60 cm
For second lens
u = 30 cm, f = +20 cm
1 1 1
= –
f v u
1 1 1
 = –
v 20 30
1 3–2 1
 = 
v 60 60
 v2 = 60 cm
 m= –2
So coordinates are (150 cm, – 30 mm)

34. A closed organ pipe of length 99.4 cm is vibrating in its first overtone and is always in resonance with a
tuning fork having variable frequency f = (300 – 2t) Hz, where t is time in second. The rate by which radius of
1
organ pipe changes when its radius is 1 cm is m/s then find N. (speed of sound in organ pipe = 320 m/s)
N
99.4 cm y EckbZd k ,d cUn vkxZu ikbZi bld sizFke vf/kLojd esad EiUu d j jgk gSrFkk ,d Lofj=k f}Hkqt
ft ld h ifjofrZr vkof̀Ùkf = (300 – 2t) Hz gS] d slkFk lnSo vuqukn d h fLFkfr esagSA vkxZu ikbZi d h f=kT;k esa
1
ifjorZu d hnj m/s gSt c bld hf=kT;k1 cm gSrc N Kkr d hft ,A (vkxZu ikbZi esa/ofu d hpky = 320 ms
N
gS
A) [SW_OP]
Ans. 72
3v
Sol. f = 4  L  0.6r 

dr
df 3v [–0.6 ]
 = dt
2
dt 4  L  0.6r 

dr 1
= m/s
dt 72
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 10

35. AB is a solid cylinder of radius a0 and length L. Resistivity of the material varies with x-coordinate from end
0 x
A as  = . An ideal battery of emf E is connected from end A and B as shown. [CE_RE]
L
0 x
a0 f=kT;krFkkL y EckbZd k,d Bksl csy u AB gSA inkFkZd hizfrjks/kd rkfljsA lsx funsZ'kkad d slkFk = ds
L
vuql kj ifjofrZr gksrh gSA E fo|qr okgd cy d h ,d vkn'kZcSVjh A rFkk B d se/; fp=kkuql kj t qM+h gqbZgSA

dP Na 02E 2
If power gradient (i.e. , from end A) is x , then find N
dx  0L3

dP Na 02E 2
;fn 'kfDr izo.krk (vFkkZr~ fljsA ls) x gSrksN Kkr d hft ,A
dx  0L3
Ans. 04
2
E
Sol. P =   Rx
R

dp E2 dR
 = 2
dx R dx

E2 0 x
=
 02L4 LA
2 2
4A L
36. Electrons in a hydrogen like atom (Z = 3) make transitions from the fourth excited state to the third excited
state and from the third excited state to the second excited state. The resulting radiations are incident on a
metal plate to eject photoelectrons. The stopping potential for photoelectrons ejected by shorter wavelength
is 3.95 eV. If the stopping potential for the photoelectrons ejected by the longer wavelength is N × 10–2 V,
then find N. (Take energy of the hydrogen atom in ground state as –13.6 eV) [MP_TR]
gkbMªkst u leku ijek.kqesa(Z = 3) by sDVªkWu prqFkZmÙksft r voLFkk lsrr̀h; mÙksft r voLFkk esalaØ e.kd jrk gS
rFkk fQ j rr̀h; mÙksft r voLFkk lsf}rh; mÙksft r voLFkk esalaØ e.k d jrk gSA ifj.kkeh fofd j.k /kkrqd h Iy sV
ij vkifrr gksrsgSft llsQ ksVksbysDVªkWu mRlft Zr gksrkgSA y ?kqre rjaxnS/;Z}kjkmRlft Zr Q ksVkWby sDVªkWu d sfy ,
fojks/kh foHko 3.95 eV gSA ;fn nh?kZre rjaxnS/;Z}kjk mRlft Zr Q ksVkWby sDVªkWu d sfy , fojks/kh foHko N × 10–2 V
gS, rksN d k eku Kkr d hft ,A (gkbMªkst u ijek.kqd h ewy voLFkk esaÅ t kZ–13.6 eV y hft ,)
Ans. 75
1 1
Sol. hv = 13.6(3)2  2  2  = 2.75 eV
4 5 
for n = 4 to n = 3
1 1
hv = (13.6) × (3)2  2  2  =5.95 eV
3 4 
for shorter wavelength y ?kq
Ùke rjaxnS/;Zd sfy ,
3.95 = 5.95 –    = 2eV
for longer wavelength nh?kZ
re rjaxnS
/;Zd sfy ,
eVs = 2.75 – 2 = 0.75 eV
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 11

37. A commander fires a shell at certain angle of projection from ‘A’ which clears the building (cuboid) of dimensions
20 × 15 × 12.5 m3 in it’s diagonal plane. Shell just clears the roof diagonally at points P and Q and falls on
the other side of the building at B, and makes 45° angle with horizontal at P and Q as shown in the figure. If
the range AB of the shell is N × 3 metre then find N. (g = 10 m/s2) [PM_PH]
,d lsukd kt oku fcUnqA lsxksy hd ks,d fuf'pr d ks.kij nkxrkgSt ksehukj (?kukHk) ft ld hfoek;sa20 × 15
× 12.5 m3 d ksbld sfod .khZry es
aikj d jrhgSA xksy hehukj d sfcUnqP rFkkQ lsBhd gksd j xqt jrhgSrFkkehukj
d snwl jh vksj B ij fxjrh gSrFkk xksy h P o Q ij {kSfrt d slkFk fp=kkuql kj 45° d k d ks.k cukrh gSA ;fn xksy h
d h ijkl AB, N × 3 ehVj gS, rksN Kkr d hft ,A (g = 10 m/s2)

Ans. 25
Sol. PQ  152  202  25m
VP2 sin 2(45)
25   VP  5 10m / s
g

 VA2 sin2   2  10  12.5  (5 5)2  VA sin   5 15 m / s

VA cos   VP cos 45  5 5 m / s and   60

VA2 sin 2
 AB   25 3
g

38. In the diagram, the variation of coefficient of friction of the surface is shown. The external force F applied on
board is equal to 2 µMg. Now the board of mass M is gently pushed so that it starts moving. The variation of
3
 tan 1 
acceleration a of board with respect to displacement x has been shown. Find the value of   .

 tan 3 
fp=k esalrg d s?k"kZ.k xq.kkad d k ifjorZu iznf'kZr gS, cksMZij vkjksfir ckg~; cy F, 2 µMg d scjkcj gSA vc M
nzO;eku d scksMZd ks/khjslslko/kkuhiwoZd /kDd k fn;k t krk gSft lls;g xfr izkjEHk d jrk gSA cksMZd sRoj.k a
3
 tan 1 
d k ifjorZu foLFkkiu x d slkFk fp=k esaiznf'kZr gSA 
 tan 

 d k eku Kkr d hft ,A
 3 
[FR_MQ]
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 12

Ans. 27
Sol. If the block has moved by distance x.
;fn Cy kWd x nwjh lsxfr d jrk gSA
 µMg µMg µMg 
Ma = 2µMg –    (  – x)
 3 3 3 
 µg 2 µg 3 µg 
a= 2µg –    ( – x ) 
 3 3 3 
da1 3 µg
= [for 2nd and 3rd cells similarly] [2nd rFkk3rd ls
y ksad sfy ,]
dx 3
tan 1 : tan 2 : tan 3. = 3 : 2 : 1

39. Light of intensity  is incident on a fixed plane surface at an angle 30º with the surface. If 50% light is reflected
3
and remaining light is absorbed then radiation pressure on the plate is , then find n (speed of light is C):
nC
 rhoz
rk d k çd k'k fLFkj lery lrg ij lrg ls30º d sd ks.k ij vkifrr gSA ;fn 50% çd k'k ijkofrZ
r gksrk
3
gSrFkk'ks"kçd k'kvo'kksf"kr gksrkgSrksIy sV ij fofd j.knkc nC
gSrksn d keku Kkr d hft ,A (çd k'kd hpky
c gS
): [MP_RP]
Ans. 8
(1  r )  cos 2 
Sol. Pressure nkc =
C
Where,  is the angle with normal
t gk¡,  vfHky Ec d slkFk d ks.k gSA
3
= .
8C
40. The figure shows an RC circuit with a parallel plate capacitor. Before switching on the circuit, plate A of the
capacitor has a charge –Q0 while plate B has no net charge. Now, at t = 0, the circuit is switched on. How
much time (in second) will elapse before the net charge on plate A becomes zero. (Given C = 1F, Q0 = 1mC,

2  10 6
 = 1000 V and R ) [CP_EQ]
ln 3
fp=k esaçnf'kZr RC ifjiFk esal ekUrj iê l a/kkfj=k gSA ifjiFk d kspky wd jusd sigy sl a/kkfj=k d h Iy sV A
ij –Q0 vkos'kgSA t cfd Iy sV B vukosf'kr gSA vc t = 0 ij ifjiFkpky wfd ;kt krkgSA Iy sV A ij d qy vkos'k
6
'kwU; gksusesfd ruk l e; (l Sd .M esa) y xsxkA (fn;k gS%C = 1F, Q0 = 1mC,  = 1000 V rFkk R  2  10  )
ln 3

Ans. 2
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 13

Sol. Let at any time t charge flown through the plate B to plate A is q and instantaneous current is I.
ekuk fd l h Hkh l e; t ij Iy sV B l sIy sV A d h rjQ izokfgr vkos'k q gSrFkk rkR{k.khd /kkjk I gSA

–Q0 +q –q –Q0 +q –q

A B A B
I I

R  R 

 2q  Q0 
From loop theorem y w
i fl ) kUr l s   IR    0
 2C 
dq  2q  2C  Q0
 R 
dt 2C
dq dt
 
2C  Q 0  2 q 2 RC
Now for charge on plate A to be zero q = Q0.
vc Iy sV A ij vkos'k 'kwU; gSq = Q0.
Q0 t
dq dt
Integrating l ekd y u d jusij  
0
2C  Q0  2q 0 2 RC

 2C  Q0 
= t  RC ln  
 2C  Q0 

Putting the value of C, Q0,  and R We get t = 2 seconds.

C, Q0,  rFkk R d k eku j[kusij t = 2 l sd .M izkIr gksrk gSA
41. In the shown circuit, all three capacitor are identical and have capacitance C F each. Each resistor has
resistance of R . An ideal cell of emf V volts is connected as shown. If the magnitude of potential
a
difference across capacitor C3 in steady state is V then value of a × b is :
b
fn[kk;sx;sifjiFkesa]rhuksala/kkfj=k,d leku gSrFkkbud hizR;sd d h/kkfjrkC F gSA izR;sd izfrjks/kd kizfrjks/
keku R  gS
A V oksYV fo|qr okgd cy d s,d vkn'kZlsy d ksfp=kkuql kj t ksM+kt krkgSrksLFkk;hvoLFkk
a
esala/kkfj=k C3 d sfljksij foHkokUrj d k ifjek.k b V gSrc a×b d k eku gksxk &
[CP_CK]

Ans. 18
 AIOT-XII_(Adv)_Paper-2_02-2-14_Pg.No # 14

Sol. No current passes through capacitors in

steady state. Assume potential at point '4' to be zero.
2V
Then points '1' and '2' are at same potential .
3

Hence C1 and C2 can be taken in parallel.

V
The potential at point 3 is .
3
 Equivalent circuit of all three capacitors is shown
Hence potential difference across capacitor C3 is
2C  2V V  2V
=    =
2C  C  3 3 9

gy % fLFkj voLFkk ij la/kkfj=k ls/kkjk izokfgr ugh gksrh gS

ekuk fcUnq'4' ij 'kwU; gSA .
2V
rc fcUnq'1' rFkk'2' ij foHko leku gSA vr%
3

C1 rFkk C2 d kslekUrj Ø e esay sld rsgSA fcUnq

V
3 ij foHko 3
gSA
lHkh rhu la/kkfj=k d k rqY; ifjiFk fp=kkuql kj gksxkA
vr%C3 d sfoHkokUrj
2C  2V V  2V
=    =
2C  C  3 3 9

42. A constant tangential force of 0.02 N is acting on a large wooden plate of area 10 m2 floating on the surface
of river and plate moves with the constant speed 2 m/s on the river surface. The river is 1 m deep and the
water in contact with the river bed is stationary. Assuming constant speed gradient, coefficient of viscosity of
–n
water is 10 poise. Find the value of n. [EC_GE]
0.02 U;w Vu d k ,d fu;r Li'khZ; cy unh d sikuh d h lrg ij rSj jgh 10 m2 {kS=kQ y d h ,d cM+h y d M+h d h
Iy sV ij vkjksfir fd ;k t krk gSA Iy sV unh d h lrg ij 2 m/s d h fu;r pky lsxfr d jrh gSA unh 1m xgjh
gSrFkk unh d sry d slEid ZesafLFkr ikuh fLFkj gSA ekfu, fd pky izo.krk fu;r gSA ikuh d k ';kurk xq.kkad
10 ikbZ t gSA n d k eku Kkr d hft ,A
–n

Ans. 02
 F  0.02
A
     10  10 3 kg / ms  10 2 poise
Sol.  dv  2
 dx  1
 
 PAPER-2

MCQ(2)
43. 10 ml of a sample of H2O2 solution liberates 112 ml of O2 gas at STP upon decomposition. Identify the correct
statement(s) : (STO(P))
(A) Normality of the above sample of H2O2 is 0.5 N
(B*) 15 ml of the same sample of H2O2 solution liberates 224 ml of O2 gas at 1.5 atm and 273°C
(C*) Milliequivalents of hypo required for the titration of liberated I2 when 10 ml of the same sample of H2O2
solution is treated with excess of acidified solution of KI are 20
(D*) % (w/v) of given sample of H2O2 is 3.4 %.
H2O2 foy ;u d s10 ml d sfo?kVu lsSTP ij 112 ml O2 eq Dr gksrh gSA lgh d Fku@d Fkuksad ksigpkfu;sA
(A) H2O2 d smijks
Dr uewusd hukeZy rk 0.5 N gSA
(B*) 1.5 atm rFkk 273°C ij H2O2 foy ;u d sleku iz kn'kZd s15 ml ls224 ml O2 xSl eqDr gksrh gSA
(C*) H2O2 foy ;u d sleku uew usd k 10 ml vEy h; KI foy ;u d svkf/kD; d slkFkvfHkfØ ;k d jrk gSA rc eqDr
I2 d svuqekiu d sfy , vko';d gkbiksd sfey hrqY;kad 20 gSA
(D*) H2O2 d sfn;sx;suew usd k % (w/v) 3.4 % gSA
Sol. 10 ml of H2O2 solution liberates 112 ml O2 at STP
 1 L of H2O2 solution liberates 11.2 L O2 at STP
 volume strength of H2O2 solution = 11.2 V
V 11.2 N  17
N= = =2 % w/v = = 3.4%
5 .6 5 .6 10
15  112
15 ml of same H2O2 solution liberates ml O2 at STP
10
15  112 2
=   2 ml O2 at 1.5atm and 273°C
10 3
= 224 ml O2
meq. of H2O2 reacted with KI = N  V = 2  10 =20
 meq. of hypo required = 20
H2O2 foy ;u d s10 ml }kjk STP ij mRlft Z r O2 = 112 ml
 H2O2 foy ;u d s1 L }kjk STP ij mRlft Zr O2 = 11.2 L
 H2O2 foy ;u d h vk;ru lkeF;Z= 11.2 V
V 11.2 N  17
N= = =2 % w/v = = 3.4%
5 .6 5 .6 10
15  112
H2O2 d sfd lh foy ;u d s15 ml }kjk mRlft Zr O2 d k STP ij vk;ru = ml
10
15  112 2
=   2 ml (1.5 atm rFkk 273°C ij ½
10 3
= 224 ml O2
KI lsfØ ;k d jusoky sH2O2 d sfey h rq
Y;kad = N  V = 2  10 =20
 gkbiksd svko';d fey h rqY;kad = 20

44. In the crystal field of the complex [Fe(Cl) (CN)4(O2)]4– the electronic configuration of metal is found to be
t 62g , e 0g then which of the following is true about this complex ion : (COR(I))

lad qy [Fe(Cl) (CN)4(O2)]4– d sfØ LVy {ks=kesa]/kkrqd kby sDVªkWuh; foU;kl t 62g , e 0g ik;kx;k]rksbl lad qy vk;u
d slanHkZesafuEu esalsd kSulk lR; gS&
(A*) It is a paramagnetic complex
(B) O–O bond length will be less than found in O2 molecule
(C*) Its IUPAC name will be chlorotetracyanosuperoxidoferrate () ion
(D) It is a diamagnetic complex

[1]
 (A*) ;g ,d vuqp qEcd h; lad qy gSA
(B) O–O ca/k y ackbZO2 v.kqesaikbZt kusaoky h ca/k y ackbZlsd e gksrh gSA
(C*) bld k IUPAC uke Dy ks jksVsVªklk;uksl qijvkWDlkbMksQ sjsV () vk;u gSA
(D) ;g ,d iz frpqEcd h; lad qy gSA
Sol. (A, C)
The given complex is actually
okLro esafn;k x;slad qy
4
 
Fe (Cl) (CN) 4 (O 2 )
  2  1 4 1  
hence Fe() is t2g6, eg0 due to effect of strong ligands but it is paramagnetic due to O2–1 ligand.
bl izd kj izcy {ks=kfy xs.M d sizHkko d sd kj.k Fe() esat2g6, eg0 gSA y sfd u ;g O2–1 fy xs.M d sd kj.kvuq
p qEcd h;
gSA

MCQ(2)

45. Which of the following statements are true? (PBC (I))

(A*) ClO2 in alkaline solution undergoes disproportionation.
(B*) Ionisation enthalpy of molecular oxygen is very close to that of xenon.
(C*) Hydrolysis of XeF6 may involve a redox reaction.
(D*) Both P4O6 and P4O10 contain 12 P–O bonds
fuEu esalsd kSulsd Fku lgh gSa\
(A*) {kkjh; foy ;u esaClO2 fo"kekuqikru vfHkfØ ;k nsrk gSA
(B*) vkf.od vkWDlht u d h vk;uu ,UFksYih d k eku ft ukWu d h vk;uu ,UFksYih d scgqr fud V gSA
(C*) XeF6 d st y vi?kVu es ajsMkWDl vfHkfØ ;k lfEefy r gksld rh gSA
(D*) P4O6 o P4O10 nks
uksaesa12 P–O ca/k gksrsgSA
Sol. ClO2 is powerful oxidising agent, also strong chlorinating agent. Its bleaching power is almost 30 times
stronger than Cl2. In alkaline solution undergoes disproportionation.
2ClO2 + 2NaOH  NaClO + NaClO3 + H2O
gy % ClO2 'kfDr'kky h vkW
Dlhd kjd gSo izcy Dy ksjhuhd kjd (chlorinating agent) Hkh gSA bld k fojt ad pw.kZCl2 d h
vis{kk y xHkx 30 xquk izcy gksrk gSA {kkjh; foy ;u esafo"kekuqikru vfHkfØ ;k lEiUu gksrh gSA
2ClO2 + 2NaOH  NaClO + NaClO3 + H2O
I II
46. Pyrolusite is MnO2 used to prepare KMnO4. Steps are, MnO2 
 MnO42–  MnO4– .
Steps I and II are respectively : (DBC (I))
I II
ik;jksy ql kbV MnO2 gSft ld ksKMnO4 cukusesaiz;qDr d jrsgSA in bl izd kj gS]MnO2 
 MnO42– 
MnO4– in I rFkk II Ø e'k%gS a%
(A*) fuse with KOH / air and electrolytic oxidation.
(B*) fuse with KOH / KNO3 and electrolytic oxidation.
(C) fuse with conc. HNO3 / air and electrolytic reduction.
(D) dissolve in H2O and oxidation.

(A*) KOH @ ok;qd slkFk laxy u rFkk fo|qrvi?kVuh; vkWDlhd j.kA

(B*) KOH @ KNO3 d slkFk la xy u rFkk fo|qrvi?kVuh; vkWDlhd j.kA
(C) lkUnzHNO3 @ ok;qd slkFk la xy u rFkk fo|qrvi?kVuh; vip;uA
(D) H2O esafoy s; d juk rFkk vkWDlhd j.kA
Sol. (A,B)
Fuse with KOH in presence of air or oxidising agents like KNO3 , KClO3 etc.
ok;q;k vkWDlhd kjd t Sl sKNO3 , KClO3 bR;kfn d h mifLFkfr esaKOH d slkFk laxfy r d jukA
fuse
2MnO2 + 4KOH + O2  2K2MnO4 + 2H2O
electrolyt ic oxidation
MnO42–        MnO4– + e–

[2]
 laxy u
Sol. 2MnO2 + 4KOH + O2 
 2K2MnO4 + 2H2O
fo| qrv i?kVuh; vkWDlhd j.k
MnO42–  MnO4– + e–

MCQ(1)

47.

The correct statements about (I) and (II) are : (RM & CBC(O))
(A*) The acid catalysed hydrolysis of (I) and (II) yields one product identical.
(B*) For Wolff Kishner reduction (I) is the better reactant.
(C) (II) gives positive haloform reaction.
(D) Reduction by LiAlH4 forms a diol in both the cases.
;kSfxd (I) rFkk (II) d slanHkZesalgh d Fku gS%
(A*) (I) rFkk (II) d svEy mRizsfjr t y vi?kVu lscuusoky k ,d mRikn leku gSA
(B*) oksYQ fd 'uj vip;u d sfy , (I) mÙke fØ ;kd kjd gSA
(C) (II) /kukRed gS
y ksQ kWeZvfHkfØ ;k nsrk gSA
(D) LiAlH4 d s}kjk vip;u d jkusij nks uksafLFkfr esaMkbZv kWy curk gSA

Sol. (I) H O + CH3OH

3

(II) H O + CH3COOH
3

Wolff Kishner reduction is not used in presence of base sensitive group.

oksYQ fd 'uj vip;u d k mi;ksx {kkj laosnh lewg d h mifLFkfr esaughafd ;k t krk gSA

COMPREHENSION (1 COMP. X 3 Q.)

Paragraph for Question Nos. 48 to 50

iz'u 48 l s50 d sfy , v uqPN sn

[3]
 Concentration of a solution can be represented in many ways. Some of the important concentration terms
are as follows :
number of moles
Molarity of solution =
volume of solution in litre
Let a solution is prepared by dissolving w gm of solute of mol.wt. M in V ml water.
w
 Number of moles of solute dissolved =
M
number of moles of solute
molality =  1000
mass of solvent in gram

mass of solute in gm
% w/v =  100 (MOL(P))
mass of solution in ml

foy ;u d hlkUnzrkd ksvusd izd kj lsiznf'kZr fd ;kt k ld rkgSA d qN egRoiw.kZlkUnzrkin fuEu fn;sx;sgSA
foy s; d h eksy ksd h la[; k
foy ;u d h eksy jrk = foy;u d k vk;ru ¼yhVj esa½

;fn V ml t y esav.kqHkkj M oky sfoy s; d sw xzke d ks?kksy d j ,d foy ;u cuk;k t krk gSrks
w
 foy s; d s?kqy usoky seksy ksd h la[;k =
M

foy s; d seksy ksad h la[; k

eks
y y rk=  1000
xzke esafoy k; d d k nzO; eku
foy s; d k nzO;eku ¼xzke esa½
% w/v = foy ;u d k vk;ru ¼fey h esa½ 100

48. Equal volume of 1M NaOH, 10% w/v NaOH and 1m NaOH (d = 1.2 g/ml) are mixed then what will be M of final
solution. (All aqueous)
121 310 39
(A*) (B) (C) (D) None of these
78 617 17
1M NaOH, 10% Hkkj/vk;ru NaOH rFkk1m NaOH (d = 1.2 g/ml) d sleku vk;ru d ksfeyk;kt krkgSrksvfUre
foy ;u d h M D;k gksxh (lHkh t y h;)
121 310 39
(A*) (B) (C) (D) bues
alsd ksbZugha
78 617 17
10 V 1200 V
1V  
40  0.1 1040
Sol. M=
3V

121
= .
78

49. A solution containing 0.1 mole of a metal chloride MClx requires 500 mL of 0.8 M AgNO3 solution for complete
precipitation. The value of x is :
,d /kkrqDy ksjkbM MClx d s0.1 eksy ;qDr ,d foy ;u d siw.kZ: i lsvo{ksi.k d sfy , 0.8 M AgNO3 foy ;u d s
500 mL vko';d gaSA x d k eku fuEu gS% (MOL)
(A) 1 (B) 2 (C*) 4 (D) 3

[4]
Sol. MClx + AgNO3  AgCl + MNO3

POAC on Ag
500
× 0.8 = 1 × mole of AgCl
1000
 mole of AgCl = 0.4 ...........(A)
POAC on Cl
0.1 × x = 1 × mole of AgCl = 0.4..............(A)
 mole of AgCl = 0.1 x ....................(B)
put eq (B) in eq (A)
0.1 x = 0.4
x=4
gy % MClx + AgNO3  AgCl + MNO3

Ag ij POAC
500
1000
× 0.8 = 1 × AgCl d seksy
 AgCl d seks
y = 0.4 ...........(A)
Cl ij POAC
0.1 × x = 1 × AgCl d seks
y = 0.4..............(A)
 AgCl d seksy = 0.1 x ....................(B)
leh-(A) esa(B) d ksj[kusij
0.1 x = 0.4
x=4

50. 120 gm of 1 M aqueous NaOH solution (d = 1.2 g/ml) is mixed with x ml of 9.8% w/v H2SO4 solution. pH of
resulting solution is 13 then value of x will be :
1 M t yh; NaOH foy;u (d = 1.2 g/ml) d s120 gm d ks9.8% Hkkj@vk;ru H2SO4 foy;u d sx ml d slkFkfeyk;k
t krk gS] ifj.kkeh foy ;u d h pH,13 gSrksx d k eku Kkr d hft ,A
(A) 50.92 (B) 75.27 (C) 15.75 (D*) 42.85
Sol. 2NaOH + H2SO4  Na2SO4 + 2H2O
1M 1M
100ml x ml
100 – 2x 0
100 – 2x 90
= 0.1 x= = 42.85 ml
100  x 2.1

COMPREHENSION (1 COMP. X 3 Q.)

Paragraph for Question Nos. 51 to 53
iz'u 51 l s53 d sfy , v uqPN sn

OH +
(1) /H
HNO3 + conc.H2SO4 OH
Q R S T (U)
(2) Sn / HCl
+
(3) H3O

OH
(1) / H+
HNO3 + lkUnzH2SO4 OH
Q R S T (U)
(2) Sn / HCl
+
(3) H3O

[5]
51. The product U is : (CAD(O))
mRikn U gS%

(A) (B)

(C*) (D)

52. Which of the following will not be the products when S on reaction with Cl2 / NaOH or on reaction with
Cl2/NaOH followed by acidification. (CAD(O))
Cl2 / NaOH d slkFk ;kSfxd S d h vfHkfØ ;k d jkusij vFkok Cl2/NaOH d slkFk vfHkfØ ;k d jkusd si'pkr
vEy hd j.k d jusij fuEu esalsd kSulk mRikn izkIr ughagksxk %

(A) (B*) (C) CHCl3 (D)

53. T on reaction with NaNO2/ HCl followed by reaction with H3PO2 will give : (CAD(O))
;kSfxd T , NaNO2/ HCl d slkFk vfHkfØ ;k d jusd sckn H3PO2 lsvfHkd r̀ gksd j nsxk %

(A) (B) (C*) (D)

Sol.

(51to53)

(P) (Q) (R)

(S) (T)

(U)

[6]
INTEGER(DOUBLE DIGIT) (3)
54. A sparingly soluble salt MX is dissolved in water to prepare 1 lit. saturated solution. Now 10–6 mol NaX is
added into this. Conductivity of this solution is 29  10–6 S/m. If KSP of MX is a  10–b then find value of (a + b)?

,d vYi foy s;h y o.k MX d kst y esa?kksy d j 1 y hVj larÌr foy ;u cuk;kt krk gSA vc blesa10–6 eksy NaX
fey k;k t krk gSrksbl foy ;u d h pky d rk 29  10–6 S/m gSA ;fn MX d k KSP a  10–b gSrks(a + b) d k eku
Kkr d hft ,\ (ECH(P))
fn;kx;kgSGiven 0x –  4  10 –3 S m2 mol–
0Na   5  10 –3 S m2 mol–

0M  6  10 –3 S m2 mol–

Ans. 18
Sol. MX M+ + X–
–6
x x + 10
[Na+] = 10–6 M
KSol = K M + K X – + K Na
29  10–6 = 103[6  10–3x + (4  10–3 (x + 10–6) + (5  10–3  10–6)]
x = 2  10–6
KSP = 6  10–12
55. Consider the following equilibrium in a closed container. (CEQ(P))
PCl5(g) PCl3 (g) + Cl2(g)
PCl5 gas at a certain pressure is introduced in the container at 27°C. However , the total pressure at equilibrium
at 207°C was found to be double the initial value. The % dissociation of PCl5 at 207° C is :
,d cUn ik=k esafuEu lkE;koLFkk ij fopkj fd ft ,
PCl5(g) PCl3 (g) + Cl2(g)
27°C ij ik=k es
afuf'pr nkc ij PCl5 xSl y srsgSA 207°C ij lkE;koLFkk ij d qy nkc izkjfEHkd eku d k nksxquk
ik;k t krk gSA 207°C ij PCl5 d k % fo;kt u gSA
Ans. 25
Sol. PCl5 PCl3 + Cl2
t=0 P 0 0 (at 27°C)
480 P
t=0 0 0 (at 207°C)
300
480 P
t = eq. –P' P' P' (at 207°C)
300

480 P
 Total pressure at eq. at 207°C = –P' + 2P' = 2P (given)
300
480 P
207°C lkE;koLFkk ij d qy nkc = 300
–P' + 2P' = 2P ¼fn;k x;k gS½
8P
 + P' = 2P
5
2P
 P' =
5

P' 2 P/5
 % dissociation of PCl5 at 207°C =  100 = 8 P / 5  100 = 25%
 480 P 
 
 300 

P' 2 P/5
 207°C ij PCl5 d k % fo;ks
tu =  100 = 8 P / 5  100 = 25%
 480 P 
 
 300 
[7]
56. A solute’S’ undergoes a reversible trimerization when dissolved in a certain solvent. The boiling point elevation
of its 0.1 molal solution was found to be identical to the boiling point elevation in case of a 0.08 molal solution
of a solute which neither undergoes association nor dissociation. To what percent had the solute ‘S’ undergone
trimerization? (SCP(P))
t c ,d foy s; ’S’ d ks,d fuf'pr foy k;d esa?kksy k t krk gSrc ;g mRØ e.kh; f=ky d hd j.k n'kkZrk gSA bld s
0.1 eks
y y foy;u d kDoFkukad esamUu;u],d foys ; d s0.08 eksy y foy;u d sDoFkuka d esamUu;u d sleku ik;k
t krkgSA ft ld ku rksla;kst u gksrkgS
au ghfo;kst u gksrkgSrc foy s; ‘S’ d kf=ky d hd j.k¼trimerization½fd rus
izfr'kr gksrk gS\
Ans. 30
Sol. 3S S3
1 0
 2
1–  i=1–
3 3

 2 
Now 0.1 1   = 0.08  = 0.3. 30% trimerization.
 3 

 2 
vc 0.1 1   = 0.08  = 0.3. 30% f=ky d hd j.k
 3 

INTEGER(DOUBLE DIGIT) (4)

57. How many of the following species have been correctly matched with their property (Give your answer by
multiplying with two). (PBC (I))
(i) Cl2O : bond angle greater than 109º28'.
(ii) O3– : Paramganetic.
(iii) H2S2O8 : Contains a peroxy linkage.
(iv) XeF4 : d orbitals involved in hybridisation of central atom.
x2 y2
(v) N2H4 : NN bond length greater than expected.
(vi) P3O105– : 3 different types of P–O bond length are observed.
fuEu esalsfd ruh Lih'kht d k mud sxq.k/keZd slkFk fey ku lgh gSA ¼viuk mÙkj nkslsxq.kk d jd snsa½
(i) Cl2O : cU/k d ks
.k]109º28' lsvf/kd gksrk gSA
(ii) O3 : vuq
–
p qEcd h;
(iii) H2S2O8 : ,d ijkW Dlhfy Ud st j[krk gSA
(iv) XeF4 : d 2 2 d {kd d s fUnz; ijek.kqd slad j.kesaHkkx y srsgSA
x y

(v) N2H4 : NN cU/k y EckbZvuq

ekfur ekuksalsvf/kd gksrh gSA
(vi) P3O10 5–
: 3 fHkUu iz
d kj d hP–O d h y EckbZik;h t krh gSA
Ans. 10 (2 × 5)
Sol. Incorrect are :
(v) N2H4 : NN bond length same as expected since the two lone pairs on N–atoms are at anti position wrt
each other so LP–LP replusion is not effective.
Sol. vlR; gSa:
(v) N2H4 : NN cU/ky EckbZvuq
ekfur : i lsleku gks
rhgSpw fd ,d nw
a l jsd slUnHkZes
aN–ijek.kqij nks,d kd h;qXe
,.Vh fLFkfr ij mifLFkr gksrsgSA blfy , LP–LP izfrd "kZ.k izHkkoh ughagksrsgSA
58. If for complex [Cr(H2O)6]2+ CFSE is (–RO) calculated from general formula of CFSE than determine value of
100 R. (COR (I))
;fn CFSE d slkekU; lw=k lslad qy [Cr(H2O)6] d sfy , CFSE (–RO) ifjd fy r gksrks100 R d k eku Kkr
2+

d hft ,A
Ans. 60.

[8]
 1,1,1 1,0
Sol. 24
Cr2+ = [Ar] 3d4 (as H2O is WFE Ligand). Therefore 24
Cr2+ is t 2g , e g
or CFSE = (–3 × 0.4 + 1 × 0.6)0
= – 0.6 0 .

Sol. 24
Cr2+ = [Ar] 3d4 (t S
l sH2O ,d WFE fy xs.M gSA) bl izd kj 24Cr2+ is t12,1g,1 , e1g,0 gS
A
vFkokCFSE = (–3 × 0.4 + 1 × 0.6)0
= – 0.6 0 .

59. (i) Number of P–P bonds in P4S3 is (A).

(i) P4S3esaP–P ca/kksd h la[;k (A) gSA
(ii) Amongs the following number of planar species is (B).
XeF2, ClF3, H2O, [XeF5]–, I3–, BCl3, XeF4, SF4, PCl5, SF6, IF7.
Determine the value of (A + B).
(ii) fuEu esalslery h; Lih'kht d h la[;k (B) gSA
XeF2, ClF3, H2O, [XeF5]–, I3–, BCl3, XeF4, SF4, PCl5, SF6, IF7.
(A + B) d k eku Kkr d hft ,A
Ans. 10
Sol. (i) 3

Sol. (ii) 7.
Planar molecules : XeF2, ClF3, H2O, [XeF5]–, I3–, BCl3, XeF4.
SF4 – See - Saw shape
PCl5 – Trigonal bipyramidal
SF6 – Square bipyramidal
IF7 – Pentagonal bipyramidal
lery h; v.kq: XeF2, ClF3, H2O, [XeF5]–, I3–, BCl3, XeF4.
SF4 – lh&lkWvkd f̀r
PCl5 – f=kd ks.kh; f}fijsfefM;
SF6 – oxkZd kj f}fijsfefM;
IF7 – ia
p d ks.kh; f}fijsfefM;
60. How many of the following molecules or ions may act as a multidentate ligand ?
(COR (I))
fuEUk esalsfd rusv.kq;k vk;u cgqnUrqd fy xs.M d h Hkkafr d k;Zd j ld rsgSa\
CO32– NO3– edta [N(CH2–COO)3]3–
C2O42– SO42– CH3COCHCOCH3– gly
CH3C  N SCN¯ dmg dipy
Ans. 10
Sol. CO32– and NO3– : 1 or 2 donor oxygen atoms.
edta : 5 or 6 donor atoms (N and O).
C2O42– : 2 donor oxygen atoms.
SO42– : 1 or 2 donor oxygen atoms.
CH3COCHCOCH3– : 2 donor oxygen atoms.
CH3C  N : 1 donor nitrogen atom.
SCN¯ : Either one nitrogen atom or one sulphur atom.
dmg : 2 donor nitrogen atoms.
[N(CH2–COO)3]3– (or nta) : quadridentate ligand, 3 donor O atoms and 1 N atom.

[9]
 gly : 1 donor N atom and 1 donor O atom.
dipy : 2 donor N atoms
Sol. CO32– rFkkNO3– : 1 ;k 2 nkrk vkW
Dlht u ijek.kq
edta : 5 ;k 6 nkrk ijek.kq(N o O).
C2O42– : 2 nkrk vkW
Dlht u ijek.kq
SO 4
2–
: 1 ;k 2 nkrk vkW Dlht u ijek.kq
CH3COCHCOCH3 –
: 2 nkrk vkW Dlht u ijek.kq
CH3C  N : 1 nkrk ukbVª kst u ijek.kq
SCN¯ : ;k rksukbVª kst u ijek.kq;k ,d lYQ j ijek.kq
dmg : 2 nkrk ukbVª kst u ijek.kq
[N(CH2–COO)3] (or nta) : prq
3–
FkZfy xs.M] 3 nkrk O ijek.kqo 1 N ijek.kq
gly : 1 nkrk N ijek.kqo 1 nkrk O ijek.kq
dipy : 2 nkrk N ijek.kq

INTEGER(DOUBLE DIGIT) (3)

61. How many position isomers of dibromonaphthalene is possible if each ring of naphthalene has one
halogen? (STI(O))
MkbZczkseksus¶FkSy hu d sfd rusfLFkfr leko;ohlaHko gSa];fn us¶FkSy hu d sizR;sd oy ; ij ,d gSy kst u mifLFkr gks\
Ans. 06

Sol.

62. An aromatic tetracarboxylic acid (C10H6O8) can form two type of monoanhydrides on heating with P2O5.
The sum of locants of all carboxylic groups in this compound will be :
(AC(O))
,d ,sjkseSfVd VsVªkd kcksZfDlfy d vEy (C10H6O8) d ksP2O5 d slkFk xeZd jusij nksizd kj d seksuks,ugkMªkbM
izkIr gksrsgSA bl ;kSfxd esalHkh d kcksZfDlfy d lewgksad sLFkkukad ksad k ;ksx D;k gksxk \
Ans. 10
Sol. O O
COOH C COOH
1
2 COOH C O CO
+ O
COOH 3 COOH CO
4
COOH COOH COOH

63. A mixture of 1 amides (benzenoid) having molecular formula (C8H9NO) reacted with Br2/
NaOH. The number of 1 amines products formed will be :
(Nitrogen containing compound (O))
t c C8H9NO v.kql w=k oky s1° ,ekbZM ¼csUt suksbM½ d sfeJ.k d h vfHkfØ ;k Br2/NaOH d slkFk d jkrsgS] rks
fd rus1 ,ehu mRikn d s: i esaizkIr gksrsgS%
Ans. 04

[10]
 O
O O
O C–NH2
CH2–C–NH2 C–NH2 C–NH2
Sol. + + +
CH3
CH3 CH3

NH2
CH2–NH2 NH2 NH2
Br2+NaOH CH3
+ + +
CH3
CH3

[11]