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1. (20Points)NomenclatureandMolecularFormula
A.(10Points)Foreachsubstancebelow,writethecorrectformulaforthegivenname,or
writethecorrectnameforthegivenformula.

Name

ChemicalFormula

Vanadium(VI)phosphate

V(PO4)2

Manganese(IV)ion

Mn4+

HypoiodousAcid

HIO

Potassiumhydrogencarbonate

KHCO3

Ammonia

NH3

B.(10Points)Inacombustionexperiment,2.912gofacompoundthatconsistsofcarbon
andhydrogenwasburned.Thereactionproduced7.691gofcarbondioxideand3.123gof
water.Inaseparateexperiment,themolarmassofthecompoundwasdeterminedtobe
100.1g.whatisthemolecularformulaofthecompound?

Carbon
Hydrogen
7.691 g CO 2

1 mol CO 2
1 mol C

=
44.01 g CO 2 1 mol CO 2

0.1748 mol C
0.1748 mol C / 0.1748 mol C = 1.000
1

(CH2)x
EM=12.01g+2x1.008g=14.03g

3.123 g H 2O

1 mol H 2O
2 mol H

=
18.02 g H 2O 2 1 mol H 2O

0.3466 mol H
0.3466molH/0.1748 mol C = 1.983
2

MM 100.1 g
=
= 7.135 ~ 7
EM 14.03 g

Molecular Formula C7H14

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2.(20Points)SolutionsandStoichiometry
InGroupExercises#910,applicationsofsolutionsandstoichiometrywereexplored.
Completethefollowingquestionsfromtheseexercises.

A. (6Points)Calculatethepercentyieldofsolidpotassiumoxideif2.92gramsare
producedfromthereactionof3.21gramsofsolidpotassiumwithexcessoxygengas.
4K(s)+O2(g)2K2O(s)

Problem-Solving Path: mass K moles K moles K2O mass K2O ratio AY/TY
3.21 g K

%Y=

1 mol K
2 mol K 2O 94.20 g K 2O

= 3.87gK2O=TY
39.10 g K
4 mol K
1 mol K 2O

2.92 g K 2O AY
100 =
3.87 g K 2O TY

B.(10Points)Solidlithiumhydroxideisplacedinasolutionofselenousacid.Identifythe
typeofreaction.Writeabalancedchemicalequationforthereaction.Writethenet
ionicequation.Howmanygramsofsolidlithiumhydroxidearerequiredtoreact
completelywith10.8molesofselenousacid?

TypeofReaction:
Ionic/DoubleReplacement/Neutralization

ChemicalEquation: 2LiOH(s)+H2SeO3(aq)Li2SeO3(aq)+2H2O(l)

NetIonicEquation

H+(aq)+OH(aq)H2O(l)

Problem-Solving Path: mol H2SeO3 moles LiOH mass (g) LiOH

10.8 mol H 2SeO 3

75.4%

2 mol LiOH
23.95 g LiOH

=
1 mol H 2SeO 3
1 mol LiOH

517 g LiOH

C.(4Points)Howmanymolesofchlorideionsarein250.0mLofa0.420Maluminum
chloridesolution?
Problem-Solving Path: molarity AlCl3 mol AlCl3 mol Cl-
250.0 mL AlCl3

1 L AlCl3
0.420 mol AlCl3
3 mol Cl

= 0.315 mol Cl-

1000 mL AlCl3
1 L AlCl3
1 mol AlCl3

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3.(20Points)ChemicalReactions
Solidaluminummetalisaddedtoaqueoushydrochloricacidasameansofproducing
elementalhydrogengas.Anunbalancedchemicalequationforthisreactionappearsbelow.

2Al(s)+6HCl(aq)2AlCl3(aq)+3H2(g)

A.(2Points)Identifythetypeofreaction.
SingleReplacementReaction/RedOx

B.(4Points)Writethetotalionicandnetionicequationsforthisreaction.
2Al(s)+6H+(aq)+6Cl(aq)2Al3+(aq)+6Cl(aq)+3H2(g)

2Al(s)+6H+(aq)2Al3+(aq)+3H2(g)

C.(2Points)Writeabalancedchemicalequationthatillustratestheoxidationhalfreaction
forthereactionbetweenaluminumandhydrochloricacid.
OxidationHalfReaction
Al(s)Al3+(aq)+3e

D.(12Points)Whatisthemassingramsofprecipitateproducedinareactionbetween
35.00mLof0.3500Mhydrochloricacidwith0.7500gofaluminum?
Problem-Solving Path: molarity HCl moles HCl moles H2
35.00 mL HCl

1L
0.3500 mol HCl 3 mol H 2

1000 mL
1L
6 mol HCl

= 0.006125 moles H2 Limiting Reactant LR

Problem-Solving Path: mass Al moles Al moles H2

0.7500gAl

1 mol Al 3 mol H 2

= 0.04170 mol H2
26.98 g Al 2 mol Al

Problem-Solving Path: moles LR moles H2 mass H2

35.00 mL HCl

1L
0.3500 mol HCl 3 mol H 2 2.016 g H 2

=
1000 mL
1L
6 mol HCl 1 mol H 2

0.01235 g H2(g)

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4.(20Points)AcidBaseNeutralization
Astudentinthegeneralchemistrylaboratorycompletedatitrationexperimentinwhich
22.65mLof1.250Mpotassiumhydroxidesolutionwasusedtoneutralizea25.00mL
sampleofadilutesolutionofsulfuricacidsolution.

A.(2points)Writetheionizationequationforsulfuricacid.Identifythemajorandminor
speciesinsolution.
H2SO4(aq)2H+(aq)+SO42(aq) OR
H2SO4(aq)+H2O(l)2H3O+(aq)SO42(aq)
MajorSpecies:H+(aq)orH3O+(aq),SO42(aq),H2O(l)
MinorSpecies:H2SO4(aq)

B. (4Points)Writeabalancedchemicalequationforthereactionbetweenpotassium
hydroxidesolutionandthedilutesolutionofsulfuricacid.
H2SO4(aq)+2KOH(aq)K2SO4(aq)+2H2O)(l)

C. (8Points)Determinetheconcentrationinmolarityofthedilutesulfuricacidsolution
usedinthetitrationexperiment.
22.65 ml KOH

1L
1.250 mol KOH 1 mol H 2SO 4
1
1000 mL

=
1000 mL
1 L KOH
2 mol KOH 25.00 mL
1L

= 0.5663 M H2SO4(aq)

D. (6Points)Drawaparticulatelevelrepresentationofthespeciesthatexistinsolutionat
twopointsduringthetitrationofsulfuricacidwithpotassiumhydroxide;1)beforethe
equivalencepointisreached,and2)attheequivalencepoint.Provideamodelkeythat
identifiesthesymbolsusedtoillustratetheatoms/ions/moleculesinyour
representations.
"#$%&'(%)

!
>'0%$')?@.*A1/'(=')7%*(2

!"#$%&'()*%(+)!,
-./012')*%(+)-3456

7%2188*.9)*%(+):,
!"#$%;*#')*%(+)3!6

!
B02'$)?@.*A1/'(=')7%*(2

<12'$)9%/'=./'+)!53

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5. (20Points)Thermodynamics
Copperisatransitionthatmeltsat10840Candboilsat2560.0C.Thespecificheatofsolid
copperis0.386J/goC,theheatoffusionis2054kJ/kgandthespecificheatofliquid
potassiumis0.112J/goC.Acubeofsolidcoppermetalwithamassof85.00ganda
temperature20.00Cisplacedinanovensetat100.00C.

A. (2Points)Inthediagrambelow,labelthesystemandsurroundings,ifaCHEM120A
studentwishestodeterminethetotalheatflowabsorbedbythecoppercube.

Surroundings

Temperature(oC)

Cu

System

Oven100.00C
B. (8Points)Sketchaheatingcurvefortheexperimentwithcoppermetal.Besuretolabel
theaxes,labeltheunitsofmeasure,andlabeleachpartoftheheatingcurvewithan
appropriatephysicalstate.

HeatingCurveCopperCube

110.0

100.0

90.0

80.0
70.0

60.0

S
50.0

40.0
30.0
20.0
10.0
0.0

0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0 55.0
Time(min)

C. (10Points)CalculatethetotalamountofheatenergyinkJthatisabsorbedbythecubeof
coppermetalafteritachievesthermalequilibriumintheoven.
qT=qsmsTs=85.00g(0.386J/g0C)(100.000C20.000C)(1kJ/1000J)=2.63kJ