Professional Documents
Culture Documents
CITATIONS
READS
1,561
6 authors, including:
Abdulrasoul Alomran
Anwar Aly
24 PUBLICATIONS 83 CITATIONS
SEE PROFILE
SEE PROFILE
Mohammad I Al-Wabel
SEE PROFILE
SEE PROFILE
Introduction
Water has always been essential to survival of all organisms. Water makes up 62 to 70 % of an adult's total body
weight; without it in a regular range, the body's survival
time is limited to a matter of days (Ogbonmwan 2011).
Drinking water is water pure enough to be consumed
with low immediate or long-term risks. In many parts of
the world, humans have inadequate access to drinking
water and use sources contaminated with disease vectors, pathogens, or unacceptable levels of toxins or
suspended solids (William and Frank 2000). Using such
water leads to widespread acute and chronic illnesses
and is a major cause of death and misery in many
countries. For these reasons, the reduction of waterborne
diseases is considered as a main public health goal in
developing countries. Drinking water with different
qualities is now bottled and sold for public consumption
throughout the world. The periodical analysis of the
drinking bottled water is essential to ensure its safety
(U.S. Environmental Protection Agency (USEPA)
2007). In this respect, Guler (2007) found that a significant number of bottled water brands in Turkey contain
Na, Cl, SO4, F, polycyclic aromatic hydrocarbons, and
Wasia-Biyadh aquifer
The Wasia-Biyadh is a vast aquifer of lower
and middle Cretaceous sandstones located in the
northern interior Homocline and the Widyan Basin margin. The aquifer supplies water to Riyadh
with total dissolved solids (TDS) of 555 mgL1.
Saq Sandstone aquifer
The Saq sandstone is early Ordovician age and
forms the major aquifer in northern Saudi Arabia,
especially in the Tabuk Basin. Water from this
aquifer is generally of good quality.
19 and 41
Najran
8, 9, 30, and 40
7, 10, and 51
Mecca
Jeddah
45 and 49
Qassem
of As, B, Be, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Se, Sr,
Ti, V, and Zn in the collected bottled water was determined using ICP-Perkin Elmer Model 4300DV. The
hydrochemical characteristics of the mineral water were
evaluated by Piper diagram (Table 1 and Fig. 1).
Geochemical modeling
Interactions between water and surrounding rocks and
soil are considered to be the main processes controlling
the observed chemical characteristics. The deviation of
water from equilibrium with respect to dissolved minerals is quantitatively described by saturation index (SI).
The SI of a mineral is obtained from the following
formula:
SI log IAP=kt
Unit
Determined
Labeled in bottles
Mean
Min
pH
TDS
mg/L
126.098
Ca
mg/L
13.401
Mg
mg/L
3.912
Na
mg/L
7.480
Max
6.700
Mean
Min
Max
8.440
7.20
6.70
7.50
235.000
122.63
43.00
235.00
0.019
41.880
14.31
0.30
40.00
0.038
22.000
4.33
0.50
22.00
20.541
0.300
69.750
18.23
0.30
35.00
mg/L
1.370
0.018
13.400
1.62
0.10
13.40
CL
mg/L
32.483
0.090
88.000
26.25
2.60
88.00
120.00
43.00
HCO3
mg/L
34.720
1.300
135.217
32.88
1.30
SO4
mg/L
23.266
N.D.
90.466
21.91
N.D.
51.00
NNO3
mg/L
5.731
N.D.
35.718
3.40
N.D.
20.00
mg/L
1.040
0.050
BrO3
g/L
4.733
N.D.
5.000
0.89
0.05
5.00
111.600
1.76
N.D.
9.99
Direct/indirect:
O3
OH
disproportionation
O3
Br
!HOBr =OBr ! OBr ! BrO
!BrO
2
3
Indirect/direct:
OH
O3
disproportionation
O3
Br
! Br
! OBr ! BrO
! BrO
2
3
Direct:
O3
O3
O3
! HOBr=OBr
! BrO
! BrO
Br
2
3
Fluoride and nitrate were also found in high concentration in some of studied water samples. About 30
and 20 % of the samples fall over the acceptable limits
Fig. 2 Comparison of the determined parameters in laboratories and labeled in bottles of drinking water (n=52): a mean values, b
maximum values
Unit
Mean
Min
Max
SD
Permissible limits
KSA
WHO
USEPA
Nitrite
mg/L
0.005
N.D.
0.033
Bromide
mg/L
0.082
0.014
0.680
0.091
Al
mg/L
0.007
N.D.
0.145
0.2
0.2
As
mg/L
0.003
N.D.
0.033
0.01
0.01
0.01
mg/L
0.327
0.019
1.656
0.349
0.5
0.5
Ba
mg/L
0.004
N.D.
0.061
0.7
0.7
Be
mg/L
N.D.
N.D.
N.D
Cd
mg/L
N.D.
N.D.
N.D.
0.003
0.003
0.003
Co
mg/L
N.D.
N.D.
N.D.
Cr
mg/L
0.001
N.D.
0.009
0.05
0.05
0.1
Cu
mg/L
N.D.
N.D.
N.D.
1.3
Fe
mg/L
N.D.
N.D.
N.D.
0.3
0.3
0.3
Mn
mg/L
N.D.
N.D.
N.D.
0.1
0.2
0.05
Mo
mg/L
0.002
N.D.
0.009
0.07
Ni
mg/L
N.D.
N.D.
N.D.
0.02
Pb
mg/L
0.008
N.D.
0.024
0.01
0.01
Se
mg/L
0.008
N.D.
0.086
0.01
0.01
Sr
mg/L
0.105
N.D.
0.382
Ti
mg/L
N.D.
N.D.
N.D.
mg/L
0.000
N.D.
0.010
Zn
mg/L
0.001
N.D.
0.029
pH
7.480
6.700
8.440
0.385
6.58.5
6.58.5
6.58.5
TDS
mg/L
126.098
43.000
235.000
30.208
500
600
755
Ca
mg/L
13.401
0.019
41.880
8.358
Mg
mg/L
3.912
0.038
22.000
3.743
Na
mg/L
20.541
0.300
69.750
9.925
100
200
mg/L
1.370
0.018
13.400
1.744
Cl
mg/L
32.483
0.090
88.000
17.596
150
250
250
HCO3
mg/L
34.720
1.300
135.217
21.410
SO4
mg/L
23.266
N.D.
90.466
16.319
150
400
250
NNO3
mg/L
5.731
N.D.
35.718
6.511
10
10
10
mg/L
1.040
0.050
5.000
0.550
1.5
1.5
BrO3
g/L
4.733
N.D.
111.600
2.451
10
10
10
and compare bottled water types collected from groundwater, based on the ionic composition of different water
samples (Semerjian 2011; Baba et al., 2008). This diagram reveals that there are different types of mineral
water in Saudi Arabia. Four main mineral water types
have been identified on the basis of the major ion concentrations as in Aly and Benaabidate (2010) and Baba
et al. (2008). The first is rich in sodium chloridesulfate
water types which correspond to 66.7 % of water samples. The second is rich in calcium sulfatechloride
water type corresponding to 15.7 % of water samples.
The third is rich in sodium bicarbonate water type
corresponding to 15.7 % of water samples. The fourth
is rich calciummagnesium bicarbonate water type
corresponding to 1.9 % of water samples. In the study
area, the type of water that predominates is NaCl, which
is mainly due to the geology of the area which comprises
halite (Fig. 3).
Geochemical modeling
The SI is the form most commonly used for groundwater. Water is in equilibrium with a mineral when the
SI of this mineral is equal to 0. It is undersaturated if
this index is below 0 and it is oversaturated when the
SI is above 0. However, these factors result in an
saturated for calcite, and samples 5 and 33 were saturated for dolomite (Fig. 4).
Conclusion
Many people prefer to use bottle water than tap water
for drinking. However, not all bottled waters are of
high qualities. Analysis of 52 bottled mineral waters in
Saudi Arabia shows considerable difference between
the laboratory-determined values of some parameter
and the respective value labeled on the bottles. Eighteen percent of studied water samples indicate that the
concentration of bromate exceeded the allowable limits according to the KSA, WHO, and USEPA Standards (bromate 10 gL1). On the other hand, most
collected waters were within the permissible limits for
most parameters determined. Thus, this study recommends that in bottled drinking water treated by ozone,
bromate should be tested to identify the suitability of
bottled water for drinking. The hydrochemical analysis shows that the studied water samples corresponded
mainly to sodium chloridesulfate water types which
are mainly due to the geology of the study area comprising halite. The geochemical modeling shows that
all water samples were undersaturated with respect to
anhydrite, gypsum, and halite; however, some samples
were saturated for calcite, dolomite, and aragonite, and
only two samples were oversaturated for dolomite.
Acknowledgments The authors wish to thank King Saud
University, Deanship of Scientific Research, College of Food
and Agriculture Science, Research Center for supporting the
research work
References
Alawi, J., & Abdulrazzak, M. (1993). Water in the Arabian
Peninsula: problems and prospective. In P. Rogers & P.
Lydon (Eds.), Water in the Arab world: perspectives and
prognoses (pp. 171202). Cambridge: Division of Applied
Sciences, Harvard University.
Alexakis, D. (2011). Assessment of water quality in the
Messolonghi-Etoliko and Neochorio region (West
Greece) using hydrochemical and statistical analysis
methods. Environmental Monitoring Assessment, 182, 397
413.
Alfadul, S. M., & Khan, M. A. (2011). Water quality of bottled
water in the kingdom of Saudi Arabia: a comparative study
with Riyadh municipal and Zamzam water. Journal of
Environmental Science and Health. Part A, Toxic/Hazardous Substances & Environmental Engineering, 46(13),
151928.
Al-Omran, A. M., Falatah, A. M., & Al-Matrood, S. S. (2005).
Evaluation of irrigation well water quality in Riyadh region
Saudi Arabia. J. of King Abdulaziz Univ, 16(2), 2340.
Aly, A. A., & Benaabidate, L. (2010). Salinity of water resources in the Siwa Oasis: monitoring and diagnosis. In P.
Brikle & I. S. Torres-Alvaro (Eds.), Waterrock interaction. London: Taylor & Francis. ISBN 978-0-415-604260.
Aly, A. A., Abbas, A. A. & Benaabidate, L. (2011). Hydrochemical and quality of groundwater in Egypt, case study
of Egypt Southern oases. NATO Science for Peace and
Security Series C: Environmental Security. Springer Science + Business Media, doi:10.1007/978-94-007-1623-1_
17.
Baba, A., Erees, F. S., Hicsonmez, U., Cam, S., & Ozdilek, H.
G. (2008). An assessment of the quality of various bottled
mineral water marketed in Turkey. Environmental Monitoring and Assessment, 139, 277285.
Bassam, T., & Abdulrazaq, Z. (2011). Bromate control in
phenol-contaminated water treated by UV and ozone processes. Desalination, 267, 1619.
Batarseh, M. I. (2006). The quality of potable water types in
Jordan. Environmental Monitoring and Assessment, 117,
235244.
Daoud, D. (1995). Caractrisation gochimique et isotopique
des eaux souterraines et estimation du taux dvaporation
dans le bassin de Chott Chergui (zone semi-aride) Algrie.
Thse univ. Paris sud. Centre dOrsay
Edgell, H. S. (1990). Geological framework of Saudi Arabia
groundwater resources. J. of King Abdulaziz University,
Earth Sciences, 3, 267286.
European Community Council (EC). (1998). Council Directive
98/83/EC of 3 November 1998 on the quality of water
intended for human consumption. Official Journal of the
European Communities L, 330, 3254.
Guler, C. (2007). Evaluation of maximum contaminant levels in
Turkish bottled drinking waters utilizing parameters
reported on manufacturer's labeling and governmentissued production licenses. Journal of Food Composition
and Analysis, 20, 262272.
Guler, C., & Alpaslan, M. (2009). Mineral content of 70 bottled
water brands sold on the Turkish market: assessment of
WHO. (2006). Guidelines for drinking-water quality, first addendum to third edition, Recommendations vol. 1. Geneva:
World Health Organization.
WHO. (2011). Guidelines for drinking-water quality (4th ed.).
Geneva: World Health Organization.
William, J.C. & Frank, R.R. (2000). World Water Vision: making water everybody's business. World Water Council,
Tanet Press, UK. Pp. xx.