Professional Documents
Culture Documents
Kaj Henricson
Professor Pulping Technology
Lappeenranta University of Technology
August 2005
Educational course material and only for internal and personal use during
the course: An introduction to chemical pulping technology.
BAT
The amount of water that normally has to be evaporated from the weak black liquor after
cooking and brown stock washing in order to produce thick black liquor for combustion in the
recovery boiler is in the range of 7-9 m3/ton of pulp.
Black liquor properties
Black liquor is composed of the organic material dissolved from the wood in the digester and at
the oxygen delignification plant and of the chemicals used in cooking and oxygen bleaching. In
the case of re-circulation of bleach plant effluents from final bleaching, also the dissolved
material from bleaching and used chemicals in bleaching will be found in black liquor. In
addition, non-process elements circulating with the active cooking chemical have accumulated
in the chemical recovery cycle.
Black liquor contains extractives originating from the wood raw material. Extractives are
removed from black liquor in the form of soap. The volatile components are removed from the
condensates by stripping. Soap separation is important in order to avoid scaling of heat transfer
surfaces during evaporation and to avoid foaming. Black liquor has a strong tendency to foam at
low dry solids concentrations and the soap content contributes to the foaming tendency. The dry
solids content of black liquor from the cooking and washing plant can be increased by adding to
it some intermediate liquor from the evaporation plant before entering the evaporation plant in
order to avoid foaming.
The scaling of heat transfer surfaces occurs in particular at high dry solids concentrations. The
scaling tendency of black liquor depends for instance on the content of calcium soap in the black
liquor. The contents of inert components like sodium sulfate and sodium carbonate also affect
the scaling behavior of black liquors.
Table 1 shows the composition of a hardwood kraft black liquor. Table 2 shows the elementary
composition of a softwood kraft black liquor. The composition of black liquor always depends
on the used raw material and process conditions at the mill.
Table 1.
Composition of black liquor dry solids from the kraft pulping of birch
Organics, % by weight
Degraded lignin, including Na and S, %
Isosaccharinic acids, including Na, %
Aliphatic acids, including Na, %
Resins and fatty acids, including Na, %
Polysaccharides, %
Inorganics, % by weight
NaOH, %
NaHS, %
Na2CO3 and K2CO3, %
Na2SO4, %
Na2S2O3, Na2SO3 and Na2Sx, %
NaCl, %
Non-process elements (Si, Ca, Fe, Mn, Mg, etc), %
78
37.5
22.6
14.4
0.5
3.0
22
2.4
3.6
9.2
4.8
0.5
0.5
0.2
Table 2.
Carbon, %
Hydrogen, %
Nitrogen, %
Oxygen, %
Sodium, %
Potassium, %
Sulfur, %
Chlorine, %
Inert, %
Total, %
Softwood (pine)
Typical
Range
35.0
32-37
3.6
3.2-3.7
0.1
0.06-0.12
33.9
33-36
19.0
18-22
2.2
1.5-2.5
5.5
4-7
0.5
0.1-0.8
0.2
0.1-0.3
100.0
-
Hardwood (birch)
Typical
Range
32.5
31-35
3.3
3.2-3.5
0.2
0.14-0.2
35.5
33-37
19.8
18-22
2.0
1.5-2.5
6.0
4-7
0.5
0.1-0.8
0.2
0.1-0.3
100.0
Fapet 6B: p.B15
Heating value
The heating value of black liquor expresses the amount of heat that is released when combusting
a specified amount of black liquor dry solids. The types of organic compounds present in black
liquor and inorganic material in black liquor influence the heating value of black liquor. For
instance, the type of lignin and the ratio between lignin and carbohydrates affect the heating
value of black liquor as shown in Table 3. The reactions of inorganic material during
combustion influence the heating value, and for instance the reduction of sulfate to sulfide in the
recovery boiler consumes energy. All black liquors have to be tested separately to know the
heating value and combustion properties in a recovery boiler.
Table 3.
Component
Softwood lignin
Hardwood lignin
Carbohydrates
Resins, fatty acids
Sodium sulfide
Sodium thiosulfate
MJ/kg
26.9
25.11
13.555
37.71
12.9
5.79
Btu/lb m
11.57
10.8
5.83
16.22
5.55
2.49
Fapet 6B: p.B18
Picture 2. Black liquor boiling point rise vs. dry solids concentration
The viscosity of black liquor depends on the temperature and dry solids content. The viscosity
increases at higher dry solids contents, and a temperature increase decreases the viscosity as
shown in Picture 3 for one black liquor after evaporation to a high dry solids content. The
viscosity behavior varies from one black liquor to another. The evaporation of black liquors to
high dry solids concentrations above 75% to 80% usually requires that these black liquors are
heat treated at higher temperatures to reduce the viscosity of these liquors.
Modified by KH;
Fapet 6B: p.B23
Picture 3. Effects of temperature and dry solids on the viscosity of one high dry solids black liquor
Terminology used in the evaporation of black liquors
The evaporation stage or effect is one evaporator, or possibly several parallel evaporators
operating at the same steam pressure level. The effects are numbered in the direction of the
steam flow with the first effect operating at the highest steam pressure. Multiple-stage
evaporation means evaporation in a plant consisting of a number of evaporator effects connected
4
in series. An evaporation plant normally consists of 5-7 stages in series. Picture 4 shows a
typical configuration. The condensate streams are segregated into fractions A, B and C
according to their content of methanol and COD.
CONDENSERS
FRESH
STEAM
CONCENTRATED
BLACK LIQUOR
BLACK LIQUOR
FROM COOK
KAM: p.28
The evaporator body or the evaporator itself is a heat exchanger unit used in the evaporation
stages. One stage or effect might have several bodies in parallel. Picture 5 shows some
commonly used evaporator designs in the evaporation of black liquors.
B
Modified by KH;
Fapet 6B: p.B46, 47, 51
Picture 5. Evaporators; A: rising film, B: falling film, C: forced circulation (or crystallizer)
The rising film evaporators [also called long-tube-vertical (LTV) or Kestner evaporator] were
widely used for the evaporation of black liquor in the pulp industry until the mid-1980s. In a
rising film evaporator, the forming steam causes the liquor to rise in the evaporation tubes. In
later installations, the falling film evaporator and forced circulation evaporator are more
common. In the falling film evaporator, the liquor is fed to the bottom of the evaporator from
where it is pumped to the top of the heating element by a circulating pump and flows
downwards on the heating surface by gravity. In the forced circulation evaporator, the black
liquor is pumped through the tube heat exchanger to a separate chamber where the vapor is
5
released. The power needed in black liquor evaporation and the dimensioning of the heat
transfer surfaces is dependent on the viscosity of the black liquor.
The term concentrator refers to the first effect where the liquor is evaporated to its final
concentration. Earlier, the final concentrators were clearly separated from the multiple effect
evaporation train and had a different design. In a modern evaporation plant, this difference does
not exist but the terminology is still in use. The concentrators have to be cleaned regularly to
remove scaling on the heat transfer surfaces, and evaporation plants usually have at least two
concentrators in parallel so that one concentrator can be cleaned without influencing the
operation of the whole evaporation plant.
Live steam, primary steam, or fresh steam is the clean steam from the boilers at the mill. Live
steam is mainly only used in the first effect in the evaporation plant. The steam must be at
saturation temperature or only slightly superheated. Primary condensate is the clean condensate
from the live steam. Secondary steam or vapor is the steam evaporated from the black liquor.
Vapor from the first effect is used as a heating medium in the second effect. Vapor from the
second effect is then used in the third effect etc. The surface condenser is a water-cooled heat
exchanger that condenses the vapor from the last evaporation effect.
The vapor always contains some organic materials evaporated from the liquor or even liquor
droplets entrained in the steam flow. Secondary condensate is condensate derived from the
vapor. It contains various levels of organic contaminants. It is therefore not as clean as primary
condensate. Foul condensate is the most contaminated secondary condensate and has to be
purified by stripping. The amount of organic material carried over into the condensates in the
form of droplets is reduced by installing droplet separators in the steam phase of the evaporators.
The condensates can on the side of the condensing steam of the heat transfer surface be
segregated into a foul and clean condensate fraction.
Vapor out
B
A
Vent
Flow 1%
MeO H 10%
Foul
condensate
Flow 10%
MeO H 80%
Vapor in
Liquor out
Clean
condensate
Flow 89%
MeO H 10%
MPS, Andritz
Liquor in
Picture 6. Falling film evaporator A with condensate segregation and droplet separator B at the top of
the evaporator
Vapor condensate, which has some degree of contamination mainly consisting of methanol, is
one of four fractions determined by the degree of contamination indicated in Table 4. Often,
fractions 2 and 3 are combined. Vapor condensate fraction 1 and some fraction 2 can be used in
bleaching and brown stock washing. Fraction 3 is used in the causticizing plant. Fraction 4 is
treated in the stripper and is comparable to fraction 2 after stripping.
6
Table 4.
Vapor condensate fractions from a modern 7-stage multiple falling film evaporation
Vapor
Vapor condensate
condensate
drawn
fraction
Fraction 1
From effects 2, 3 and
4
Fraction 2
From effects 5 and 6
Fraction 3
From effect 7 and
surface condensate
Fraction 4
Foul condensate
from evaporator
Total
Stripped
From evaporation
condensate and cooking foul
condensate stripping
Flow,
m3/adt
3.4
MeOH
content,
mg/l
30
MeOH
amount,
g/adt
100
Remarks
2.5
2.0
300
600
700
1,200
Slightly odorous
1.0
6,000
6,000
Malodorous
8.9
1.6
300
8,000
500
Stripper MeOH
purification
efficiency=95%
The stripping column purifies the foul or contaminated condensate from the evaporation and
cooking plants. Stripping is a mass transfer process where volatile gas components such as
methanol and reduced organic sulfur compounds transfer from the liquid phase into the gas
phase. Picture 7 shows a typical stripping column.
Evaporation process
The evaporation of black liquor has three principal unit operations: Separation of water from
black liquor to generate concentrated black liquor and condensate, processing of condensate to
segregate clean and fouled condensate fractions, and separation of soap from black liquor. The
by far most common principle in the evaporation of kraft black liquor is the multistage
evaporation concept illustrated in Picture 8.
The sum of the boiling point rise of black liquor in an evaporator plus the temperature gradient
over the heat transfer surface in the evaporator is the temperature difference between the
incoming steam and the vapor leaving the evaporator. The total temperature difference over all
the effects in an evaporation plant is the sum of the temperature differences of the individual
evaporators in the plant. There is a total temperature difference available for the evaporation
plant and this difference influences the number of evaporator stages that can be used in series in
a multistage evaporation plant.
Modified by KH;
Fapet 6B: p.B41
Picture 9 shows a perspective of a multistage falling film evaporation plant. The steam or heat
balance of the evaporation plant is dependent on the number of effects as shown in Table 5. The
number of effects chosen is a balance between the investment costs of additional effects, the
investment cost and amount of heat transfer surfaces in the individual effects and the savings in
steam due to additional effects.
Table 5.
Number of
stages
4
5
6
7
Steam economy,
ton H2O/ton steam
3.7-3.6
4.3-4.1
5.1-4.9
6.2-5.9
The mixed liquor sequence in the five-stage evaporation plant shown in Picture 10 is a favorable
sequence commonly used in the evaporation of black liquors. The mixed liquor flow pattern
gives the following advantages:
Soap separation from the intermediate liquor is optimum due to the concentration of 27%30% dry solids and the low temperature of approximately 60C.
Liquor feed to effects 3 and 4 in parallel allows balancing the feed according to the feed
liquor temperature and operating temperature in the effects.
Release of non-condensable gases that enter with the feed liquor is evened between the
effects. The gases vent from effects 4 and 5.
liquor tank arrangement is commonly used where weak liquor enters tank I and flows by gravity
to tank II. Soap skimming is carried out batch-wise as indicated in Picture 12.
10
Recovery boiler
The recovery boiler is a chemical reactor for the recovery of the cooking chemicals used and for
the generation of heat from dissolved inorganic and organic material in the black liquor. The
recovery of cooking chemicals in a recovery boiler includes several steps:
Picture 14 is a schematic diagram of a two-drum recovery boiler and Picture 15 shows some of
the chemical reactions taking place inside the recovery boiler. The components of the recovery
boilers in Picture 14 are: furnace, where the combustion of black liquor takes place, superheaters
for heating the steam with hot combustion gases, boiler generating bank where water boils, and
economizers that recover residual heat in the flue gases and cool the flue gases. In the steam
drum, water and steam are segregated. The air enters through primary and secondary air ports and
tertiary air ports. The black liquor enters through liquor guns in the lower part of the furnace. The
smelt exits through smelt spouts to the dissolving tank. The heat transfer surfaces are cleaned by
soot blowing steam. The flue gas is cleaned in an electrostatic precipitator.
11
KRB: p.5
12
BAT
13
pyrolysis gases
Liquor Guns
drying
small
droplets
devolatilization
3rd Secondary Air
char
combustion
in flight
char into
char bed
Primary Air
smelt
CHAR BED
KRB, MPS
Stage
Drying
Devolatilization
Char burning
Smelt
Characterized by
Water evaporation
Constant diameter after initial swelling
Appearance of flame, ignition
Swelling of the droplet
Release of volatiles
Disappearance of flame
Decreasing diameter
Reduction reactions
Constant or increasing diameter
Reoxidation
During char combustion, reduction reactions occur. Carbon has a major role in the reduction
reactions. Na2SO4 reacts with carbon to form Na2S. When the carbon in the char bed burns, it
causes the reduction of sodium.
Na2S+2O2 -> Na2SO4
Na2SO4+2C -> Na2S+2CO2
Na2SO4+4C -> Na2S+2CO
Degree of reduction (%) =
Na 2 S
100
(Na 2 S + Na 2 SO4 )
The degree of reduction of sulfur in the white liquor is determined by the operation of the
recovery boiler. The Na2SO4 is an inert circulating compound in the liquor system, and this
reduces process efficiency. A normal degree of reduction in recovery boilers is slightly above
90%.
Picture 18 shows the bottom of a recovery boiler with black liquor entering the boiler through the
liquor guns shown in Picture 19. Air is added above the bottom and the char bed in such a way
that reducing conditions are maintained near the char bed. The smelt flows from the recovery
boiler into the smelt dissolver.
KRB: p.8
The recovery boiler has a risk of smelt and water explosion due to the presence of the porous hot
char bed containing molten sodium salts. The water and smelt can come into direct contact due to a
recovery boiler tube failure causing a smelt and water explosion in a recovery boiler. An emergency
rapid drain system minimizes potential damage. Water remains at the lowest part of the furnace to
provide cooling for the floor tubes. If all water drains from the floor tubes, the heat from the hot char
bed will damage the boiler tubes.
15
KRB: p.12
Black liquor handling and feeding equipment for feeding the thick black liquor into the boiler.
The black liquor is fed at a dry solids concentration above 65%, in some boilers built after 1990
the dry solids content is even over 80%. At high dry solids concentrations, the black liquor
becomes highly viscous and is difficult to handle unless kept at an elevated temperature.
Air fans, air ducts and air pre-heater. The combustion air is pre-heated in the recovery boiler
house and with air pre-heaters before being fed into the recovery boiler furnace.
Flue gas cleaning. The heat is recovered from the flue gas in the economizer and the flue gases
are cleaned with an electric precipitator to recover dust-containing sodium and sulfur.
Smelt outlet ducts.
Combustion chamber or furnace where the combustion of black liquor occurs.
Tubing for steam and water that forms the heat exchangers that cool the hot combustion gases.
Feed water system.
Control systems.
The recovery boiler produces superheated steam through the combustion of black liquor with air,
and the steam is taken to a turbine to produce power as shown in Picture 21. A higher
temperature and pressure of the superheated steam going to the turbine generates more power
from the heat generated in the boiler.
From the turbine, the steam for the pulp production process is taken out at two pressure levels:
extraction or high pressure steam with a pressure of about 12 bars that is used for instance to heat
the digester and back pressure or low pressure steam that is used for instance at the evaporation
plant and the pulp dryer. Primary condensate from the condensing of fresh live steam can be
returned to the feed water tank feeding the boiler with clean water as shown in Picture 22. Feed
water is usually preheated with steam. Exhaust steam from the turbine is taken to a surface
condenser.
16
The black liquor is combusted in the furnace of the recovery boiler. About 70%-75% of the heat
value of the black liquor will convert into superheated steam when the dry solids content of the
black liquor is 72%-85%. The smelt consumes heat due to the heat of the smelt and the chemical
reactions to form the reduced sulfur in the smelt. About 15% of the heat will go to the smelt.
The rest of the heat is lost with the flue gases. Picture 23 shows how the combustion heat is
divided between recovered heat, heat to smelt and heat losses in the flue gases as the flue gas
temperature and the dry solids content of the black liquor vary.
Picture 23. Black liquor dry solids heat to smelt, as loss in flue gases, and recovered into steam
Picture 24 shows the principle of the water system in a recovery boiler and Picture 25 a
perspective of the recovery boiler construction. Feed water is pumped into the boiler and enters
the first heat transfer surface or economizer (11). The water flows from the economizer to the
steam drum (6). In the steam drum, steam separates from water. Separation occurs by gravity,
17
screens and cyclone separators in order to minimize the amount of water droplets in the steam.
Downcomers (7) feed saturated water to the evaporative surfaces that are the walls of the
combustion chamber in the boiler and tubes in the boiler bank. Saturated steam (12) exits from
the drum and flows through the superheaters (13) and is heated to superheated steam. The role
of superheaters is to heat the steam well above saturation before feeding the steam to the turbine.
10
13
12
6
11
Modified by KH;
Fapet 6B: p.B205
18
KRB: p.13
The air is typically delivered at several horizontal elevations to ensure complete combustion and to
minimize emissions. In boilers built after the year 2000, air is often introduced over almost the
whole height of the furnace section of the recovery boiler. Picture 27 shows a boiler air system. It
has an inlet duct with silencer (1), venturi for airflow measurement (2), air blower (3), air heater (4),
distribution ducts (5), and air ducts (6 and 7). Pressure and temperature measuring devices are also
necessary at proper locations. Air intake is typically high inside the boiler house to ensure an even
vertical temperature profile and to recover heat losses through boiler walls and openings.
19
KRB: p.296
KRB: p.15
Potassium and chloride in the black liquor influence the fouling of heat transfer surfaces and the
corrosion of recovery boilers. Even small amounts of potassium and chloride influence the sticky
temperature of dust. The sticky temperature is the temperature above which dust contains sufficient
amounts of sodium in molten state to stick to the heat transfer surfaces and form deposits as shown
in Picture 31. The deposits of chemicals on the heat transfer surfaces become an effective barrier to
heat transfer from the flue gas to the tube wall. From the wall, the heat is transferred to the steam or
water inside the tube.
20
T0
T70
100
Tgas
Q
Flue gas
Tsteam
KRB, MPS
Deposit
Picture 31. Deposit on superheater
Tflow
Percent melt [wt-%]
Steam
(water)
80
Tube wall
60
40
20
Tsticky
0
500
600
700
800
Temperature [C]
900
1000
KRB, MPS
The chloride and potassium levels influence the melting behavior of dust in recovery boilers and
decrease the melting point of dust as shown in Picture 32. The graphs in the picture show the
melting behavior of some typical recovery boiler dusts with varying potassium and chlorine
content. Chloride levels at Scandinavian and North American mills are typically 0.2%-0.8% of
mass. Potassium levels at Scandinavian and North American mills can vary widely: 1%-4% of
mass. Chloride and potassium enter the chemical recovery cycle mainly with the wood and
enrich into the recovery cycle. The level of chloride and potassium must be kept sufficiently low.
The levels are controlled by purging dust from the recovery boiler as dust tends to enrich more in
chlorine and potassium compared to the rest of the recovery cycle.
Increasing chloride and potassium contents reduces the melting point of sodium-containing dust.
Only a few percentages on molten metals make the metals sticky. Tsticky is the temperature when
enough sodium is in molten state and makes a dust particle stick to surfaces of the recovery boiler.
Tsticky is usually in recovery boiler defined to the temperature when 15% of the metals are in molten
state. Tflow is the temperature when enough sodium is in molten state to make the metal a flowing
smelt. Metals start to flow when over 70% is in molten form but usually in connection with recovery
boilers Tflow is defined as the temperature when 85% of the metals are in molten state.
Picture 33 shows the material balance of a recovery boiler and how the generated steam is used
inside the boiler and as steam being fed to the turbine at the mill. Dust from the heating surfaces is
mixed with the black liquor and fed back into the boiler. Some of the dust may be purged from the
recovery cycle to control the content of non-process elements, in particular chloride and potassium.
21
KRB: p.19
22
Clarification
Sedimentation
Sludge blanket clarification
Filtration
Cake filtration with or without precoat
Cross flow filtration
The closing of the process cycles has led to an increased need to control the amount of non-process
elements in the recovery cycle by separating dregs in causticizing. The non-process elements enter
with wood and with chemicals used in the process as for instance magnesium used in oxygen
delignification. Table 7 shows an example of green liquor prior to and after filtration. The green
liquor treatment process in Picture 35 includes the following main process stages:
23
Table 7.
Dregs, mg/l
Potassium (K), mg/l
Magnesium (Mg), mg/l
Aluminum (Al), mg/l
Iron (Fe), mg/l
Manganese (Mn), mg/l
Copper (Cu), mg/l
Phosphorus (P), mg/l
Filtered liquor
7
5.3
1.1
40
8.2
2.2
0.88
41.2
Fapet 6B: p.B146
Green liquor can be clarified by sedimentation. In sedimentation, the density difference between the
solid material and the liquid in green liquor separates the solid material by allowing it to settle. A
clarifier is normally an open cylindrical tank as Picture 36 shows. The solid material that is heavier
than the liquid settles to the bottom of the clarifier to form sludge. The clear liquor in the upper part
of the clarifier is removed as an overflow.
MPS
24
MPS
MPS
It is necessary to cool the green liquor and to control the temperature of the green liquor that enters
the slaker in recausticizing to prevent the liquor from boiling in the slaker. Boiling may occur due to
the heat generated as a result of the exothermic slaking reaction. Cooling of green liquor, and even
of weak liquor, is difficult with indirect heat exchangers because of the rapid scaling and plugging
due to reduced solubility at lower temperatures.
MPS
MPS
Picture 41. Water balance for causticizing with a pressurized disc filter for white liquor separation
Other commonly used machines for white liquor and lime mud separation and mud washing are
the candle filter shown in Picture 42 and the disc filter shown in Picture 43. The heat and water
balances when using these machines are somewhat different than the ones when using
pressurized disk filters.
MPS, Andritz
MPS
27
The white liquor produced and separated from the lime mud is taken to the digester for cooking.
Table 8 shows typical properties of white liquor.
Table 8.
Compound
NaOH
Na2S
Na2CO3
Na2SO4
Na2S2O3
Na2SO3
Other compounds
Effective alkali
Active alkali
Total alkali
Sulfidity, %
S/Na equivalent ratio
Causticizing degree, %
Reduction degree, %
based on total S
Reduction degree, %
based on total SO4
Concentration,
g NaOH/l
95
40
23
4
2
0.5
135
115
164.5
29.6
0.58
80.5
82.2
Concentration,
g Na2O/l
73.6
31.8
17.8
3.1
1.6
0.4
105.4
89.5
128.3
As compound,
g/l
95
39
30.5
7.1
4.0
0.8
3.0
179.4
90.9
Fapet 6B: p.B171
The target in lime mud dewatering is to complete lime mud washing and increase the dry solids so
that the lime mud can be dried thermally and fed to the lime kiln. The moisture in the lime mud has
a considerable effect on the energy consumption of the lime kiln. Dry solids contents of 80%-90%
are possible after mechanical dewatering. The water soluble alkali content in the lime mud after
mechanical filter dewatering is under 0.1% as Na2O on dry mud. A low content of sodium is
necessary for the trouble-free operation of the lime kiln.
MPS
28
A pneumatic dryer for lime mud is an emerging drying method where the lime is dried with the
exhaust gases from the limekiln in a separate cyclone. Lime mud is fed to a flue gas stream, where
the heat of the flue gases dries the mud. A cyclone separates dry mud and feeds it to the kiln as
shown in Picture 47.
29
MPS, Andritz
The traditional method for the drying of mud is the chain section of the rotary kiln. Picture 48 shows
a chain system. The length of the chain section of the limekiln is chosen so that the mud is
completely dry when leaving the chain section. The length of the chain section is usually about 20%
of the total kiln length.
30
Table 9.
Component
(expressed as
oxides)
CaO, wt. %
Na2O, wt. %
SiO2, wt. %
MgO, wt. %
Fe2O3, wt. %
MnO, wt. %
Makeup
lime
93
0.06
2.5
1.3
0.5
0.04
Silica is a serious impurity in the lime cycle and causes problems especially when pulping annual
plants and tropical wood. The lime mud becomes difficult to handle and dewater with an increasing
silica content as shown in Picture 49.
Picture 49. Lime mud dry substance and silica in lime mud
The cell structure of annual plants contains solid silica particles that dissolve in the cooking liquor,
proceed with the black liquor into the smelt, and end up in the green liquor in dissolved form. Silica
precipitates with lime mud during recausticizing because of the low solubility of calcium silicate in
white liquor. Lime mud from the pulping of annual plants cannot often be reburned at all. A large
portion of the lime mud from the pulping of tropical hardwood must be dumped to keep the
recausticizing plant in operation.
Depending on the design of the burner in the lime kilns, also fuels other than fuel oil and natural gas
can be used. A combination burner can have ports for non-condensable gases and arrangements for
feeding methanol. Primary air passes through the burner, cools it, and stabilizes the flame.
31
Lime kilns have a refractory lining that protects the kiln shell from overheating and reduces the heat
loss to an acceptable level. The temperature distribution of lime kilns is wide from the cold feed-end
housing to the hot firing hood. In conventional kilns, where the mud is dried inside the kiln, the
lowest temperature is about 100C. In the flame zone, the temperature is about 1,250C. In large
kilns with a shell diameter of over 4.5m, the flame zone lining has to tolerate even higher
temperatures like 1,300C-1,350C. In modern kilns with a separate mud dryer, the cold-end
temperature is 400C-600C. Picture 52 shows the lime kiln brick lining zones. Each zone has a
lining of a certain material and thickness.
32
Questions
1. The source of water, organic material and inorganic material in black liquor. / Mustalipen
sisltmn veden, orgaanisen aineen ja eporgaanisen aineen alkuper.
2. Properties of black liquor influencing the evaporation plant. / Mustalipen ominaisuudet
haihduttamon kannalta.
3. Multistage evaporation plant, number of stages and steam consumption, soap separation. /
Monivaihehaihduttamo, vaiheiden lukumr ja hyrynkulutus, suovan erotus.
4. The most common evaporator designs used in black liquor evaporation. / Yleisimmt
haihdutinkonstruktiot mustalipen haihdutuksessa.
5. Condensate handling and reuse at kraft pulp mills. / Lauhteiden ksittely ja uudelleenkytt
sulfaattisellutehtailla.
6. List the main steps of the kraft recovery process. / Luettele sulfaattiprosessin
talteenottopuolen trkeimmt vaiheet.
7. The smelt reactions in a recovery boiler. / Sulareaktiot soodakattilassa.
8. The combustion of black liquor in a recovery boiler; the black liquor droplet during
combustion, and the different stages of combustion. / Mustalipen poltto soodakattilassa;
mustalipepisaran kyttytyminen polton aikana ja palamisen eri vaiheet.
9. Recovery of heat in a recovery boiler. / Soodakattilan energian talteenottojrjestelm.
10. Scaling of heat transfer surfaces in the recovery boiler. / Soodakattilan lmmnsiirtopintojen
likaantuminen.
11. The main factors influencing the heating value of black liquors. / Polttoarvoon vaikuttavat
trkeimmt tekijt.
12. Influence of chlorine and potassium on recovery boiler operation; what can be done to
control chlorine and potassium levels? / Kloorin ja kaliumin vaikutus soodakattilan
toimintaan; mit voidaan tehd kloori- ja kaliumtasojen hallitsemiseksi.
13. Green liquor treatment, measures to reduce the need for makeup lime. / Viherlipen
ksittely, miten vhennetn korvauskalkin tarvetta.
14. Slaking of lime and causticizing reactions. / Kalkin sammutus ja kaustisointireaktiot.
15. The operation principle and construction of the lime kiln. / Meesauunin toimintaperiaate ja
rakenne.
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