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IChem E
INTRODUCTION
Over the last four years Pinch Technology has been
widely used for the integration of process plants. Virtually every sector of the process industries has benefitted.
This experience clearly teaches that integration must be
undertaken in a total site context.
This paper considers how process plants interface with
utility systems. It describes the development of an optimum retrofit scheme in the context of an overall site.
Individual process improvements are not taken in isolation. Rather, their total impact is considered in a
genuinely site wide context.
The paper takes as its example an ethylene process.
This is because ethylene processes are not only complex
but interact with the site utility system in a complicated
way. The process employs a large number of separate
utilities. These utilities are closely coupled with the
overall factory site.
In terms of ethylene technology the paper adds to
previous advances 1,2.
Figure 1 is a simplified schematic of a "typical"
ethylene plane showing the following, not uncommon,
process features:
Pyrolysis furnace and quench steam raising
Principal mechanical drives
-raw gas compressor
-propylene refrigeration set, Fl
--ethylene refrigeration set, F2
-boiler feed water pump
"Cold box" with steam and fridge demand (several
levels)
Other process steam demands (several levels)
S139
HP STEAM
:MP STEAM
LP STEAM
n II
FRIDGE SETS
BFW
PUMP
QUENCH
STEAM
RAW GAS
COMPRESSOR
ETHYLENE
t-o'--+-<I"PRODUCT
I
I
I
FUEL
IL
...J
t1PORTED
'n"'"
FUEL
16HW
WENCH STEAM
HP USERS
(TOTAL SITE I
II ELECTRICITY
t1PORTED
{7
UEL
lP I----......:.-----"-=---L---'--....I..l
MP USERS
!TOTAL SITE I
LP USERS
llOTAl SITE)
270 t/h TOTAl
CONDENSATE.
S140
After studying
each process carefully....
-12%
-5%
-10%
FURTHER IMPROVEMENT
The system shown in Figure 5, although offering
reasonable savings at good payback, still includes
significant amounts of shaftwork derived from condensing steam. We would ideally like to replace the propylene
compressor (FI) turbine with an electric motor. We
cannot, however, treat this turbine in isolation as closer
inspection of the steam system reveals. Figure 6 shows
the steam from the ethylene compressor (F2) turbine is
fixed by the duty of the compressor at 80 t/h. Process
requirements for LP steam are given as 80 t/h and the
import of LP steam from the power station turbine is at
a minimum value of 20 t/h determined by the characteristics of the power station turbo-alternator. To replace
F I condensing turbine by an electric motor would mean
that 20 t/h of LP steam would be surplus to demand
would have to be vented if not being condensed in the
turbine. Further savings would therefore appear to be
strictly limited because we have run up against this
operability constraint.
At this point we need a thermodynamic tool which
will address the complex interaction of heat and power
inherent in the overall plant complex in a rigorous and
systematic way.
,, , ,
~
<'RJEL "
"-24"--
',-'
QUENCH
STEAM
35
HP I - - -........~~r---- ......~-:--,.....-.........
M.P USERS
!'I.P
1-----;--......-r------''--:---;-...I.o1
LP
1 - - - - - ' - - - -........-7---L--..L-...I.o1
CONOENSATE
~,
~~~/
LP USERS
S141
F/01
POWER
STATION
1400
1200
1000
~-,,--,--aOtfh
TEMP.
20 fh
(OC)
L.P. HEADER
//
800
//
600
/
/
/
/
400
/
/
HP
PIP
1400
1200
1000
TEMP.
rOc)
800
/
/
600
/
/
/
400
__""-SITE GRAND
__
COMPOSITE
100
200
300
HEAT IMW)
'
~I
EXCESS 0
HEAT
-..
,..-----"
__ /
,/
_~J--'
100
200
300
HEAT IHWI
for process heating. Total shaftwork of 44 MW produced by the steam system is also indicated.
This diagram is thermodynamically incorrect since it
does not show the correct interaction of process and
utilities but it does give a clear picture of the power
cycles. The derivation of a more accurate utility line is
not discussed in this article but is reproduced as Figure
8. We can now see more clearly just what is happening
at the existing process/utility interface.
Now Figure 8 indicates sub-optimality in two ways:
1. The excessive use of heat caused by the lack of process
intergration (i.e. the overshoot of the utility profile on
the grand composite curve). This is equivalent (in
terms of heat duty) to the 30 t/h of steam which we
saw earlier could be saved by improved process heat
recovery within the process plants plus the unrecovered heat in the flue gases below the existing
stack temperatures.
2. The poor fit of steam levels against the grand composite curve. The curve indicates an opportunity to
use more LP steam in preference of HP and MP
steam. The process actually requires 20 t/h HP, 100
t/h MP and 120 t/h LP-the same total of 240 t/h but
in a different distribution.
Now, the revised steam distribution will allow us to
produce more shaftwork from the same total amount of
steam and the increased LP demand will avoid the
problem of minimum flow in the back end of the power
station turbine. This will give us more flexibility in our
revised steam system design. Figure 9 illustrates such a
better matched process/utility interface. Note that the
flue gas line is now slightly steeper than before because
of the reduced steam raising at the boiler house.
S142
COOLING
WATER
~--r--20.C
11.00
SUB-AMBIENT
/
FOR
ETHYLENE PLANT
o'C
1200
GRAND COMPOSITE
F1
mo
TEI'1PI"C)
,,;oJ'"
800
600
400
200
LP
/
MP
H ,,/
.1
,/
,,
/,/'
,/
F2
J-'-..J
.....\
100
200
HfAT IMWI
SUB-AMBIENT CONSIDERAnONS
The sub-ambient region of an ethylene plant is extremely complex involving perhaps six levels of refrigeration in addition to the primary cold utility of cooling
water and/or air cooling. The six levels of refrigeration
are achieved by using two separate but interlinked
systems.
Fl, propylene refrigeration system
(10 to -40C)
F2, ethylene refrigeration system
( - 60 to - 100C)
Each system may extract heat from the process at
three levels and, in addition, there will be a temperature
level at which the propylene system extracts waste heat
from the ethylene system. These interactions are illustrated in Figure lOin which the refrigeration systems are
placed against the sub-ambient grand composite curve of
the ethylene process. The "pinch" at -40C is, technically, a cooling water pinch since it is formed after
maximising the use of cooling water in the pinch analysis
(cooling water being the least expensive cold utility). We
shall see that it is the interaction of the two refrigeration
systems which allows increased flexibility in design.
Figure 11 shows the existing refrigeration levels on the
grand composite curve (chilling duties represented by
solid lines, waste heat rejection by broken lines). The
existing compressor duties are 4 MW and 7 MW for
propylene and ethylene respectively. Again we see suboptimality caused by:
I. Larger than necessary chilling duties shown by the
overshoot of each refrigeration level on the grand
composite. These can be reduced by improved process
heat (or cold) recovery.
REJECTION
+20
I
I
Fl FRIDGE
LEVELS
-20
..~--:..::=.=j=./
HEAT
-- ----1---w' --==--------------'=--- F2
REJECTION
F2 FRIDGE
LEVELS _
_80
-100
Fl LOAD
F2 LOAD
EXISTING
4-0 MW
7-0 MW
11-0
100
POSSIBILITY A
3-5 MW
6-5 MW
POSSIBILITY B
4-0 MW
6-0 MW
10-0
POSSIBILITY C
3-0 MW
7-0 MW
10-0
Sl43
I IPOWER
V ~MW
FUEL
HP I-----L......:....---,,-------L---,r---..L...j
MP I - - -
--'-_~I
~o
80
LP ~--.....:....----------lL...--.L.-..L...t
....
,"' "
The raw gas compressor turbine arrangement is unchanged since we are already at minimum condensing
flow rate but the remaining 35 tlh of condensing steam
from the propylene refrigeration system are eliminated.
VHP steam raising is reduced by a further 35 tlh from
the level in Figure 5 (85 tlh reduction on the existing
steam raising) but import electricity is increased by 4
MW over our earlier design to cater for the new motor
and the slight reduction in turbo alternator output (an
overall increase in imported electricity of 11 MW over
the existing operation). Total project savings are therefore 330 per hour or 2.6 million annually. With an
estimated capital expenditure of 3.3 million, project
payback is in the order of 15 months. This compares
with the apparent maximum savings identified earlier of
1.44 million at an 18 month payback (Figure 13).
In terms of power generation, compare the two
schemes in Figure 5 and Figure 12 to the existing design:
~'"
t Ih TOTAL
(UNC HANGED I
2~0
FINAL DESIGN
Figure 12 shows our improved design (Possibility C in
Figure 11) following the overall site analysis and the
sub-ambient consideration described above. These factors have allowed us to introduce two elements of
flexibility which avoid the earlier constraints in our
retrofit projects.
The increased LP steam demand has increased the
potential for power generation (per ton of HP steam)
and allowed us to eliminate the condensing turbine on
the propylene compressor without penalty. The
flexibility within the two refrigeration systems has further allowed us to minimise the capital cost of the new
electric motor introduced on the propylene compressor.
Chern Eng Res Des, Vol. 65, September 1987
Difference from
existing design
Figure 12
Figure 5
-3 MW
0
-4 MW
-12 MW
+7MW
-IMW
+1] MW
5
SAVINGS
$10' p..
//L"'/
/'
'" '"
//
''''
"';'"
/
// /
,v
'"
,.
PROJECT A BY
INOIVIDUAL PLANT
OPTIMISATION
18 MONTH
AVERAGE
PAYBACK
5
INVESTMENT
$ 10'
S144
CONCLUSIONS
Retrofit projects of individual process plants aimed at
improved yield, energy savings, expansion, etc. will
increase profits in an overall complex but there could be
better profit improvement still if interactions are properly understood. For example, the reduced steam demand inherent in an energy saving project can be
counter-productive since it often leads to reduced shaft-
I
Determine optimum levels of site
services from grand composite.
I
Exploit interaction between different
systems (e. g. propylene and ethylene
refrigeration I.
I
Model cogeneration and site service
systems into process consumers (not
based on design detail but based on
target curves l.
I
Design of projects (treating process and
service systems simultaneously l.
Figure 14.
Cost Savings
Industry
Petrochemicals
Inorganics
Chemicals
Pharmaceuticals
Resins
Pigments
Steelworks
Foodstuffs
Project payback
12-24 months
2-3 years
9-16 months
15 months
2-2! years
up to 3 years
15 months
2 years
2 years
REFERENCES
I. Linnhoff B. and Vredeveld D. R., 1984, Chern Eng Prog, July.
2. Linnhoff B. and Witherell W. D., 1986, Oil & Gas J, April 7.
3. Linnhoff B. et al. 1982, User Guide on Process Integration for the
Efficient Use of Energy. (I, Chern E)
ADDRESS
Correspondence on this paper should be addressed to Professor B.
Linnhoff, Department of Chemical Engineering, UMIST, PO Box 88,
Manchester M60 IQD.
The manuscript was received 26 June 1987 and accepted for publication.