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Many theoretical and experimental studies have been carried out on the LiBr H2O
absorption chillers. For instance, A.Kececiler et al. [3] performed experiments on
LiBr H2O system in lab conditions used low temperature geothermal energy as a
powering source. They concluded that low-heat geothermal sources can not be used
efficiently in electricity generation, however could be used economically for
refrigeration storing at 4-10C. Da-Wen Sun[4] simulated LiBr H2O absorption
refrigeration systems. Detailed thermodynamic design data and optimum design maps
were produced as a source of reference for developing new cycles and searching for
new absorbent/refrigeration pairs. O. Kaynakli et al. [1] Simulated single effect LiBr
H2O absorption refrigeration cycle. They showed that the COP(s) values increase
with increasing generator and evaporator temperatures but decreases with increasing
condenser and absorber temperatures. M. Izquierdo et al. [5] conducted trials to
determine the performance of a commercial ( Rotartica 045v ) 4.5 kW air cooled,
single effect LiBr H2O absorption chiller for residential use. One of their findings was
that the cooling power tends to decline with raising outdoor dry bulb temperature and
at temperature from 35 to 41.3 C the chilled water outlet temperature in the
evaporator climbed to over 15C. K. Sumathy et al. [6] developed prototype ( cooling
capacity = 100 kW ) half effect LiBr H2O chiller powered by low temperature hot
water source ranging from 60 to 75C. Test results indicated that the two-stage chiller
could be powered by solar hot water system. Mostafavi and Agnew[7] worked on
small unit (1 kW) single-stage air cooled chiller. They investigated the effect of
ambient temperature on the surface area of the generator, condenser, evaporator,
absorber and solution heat exchanger of an air-cooled absorption machine. They
concluded that ambient temperate did not affect the absorber and condenser surface
area. Whereas, generator and solution heat exchanger surface areas increase slightly
as the ambient temperature increases. In addition, the evaporator surface area
decreases as the ambient temperate increases.
Luis H. Alva et al. [8] investigated technical feasibility of using a compact air-cooled
solar assisted absorption air-conditioning system using computer simulation
modelling. A comparison was made between absorption air conditioning systems that
use a cooling tower instead of air-cooled components. Small cooling loads of 10.5, 14
and 17.5 kW were considered. Results showed that air-cooled absorption machines
could have the great advantage of reducing maintenance and cost when compared
with conventional water cooled ones for small loads, however the COP for the aircooled absorption machine decreases as the ambient temperature increases.
M. Izquierdo et al. [9] modelled solar plant, consisting of flat plate collectors feeding
the generator of the double-stage absorption machine. Their studies showed that for
condensation temperature up to 53C , the double stage LiBr/H2O absorption cycle
may be operated and calculation processes showed that about 80C of generation
temperature are required in the double-stage absorption machine when condensation
temperature reaches 50C , obtaining a COP equals to 0.38.
Xiaohong Liao et al. [10] proposed control strategy approach to prevent the
crystallization by increasing the chilled water temperature setting which will result in
improving cooling capacity and COP values.. Kiyota, et al. [11] showed analytically
and experimentally that air cooling of vertical falling-film absorber will required
about three times the heat-transfer surface compared to water cooling of the same
absorber. Saskaki, et al. [12] proposed cascaded system vapour-compression to
absorption in which the cooling space carried out by vapour-compression equipment.
In this case the vapour compression condenser and the absorption system evaporator
are in the thermal connection. Rainnai Corporation [13] proposed cascaded
absorption chiller components except two components, the desorber unit was
modelled as an adiabatic flash drum for two-phase mixture where exiting streams are
in equilibrium and exiting vapour is pure water and in the absorber unit, the restored
poor solution takes up the occurring gaseous refrigerant mixture and leaves the
absorber as a rich solution[16]. For heat exchangers, it is common to use UA
formulation along with log-mean temperature difference (LMTD) as follows:
Q = UATlm
Tlm =
(T
h ,1
(1)
Tc , 2 ) (Th , 2 Tc ,1 )
Th ,1 Tc , 2
ln
Th , 2 Tc ,1
(2)
Where, h and c are referred as hot and cold sides, respectively. The subscript 1 & 2
refer to either end of heat exchanger.
The maximum possible heat transfer can be calculated from;
(3)
(4)
1.
2.
3.
4.
The obtained results have shown that a refrigeration capacity of 1284 ton was
produced at outlet chilled water temperature of 5C. This higher capacity was roughly
double of water/air single effect chillers capacity. In this cycle more heat was
extracted from the given powering source, hence no significant economical benefit of
heat rejected from the desorber. A penalty must be paid when the cycle produced
higher cooling capacity; the COP of the half effect is roughly half (0.424) of COP
obtained from single effect chillers (0.8245-0.845). Both lower LiBr H2O mass
fraction (0.41-0.44) in high pressure cycle and higher mass fraction (0.52-0.55) in low
pressure cycle were circulated within modelled cycle.
Figure 5. Water-cooled half effect cascaded with CO2 compression cycle chiller
4.5 Direct electrical generation organic Rankin cycle
The community in Waddan city could directly benefit from the existing geothermal
source by simply installing an organic Rankin cycle (ORC) for direct electricity
generation. R245fa was found the most suitable working fluid among other related
organic refrigerants, such as R134a. As shown in figure 6, the simulated results have
indicted that 1324 kW was produced at an ORC efficiency of 8.4%.
4.6 Water-cooled half effect cascaded with gas turbine (GT) and R-245fa organic
Rankin cycle (ORC)
Geothermal sources available in hot climate places and near natural gas fields could
economically encourage local electrical investment companies to install combined
cycle power plant (GT and ORC) to supply Waddan community and surrounding
villages with their demand of direct generated electricity and hot water supply.
Results obtained in figure 7 have shown that the net output electrical energy and hot
water energy were 103 MW and 25 MW respectively. Around 21% (18108 kW) of
total produced electricity was from ORC unit. This can be considered as good
achieved contribution in saving ozone layers from harmful LNG exhaust emissions.
Figure 7. Water-cooled half effect cascaded with gas turbine (GT) and R-245fa
organic Rankin cycle (ORC)
5. Results summery
The obtained output results of the proposed simulated models are summarised, and
for clarity, separated in two tables. Table 1 lists COP, chilled and hot water energies.
Table 2 shows produced electrical energy. Graphical presentations for COP and
refrigeration capacity are also produced in figure 8 and 9 respectively.
Air-cooled
Single
effect
water-cooled
Half effect
Water-cooled
half effect
cascaded with
CO2 chiller
0.8245
0.845
0.424
0.424
Evaporation power
(kW)
1970
2197
4495
4495
Refrigeration capacity
(ton)
563
628
1284
835
22
15739
15518
68
67.5
output parameters
COP
8.4
16.74
1,324
18,000
85,000
1,324
103,000
25,000
Chiller type
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
COP
Chiller type
Water-cooled single
effect at 5C
200
400
600
800
1000
1200
1400
significant outlet temperatures (about 68C) which can be furtherer used in central
heating and domestic hot water supply.
For further reduction in the value of evaporator outlet chilled water temperature
(0 or below) the absorption cycles need to be cascaded with conventional
compression CO2 cycle.
If cooling air-conditioning system is decided to be the only suitable choice for
Waddan communities, without utilizing hot water energy, then water-cooled half
effect chiller is probably the best system to be installed. If air-conditioning and hot
water supply systems are desired, in summer and winter seasons, then the water
cooled single effect chiller has to be selected instead.
Low temperature artesian geothermal sources could be utilized to generate direct
electricity using R245fa organic Rankin cycle (ORC) without any further significant
benefit of rejected heat from the evaporator. This geothermal source, along with
surrounding natural gas fields, seems economically and environmentally very
attractive to build clean combined power station (GT & ORC).
7. Future work
1. More investigations will be carried out on various operating parameters of
simulated models.
2. An economical study will be conducted to select the most suitable chiller
model for Waddan city.
Acknowledgement
I would like to express my sincere thanks to my supervisor Dr. Brain Agnew for his
kind guidance and assistance throughout the work.
References
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