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PII: SOO21-8502(97)00037-2
AN EXPERIMENTAL
STUDY OF THE DRY DEPOSITION
MECHANISM FOR AIRBORNE DUST
Sergey Biryukov
Ben-Gurion
National Solar Energy Center, The Jacob Blaustein Institute for Desert
Ben-Gurion
University of the Negev, Sede Boqer Campus, 84990, Israel
(First received 12 March
Research,
29 May 1997)
Abstract-A
study of dry deposition of the coarse mode of airborne dust on mirror surfaces has been
performed at Sede Boqer, Israel, as a part of a research program to protect the reflective surfaces of
solar concentrating
collectors. In particular,
the angular dependence
of the deposition
rate was
measured in order to separate between its diffusive (isotropic) and vertical components.
Dust was
collected on a flat sampler with changeable
slope, mounted on a wind vane. No deviation from
a cosine-type
angular dependence
was found for dust particles larger than 4pm. This result is
interpreted as domination,
in the vicinity of the collecting surface, of vertically directed particle flux
over diffusive components.
This conclusion was compared to the results of existing dry-deposition
models. The size distribution
of particles, collected on the flat horizontal surface, was converted to
a volume-mass
concentration
using calculated
sedimentation
velocity as the only component
of
deposition
velocity. The resulting value was confirmed
by our control measurements
of the
volume-mass
concentration.
Our results are also compared
with recent data on deposition
velocities, published by Lin et al. (1994). 0 1998 Elsevier Science Ltd. All rights reserved
1.
INTRODUCTION
(1)
(See Hinds, 1982, for definition of the projected urea diameter, and Stine and Harrigan, 1985,
for optical efficiency of solar collectors.)
Here J(d,) = V(d,)n(d,)
is the flux of particles with diameter d,, where V(d,) is the
deposition velocity (see Williams and Loyalka,
1991, p. 327, for definition) and n(d,) the
numerical volume concentration
of particles, q(d,) S(d,) the reduction of mirror reflectivity
or of glass transmissivity
due to a single particle, where S(d,) is the particle projected area
and coefficient q(d,) depends on surface properties
(e.g. it is different for the first- or
129
130
Serpey Biryukov
second-surface
reflectors) and on physical properties of dust, and $(d,) the efficiency of
surface cleaning or protection
against dust accumulation.
Our research program obviously
requires a twofold starting point: determination
of
(a) the relevant particle-size distributions
and (b) the principal mechanisms for their deposition. The first is important
because their size is the main factor which determines
the
physical interaction
of particles. The second, because knowledge of the actual deposition
mechanisms
provides-via
deposition
velocity-a
quantitative
basis for measuring
the
efficiency of any resulting cleaning or surface protecting techniques. This knowledge also
results in a relationship
between data on surface deposition
rates and the corresponding
particle-volume
concentrations.
In some cases, moreover, it renders possible the use of
a reference sample in order to normalize other surface data. At the practical level, of course.
such knowledge constitutes the required basis for designing solar collectors with better antisoiling properties.
The atmospheric
dust accumulation
on solar collectors has previously been studied by
Sayigh et al. (1987), Guddihy (1988) and El-Nashar
(1994). These works present results
which are integrated over long time periods and which include a wide spread of meteorological conditions.
They provide no quantitative
information
about the relative contribution of particles with different sizes to surface contamination,
or about the mechanisms
of
dust deposition on the solar collector surfaces from the ambient atmosphere.
Quantitative
information
about the influence of artificially produced and deposited dust particles of
different sizes (optically determined
mean diameters
5, 10, 50, 60 and 80,~m) on the
performance
of photovoltaic
panels can be extracted from the laboratory
measurements
of
El-Shobokshy
and Hussein (1993).
In the present article we report data on the size distribution
of natural airborne particle
flux J to glass-coated
mirror samples for particles having projected area diameter larger
than 4pm. As previously
demonstrated
by our measurements
of specular refectivity
degradation,
accompanied
with microscopic studies (Biryukov et NI., 1994) particles in this
size range play the dominating
role in the kind of optical degradation
under investigation
here.
The presently reported size distributions
of deposition
rates, on glass and glass-coated
mirror samples of different orientations,
demonstrate
high stability of their shapes. They
peak between 10 and 20,um in the projected area diameter. This shape repeats itself under
similar meteorological
conditions,
which will be discussed later. This fact points to the
existence of a definite mechanism for particle accumulation
(at least for the coarse particle
region, of interest to us) and provides the possibility to study it using both long-term (days)
and short-term
(hours) measurements.
In the present study we have placed a high level of importance
on using natural rather
than simulated dust-deposition
conditions. On the other hand, the conditions had to be well
defined in order to permit a clear-cut theoretical interpretation
of the results. To these ends,
the measurements
reported here were all performed under conditions, corresponding
to the
dry-deposition
process. Common definitions of this process can be found in Twomey (1977)
and Brimblecombe
(1986). This ensured the absence of complicating
water condensation
effects. Furthermore,
we were also able to ensure that all particle deposition
data would
correspond to conditions of wind parallel to flat surfaces of known slope. In this manner we
could determine the angular dependence of particle fluxes to glass surfaces, for particles of
different sizes.
As will be shown below, one can use the measured angular dependence
in order to
estimate the relative contribution
of the isotropic (diffusive) and vertically directed components in the particle flux. One must, however, ensure the absence of particle deposition by
impact on the obstacle from the disturbed air stream. In order to eliminate this mechanism,
glass samples with a variety of fixed slopes relative to the horizontal
were kept parallel to
the wind direction by attachment
to a wind vane. In order to take into account effects of
resuspension,
measurements
were performed with the samples half-coated with an adhesive
layer. Particle-size
distributions
for the collected samples were then determined
using
a computerized
microscope.
An experlmental
131
The common
predictions
of the model of dry deposition
from turbulent
flow under
gravity are compared with our measured angular dependence of particle flux. We conclude
from our results that, for the particle sizes of interest, gravitational
settling effectively
dominates over the totality of all diffusive mechanisms. That means that air motion parallel
to a Aat collecting plate is slow enough to preserve laminar boundary layer near its surface
(see the discussion of conditions for turbulent deposition from the flow parallel to surface in
Friedlander,
1977, p.115).
Using this conclusion together with our data on particle fluxes to horizontal surfaces we
are able to estimate the corresponding
volume densities of dust particles with sizes in the
range 4-64 pm. These results are compared with some direct control measurements
of our
own and with published
data for the Negev region. We also compare our results with
measurements
of dry-deposition
velocities, reported by Lin et al. (1994).
2.
2.1. Measurements
EXPERIMENTAL
of particle-size
distributions
TECHNIQUE
on a surface
As previously
stated, the particles of interest for our research have projected
area
diameters larger than 1 pm. This size is large enough to permit the use of optical microscopy
for analysis purposes. For the study of particle-size
distributions
on mirror surfaces we
developed a computerized
set up, based on the MonoZoomVideo Microscope System of
Cambridge Instruments Corp. The optical image of the microscope is viewed by a Javelin
Corp. JE 7442X B/W video camera, which has a sensitive CCD-array
of 756 x 512 pixels.
The output of the CCD-camera
was recorded by a DT-2855 Quick Capture frame
grabber of Data Trunslation Corp.
Image processing of grey-scale frames was performed using a 486-based micro-computer,
with the help of specially designed software for particle recognition.
The latter included
some standard image processing operations,
which mostly are presented in Russ (1990).
The grey-scale image was converted to a binary (black and white) one with the help of
brightness discrimination
before sizing (see Russ, 1990 for a discussion of the thresholding
operation). This procedure was used for background
subtraction.
Each particle was characterized by its projected area in pixels. The last one was recalculated
to the diameter of
equivalent
circle, i.e. the projected area diameter in pm, using the beforehand
measured
scale. Special corrections
had to be applied to the effective diameters of the projected
areas of irregular particles. In particular,
it was necessary to take into account the fact
that most particles are to some extent elongated and tend to settle on a surface so as to
have minimum
potential
energy. This phenomenon
makes the average projected area
diameter for an ensemble of particles larger than it would be for the same particles if
they were randomly
oriented.
Depending
on particle and surface properties
(electric
charge, etc.) this correction,
in the most common case, depends on particle size and, if
neglected, can result in substantial
errors when calculating mass distributions,
aerodynamic
diameters, etc.
Particles were grouped into predetermined
size ranges according to their projected area
diameters. All particles in each frame were counted and sorted into their size ranges. The
histogram
over size ranges was incremented
using successive frames until at least 10
particles were counted in each size range (Hinds, 1982).
Sergey Biryukov
132
holder,
For each exposure both holder plates, with two samples, were installed symmetrically
relative to the vertical wind vane, each of them having the same angle 0 to the horizontal, as
shown in Fig. 1.
After each exposure the homogeneity
of particle density on the sample surface was
checked and the number of particles was calculated according to their sizes, for several
random positions of each of the two samples (using equal areas of integration for each pair).
The measurement
precision for a single sample, mounted close to the vertical position, is
limited by imperfections
in the determination
of the wind vanes vertical position. Equation
(2) gives the value of the relative error E in cos8, caused by an absolute error + 6 in the
value of H for such a sampling geometry
c=
-(l-cos6ftanQsin6).
(2)
2.3. Bounce-@blow-ofS
(3)
relative
negligible.
correction
Once particle has touched the surface of deposition, it may remain on it infinitely long, or
returned to air stream due to bounce-off (rebound), blow-off (reentrainment),
or due to
combined effect of these two processes.
In order to avoid experimental
errors in flux measurements,
caused by particle resuspension, the technique of coating the sample with an adhesive substance (greasing) is widely
used. But in optical measurements
the adhesive layer changes the optical properties of the
sample surface and may contribute to the error in particle diameter determination.
We used
An experimental
133
2000
1500
1.5
z
3
k
2
I
3
1;
1000
%
.$
f
E
8
u
0.5
500
IL
16
32
64
coefficient
Fig. 2. Measurement
coating
of attachment
of attachment
coefficient
on a sample,
half-coated
with a adhesive
layer.
Sergey Biryukov
134
3. EXPERIMENTAL
3.1. Frequenqs
distribution
DATA
qfparticle
AND
DISCUSSION
sizes on suyfaces
16
32
64
mirror:
particle
deposition
rates
An experimental
0.35
_r
135
4
i
-
0.3
-t
-
-~
--t----+
j
-I
-_
32
16
64
-.
rates horizontal
vertical sample
samples.
Wind vane, h = 6 m
of the angular
Sergey Biryukok
136
+ V,cosCln.
(4)
vs cos (IN
1 - exp(-
V,cos0h/D)
If Vs cos Gh/D >>1 then J z Vs cos UN, or I 2 I/, cos 0 (a situation in which gravity controls
deposition, the diffusion term being negligible). This gives similar particle-size distributions
on a surface for different slopes and zero flux (deposition
rate) on a vertical surface.
If, on the other hand, Vscos Bh/D<< 1 then J k DNjh, or V c D/h (gravity being now
negligible). In this case the deposition velocity I/ and deposition rate do not depend on the
surface slope.
We performed outdoor measurements
in order to estimate the relative contribution
of
sedimentation
and diffusion processes in the deposition rates for particles of different sizes.
The measurements
were performed at Sede Boqer, in the Negev highlands.
We measured the value of Je (flux on the inclined glass sample, kept parallel to the wind
direction) relative to J (flux on a horizontal sample) using the previously described sampling
technique
and particle sizing by means of computerized
optical microscopy.
We also
determined
the coefficient of attachment
for particles of different sizes d, in the manner
described above. Our measurements
with different slopes (for (1 = 45 and 60) revealed
a dependence of the form J,(d)/ J (II) = cos (1. Even for 0 > 80 we did not find a meaningful
deviation from this cos 0 dependence.
The results of these experiments
are shown in Fig. 5. Experiments
on horizontal
but
down-facing samples at heights of 2 and 6 m indicated a flux at least an order of magnitude
lower than on vertical samples.
The average wind speed for different data sets during the measurements
with variable
sample inclinations
never exceeded 3.6 m s- . During measurements
the highest individual
value of this parameter approached
4.9 m s -I (10 min average). This range of wind speeds
applies also to the measured values of the attachment
coefficient.
3.3. Discussion
of the model,fov
We can summarize
the main
dry deposition
properties
qf ambient dust
of the measured
deposition
rates as follows:
demonstrate
a stability of shape under conditions
wind speeds of O-6 m s- ;
of dry
An experimental
137
JW 1J(c) vse
for particles less than 8 micron
1.1
1.1
1
0.9
0.9
0.8
0.8
0.7
0.7
0.6
0.6
0.5
0.5
0.4
0.4
03
0.3
0.2
02
0.1
0.1
0
0
0
0 10 20 30 40 50 60 70 -80 90
10 20 30 40 50 60 70 80 90
1.1
1
0.9
0.9
0.8
0.8
9.7
0.7
0.6
0.6
OS
0.5
0.4
0.4
0.3
0.2 -
0.1
0
0.3
0.2
\\
2.
0 10 20 30 40 50 60 70 80 90
The slope angle, 0 (degrees)
deposition
\\
\
0.1
o-
10 20 30 40 so 60 70 80 90
rates compared
(2) the shape of the particle-size distribution does not depend on the surface slope angle
for particle sizes in the range 4-64 pm;
(3) the deposition rate is proportional to cos6 for 0 varying from 0 to at least 85.
According to our discussion of the relative role of gravitational and diffusive types of
deposition we conclude that the former mechanism dominates for particles with sizes
4-64pm under conditions of dry deposition and moderate wind speed (less than 4 m s- ), at
least for quantities, averaged over periods of several hours.
This being the case, we can make an attempt to derive data about volume dust
concentration versus particle size from data on the deposition rate on horizontal surfaces:
J,(d)
44 = I/,o.
The sedimentation
where p is the particle density, g the acceleration due to gravity, p the airs dynamic
viscosity, C the Cunningham correction factor (x 1 for d > 1 pm), and K the dynamic shape
factor (see: Williams and Loyalka, 1991, p. 52-66).
K depends on the nonsphericity of the particles and on their surface area. We estimate
this factor, to be 1.0 < K < 1.2 for our case.
.
Sergey Biryukov
138
16
Particle
+ mass concentration
+ deposition
Fig. 6. Mass concentrations
64
32
size, micrometer
(derived)
rates (measured)
of airborne
dust, derived
from deposition
rates
CONCLUSIONS
We have developed
a rapid method for determining
the particle-size
distribution
on
surfaces, which we use for assaying the contamination
by windborne dust of solar collectors.
Using this method we have estimated the range of particle sizes which are the principal
cause of reflectivity losses.
We have performed experiments
to study the process of dry deposition
of dust under
ambient conditions. It was found that this process (which corresponds to clear summer days
and is consequently
of paramount
importance for solar energy production)
is dominated by
the mechanism
of sedimentation
under gravity, for particles larger than 4pm. This conclusion is qualitatively
supported by the previous results of Lin et al. (1994).
This conclusion appears to be of widespread applicability
since the measurements
of Lin
et czl., were performed in Chicago, Illinois, USA, under very different climatic conditions.
Our results also agree with the wind tunnel experiments and dry-deposition
velocity model
calculations
by Sehmel and Hodgson (1978), cited in Lin et al.
This conclusion
enables one to use surface data on particle-size distributions
in order
to derive the corresponding
volume-dust
concentrations
and deposition
velocities, the
calculated sedimentation
velocity being used as a reference in such measurements.
An experimental
139
Using this technique, we derived values for the volume dust concentrations of particles of
various sizes from about 4 pm to about 60 pm, from our outdoor measurements of particle
size distributions on glass surfaces. Furthermore, the absolute values of such concentrations
and their dependence on particle-size agreed with previously published values.
We plan to use the technique, developed here, as a key instrument for experiments aimed
at protecting the surfaces of solar collectors from dust.
Acknowledgements-This
research was partially funded by the Israel Ministry of Science
Israel Ministry of Energy and Infrastructure.
The author is indebted to Prof. D. Faiman
to the practical importance
of this problem and for many valuable discussions. It is also
to express deep appreciation
to Prof. J. Vincent for his instructive recommendations
on
version of this paper.
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