My Rates

E:\CHEG 403 - Process Design and Evaluation\Design 15.1 In Class Pro iireg2.
out
Monday, September 19, 2016 1:03 PM
$ Generated by PRO/II Keyword Generation System <version 9.3>

$ Generated on: Mon Sep 19 13:01:54 2016
TITLE
DESC Find feed total flow that results in 20,000 kt/y acrolien
DIMENSION METRIC, PRES=BARG, WT=TONM, TIME=YR, DUTY=KJ/DAY, &
STDTEMP=0, STDPRES=0
SEQUENCE SIMSCI
CALCULATION TVPBASIS=37.7778, RVPBASIS=APIN
COMPONENT DATA
LIBID 1,PROPANE/2,PROPENE/3,H2O/4,O2/5,N2, BANK=SIMSCI,PROCESS
LIBID 6,ACROLEIN/7,ACRLACID, BANK=PROCESS
ASSAY FIT=ALTERNATE, CONVERSION=API94, CURVEFIT=CURRENT, &
KVRECONCILE=TAILS, FORMATION=VER91
THERMODYNAMIC DATA
METHOD SYSTEM=PR, SET=PR01, DEFAULT
WATER PROPERTY=IF97, TRANSPORT=IF97
STREAM DATA
PROPERTY STREAM=S1, TEMPERATURE=350, PRESSURE=2, PHASE=M, &
COMPOSITION(WT,)=1,86448.9/2,17660.5/3,7573.06/4,24434.2/ &
5,95240.8, SET=PR01
RXDATA
RXSET ID=PROPENE
REACTION ID=ACROLEIN
STOICHIOMETRY 2,-1/3,1/4,-1/6,1
REACTION ID=ACRYLICACID
STOICHIOMETRY 2,-1/3,1/4,-1.5/7,1
UNIT OPERATIONS
CONREACTOR UID=R1
FEED S1
PRODUCT M=S2
OPERATION ISOTHERMAL, TEMPERATURE=350
RXCALCULATION MODEL=STOIC
RXSTOIC RXSET=PROPENE
REACTION ACROLEIN
BASE COMPONENT=2
CONVERSION 0.85
REACTION ACRYLICACID
BASE COMPONENT=2
CONVERSION 0.15
END
FF
SIMULATION SCIENCES INC.
R
PAGE R-1
PROJECT
PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM
INPUT
THERMODYNAMIC DATA
==============================================================================
VLE K-VALUE DATA FOR SET 'PR01'
PR PURE COMPONENT DATA

COMP
CRITICAL
CRITICAL ALPHA
C1
C2
-1-
C3
E:\CHEG 403 - Process Design and Evaluation\Design 15.1 In Class Pro iireg2.out
---1
2
3
4
5
6
7
TEMPERATURE
DEG C
---------96.68
92.42
373.98
-118.57
-146.95
237.00
342.00
PRESSURE TYPE
BAR(GA)
---------- ----41.47
1
45.64
1
219.54
2
49.42
1
32.99
1
51.27
1
55.73
1
---------0.6033
0.5850
1.0086
0.4087
0.4324
0.7998
1.1447
---------N/A
N/A
0.8215
N/A
N/A
N/A
N/A
---------N/A
N/A
0.5000
N/A
N/A
N/A
N/A
PR INTERACTION PARAMETERS
KIJ = A(I,J) + B(I,J)/T + C(I,J)/T**2 + D(I,J)*T
I
J
KA(I,J)
KB(I,J)
KC(I,J)
KD(I,J)
--- --- ---------- ---------- ---------- ---------1
2 8.300E-03
0.00
0.00
0.00
1
3
0.4800
0.00
0.00
0.00
1
4
0.0800
0.00
0.00
0.00
1
5
0.0800
0.00
0.00
0.00
2
3
0.4800
0.00
0.00
0.00
2
4
0.0800
0.00
0.00
0.00
2
5
0.0900
0.00
0.00
0.00
3
5
0.5080
0.00
0.00
0.00
4
5
-0.0119
0.00
0.00
0.00
UNITS
----DEG K
DEG K
DEG K
DEG K
DEG K
DEG K
DEG K
DEG K
DEG K
FROM
---SIMSCI BANK
SIMSCI BANK
MW CORRELATION
SIMSCI BANK
SIMSCI BANK
MW CORRELATION
SIMSCI BANK
SIMSCI BANK
SIMSCI BANK
ALL PAIRS NOT PRINTED ARE DEFAULTED TO IDEAL

FF
R
PAGE R-2
PROJECT
PROBLEM
INPUT
THERMODYNAMIC DATA
==============================================================================
THERMODYNAMIC SETS USED FOR EACH UNIT OPERATION
DEFAULT METHOD IS PR01
THERMODYNAMIC SET
----------------PR01
UNIT IDENTIFIER
--------------R1
FF
SIMULATION SCIENCES
PROJECT
PROBLEM
UNIT OPERATIONS
--------------R1
UNIT OPERATION
-------------CONVERSION REACTOR
INC.
THERMODYNAMIC SET
----------------PR01
PAGE R-3
VERSION 9.3 ELEC V9.1.3
INPUT
THERMODYNAMIC DATA
==============================================================================
PRO/II
-2-
THERMODYNAMIC METHODS USED FOR EACH SET

THERMODYNAMIC SET
PROPERTY
-------KVALUE(VLE)
KVALUE(LLE)
KVALUE(SLE)
LIQUID ENTHALPY
VAPOR ENTHALPY
LIQUID DENSITY
VAPOR DENSITY
LIQUID ENTROPY
VAPOR ENTROPY
LIQUID VISCOSITY
VAPOR VISCOSITY
LIQUID CONDUCTIVITY
VAPOR CONDUCTIVITY
SURFACE TENSION
LIQUID DIFFUSIVITY
FF
PROJECT
PROBLEM
PR01 (DEFAULT)
METHOD
-----PENG-ROBINSON
UNSPECIFIED
UNSPECIFIED
PENG-ROBINSON
PENG-ROBINSON
API
PENG-ROBINSON
PENG-ROBINSON
PENG-ROBINSON
IDEAL
IDEAL
IDEAL
IDEAL
IDEAL
UNSPECIFIED
R
PAGE H-1
PRO/II

CALCULATION
HISTORY
09/19/16
==============================================================================
Find feed total flow that results in 20,000 kt/y acrolien
*** PROBLEM SOLUTION BEGINS
FEED FLASH
COMPLETE
UNIT
1
SOLVED
- 'R1
*** PROBLEM SOLUTION REACHED
'
*** THIS RUN USED 2.00 PRO/II SIMULATION UNITS

*** RUN STATISTICS
STARTED
13:01:54 09/19/16
NO ERRORS
FINISHED
13:01:54 09/19/16
NO WARNINGS
RUN TIMES
NO MESSAGES
INTERACTIVE
0 MIN, 0.00 SEC
CALCULATIONS
0 MIN, 0.10 SEC
TOTAL
0 MIN, 0.10 SEC
FF
R
PAGE I-1
PROJECT
PROBLEM
OUTPUT
INDEX
09/19/16
==============================================================================
PAGE
CONTENTS
-3-
-----1
2
2
3
4
5
6
---------------------------------------------------------------COMPONENT DATA
CALCULATION SEQUENCE AND RECYCLES
SEQUENCE MAP
PLANT MATERIAL BALANCE
CONVERSION REACTOR SUMMARY
UNIT 1, 'R1'
STREAM MOLAR COMPONENT RATES
STREAM SUMMARY
FF
PROJECT
PROBLEM
PAGE P-1
OUTPUT
COMPONENT DATA
09/19/16
==============================================================================
COMPONENT
PRO/II
COMP. TYPE
PHASE
MOL. WEIGHT
--------------------1 PROPANE
2 PROPENE
3 H2O
4 O2
5 N2
6 ACROLEIN
7 ACRLACID
----------LIBRARY
LIBRARY
LIBRARY
LIBRARY
LIBRARY
LIBRARY
LIBRARY
----------VAP/LIQ/SOL
VAP/LIQ/SOL
VAP/LIQ/SOL
VAP/LIQ/SOL
VAP/LIQ/SOL
VAP/LIQ
VAP/LIQ
----------44.097
42.081
18.015
31.999
28.013
56.065
72.064
DENSITY
TONNE/M3
----------0.506
0.519
0.999
1.142
0.808
0.844
1.056
COMPONENT
--------------------1 PROPANE
2 PROPENE
3 H2O
4 O2
5 N2
6 ACROLEIN
7 ACRLACID
NBP
C
-----------42.040
-47.690
100.000
-182.962
-195.806
52.700
141.000
CRIT. TEMP.
C
----------96.680
92.420
373.980
-118.570
-146.950
237.000
342.000
CRIT. PRES.
BAR(GA)
----------41.467
45.637
219.537
49.417
32.987
51.270
55.729
CRIT. VOLM.
M3/TONNE-MO
----------200.0000
188.4000
55.9478
73.4000
89.2100
189.0000
210.0000
COMPONENT
ACEN. FACT.
--------------------1 PROPANE
2 PROPENE
3 H2O
4 O2
5 N2
6 ACROLEIN
7 ACRLACID
----------0.15229
0.13982
0.34486
0.02218
0.03772
0.29046
0.54640
HEAT FORM.
KCAL/TONNE-----------2.5002E+07
4707652.62
-5.7756E+07
0.00
0.00
-1.7790E+07
-7.5166E+07
G FORM.
KCAL/TONNE-----------5825451.42
1.4844E+07
-5.4598E+07
0.00
0.00
-9016838.45
-5.3825E+07
COMPONENT
--------------------1 PROPANE
2 PROPENE
DATABANK(S) USED
--------------------SIMSCI
SIMSCI
-4-
3
4
5
6
7
H2O
O2
N2
ACROLEIN
ACRLACID
SIMSCI
SIMSCI
SIMSCI
PROCESS
PROCESS
FF
PROJECT
PROBLEM
PAGE P-2
PRO/II

OUTPUT
CALCULATION SEQUENCE AND RECYCLES
09/19/16
==============================================================================
CALCULATION SEQUENCE
SEQ
--1
UNIT ID
-----------R1
UNIT TYPE
---------CONV REAC
SEQUENCE MAP
SEQ
DESCRIPTION
---- ----------------------------------------1 CONV REAC 'R1'
FF
R
PAGE P-3
PROJECT
PROBLEM
OUTPUT
PLANT MATERIAL BALANCE
09/19/16
==============================================================================
FEED STREAMS:
S1
PRODUCT STREAMS:
S2
OVERALL PLANT MOLAR BALANCE
COMPONENT
--------------------1 PROPANE
2 PROPENE
3 H2O
4 O2
5 N2
6 ACROLEIN
7 ACRLACID
-------------- TONNE-MOL/YR --------------FEED

+REACTION -PRODUCT =DEVIATION
---------- ---------- ---------- ---------1960.448
0.000
1960.448
0.000
419.682
-419.682
0.000
0.000
420.369
419.682
840.051
0.000
763.598
-451.158
312.439
0.000
3399.824
0.000
3399.824
0.000
0.000
356.730
356.730
0.000
0.000
62.952
62.952
0.000
TOTAL
6963.922
-31.476
6932.446
OVERALL PLANT MASS BALANCE

-5-
0.000
PERCENT
DEV
------0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
COMPONENT
--------------------1 PROPANE
2 PROPENE
3 H2O
4 O2
5 N2
6 ACROLEIN
7 ACRLACID
TOTAL
FF
PROJECT
PROBLEM
---------------- TONNE/YR ----------------FEED

+REACTION -PRODUCT =DEVIATION
---------- ---------- ---------- ---------86448.89
0.00
86448.89
0.00
17660.49 -17660.49
0.00
0.00
7573.06
7560.69
15133.75
0.00
24434.20 -14436.52
9997.68
0.00
95240.84
0.00
95240.84
0.00
0.00
20000.05
20000.05
0.00
0.00
4536.59
4536.59
0.00
231357.47
0.33
231357.79
0.00
PERCENT
DEV
------0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
PAGE P-4
PRO/II

OUTPUT
CONVERSION REACTOR SUMMARY
09/19/16
==============================================================================
UNIT 1, 'R1'
OPERATING CONDITIONS
REACTOR TYPE
DUTY, M*KJ/DAY
TOTAL HEAT OF REACTION AT 25.00 C, M*KJ/DAY
FEED
VAPOR PRODUCT
TEMPERATURE, C
PRESSURE, BAR(GA)
ISOTHERMAL REACTOR
-426.0033
-427.4870
INLET
----------S1
OUTLET
----------S2
350.00
2.0000
350.00
2.0000
REACTION DATA
COMPONENT
-----------------1 PROPANE
2 PROPENE
3 H2O
4 O2
5 N2
6 ACROLEIN
7 ACRLACID
TOTAL
BASE COMPONENT
-------- RATES, TONNE-MOL/YR -------FRACTION

FEED
CHANGE
PRODUCT
CONVERTED
----------- ----------- ----------- ----------1960.4484
0.0000
1960.4484
419.6823
-419.6823
0.0000
1.0000
420.3689
419.6823
840.0511
763.5979
-451.1584
312.4394
0.5908
3399.8243
0.0000
3399.8243
0.0000
356.7299
356.7299
0.0000
62.9523
62.9523
6963.9217
REACTION
-31.4762
TONNE-MOL/
CONVERTED
-6-
6932.4456
FRACTION
CONVERTED(1)
-----------------2 PROPENE
2 PROPENE
----------1
2
----------356.7299
62.9523
-----------0.8500
0.1500
(1) FRACTION CONVERTED BASED ON AMOUNT IN FEED
REACTOR MASS BALANCE
Component
-------------------1 PROPANE
2 PROPENE
3 H2O
4 O2
5 N2
6 ACROLEIN
7 ACRLACID
TOTAL
FF
PROJECT
PROBLEM
---------- Rates, TONNE/YR ---------Fraction

Feed
Change
Product
Converted
----------- ----------- ----------- ----------86448.9530
0.0000
86448.9530
17660.4980 -17660.4980
0.0000
1.0000
7573.0627
7560.6935
15133.7562
24434.2156 -14436.5288
9997.6868
0.5908
95240.9068
0.0000
95240.9068
0.0000
20000.0629
20000.0629
0.0000
4536.5976
4536.5976
231357.6360
0.3273
231357.9633
PAGE P-5
OUTPUT
STREAM MOLAR COMPONENT RATES
09/19/16
==============================================================================
PRO/II
STREAM ID
NAME
PHASE
THERMO ID
S1
S2
WET VAPOR
PR01
WET VAPOR
PR01
FLUID
1
2
3
4
5
6
7
1960.4484
419.6823
420.3689
763.5979
3399.8243
0.0000
0.0000
1960.4484
0.0000
840.0511
312.4394
3399.8243
356.7299
62.9523
6963.9217
6932.4456
350.0000
2.0000
516.6075
33.2223
1.0000
0.0000
0.0000
0.0000
350.0000
2.0000
592.4093
33.3732
1.0000
0.0000
0.0000
0.0000
RATES, TONNE-MOL/YR
PROPANE
PROPENE
H2O
O2
N2
ACROLEIN
ACRLACID
TOTAL RATE, TONNE-MOL/YR

TEMPERATURE, C
PRESSURE, BAR(GA)
ENTHALPY, M*KJ/DAY
MOLECULAR WEIGHT
MOLE FRAC VAPOR
MOLE FRAC TOTAL LIQUID
MOLE FRAC H/C LIQUID
MOLE FRAC FREE WATER
FF
-7-

PROJECT
PROBLEM
PAGE P-6
OUTPUT
STREAM SUMMARY
09/19/16
==============================================================================
STREAM ID
NAME
PHASE
THERMO ID
PRO/II
S1
S2
WET VAPOR
PR01
WET VAPOR
PR01
----- TOTAL STREAM ----RATE, TONNE-MOL/YR

K*TONNE/YR
TEMPERATURE, C
PRESSURE, BAR(GA)
MOLECULAR WEIGHT
ENTHALPY, M*KJ/DAY
KCAL/TONNE
MOLE FRACTION LIQUID
MOLE FRACTION FREE WATER
6963.922
231.357
350.000
2.000
33.222
516.608
194797.078
0.00000
0.00000
6932.446
231.358
350.000
2.000
33.373
592.409
223379.319
0.00000
0.00000
----- TOTAL VAPOR -----RATE, TONNE-MOL/YR

K*TONNE/YR
ACTUAL K*M3/YR
NORM VAP RATE(1), K*M3/YR
MOLECULAR WEIGHT
ENTHALPY, KCAL/TONNE
CP, KCAL/TONNE-C
ACTUAL DENSITY, TONNE/K*M3
Z (FROM ACTUAL DENSITY)
THERMAL COND, KCAL/HR-M-C
VISCOSITY, CP
KVIS (VISC/DENS), CSTOKE
6963.922
231.357
119754.216
156089.172
33.222
194797.078
462.497
1.932
1.0001
0.04653
0.02501
12.9456
6932.446
231.358
119175.382
155383.666
33.373
223379.319
463.471
1.941
0.9998
0.04534
0.02411
12.4168
----- TOTAL LIQUID ----RATE, TONNE-MOL/YR

K*TONNE/YR
M3/YR
ACTUAL GAL/MIN
STD LIQ RATE, M3/YR
MOLECULAR WEIGHT
ENTHALPY, KCAL/TONNE
CP, KCAL/TONNE-C
ACTUAL DENSITY, TONNE/M3
Z (FROM ACTUAL DENSITY)
SURFACE TENSION, DYNE/CM
TH COND, KCAL/HR-M-C
VISCOSITY, CP
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
(1) NORMAL VAPOR VOLUME IS 22.414 M3/KG-MOLE (0 C AND 1 ATM)

-8-
FF
PROJECT
PROBLEM
PAGE P-7
OUTPUT
STREAM SUMMARY
09/19/16
==============================================================================
STREAM ID
NAME
PHASE
THERMO ID
PRO/II
S1
S2
WET VAPOR
PR01
WET VAPOR
PR01
------ DRY STREAM -----RATE, TONNE-MOL/YR

K*TONNE/YR
STD LIQ RATE, M3/YR
MOLECULAR WEIGHT
MOLE FRACTION LIQUID
REDUCED TEMP (KAYS RULE)
PRES (KAYS RULE)
ACENTRIC FACTOR
WATSON K (UOPK)
STD LIQ DENSITY, TONNE/M3
SPECIFIC GRAVITY
API GRAVITY
6543.553
223.784
344244.326
34.199
0.0000
2.8604
0.0767
0.0768
10.070
0.650
0.6507
85.953
6092.394
216.224
325547.964
35.491
0.0000
2.6678
0.0775
0.0938
10.035
0.664
0.6648
81.333
------ DRY VAPOR ------RATE, TONNE-MOL/YR

K*TONNE/YR
K*M3/YR
NORM VAP RATE(1), K*M3/YR
SPECIFIC GRAVITY (AIR=1.0)
MOLECULAR WEIGHT
CP, KCAL/TONNE-C
DENSITY, TONNE/K*M3
VISCOSITY, CP
6543.553
223.784
112528.442
146667.034
1.181
34.199
461.720
1.989
0.04677
0.02513
12.6379
6092.394
216.224
104740.259
136554.780
1.225
35.491
461.906
2.064
0.04570
0.02427
11.7589
------ DRY LIQUID -----RATE, TONNE-MOL/YR

K*TONNE/YR
M3/YR
GAL/MIN
STD LIQ RATE, M3/YR
SPECIFIC GRAVITY (H2O=1.0)
MOLECULAR WEIGHT
CP, KCAL/TONNE-C
DENSITY, TONNE/M3
SURFACE TENSION, DYNE/CM
VISCOSITY, CP
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
-9-
(1) NORMAL VAPOR VOLUME IS 22.414 M3/KG-MOLE (0 C AND 1 ATM)
-10-

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E:\CHEG 403 - Process Design and Evaluation\Design 15.1 In Class Pro iireg2.

Monday, September 19, 2016 1:03 PM

$ Generated by PRO/II Keyword Generation System <version 9.3>

PR PURE COMPONENT DATA

Monday, September 19, 2016 1:03 PM

ALL PAIRS NOT PRINTED ARE DEFAULTED TO IDEAL

Monday, September 19, 2016 1:03 PM

THERMODYNAMIC METHODS USED FOR EACH SET

VERSION 9.3 ELEC V9.1.3

*** THIS RUN USED 2.00 PRO/II SIMULATION UNITS

Monday, September 19, 2016 1:03 PM

Monday, September 19, 2016 1:03 PM

VERSION 9.3 ELEC V9.1.3

OVERALL PLANT MOLAR BALANCE

-------------- TONNE-MOL/YR --------------FEED

OVERALL PLANT MASS BALANCE

Monday, September 19, 2016 1:03 PM

---------------- TONNE/YR ----------------FEED

VERSION 9.3 ELEC V9.1.3

-------- RATES, TONNE-MOL/YR -------FRACTION

Monday, September 19, 2016 1:03 PM

(1) FRACTION CONVERTED BASED ON AMOUNT IN FEED

REACTOR MASS BALANCE

---------- Rates, TONNE/YR ---------Fraction

TOTAL RATE, TONNE-MOL/YR

SIMULATION SCIENCES INC.

Monday, September 19, 2016 1:03 PM

----- TOTAL STREAM ----RATE, TONNE-MOL/YR

----- TOTAL VAPOR -----RATE, TONNE-MOL/YR

----- TOTAL LIQUID ----RATE, TONNE-MOL/YR

(1) NORMAL VAPOR VOLUME IS 22.414 M3/KG-MOLE (0 C AND 1 ATM)

Monday, September 19, 2016 1:03 PM

------ DRY STREAM -----RATE, TONNE-MOL/YR

------ DRY VAPOR ------RATE, TONNE-MOL/YR

------ DRY LIQUID -----RATE, TONNE-MOL/YR

Monday, September 19, 2016 1:03 PM

(1) NORMAL VAPOR VOLUME IS 22.414 M3/KG-MOLE (0 C AND 1 ATM)

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