Teaching Plan2015-2016

Mahishadal Raj College: Department of Chemistry

Teaching Plan : 2015-2016

PART- I PAPER-II
Level: B.Sc. (Honours) Part-I * Paper-II, Marks-50

Physical Chemistry (Theoretical)

Schedule:
Duration
From 1ST July to
3rd week of
September
From 1st week of
November to 3rd
week of December
From 1st January
to 31st March

Module
No.
1

Unit No.

No. of
Classes

Unit I +Unit III

44

Examination
1stIntertnal
Assesment
Total

Unit I + Unit II + Unit III +

Unit IV

28

Unit II + Unit IV

48

MahishadalRajCollege : Dept. of Chemistry

: 120

2ndIntertnal
Assesment

Teaching Plan2015-2016

Module
1
G
A
S
AND
S
U
R
F
A
C
E
T
E
N
S
I
O
N

Topics

No. of
Lecturers

Teacher(s)

16

SK

Unit I

Gas:
Distribution of components of molecular speed and kinetic
energy. Maxwell molecular speed distribution, K.E.
distribution, calculation of average quantities, different
types of speeds, velocities. Barometric distribution. Principle
of equipartition of energy, degree offreedom, calculation of
Cpand Cv, variation with temperature.

Collision of gases:
collision diameter, collision cross-section, collision
frequency, collision density, mean free path, viscosity of
gases, effect of pressure and temperature. Wall collision and
rate of effusion.

6
SK

Unit II

Surface tension:
AND
A
D
S
O
R
P
T
I
O
N
AND
C
O
L
L
O
I
D

Properties of liquid, vapour pressure equation,

surfacetension, surface energy, interface, effect of
temperature (Etvs equation, critical temperature),
determination of surface tension (capillary rise, capillary
depression, stalagmometer), excess pressure inside
bubbleand drops (basic idea of the Young-Laplace
equation), cohesion, adhesion, work of cohesion and
adhesion, spreading of liquid over other surface.

08

Adsorption:

06

Physical and chemisorption, adsorption isotherms:

Freundlich, Langmuir andGibbs absorption isotherms,
surface excess, BET equation (no derivation).

MM

08

Colloidal state:
Definition,
colloids
classification,
properties,
ultracentrifuge, electrokinetic phenomena, zeta potential,
iso-electric point, Schulze-Hardy rule, protective colloids,
gold number, Perrin method for determination of Avogadro
number, colloidal electrolytes, CMC values, emulsions, gels,
thixotropy.

MahishadalRajCollege : Dept. of Chemistry

MM

MM
44

Teaching Plan2015-2016

Module
Topics
2
G
Unit I
A
S
Real gases:
Compressibility factor, Andrews and Amagats curves,
AND
continuity of state.van der Waals equation of state, virial
equation, critical state, critical parameters in terms of van
T
der Waals constants, determination of critical constants, law
H
of corresponding states.
E
R
Unit II
M
O
ThermodynamicsI
D
Scope, definition of systems (isolated, closed, open),
Y
surroundings, boundary, different types of processes,
N
variables (intensive and extensive), functions (state and
A
path). Partial and total derivative, Eulers reciprocity, cycle
M
rule, exact and inexact differentials, slopes.
I
C
Unit III
S

Viscosity:

AND
V
I
S
C
O
S
I
T
Y
AND
K
I
N
E
T
I
C
S

No. of
Lecturers

Teacher(s)

06

SK

08

SK

06

MM

08

MM

Definition, viscosity of gas and liquid and effect of

temperature, laminar and turbulent flow, Newtonian, nonNewtonian fluid,Newtons law of viscosity, Poiseuilles law,
viscosity coefficient, effect of temperature on viscosity
coefficient, measurement (Ostwald viscometer, falling
sphere method).
Unit IV

Chemical Kinetics:
Rate law, integrated rate law, advancement of reaction,
order, molecularity. Zero, first, second, higher and pseudofirst order reactions. Determination of order of reaction,
temperature dependence of reaction rates, Arrhenius
equation, activation
energy.
Elementary
reactions;multi-step
reactions:
consecutive, opposing,and parallel reactions(all first order).

MahishadalRajCollege : Dept. of Chemistry

28

Teaching Plan2015-2016

Module
3

Topics

No. of
Lecturers

Teacher(s)

14

SK

Unit I
T
H
E
R
M
O
D
Y
N
A
M
I
C
S
AND
K
I
N
E
T
I
C
S
AND
C
A
T
A
L
Y
S
I
S

Zeroth and first laws of thermodynamics:

Heat and work (reversible, irreversible, isothermal,
adiabatic), Internal energy, enthalpy, Joules experiment
(ideal and van der Waals gas), different types of heat
capacities. Second law of thermodynamics, Carnot and
refrigeration cycles, entropy change, Clausius inequality,
Gibbs and Helmholtz free energies, GibbsHelmholtz
equation, equilibrium and spontaneity criteria. Maxwells
relations and the thermodynamic equations of state,
Combination of first and second law of thermodynamics.
JouleThomson experiment (ideal and van der Waals gas).

Thermochemistry:
Thermochemical equation, Kirchoffs equations, different
type of heats of reactions (entropy, enthalpy and Gibbs
energy) and their standard state. Hesss law, Lavoisier and
Laplaces law.

10

SK

Unit II

Collision theory:
Unimolecular (Lindemann) and bimolecular reactions;
transition state theory (TST), entropy of activation, Eyring
equation, primary kinetic salt effect, relation between TST
and hard sphere collision theory.

MM
08

Catalysis:
Definition, catalyst and inhibitor, criteria of catalysis, types
of catalysis (homogeneous and heterogeneous), autocatalytic reaction. Theory of acid-base catalysis with
examples.

MM
10
MM

Enzyme catalysis:
Properties of enzymes, MichaelisMenten equation,
Lineweaver Burk equation, turnover frequency, catalytic
efficiency, effect of temperature and pH.

06

48

MahishadalRajCollege : Dept. of Chemistry

Teaching Plan2015-2016

Mahishadal Raj College: Department of Chemistry

Teaching Plan : 2015-2016

PART- II PAPER-IV
Level: B.Sc. (Honours) Part-II * Paper-IV, Marks-50

Physical Chemistry (Theoretical)

Schedule:

Duration
From 1ST July to
3rd week of
September
From 1st week of
November to 3rd
week of December
From 1st January
to 31st March

Module
No.
1

Unit No. (as per V.U.

syllabus)
Unit 1 + Unit II + Unit IV

No. of
Classes

1stIntertnal
Assesment

44
Total

Examination

Unit 1 + Unit II

28

Unit III + Unit IV

48

MahishadalRajCollege : Dept. of Chemistry

: 120

2ndIntertnal
Assesment

Teaching Plan2015-2016

Module
1
C
O
L
L
I
G
A
T
I
V
E
P
R
O
P
E
R
T
I
E
S
AND
E
Q
U
I
L
I
B
R
I
U
M
AND
C
O
N
D
U
C
T
I
O
N

Topics

No. of
Lectures

Teacher(s)

10

SK

12

SK

Unit I

Colligative properties:
Solutions
Ideal solutions, thermodynamic properties of binary
solution, colligative properties. Raoults laws.
Colligative properties
relative lowering of vapour pressure, elevation of boiling
point, depression of freezing point, vant Hoffs law for
osmotic pressure, statement, derivation (using chemical
potential), application, critical comment on limitation.
Abnormal colligative properties, vant Hoffs factor,
deviation from ideality (negative, positive). Duhem
Margules relation, Konowaloffs rule, non-ideal and ideally
dilute solutions.
Unit II

Chemical equilibrium:
Extent of reaction, law of mass action, thermodynamic
equilibrium constant, Kp, Kc and Kxand relationship between
them, effect of temperature, pressure and addition of inert
gas on equilibrium and equilibrium constant, Le
Chatelierprinciple,vant Hoff isotherm and equation.
Examples of equilibria in homogenous and heterogeneous
systems.

06

MM

Unit III

Electrolytic conduction:
Conductance, conductivity, molar and equivalent
conductivities, limiting molar conductivity, measurement,
variation with dilution, Ostwalds dilution law, ionic
mobility, Kohlrausch law, asymmetry effect, electrophoretic
effect, temperature dependence of ion conductivity. Stokes
law, Hittorfs rule, conductivity of ions in aqueous and nonaqueous
solvent,
Debye-Huckell-Onsagar
equation
(noderivation), Debye-Falkenhagen effect and Wien effect,
application of conductance measurement, conductometric
titration, Transport number, abnormal transport number,
solvation of ions, measurement of transport numbers
(moving boundary method).

MahishadalRajCollege : Dept. of Chemistry

16
MM

44

Teaching Plan2015-2016

Module
2

T
H
E
R
M
O
D
Y
N
A
M
I
C
S
AND
I
O
N
I
C
E
Q
U
I
L
I
B
R
I
U
M

No. of
Lectures

Topics

Teacher(s)

Unit I

Thermodynamics-II
Clapeyron equation
Clapeyron
equation,
ClausiusClapeyron
equation,
Troutons rule. Open systems, activity, fugacity, activity
coefficients,partial molar quantities, chemical potential.
Thermodynamics of mixing
Thermodynamics of mixing ( mixG, mixS, mixH), Gibbs
Duhem equation.

07

07

SK

SK

Unit II

Ionic Equilibrium:

14

Introduction
Debye-Huckel limiting law (no derivation), solubility and
solubility product, ionic product of water, pH, Henderson
equation,.

06

MM

04

MM

04

MM

Buffer solutions
concept of buffer solution, buffer capacity, hydrolysis.
Indicators
Indicators (acid base, adsorption, redox, metal ion).

MahishadalRajCollege : Dept. of Chemistry

28

Teaching Plan2015-2016
Module
3
Q
U
A
N
T
U
M
M
E
C
H
A
N
I
C
S

Unit III

No. of
Lectures

Topics

Quantum mechanics1:
Introduction
Drawback of classical mechanics, stability of
atom, black body radiation, photoelectric effect; Compton
effect, waveparticle duality, de Broglie hypothesis,
Heisenbergs uncertainty principle.
Operators
Concept of operators, different types of operators,
properties
and
interpretation
of
wavefunctions
(normalization, orthogonality, probability distribution)
eigen function, eigen values. Commutation of operators,
commutators, theorem, postulates of quantum mechanics,

E
M
F

06

SK

08
SK

Schrodinger equation
Time-dependent and time-independent Schrodinger
equation, stationary state, stationary state wavefunction,
applications, free particle, boundary condition.
10

1
AND

Teacher(s)

SK

Unit IV

Electromotive Force:
Introduction
Electrochemical cell, reversible and irreversible, EMF and
electrical work, measurement of EMF, temperacture coefficient
of EMF, standard cell, different type of electrodes,
electrodepotential,
Nernst equation
Nernsts equation, standard electrode potential, reference
electrode, (hydrogen, quinhydrone, glass, calomel), chemical
and concentration cells, liquid junction potential, salt
bridge,
Applications
Applications of potentiometric measurement.

MM

08

MM
12
MM
04

48

MahishadalRajCollege : Dept. of Chemistry

Teaching Plan2015-2016

Mahishadal Raj College: Department of Chemistry

Teaching Plan : 2015-2016

PART- III PAPER-VII
Level: B.Sc. (Honours) Part-III * Paper-VII, Marks-50

Physical Chemistry (Theoretical)

Schedule:

Duration
From 1ST July to
3rd week of
September
From 1st week of
November to 3rd
week of December
From 1st January
to 15TH March

Module
No.
1

Unit No. (as per V.U.

syllabus)

No. of
Classes

Unit I + Unit II

44

1stIntertnal
Assesment
Total

Examination

Unit II + Unit III

28

Unit III + Unit IV

48

MahishadalRajCollege : Dept. of Chemistry

: 120 2ndIntertnal
Assesment

Teaching Plan2015-2016

Module
1
Q
U
A
N
T
U
M
M
E
C
H
A
N
I
C
S
-II
AND
M
O
L
E
C
U
L
A
R
G
E
O
M
E
T
R
Y

Topics

No. of
Lecturers

Teacher(s)

08

SK

Unit I

Quantum mechanicsII:
Particle in one dimensional box
Introduction,wavefunction,normalized
wavefuction,
probability of finding of particle, expectation values (<x>,
<x2>, <px>, <px2> etc.), uncertainty, particle in
onedimensional box, degeneracy, tunneling effect.
Simple harmonic oscillator
Introduction,
Schrodinger
equation,
energy
(no
derivation)wavefunction (no derivation), probability
density, expectation values,uncertaninty.Rigid rotator,
Schrodinger equation, energy (no derivation)wavefunction
(no derivation).
Hydrogen atom
Hydrogen-like
system,
Schrodinger
equation
in
polarcoordinates, radial solution, radial wavefunction, real
hydrogen-likewavefunction, probability density, probability
of finding ofelectron, radial distribution function, quantum
numbers, energyexpression (no derivation), degeneracy,
concept of orbitals (s,p,d) andshapes.

06
SK

08

SK

Unit II
10

Molecular geometry:

MM

Dipole moment
Polarization,
dipole
moment,
permittivity,
relativepermittivity,
Debye-Langevin
equation
(No
derivation), Clausius-Massotiequation (No derivation),
application towards explanation of structure.
12
Spectroscopy
Microwave and I.R spectra energy expressions
(noderivation) selection rule applications, potential energy
diagram, Franck-Condon principle, Raman spectra,
comparison with fluorescence.

MahishadalRajCollege : Dept. of Chemistry

44

10

MM

Teaching Plan2015-2016

Module
2
P
H
O
T
O
C
H
E
M
I
S
T
R
Y
AND
S
O
L
I
D

Topics

No. of
Lecturers

Teacher(s)

08

MM

06

MM

Unit I

Photochemistry:
Introduction
Thermal versus photochemical reactions, Grotths-Draper
law, Lambert-Beers law, Einsteins law of photochemical
equivalence, quantum yield, actinometer, effect of
adsorption of light, phosphorescence, fluorescence.
Photochemical reactions
Decomposition of HI and combination of H2 and Br2 , photostationary state, Jabolonsky diagram.

Unit II

Crystalline state:

SK

Introduction
Laws of Crystallography, unit cell, lattice, different
crystalline systems with characteristics.

06

Braggs equation
Introduction, application towards structure of NaCl and
KCl.

02

SK

06

SK

Specific heats of solid elements

Introduction, Dulong-Petits law, limitations, Einsteins
equation, success and limitations, Debyes T3 law (no
derivation).

MahishadalRajCollege : Dept. of Chemistry

11

28

Teaching Plan2015-2016

Module
3
T
H
E
R
M
O
D
Y
N
A
M
I
C
S
AND
P
H
A
S
E
R
U
L
E

Topics

No. of
Lecturers

Teacher(s)

04

SK

Unit III

ThermodynamicsIII:
Third law of thermodynamics
Introduction, Nernst heat theorem, Lewis-Randall
statement Plank statement.
Statistical Thermodynamics
Introduction, Macrostates and microstates, Ensemble,
mathematical
probability
versusthermodynamic
probability,thermodynamic probability and the concept of
entropy.

10

Partition function
Introduction
and
representation
of
the
thermodynamicfunctions; Boltzmann distribution, nondegenerate and degenerate cases.

10

SK

SK

Unit IV

Phase Equilibrium:
Introduction
Phase, phase stability, first-order phase transition,
transition temperature, phase boundary, slope of phase
boundary, vapour pressure, critical point, boiling point and
melting point (normal and standard).

04

Nernst distribution law

Henrys law, Nernsts distribution law, solvent extraction,
phase, component, degree of freedom, phase rule, derivation
from thermodynamics.

08

Examples of various types of systems

One component system, (water, CO2 and sulphur), triple
point. Two component system liquid-liquid and solid-liquid
systems (phenol-water, triethylamine-water, nicotine-water)
isopleths, tie-line, lever rule, critical solution temperature,
simple eutectic compound with congruent and incongruent
melting points, peritectic line.

12

48

MahishadalRajCollege : Dept. of Chemistry

12

MM

MM

MM