Professional Documents
Culture Documents
by
ABSTRACT
The objective of this thesis is to better understand the impact of paper and printer types
on xerographic print quality. To achieve this objective, commercially printed samples
comprising of ten different paper substrates printed using three different xerographic
printers were examined. The print quality of these samples was assessed in terms of
print microgloss and its nonuniformity, print density, print and gloss mottle, print
roughness, and visual ranking. This study showed that print mottle conducted by Fast
Fourier Transform produced the best correlation with visual ranking at the size range of
0.1 - 1mm, while print gloss mottle was found to affect print quality regardless of the
mottle size. Brightness, opacity, basis weight, gloss 75o, and roughness of these paper
substrates were found to have the most significant effect on print quality. All of the
optical properties of paper included in this analysis showed a strong correlation to print
quality.
ii
ACKNOWLEDGMENTS
First and foremost, I would like to thank my co-supervisors, Professor Ramin Farnood
and Professor Ning Yan, for their continuous support, valuable advices and excellent
guidance. I would like to acknowledge members of the Surface Science III Consortium
and U of T pulp and paper center and forestry group for their funding and contributions
to the visual ranking analysis respectively.
Thanks to Carlos Quijano for his excellent and selfless guidance in PLS analysis, Neetu
Chhabra for writing the print mottle MATLABTM algorithm, and Sabina Di Risio for her
help with the X-rite densinometer and countless advice in the writing and presentation of
this thesis. I would also like to thank my colleagues and friends from the Pulp and Paper
Centre: Stacy, Yaldah, Kieron, Pooya, Chong, Turn, Peter, and Pawel for making my 2year program an enjoyable experience.
Last but not least, I would like to express my deepest gratitude to my family back in
Singapore for their emotional and financial support. I would also like to thank myself for
not giving up when I am faced with a harsh situation and motivating myself to continue
with this project. Finally, special thanks to my good friends: Stacy, Song, Emily, Ken, and
Jennifer for their continuous support and words of encouragements throughout these
years and for bringing me food during the busiest period of this study (i.e. writing of this
thesis).
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TABLE OF CONTENTS
ABSTRACT ....................................................................................................................ii
ACKNOWLEDGMENTS ................................................................................................iii
TABLE OF CONTENTS.................................................................................................iv
LIST OF TABLES .........................................................................................................vii
LIST OF FIGURES.......................................................................................................viii
LIST OF ACRONYMS....................................................................................................xi
CHAPTER 1
1.1
INTRODUCTION .............................................................................1
CHAPTER 2
BACKGROUND ..............................................................................4
2.1
Introduction..........................................................................................................4
2.2
Paper.....................................................................................................................4
2.2.1 Composition, Formation, Coating, & Finishing.......................................4
2.2.2 Paper Parameters......................................................................................6
2.2.2.1 Structure & Composition .....................................................................6
2.2.2.2 Optical & Appearance of Paper...........................................................8
2.2.2.3 Electrical & Thermal Properties of Paper...........................................11
2.2.3 Impact of Paper Property on Print Quality ............................................13
2.3
Xerographic Printing..........................................................................................15
2.3.1 A Brief Overview .....................................................................................16
2.3.2 Impact of Xerographic Print Parameters on Print Quality....................19
2.4
2.4.2.2
2.5
Other Attributes.................................................................................27
CHAPTER 3
3.1
Overview.............................................................................................................31
3.2
3.3
Xerographic Printing..........................................................................................32
3.3.1 Printers & Printing Conditions ...............................................................32
3.3.2 Sample Preparation ................................................................................33
3.4
CHAPTER 4
4.1
Introduction........................................................................................................50
4.2
4.3
4.4
CHAPTER 5
5.1
Conclusions .......................................................................................................85
5.2
REFERENCES..............................................................................................................87
APPENDICES...............................................................................................................93
Appendix A Microgloss OPTIMASTM 6.0 Program ..................................................93
Appendix B Print Mottle and Gloss Mottle MATLABTM Program...........................94
Appendix C SEM Detailed Procedure ...................................................................100
Appendix D Raw Data ............................................................................................102
Appendix E Additional Plots..................................................................................108
Appendix F 3D Topographic Maps........................................................................112
vi
LIST OF TABLES
Table 2-1. List of Paper Property & their Impact............................................................14
Table 2-2. List of Print Parameters and their Impact .....................................................19
Table 2-3. List of Paper Parameters to be Correlated ...................................................30
Table 3-1. Paper Sample Description............................................................................31
Table 3-2. Print Parameters ..........................................................................................32
Table 3-3. Resolution and Scanning Area of WYKOTM NT-2000 [22] ............................43
Table 4-1. List of Paper Properties................................................................................51
Table 4-2. Print Quality of 100% Black Print Samples...................................................52
Table 4-3. Print Roughness Data: RMS, Skewness, & Kurtosis ....................................63
Table 4-4. Correlation as Measured by R2 between Print Mottle and Paper Roughness
Measured using Different Methods on Samples Printed with Different Laser Printers
...............................................................................................................................64
Table 4-5. PLS Raw Data for Paper versus Print Quality ..............................................71
Table D-1. Paper Gloss, Microgloss, & Nonuniformity for Different Paper Samples ....102
Table D-2. Print Gloss, Microgloss, & Nonuniformity for HP2600 Print Samples .........102
Table D-3. Print Gloss, Microgloss, & Nonuniformity for HP4700 Print Samples .........103
Table D-4. Print Gloss, Microgloss, & Nonuniformity for HP9500 Print Samples .........103
Table D-5. Paper & Print Roughness (Rq) for Different Paper & Print Samples ...........104
Table D-6. Print Density for Different Print Samples....................................................104
Table D-7. Power Spectrum for HP2600 Print Samples (Grayscale) ...........................105
Table D-8. Power Spectrum for HP4700 Print Samples (Grayscale) ...........................105
Table D-9. Power Spectrum for HP9500 Print Samples (Grayscale) ...........................106
Table D-10. Power Spectrum for HP2600 Gloss Samples (Grayscale) .......................106
Table D-11. Power Spectrum for HP4700 Gloss Samples (Grayscale) .......................107
Table D-12. Power Spectrum for HP9500 Gloss Samples (Grayscale) .......................107
vii
LIST OF FIGURES
Figure 1-1. Summary of Thesis Approach ......................................................................1
Figure 2-1. Illustration of Different Levels of Surface Roughness Measurement .............7
Figure 2-2. Schematic Diagram Illustrating Specular and Diffuse Gloss .......................11
Figure 2-3. Schematic Diagram Illustrating Thermal Printing ........................................13
Figure 2-4: Cyclic Color Xerography.............................................................................16
Figure 2-5. Image Developer: Carrier Beads & Toner Particles ....................................17
Figure 2-6. Schematic Diagram of a Brush Cleaning Subsystem..................................18
Figure 2-7. Gloss Measurement Geometry...................................................................20
Figure 2-8. Visual Evaluation: (a) perpendicular and (b) hand-held ..............................27
Figure 2-9. Image Resolution: (a) desired line representing the devices native
resolution, (b) line rendering of each pixel on the line, and (c) line rendering with
some pixels rendered gray .....................................................................................28
Figure 3-1. Schematic Diagram of a Printed Paper Sample..........................................32
Figure 3-2. Sample Preparation....................................................................................33
Figure 3-3. (a) NOVO-GLOSSTM glossmeter and (b) calibration tile..............................34
Figure 3-4. Microgloss Setup [18, 29] ...........................................................................35
Figure 3-5. Schematic Diagram of a Microgloss Image Captured ................................35
Figure 3-6. Autocorrelation Plot of Grey Level ..............................................................37
Figure 3-7. X-Rite 500 Series Spectrodensitometer......................................................38
Figure 3-8. Print Mottle Analysis ...................................................................................39
Figure 3-9. WYKOTM NT-2000 Surface Scanner [22] ..................................................41
Figure 3-10. Interference Microscope (WYKOTM NT-2000) [22] ....................................42
Figure 3-11. KLA Tencor P-16+ Stylus Profiler..............................................................44
Figure 3-12. KLA Tencor P-16+ Stylus Tip ....................................................................45
Figure 3-13. SEM Image of Print Sample Showing White Spots ...................................46
Figure 3-14. EDX Plot Showing Elements Present in Print Image.................................47
Figure 3-15. General View of an Optical Microscope ....................................................47
Figure 3-16. Printed Sample Image at Different Focal Planes ......................................48
Figure 3-17. Pairwise Ranking Procedure ....................................................................49
Figure 4-1. Impact of Paper Microgloss on Print Microgloss .........................................54
viii
Figure 4-30. Variable Importance Plot of PC[1] for Paper versus Print Mottle ...............78
Figure 4-31. Impact of Different Paper Samples Printed using Three Different Printers
on Visual Ranking ..................................................................................................79
Figure 4-32. Plot of HP 4700 and HP 9500 Ranking vs. HP 2600 Ranking...................80
Figure 4-33. Optical Microscopic Images of the Worse Rated 100% Black Samples
Corresponding to (a) HP 2600, (b) HP 4700, and (c) HP 9500 series and the Best
Rated Samples for (d) HP2600, (e) HP 4700, and (f) HP 9500 at 10X Magnification
...............................................................................................................................81
Figure 4-34. Optical Microscopic Images of the Worse Rated 40% Black Samples
Corresponding to (a) HP 2600, (b) HP 4700, and (c) HP 9500 series and the Best
Rated Samples for (d) HP2600, (e) HP 4700, and (f) HP 9500 at 50X Magnification
...............................................................................................................................82
Figure 4-35. Optical Microscopic Images of the Worse Rated 40% Black Samples
Corresponding to (a) HP 2600, (b) HP 4700, and (c) HP 9500 series and the Best
Rated Samples for (d) HP2600, (e) HP 4700, and (f) HP 9500 at 10X Magnification
...............................................................................................................................82
Figure 4-36. Microgloss Images of Paper Corresponding to (a) Best Rated Sample and
(b) Worst Rated Sample in HP 9500 series and 100% Black Coverage of (c) Best
Rated Sample and (d) Worst Rated Sample in HP 9500 series..............................83
Figure 4-37. EDX Analysis on White Spots Present in Print Sample.............................84
Figure 4-38. EDX Plot Showing Presence of Calcium in White Spot Tested .................84
Figure A-1. Microgloss Data Analysis ...........................................................................93
Figure A-2. Microgloss Histogram Saturated data that requires autocorrelation ........93
Figure B-1. Print Mottle Program: Power Spectrum Output ..........................................98
Figure C-1. Schematic Diagram of a Detailed SEM Scanning Process.......................100
Figure E-1. Coefficient Plot of PC[1] and Y-Variable HP 4700 and HP 9500...............108
Figure E-2. Coefficient Plot of PC[2] and Y-Variable HP 2600, 4700 and 9500...........109
Figure E-3. Print Mottle versus Paper Roughness (PPS)............................................110
Figure E-4. Print Mottle versus Paper Roughness (WYKO) ........................................110
Figure E-5. WYKO Images of Paper Corresponding to (a) Worst Rated Sample and (b)
Best Rated Sample in HP 9500 series and 100% Black Coverage of (c) Worst
Rated Sample and (d) Best Rated Sample in HP 9500 series..............................111
Figure F-1. 3D Topographic Maps Illustrating the Print Surface of the 10 Different Paper
Samples Printed Using 3 Different Printers ..........................................................113
x
LIST OF ACRONYMS
AFM
CD
Cross Direction
CLJ
Color LaserJet
dpi
EDX
Energy-Dispersive X-ray
IP
International Paper
MD
Machine Direction
MLR
ms
Milliseconds
PC
Principal Component
PCA
PLS
PLSR
ppm
PPS
PSI
RGB
SEM
SS
Seam-side
VIP
VSI
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CHAPTER 1
INTRODUCTION
Over the past decade, there has been an extensive transformation in the performance of
xerographic printers. Dramatic gains have been made in four key areas: cost,
throughput, reliability and most significantly, print quality [1]. As the printing industry
continues to reduce cost and improve the quality of xerographic printers, the effective
measurement of print quality becomes increasingly important [2]. However, it is difficult
to define print quality objectively because the concept of print quality is subjective and
depends highly on the perception of potential observers [1, 3].
Since the ultimate goal for any printed product is to satisfy the customers requirements,
print quality should be assessed and defined by paper end-users. Some common
attributes of print quality include edge sharpness, contrast in lightness and color,
roughness, background noise, resolution, gloss mottle, and optical density or
homogeneity [1, 4, 5]. Visual ranking analysis is one of the methods used to quantify
consumers perception. However, to help with producing higher print quality products at
minimum cost, visual rankings need to be correlated with other measurable objective
print qualities. In addition, factors that affect print quality have to be determined. These
factors can be grouped into either paper properties or printing parameters [6, 7].
Previous researches have shown that main paper factors affecting print quality included
paper surface and structural properties, such as surface roughness, electrical resistivity,
moisture content, thickness, thermal conductivity, and optical properties such as
brightness and opacity [8-10]. The web formation of paper, types of fibers used
(hardwood or softwood), coat weight and formulations, amount of fillers/additives, and
calendering conditions during papermaking are parameters that control paper properties.
These parameters alter the surface morphological properties such as roughness and
optical properties such as paper reflectance.
Printer parameters that may contribute to the difference in print qualities include toner
particle characteristics, such as toner size, toner adhesion, melting temperature, heat
capacity, and printer settings, such as fusing temperature fuser dwell time and fuser roll
speed [11-16]. In xerographic printing, fusing is the stage where the toner spreads,
1
sinters, and penetrates into paper [6]. Since it is the last stage in the xerographic
process, it dominates the final physical and optical print quality.
Many previous studies have focused on issues related to printing factors that can affect
print quality (mainly on print gloss or print respectively) and paper properties that affect
other print qualities such as runnability, adhesion, and fusing effect. Even though it is
well known that different papers and printers have a significant effect on print quality, the
relationship between paper properties and xerographic print quality is still not well
understood. In addition, past researches primarily studied the effects of paper on offset
and ink-jet print qualities rather than on xerographic print qualities. However, it is equally
important to look into paper properties that can affect xerographic print qualities such as
print gloss nonuniformity, print density, print mottle, and surface topography - roughness.
Due to the long list of paper properties that can affect the print quality, there is a need to
identify the critical paper properties of importance. Moreover, it is highly beneficial for
papermaker to understand how different paper grades contribute to both objective and
subjective print qualities under different printing conditions.
1.1
Figure 1-1 summarizes the general research approach untaken in this thesis. The
background and previous work related to paper properties and print quality evaluation
are covered in Chapter 2 while Chapter 3 provides detailed experimental and
instrumentation methods. In Chapter 4, the experimental results relating to key paper
properties and selected print qualities are analyzed and discussed. Significant findings of
this study are summarized and concluded in Chapter 5 together with recommendations
for future work.
Printer Type
Paper Parameters
Structure &
Composition
HP 2600
Optical
Properties
HP 4700
HP 9500
Print
Quality
1. Basis Weight
1. Brightness
2. Fluorescence
3. Caliper
3. Gloss
4. Hardwood %
4. Microgloss
5. Sizing
5. Microgloss
Nonuniformity
6. Porosity
6. Opacity
7. Roughness
8. Youngs Modulus
Objective
Subjective
1. Microgloss &
Microgloss
Nonuniformity
Visual
Ranking
Relationship between
Paper Properties &
Print Quality
Figure 1-1. Summary of Thesis Approach
CHAPTER 2
2.1
BACKGROUND
Introduction
Most images printed using digital printing technologies are on paper [17]. Hence,
knowledge on paper substrates is needed to understand and improve the digital printing
performance. Section 2.2 examines the structure & composition, optical & appearance,
and electrical & thermal properties of paper that are relevant to digital printing. Section
2.3 briefly introduces the xerographic printing process and highlights key factors that can
affect print performance.
Section 2.4 defines print quality in subjective and objective terms. Previous literature
dealing with the objective assessment of print quality using microgloss, microgloss
nonuniformity, print density, print mottle, surface topography and roughness is critically
reviewed. Research related to the subjective evaluation of print quality using the visual
ranking method is examined as well. Finally, the last section of this chapter emphasizes
the importance of connecting end-user perception (i.e. subjective print quality) with paper
properties and printing process factors that can be objectively measured (i.e. objective
print quality). Based on the literature review, unexplored areas of investigation are
identified.
2.2
Paper
2.2.1
Paper is made from an assembly of cellulosic fibers that are attached to each other by
hydrogen bonds [18-22]. Therefore, the characteristics of individual fibers play an
important role in papermaking and paper end-use.
Fibers consist of three main components: cellulose, hemi-cellulose, and lignin, which are
extracted from wood using chemical and/or mechanical process to form pulp.
Mechanical fibers are composed of all the above-mentioned components, whereas
chemical fibers are treated to eliminate lignin. Depending on the wood source, fibers can
be divided into softwood and hardwood pulps. Softwood fibers are obtained from
4
coniferous trees, hardwood fibers come from angiosperm trees. Softwood fibers tend to
be longer and have better bonding ability than hardwood fibers, resulting in papers with
superior strength compared to papers made of hardwood fibers [21]. However, papers
containing hardwood fibers tend to have better surface smoothness because the fibers
are shorter and have a narrower fiber length distribution [23].
In addition to fibers, paper consists of fiber fragments, mineral fillers, and chemical
additives. During papermaking, a highly diluted suspension of fibrous and inorganic
components is deposited on a moving web. Throughout the process known as web
formation, different dewatering strategies are applied to transform the fiber suspension
into a fibrous network [20]. As a consequence, the distribution of fibers and fillers in the
sheet is nonuniform and the orientation of the fibers in the network is anisotropic
producing local variability in the paper basis weight [20]. In addition, formation affects
the roughness and the optical properties of the final product [18].
Paper parameters can be grouped into three main categories: structure & composition,
optical & appearance, and electrical & thermal. Physical and mechanical properties of
paper play an important role in its runnability and printability, while optical properties play
a factor in determining the image quality of a print [17]. Hardwood and mechanical
pulping process are more suitable than their counterparts in making paper with better
optical properties, because shorter fibers from hardwood pulp give higher opacity by
increasing the bulk scattering [18]. In the following section, each category of properties
will be discussed.
One can easily see the uneven structure of paper (i.e. base paper) with the naked eye at
length scales ranging from fractions of a millimeter to a few centimeters [20]. Hence,
paper is often coated to enhance its physical appearance and surface quality. The
quality improvement can be aimed at optical properties such as brightness, gloss or
opacity, at surface properties such as smoothness, but most importantly at printability
and print image quality [24]. Calendering is generally the last step in paper manufacture
and is often designated as finishing [18]. Calendering tends to create a uniform paper
sheet without large voids on its surface and within its structure.
2.2.2
Paper Parameters
make the paper prone to break or too weak to meet all of its specified strength
parameters.
Strength (particularly stiffness) and dimensional stability of paper are affected by paper
formation due to the degree of fiber-fiber contact and bonding [31]. In general, a sheet
with uneven formation (i.e. contains large voids and fiber flocks) will have an uneven
appearance and exhibit low paper strength [31]. Other print machine factors that affect
dimensional stability include wet pressing, wet straining, and sheet shrinkage.
Opacity
Opacity is the amount of light that is allowed to pass through paper [17]. Given two
sheets of paper with identical structure, the darker paper will appear more opaque than
the lighter one [35]. Paper opacity is higher with the larger amount of fillers used in
production and the larger basis weight of the finished sheet; it also depends on the fiber
type [17]. On the other hand, printing opacity is the ratio of the reflectance of a solid
black printed area viewed through one thickness of the paper under test to the
reflectance of a pile of the unprinted paper [35]. For an entirely transparent paper, the
opacity ratio is 0% while the ratio for a completely opaque paper is 100%.
In order to keep the opacity of paper high, it is essential to make the scattering
coefficient as high as possible by encouraging the inter-reflection of light between the
fibers in paper [35]. With the use of filler, the higher refractive index of the filler results in
an increase in the scattering coefficient of paper. Under acid papermaking conditions,
kaolin-based clay fillers are often added to improve paper opacity and whiteness [36].
9
On the contrary, excessive heating and wet calendering will increase the transparency of
paper.
Specular Gloss
Gloss is the lustre of the paper surface and is closely connected with the reflection of a
collimated beam of light that falls upon a paper surface [17, 35]. Due to the method of
formation of the sheet and particularly if it is supercalendered, there is some
arrangement of fibers oriented near the plane of the sheet, so that some degree of
specular reflection takes place [35]. The rest of the light penetrates more deeply into the
paper and is reflected and refracted from the fibers [35].
The total light reflected from the surface is thus made up of specularly reflected and
diffusely reflected components [35]. When light strikes a surface, some of the light
penetrates where it can then be absorbed, scattered, or even transmitted if the layer is
sufficiently thin [37]. Nevertheless, because of the change in refractive index between air
and most substances, a certain proportion of the incident light is reflected directly from
the surface [37].
Specular reflection is a sharply defined light beam resulting from the reflection of a
smooth, uniform surface [37]. This reflection makes an object look glossy or shiny.
However, as shown in Figure 2-2, when light shines on a rough surface, the reflective
angle is different for each ray and hence, the object tends to look less glossy. Since
some of this light is reflected from the fibers in the surface of the paper, the formation of
paper plays an important role in influencing paper gloss.
Gloss variation is an indication of print surface unevenness; hence, the rougher the print
surface, the higher is the gloss variation [6]. Very smooth surfaces can produce high
levels of light reflection or gloss from the paper surface. Hence, the smoothness of the
paper surface is indirectly related to the visual appearance of paper (but is not identical
with gloss) and is closely connected with the scattering of light from the paper surface
[35].
10
current running along the surface, while the dielectric constant of a material is the ratio
between the materials conductivity and the conductivity of vacuum [32]. The dielectric
constant of paper usually ranges from 2 to 6 and is highly dependent on density, thermal
conductivity, moisture content and paper composition [32].
Another parameter closely related to electrical resistivity are the static properties of
paper. Static properties of papers are generally expressed by the parameter resistivity,
which expresses the time it takes for a static charge to decay [31]. Resistivity may not
correlate fully with print quality performance; however, other parameters such as
electrostatic charge decay may be more significant. Therefore, the electrical properties
of paper, the maximum charge the paper can hold, and the rate of decay of that charge
all play an important role in quality image production for xerographic printing and will be
related to toner transfer efficiency and runnability on printing press [31, 32].
Paper with a high resistance to electrical charge or entering a system with a high charge
or the characteristic to hold a charge will cause a build-up of static electricity and hamper
the toner transfer process, which will eventually result in poor image quality [17]. This
build-up may lead to handling problems such as jamming in the digital printing system or
in downstream finishing processes [10, 17]. On the other hand, if the paper is too
conductive or enters the process with low charge properties, toner adhesion problems
may result and loss of image density can occur due to charge leakage to the ground [10,
17]. A decrease in paper bulk was thus found to cause a reduction in electrical surface
resistance, which in turn reduces the possibility of undesirable image quality or poor
toner transfer.
Since the amount of toner transferred is related to the resistivity of paper and the
magnitude of the transfer current, it is necessary to control the surface resistivity of
paper [33]. Paper resistivity can be modified by adding sodium chloride (NaCl) or
polydiallyl dimethyl ammonium chloride (PDADMAC) as a form of electroconductive
additive. In order to prevent the paper from having undesirable resistance, it is also
important to control its moisture. Ensuring uniform surface resistivity requires moisture
content of the paper to be spatially uniform [17]. The range of surface resistivity of
significance in xerography is 0.01 to 10 terraohms and any value below 0.01 will produce
a significant loss in image density [10].
12
2.2.3
becoming a more popular option due to its ability to produce greater document quality in
high volume centralized printing systems [42]. Table 2-1 summarizes the paper
parameters mentioned above and their impact on xerographic printing.
Table 2-1. List of Paper Property & their Impact
Paper Property
Control Parameter
Impact (Affects)
- Sizing agents
Smoothness &
Caliper Variation
- Filler distribution
- Fiber type
- Calendering
Strength &
Dimensional Stability
Brightness &
Whiteness
- Moisture nonuniformity
- Lignin content
- Fiber distribution & type
Print/Image Quality
Opacity
Filler content
Fiber type
Heat & wet calendering
Additives & fillers
Print/Image Quality
Specular Gloss
Electrical Resistivity
& Static Properties
Thermal Conductivity
& Porosity
Printability
- Calendering
- Fiber orientation &
distribution
- Moisture nonuniformity
- Toner transfer efficiency
- Moisture content
- Mass density
- Paper composition
- Fiber distribution
- Porosity
- Pore size distribution
Print/Image Quality
(mottle, density loss, &
image transfer)
Runnability & Image
Resolution
Runnability & Electrostatic
Transfer Efficiency
(mottle & toner density)
Print/Image Quality
Paper substrate in the xerographic printing system must have specific properties to
provide the appropriate functional performance to ensure that image resolution and print
14
sheet integrity are preserved and to enable efficient toner transfer from the
photoreceptor to the paper and from the fuser roll to the paper [42].
2.3
Xerographic Printing
In the commercial printing industry, a great number of printing machines that follow
different printing techniques have been invented. The printing industry can be classified
into six main types of printing techniques, namely: offset, screen, letterpress,
flexography, gravure, and digital printing [39]. Other less significant yet popular types of
printing techniques include electrostatic, embossing, engraving, and thermography
printing.
Besides offset printing, digital printing is one of the most popular and effective forms of
printing since its introduction. As opposed to offset printing, digital printing does not
require a minimum number of prints to be cost effective [41]. This printing technique
eliminates the use of film and plates by transferring the digital file directly from a
computer to the printing press, thus making the process cost effective [40]. The different
types of digital printing methods include laser (i.e. electrographic or xerographic), inkjet,
thermal transfer, dye sublimation, etc. Among the different existing types of digital
printing techniques, laser and inkjet printing are the most common and typically used
methods.
A laser printer tends to cost more than an inkjet printer; however, an ink jet printer will
eventually cost more overtime due to the frequent need to purchase ink cartridge refills
and printer head replacements [39]. Laser printers on the other hand, can deliver more
copies per cartridge. Other advantages of laser printers include maximum printing
efficiency (i.e. able to handle large volumes of printing at a fast rate), excellent image
quality, and the printed image is dry to touch after immediate emergence from the
printer. Due to the numerous advantages of laser printing and the limited understanding
of factors affecting xerographic print qualities, this print method is chosen and further
analyzed in this study.
15
2.3.1
A Brief Overview
materials, and the substrate (i.e. paper). More than 10 high quality prints are often
produced before some of the main materials components require to be replaced. The
performance of the printing system is almost exclusively dependent on the quality and
reliability of the xerographic materials utilized [42].
The xerographic printing process consists of seven key steps as illustrated in Figure 2-4:
16
particles to be attracted to the print sheet, thus transferring the image from the
photoreceptor to the print sheet [41]. This current produces an ionization of the air in its
vicinity and the ions act as a source of corona wind that charges the photoreceptor
[43]. The surface of the belt or drum is usually covered by amorphous selenium or
ceramic [41]. Photoreceptor serves as the image-generating surface and also transfers
the image through each stage of the printing process [41].
17
Step 5: Fusing
The paper together with the toner image then proceeds through the fuser rolls that melts
and permanently fixes the toner onto the paper with the use of heat and pressure.
18
For colored printing, each color is imaged, developed, and transferred in each pass of
the photoreceptor belt and the four-color image is built up on the paper as each of the
developed powder images in transferred sequentially (i.e. the paper goes through the
printing process four times) [43]. The final four-color image is then fused as it exits the
transfer zone.
2.3.2
Print factors that affect print quality include fusing parameters such as fuser dwell time,
fusing pressure, and fusing temperature; and toner properties such as adhesive
behavior, particle-particle interactions, thermal melting behavior, toner charging, toner
fluidity, toner mass transfer, and toner particle size and uniformity [68-73]. In addition,
some researches have started applying a uniform layer of clear toner to full color
xerographic images to improve the print quality [48]. Based on past studies, a list of print
parameters that have an impact on print quality are as summarized in Table 2-2.
Table 2-2. List of Print Parameters and their Impact
Print Parameters
2.4
Grain
Mottle due to uneven toner layer
resting on the paper surface
Toner charging
Toner mass transfer
Tone reproduction
Gray balance
Print Quality
Print quality can be quantified objectively through print quality analysis and subjectively
using panel or visual ranking of print attributes [74]. Objective print quality analysis uses
instruments to assess print characteristics and attributes, which have an impact on
perception of print quality. These objective analyses as mentioned in Section 2.4.1 can
be compared to numerical measurements to ensure solid and accurate results. On the
19
other hand, subjective visual assessment as discussed in Section 2.4.2 allows print
quality to be ranked based on human perception of print quality.
2.4.1
Objective Computation
as shown [45]. When a xerographic print sample is viewed at different angles, a gloss
difference, or differential gloss, can be observed. During the quantification of gloss on a
reflective print, 20, 60, and 75 degree TAPPI gloss measurements are commonly chosen
as standards within the printing industry.
Many factors, such as substrate porosity, toner/ink blistering, process heat/pressure
inconsistencies, etc., may contribute to the existence of microgloss variations in a
printing system [11]. However, gloss does not depend on the surface roughness alone
and it is also sensitive to other surface properties [46]. The major contributor to gloss is
the light reflection of the outermost surface and its roughness. In this study, the
outermost surface is the toner layer. Hence, xerographic printing produces prints in
which the surface roughness of the toner layer dominates the gloss appearance.
Past studies have shown that dry toner is typically not completely fused and can be
described as a surface composed of two distinct regions [47]. These two regions differ in
the extent of fusing that has occurred, as manifested by their differences in specular
reflectance characteristics [47]. Since the amount of toner put on the paper depends on
the image content, the gloss of a xerographic print is also strongly image-dependent
[45]. Print gloss is also strongly dependent on the image density. This is because in
xerographic printing, the ink (toner) is deposited onto the paper substrate in much higher
mass densities than in other printing techniques such as lithographic printing [48].
This image dependence may result in a phenomenon known as differential gloss, which
can be very objectionable to the observers [45]. The term of differential gloss typically
implies a quantitative difference between gloss measurements of two different surfaces,
such as the differential gloss produced between the toner and the paper surface. In
addition, there may be a differential gloss between two printed areas covered with
different toner amounts [45]. This kind of differential gloss is usually associated with a
color or density difference between the two surfaces [45]. The perception of color images
is directly connected to gloss through the light reflected from fused toner surfaces [49]. It
is well recognized that glossiness accentuates color appearance because both color and
gloss are determined by the intensity of the reflected light which is composed of two
parts: specular reflection and diffuse scattering [49].
21
In order to reduce the color or density difference, researchers have tried covering the
image with a uniform layer of the clear toner to provide better print appearance. In this
method, the specular gloss became much more uniform and the grainy noise was
remarkably reduced [48]. Noise reduction was attributed to the decrease of gloss
fluctuation with image surface flattening and prevention of image disturbance during
transfer and fusing, which in turn improved the subjective impression of a pictorial image
[48].
Delta gloss (i.e. the gloss difference between print and paper gloss) and print gloss
variation also play an important role in the resulting image quality. It is believed that print
gloss variation is strongly affected by variations in the base paper surface texture,
surface roughness, and drying conditions [50]. In general, the differential gloss and print
gloss variation are considered as an image defect; hence, a significant effort within the
xerographic printing industry has been made to suppress the differential gloss for
reaching a uniform image gloss [45]. On the other hand, differential gloss itself is not
inherently undesirable under all circumstances and some consumers prefer strong gloss
contrast for certain images and certain applications [45].
22
a dominant
role in glossiness
quality.
In
23
Before fusing, the topography of the surface is characteristically similar to that of the
paper surface [12]. Upon fusing, the pressure and heat applied causes the toner to
spread sideward, thus yielding a printed surface that is different from the original paper
surface topography [12]. This new printed surface is generally smoother than the original
paper surface.
Surface topography can be optimized by a suitable combination of surface treatments
and finishing to give a surface texture with good toner-recipient properties [30]. With
sufficient fusing power applied, an increased toner coverage degree, or a thicker toner
layer help in reducing the surface roughness [56]. Increases in the radiant fusing
temperature also yield a decrease in overall print roughness; however, this decrease is
more pronounced on coated paper and with higher toner amounts [56].
One important factor in surface engineering is the evaluation of the surface topography
(i.e. measurement and analysis) [57]. The surface profile measurements that are most
commonly performed by the industry include optical profilers (such as WYKOTM white
light interferometer and confocal microscopy) and pseudo- contact methods (such as
stylus profilometry and atomic force microscopy, AFM)). Other roughness measurements
or surface analysis methods include scanning electron microscopy (SEM), optical
microscopy, and Parker Print-Surf (PPS) method.
Measurements of surface roughness are normally performed using 2D or 3D profiles. 2D
profiles provide line measurements of the surface roughness, whereas 3D profiles
provide evaluation of the surface topography. The stylus profiler in general gives lower
roughness values than WYKO or PPS measurements for the same samples. This
difference may be explained in part by the stylus tip geometry and the relatively high
contact pressure during the test (the tip could damage softer surfaces and cause
difficulties in measuring small features) [57]. Other factors contributing to the difference
in value include the measurement area size and number of sampling points. WYKO on
the other hand specializes in phase-measuring interferometry systems for a wide variety
of applications from measuring microsurface roughness to contouring large surfaces
[58].
24
When a surface profile is measured at N discrete and equally separated points along a
line, Rq is the square root of the mean value of squares of the distances, zj, of the points
from the mean level [53]. The distances zj of the points are surface heights; therefore
RMS roughness is also interpreted as the standard deviation of the distribution of
heights [29].
(c) Skewness, Rsk
(Equation 2-4)
25
Skewness is a measure of the asymmetry of the profile about the mean line. The sign of
the skewness will tell whether the farther points are proportionately above (positive
skewness) or below (negative skewness) the mean surface level [19]. Thus the
predominance of bumps or peaks on a surface will have a positive skewness, and the
predominance of holes or valleys in a surface will have a negative skewness [19].
d) Kurtosis, Rku
(Equation 2-5)
Kurtosis is a measure of the peaked-ness of the surface profile about the mean line or
a measure of the randomness of profile heights. Kurtosis values can range from 0 to 8,
with a perfectly Gaussian or random surface having a kurtosis value of 3 [19]. Hence, the
further the value is from 3, the less random and more repetitive the surface is. Profiles
with fewer low and high extreme points have a kurtosis value less than 3 while those
with a significant number of low and high extreme points have a kurtosis value greater
than 3 [19]. When the kurtosis is high, a high proportion of the profile heights fall within a
narrow range of heights and more of the variance is due to infrequent extreme
deviations. On the other hand, a low kurtosis value represents a surface that is relatively
more randomly distributed in different surface heights.
2.4.2
Subjective Quantification
26
method involves preferential judgment of the image in terms of printing quality. Although
paper and print experts have a better knowledge on print quality standards than
participants with no prior knowledge, research has shown that there is a good
agreement between experts and naive observers [76].
Visual examination is often carried out at arms length distance and as shown in Figure 28, print images can be visually analyzed using two methods. In Figure 2-8 (a), the image
is placed on a support under a diffuse, uniform light and the observer examines the
image at a perpendicular (90 degrees) direction from the sample [53]. The second
method as shown in Figure 2-8 (b), the observer holds the sample and examines it at
different angles under a direct light. This form of evaluation allows gloss nonuniformity
and print mottle to be detected [53].
27
Figure 2-9. Image Resolution: (a) desired line representing the devices native
resolution, (b) line rendering of each pixel on the line, and (c) line rendering with some
pixels rendered gray
Toner adhesion also affects print quality. In the electrographic process, charged toner
particles are transferred from the bulk to the photoreceptor drum and from there to the
paper. [63]. Since commercial xerographic printing requires the print device to run at
high speed while maintaining good performance, toner loss often become the main
concern in this printing system. The extent of toner loss is a function of several factors
28
including instrument parameters (smaller gaps and more cycles increase toner loss),
copier parameters (lightest and darkest settings are least durable), and paper properties
(toner is more durable on 20% recycled content copier paper than on virgin copier paper)
[64].
Adhesion force consists of electrostatic and non-electrostatic (e.g. van der Waals force)
components. Measurements of toner adhesion are usually at least one order of
magnitude larger than the toner adhesion predicted by image force calculations that
model the toner charge located in the center of the toner particle [65, 66]. Past
researches showed that adhesion force between toner particles tend to increase with an
increase in either particle size or charge [67]. In addition, adhesion force of an irregularly
shaped toner particle is generally larger than that of a spherical toner particle of similar
size and charge because an irregular shaped toner has more contact points than a
spherical one.
On the other hand, an increase in surface roughness of the paper substrate was found
to cause a decrease in mean adhesion forces [67]. Since toner particles are less than 10
m in diameter, it is difficult to measure the adhesion force of the fine particles.
Therefore, colloid probe AFM is often used to evaluate the particle-particle interactions
and adhesion force between a toner particle glued to the AFM cantilever tip and a toner
particle in a compressed layer of toner powder [68].
2.5
As evident in past studies summarized in Table 2-1 and 2-2, both print conditions and
paper substrate are known to play an important role in determining print quality.
However, when dealing with uncoated papers, the receiving substrate becomes
significantly more important in the determination of the final print quality than the print
properties. Unlike coated papers, uncoated papers possess more voids and have a
rougher surface; hence, the requirements of the substrate to produce quality print
become more stringent.
Since the xerographic printer has a rapidly growing market that continues to reduce cost
while improving the quality of print images, better understanding of the interactions
29
between printer and paper in the printing process is highly beneficial. Hence the aim of
this study is to investigate the effect of key surface, structural, optical, electrical, and
thermal properties of the underlying base sheet on print quality. Based on past literature,
the paper parameters mentioned in Section 2 have an impact on offset and digital print
quality (including inkjet printing). However, it is still unclear whether similar paper
properties will have identical effect on xerographic printing. In addition, it is essential to
identify and rank the key paper properties based on their significance in affecting
xerographic print quality so that papermakers can focus and improve on those areas.
The paper properties of interest in this project are listed in Table 2-3:
Table 2-3. List of Paper Parameters to be Correlated
Structure & Composition
Optical Properties
- Basis weight
- Caliper
- Brightness
- Density
- Gloss
- Hardwood percentage
- Microgloss Nonuniformity
- Porosity
- Opacity
- Roughness
- Tensile modulus
In this study, print quality is characterized objectively through print gloss and its
nonuniformity, print mottle, print density, and roughness of the printed surface and
subjectively by visual ranking analysis. It is crucial to correlate both the objective and
subjective print qualities because the concept of print quality is intangible and it is hard
to grade print quality in terms of good or poor quality. Hence, by correlating against
subjective print quality (i.e. visual ranking), it allows one to classify the objective print
quality based on the perspective of potential observers. Although there are many ways
to improve print quality, the different strategies chosen have to be economical in order
for the changes to be feasible.
30
CHAPTER 3
3.1
EXPERIMENTAL PROCEDURES
Overview
This chapter gives a detailed description of the experimental approach shown in Figure
1-1. The source and properties for the different paper and printed samples tested are
listed in section 3.2. Instrumental specifications for the equipments used are also
included in this chapter. In addition, this chapter summarizes the experimental details on
the objective and subjective methods used to characterize print quality.
3.2
Paper Samples
In this study, ten different uncoated commercial papers as listed in Table 3-1 were
printed using three different color LaserJet (CLJ) printers (i.e. 30 different printed
samples in total).
Table 3-1. Paper Sample Description
Sample
Number
1
Paper Description
HM Copy Plus
HP Office Riverdale
HP Office C35
HM Laser Print
Premium Multipurpose
HP Multipurpose
HM Color Copy
HP Color Laser
HP Premium Choice
10
LaserJet Saillat
The paper samples were obtained from International Paper (IP) and a schematic
diagram illustrating a generic uncoated print sample is shown in Figure 3-1. Each paper
sample contained three different color prints with two different coverages (i.e. 40% black,
100% black, 40% blue, 100% blue, 40% purple, and 100% purple) and a print area of 5
by 5mm.
31
3.3
Xerographic Printing
3.3.1
Three xerographic printers, namely HP CLJ 2600, HP CLJ 4700, and HP CLJ 9500 were
used to print the paper samples using the print parameters shown in Table 3-2. Five
replicates of each uncoated paper samples with 100% black prints from the three
different printers were analyzed in this study. In addition, paper samples with 40% black
prints were also used to illustrate the different toner patterns obtained from the 3
different toner cartridges.
Table 3-2. Print Parameters
Printer Type
Printer Speed
(ppm)
Maximum Resolution
(dpi)
HP 2600
600
HP 4700
30
600
HP 9500
24
600
32
3.3.2
Sample Preparation
As shown in Figure 3-2, five specimens of each paper sample with a size of 1.5 by
1.5cm were cut out in the machine direction. Each specimen was then adhered
delicately on microscopic slides using tweezers and double-sided tapes. It was important
not to scratch or contaminate the surface of the print sample because any disturbance
would have caused a significant change in the values of print microgloss and print
microgloss nonuniformity. After placing the samples on the microscopic slides, the slides
were then transferred to a slide box and kept under 50% relative humidity condition,
ready to be analyzed.
3.4
Print Quality
As mentioned in Section 2.4, print quality can be assessed with either objective or
subjective tests. Most of the objective methods used to characterize the printed samples
can be applied to the paper. These methods include paper microgloss, paper microgloss
nonuniformity, and paper roughness. On the other hand, visual ranking is the sole
subjective test conducted on the printed samples.
33
3.4.1
Objective Measurements
35
(Equation 3-1)
(Equation 3-2)
G - average microgloss
G - average microgloss nonuniformity
G (i, j) - grey level for the element in the ith row and jth column of the array of pixels
representing the captured image [29]
N - total number of pixels (i,j) representing the captured image.
The digitized images captured from the microgloss setup were processed and calculated
using the OPTIMASTM 6.0 software. An illustration of the data analysis performed with
the software is presented in Appendix A.
Some printed samples could have a much lower or higher microgloss value than other
printed samples of the same batch due to the different paper substrates and surface
properties; hence, the image is considered to be over-saturated or over-exposed. To
objectively define these samples the following criteria were followed:
-
if more than 5% of the area under the gray values histogram of the image (see
Appendix A) was within the microgloss range 0-150, the sample was considered
to be in the low range.
if more than 5% of the area under the gray values histogram of the image (see
Appendix A) was within the microgloss range 1000-1023, the sample was
considered to be in the high range.
To correct the low range samples, an additional test was conducted by increasing the
shutter speed of the CCD camera from 1600ms (original exposure time) to a higher
exposure time such that the new image captured was not be over-saturated. In order to
avoid changes in the shutter speed, a MATLAB autocorrelation program was applied to
correct the saturation problems. Therefore, 4 different exposure times (1800, 1900,
2000, and 2100 ms) were needed to create a linear transformation of images as shown
36
in Figure 3-6. Based on the regression line, the measured value is then correlated and a
new microgloss value is obtained based on the corrected value of the image captured at
1600 ms.
38
(Equation 3-3)
- Wavelength (mm)
L - Image size (in this study, 43 by 43mm)
- Frequency in cycles
In order to determine print mottle within a certain size range, Equation 3-3 has to be
applied to determine the frequency ranges that have to be input in the MATLAB Fourier
program. For instance, the wavelength associated with mottling in the range 1-10mm
from a 43 x 43mm image will correspond to a frequency range of 5 to 45Hz. In this study,
the following four frequency ranges for print mottle were used:
39
To determine gloss mottle, a 100% black image of each sample with a printed area of 10
by 10mm was first imaged using the microgloss setup (see Section 3.4.1.1). The
grayscale image was then decomposed into various wavelengths (i.e. gloss mottle)
using the Fast Fourier Transform (FFT) algorithm coded in MATLABTM 7.0 (see
Appendix B).
In order to compare the print mottle and gloss mottle results, the frequency ranges used
for gloss mottle have to correspond to the same mottle size range (i.e. wavelength) as
those obtained from the print mottle results mentioned above.
Hence, in this study, the following four frequency ranges for gloss mottle were used:
These frequency ranges were approximately selected to closely represent the same
mottle size ranges as the print mottle evaluation.
40
interferometric microscope is equipped with a turret that houses three objectives and the
sample stage is located beneath the magnification objective. During measurement, the
white light beam passes through the selected microscope objective and illuminates the
sample (see Figure 3-10). A beam splitter reflects half of the incident beam to the
reference surface [19]. The light reflected from the reference surface then recombines
with the beam reflected from the sample to form interference fringes that determine the
best focus point. The reference arm containing the interferometric objective moves
downward vertically to scan the sample surface so that each point on the surface
produces an interference signal [19, 58]. A linearized piezoelectric transducer is used to
ensure precise step motion by controlling the evenly spaced internals during scanning.
surface. In-plane resolution is the size of the smallest area over which the local height
can be measured and is a function of the magnification and the array size of the detector
[22, 58]. In this study, the equipment used has a fixed detector array size of 736 by
480m; therefore, the magnification will determine the field of view and in-plane
resolution as listed in Table 3-2.
Table 3-3. Resolution and Scanning Area of WYKOTM NT-2000 [22]
In this study, the following settings were utilized for all WYKOTM roughness
measurements:
Magnification = 10.24 X
Backscan = 10m
Length = 60m
In addition to the above settings, a median Gaussian pass filter was also chosen to
smooth the images and reduce noise. WYKO measurements were performed on five
randomly selected points for each sample and the average roughness (Rq) value was
43
recorded. Since the printed samples were too dark, WYKO was only used to measure
the roughness of the unprinted area of the uncoated papers while Stylus was used to
characterize the topography of the printed samples.
A contact surface Stylus profiler (KLA Tencor P-16+) was used to measure the surface
roughness of the printed samples (see Figure 3-11). The instrument enables process
control and analysis of features below 10 nm up to approximately 1 mm in height [77].
Stylus P-16+ delivers automated step height, surface contour, waviness and roughness
measurements with detailed 2D or 3D analysis of topography for a variety of surfaces
and materials.
Stylus profiling uses a finely pointed and balanced diamond tip, drawn across the
surface to measure height or roughness variation with extreme precision. As shown in
Figure 3-12, the sample stage provides full access to a 9.5 by 9.5 inch area and
measurements made by the diamond stylus are transferred to the KLA Tencor P-16+
software using Windows XP operating system.
[77]. In addition, the software discriminates roughness and waviness components from
the raw data trace using a variety of standard filters including Cubic Spline and Gaussian
[77]. In this study, the following settings were utilized for all stylus roughness
measurements:
Scanning Mode = 3D
Frequency = 200Hz
Spacing = 10m
The stylus tip, as shown in Figure 3-12, has a precise force control that provides
excellent vertical resolution, precision, and reliability in the measurements [77]. Since
paper is considered a soft material (as opposed to harder materials such as aluminum)
measurements were made based on the soft surface category. Therefore, a constant
stylus tip force control of 1mg with a tip size of less than 1m was used to measure the
surface roughness of the substrate.
45
Resolution = 4nm
46
Due to the high roughness of the surfaces, it was difficult to obtain clear images. Hence,
CombineZTM software was used to combine several shots of images with areas out of
focus into one final image with all areas in focus (see Figure 3-16). When capturing
images at different focal planes, the focal distance increments had to be uniform. This
was achieved by controlling the knob on the optical microscope. The CombineZTM
software was then used to increase the depth of field by stacking the images taken at
different focal planes to form the final in-focus image.
3.4.2
Visual evaluation, as mentioned in Section 2.4.2, was performed in an open space in the
laboratory with natural light from the windows and an additional white light source placed
above the participants. The paper samples were split into three separate batches
according to the printer type. Each batch consisted of ten different uncoated papers with
100% black prints and participants were asked to visually rank them based on their
perception of good print quality. In order to test the credibility of each participant, 2
similar print samples were added to each batch. Participants that gave similar print
samples extreme rankings were removed from these experiments. Due to limitations,
only 10 participants, 4 male and 6 female observers, with normal or corrected-to-normal
vision were chosen to participate in this visual exercise. Out of the 10 participants, 8 of
them did not have prior experience in print mottle evaluation.
48
Participants were asked to use the pairwise method (i.e. comparing two print patches
with print area of 45 by 45 mm at a time) to evaluate the print samples. Each sample
was backed with a white sheet and masked at the front with a white sheet so as to reveal
only the area of analysis. This is to avoid other visual disturbance that might affect the
participants vision. The participants were allowed to hold the print sample and examine
it at different angles under a direct light source as illustrated in Figure 2-6 (b). As shown
in Figure 3-17, the sample that has a better print quality will be noted and the sample
with the most count will be ranked as one. Therefore, lower ranking values indicate
better print quality and the lowest count would indicate samples with the lowest print
quality (high mottling).
Although visual ranking is the sole method to quantify visual ranking subjectively, there
are several limitations in the results obtained. Since these samples are ranked from 1 to
10, the results do not reflect on the exact quality of the prints (i.e. samples ranked 1 to 3
might be much better than samples ranked 4 to 10 but ranking does not provide this
information). These ranking results were a mere reflection on the proportion of
customers that prefer a print sample to another.
49
CHAPTER 4
4.1
Introduction
Results obtained in this study are presented and discussed in this chapter. Chapter 4 is
separated into two main parts. Section 4.2 summarizes the experimental results
obtained and identifies the main paper parameters that have a strong effect on print
quality. Sections 4.3 to 4.5 explore the relationship between the different objective (print
microgloss, microgloss nonuniformity, print mottle, print density, surface roughness,
surface topography) and subjective (visual ranking) types of print quality evaluation.
Finally, Section 4.6 addresses the different printers and their printing effects. Optical
images of the different print patterns will also be provided and discussed.
4.2
This study focuses only on the structure and composition, and optical properties of paper
as listed in Table 4-1. International Paper (IP) provided all of the paper properties except
paper microgloss and paper microgloss nonuniformity. These properties were known to
play a role in affecting print quality; however, their significance was not known. Hence,
an analysis of their importance was performed in Section 4.4.
Print quality attributes, on the other hand, were measured on 100% black print samples
as listed in Table 4-2. The objective attributes included print microgloss, print microgloss
nonuniformity, print and gloss mottle (>10mm, 1 - 10mm, 0.1 - 1mm, and <0.1mm size
ranges), print density, and print surface roughness; whereas the subjective attribute
measured was visual ranking. The tests were performed on the different paper samples
printed using the 3 different printers. Raw data corresponding to the measured paper
parameters and print quality tests can be found in Appendix D.
50
10
Basis Wt (g/m2)
77.1
77.8
77.6
91.4
92.2
93.1
106.9
106.4
120.9
87.5
Brightness (%)
90.6
90.9
91.5
94.6
93.9
91.9
97.2
95.9
95.9
93.6
1.4
1.3
1.4
1.1
1.3
1.2
1.1
1.2
1.1
1.3
Caliper/Thickness
(microns)
104
100
105
103
116
114
120
122
132
113
Density (g/cm3)
0.74
0.77
0.73
0.88
0.79
0.81
0.89
0.87
0.91
0.77
Fiber
(Hardwood %)
53
55
57
87
43
72
89
83
91
100
Fluorescence IP
71.2
72.6
75.2
79.0
95.0
83.6
81.4
93.2
92.8
83.4
Gloss 75 (%)
5.0
5.5
6.2
9.4
7.7
8.6
9.6
9.1
10.8
6.5
46
29
48
36
34
76
309
54
535
Microgloss
861
859
860
973
901
900
978
915
902
846
Microgloss
Nonuniformity
35.8
42.0
39.5
48.9
37.0
35.7
42.9
42.2
40.8
31.5
Opacity (%)
88.6
88.9
90.5
91.8
92.6
94.1
94.1
94.5
96.3
93.9
Porosity Gurley
(s)
19.8
18.9
15.8
40.1
14.1
21.2
35.4
30.4
48.8
24.9
PPS Roughness
(m)
6.98
7.23
5.87
4.34
6.00
4.72
4.17
4.52
4.12
5.72
Sheffield
Roughness (SU)
161
167
197
57
118
116
62
66
57
122
Stiffness Gurley
(mg)
182
159
156
198
274
225
290
282
416
221
Tensile Energy
Absorption
(ft-lb/ft2)
3.97
5.02
3.98
6.60
3.95
3.64
6.70
5.97
9.04
7.04
Tensile Index
(Nm/g)
65.8
68.9
57.8
64.3
57.9
51.6
56.7
56.7
59.6
62.5
Youngs Modulus
(1000 lb/in2)
754
731
619
704
725
660
651
674
663
648
51
10
24.7
21.7
20.5
27.7
27.3
23.4
21.0
27.7
29.6
23.0
18.1
17.4
14.9
23.0
24.2
20.7
27.0
26.5
25.3
18.8
18.2
15.5
16.2
18.6
17.2
16.4
17.9
19.7
15.5
15.1
335.2
281.4
287.7
316.2
325.2
331.5
238.1
317.3
360.5
281.8
246.1
246.8
227.3
287.5
283.5
261.9
306.3
318.1
309.5
260.5
265.3
240.4
240.4
247.5
232.7
223.7
235.2
259.9
204.6
217.3
101.3
96.9
102.4
74.9
85.2
95.5
52.4
77.7
88.8
92.2
77.9
80.1
84.5
73.0
79.1
79.8
76.2
79.1
80.2
92.2
71.1
71.4
75.2
48.4
51.6
53.6
43.6
50.0
40.2
59.0
3.83
3.58
2.95
3.25
3.87
4.36
5.31
2.67
2.57
3.36
2.45
3.28
2.65
2.82
3.03
3.10
3.13
4.02
4.48
2.39
2.69
2.47
2.54
2.62
3.13
2.22
2.71
2.13
2.94
1.65
7.60
6.22
7.19
3.67
4.76
5.96
2.76
3.38
2.79
6.48
6.73
6.59
5.99
5.45
6.88
6.45
5.16
4.91
5.72
5.58
8.26
6.78
6.88
3.95
4.82
4.90
2.89
2.33
2.69
4.01
43.05
37.87
38.51
30.48
29.13
30.16
16.96
25.19
21.86
45.30
22.84
23.81
22.02
20.01
23.54
22.76
17.56
16.88
19.28
20.73
39.40
34.82
36.89
23.45
24.37
26.55
15.38
12.24
12.50
23.76
11.74
10.10
11.02
10.12
8.89
9.18
5.72
8.61
7.21
11.80
6.85
7.16
7.48
6.23
6.72
7.35
5.33
5.29
5.84
5.70
12.97
11.39
11.96
8.33
8.08
9.50
6.26
5.22
5.25
7.74
52
Gloss Mottle
[>10mm]
( 10-3)
Gloss Mottle
[1 to 10mm]
( 10-3)
Gloss Mottle
[0.1 to 1mm]
( 10-3)
Gloss Mottle
[<0.1mm]
( 10-3)
Print Density
Print Surface
Roughness
(Stylus, Rq)
Visual
Ranking
HP
0.48
2600
HP
0.18
4700
HP
0.40
9500
HP
1.30
2600
HP
1.20
4700
HP
1.50
9500
HP
6.50
2600
HP
4.00
4700
HP
6.54
9500
HP
2.30
2600
HP
1.50
4700
HP
2.20
9500
HP
2600 1.62
HP
4700 1.35
HP
9500 1.38
HP
2600 7.23
HP
4700 11.06
HP
9500 10.43
HP
2600 9.8
HP
4700 9.8
HP
9500 10.0
0.35
0.38
0.26
0.34
0.30
0.14
0.28
0.31
0.26
0.16
0.18
0.16
0.14
0.26
0.12
0.14
0.16
0.27
0.54
0.40
0.34
0.28
0.26
0.14
0.32
0.24
0.22
1.10
1.10
0.62
0.88
1.00
0.34
0.66
0.88
0.98
1.10
1.10
0.82
0.82
0.92
0.26
0.66
0.82
0.96
1.30
1.50
0.76
1.10
1.10
0.40
0.80
0.80
1.10
5.80
6.40
3.80
4.80
5.80
1.70
4.00
4.80
5.70
2.90
2.80
2.80
2.40
2.90
1.80
2.40
2.40
3.20
5.46
6.06
6.16
5.08
4.82
2.02
4.30
3.18
4.00
1.70
2.30
1.30
1.50
2.00
0.54
1.30
1.50
1.70
1.10
1.20
0.84
1.10
1.60
0.34
0.94
1.20
1.20
1.70
2.10
1.20
1.30
1.90
0.70
1.10
0.76
1.30
1.59
1.58
1.65
1.62
1.61
1.56
1.63
1.62
1.59
1.34
1.32
1.36
1.34
1.31
1.33
1.32
1.29
1.36
1.34
1.33
1.35
1.34
1.36
1.38
1.37
1.36
1.39
7.39
5.87
1.69
5.55
3.80
2.71
2.45
2.09
5.76
7.99
5.50
3.60
4.87
4.14
2.35
3.23
4.17
6.07
9.06
6.91
3.99
3.70
2.73
2.94
2.76
2.07
4.57
8.8
8.0
4.4
5.8
6.6
1.8
3.2
1.2
5.4
9.2
7.4
5.4
6.0
6.2
2.4
2.2
2.8
3.6
8.8
8.2
5.0
6.6
4.8
2.2
3.6
1.4
4.4
53
4.3
4.3.1
The relationship between print and paper microgloss and microgloss nonuniformity is
shown in Figures 4-1 and 4-2, respectively.
54
Figure 4-1 shows no significant correlation between paper and print microgloss for
uncoated paper samples printed using HP 4700 and HP 9500 series and poor
correlation for samples printed using HP 2600 series. This means that paper microgloss
does not have much effect on the microgloss of the final printed image and print
microgloss may be strongly influenced by other parameters. Similar trends can be seen
for paper and print microgloss nonuniformity as shown in Figure 4-2.
Figure 4-3 shows the correlation between print microgloss nonuniformity and print
microgloss. The labeled colored numbers on the plot correspond to the printed samples
of the different uncoated papers (see Table 3-1). If the results obtained from the 3
different printers are analyzed separately, no correlation can be found between print
microgloss and its nonuniformity for the different uncoated papers. Also, microgloss
nonuniformity does not show large changes for individual printers while microgloss does
change significantly (i.e. larger change within the given span). However, when the
results are analyzed from printer to printer, an increasing trend was observed. Generally,
print microgloss nonuniformity increases as print microgloss increases [22]. Printed
samples from HP 9500 were noted to have the lowest microgloss and nonuniformity
values while samples from HP 2600 acquired the highest corresponding values.
55
4.3.2
When print density was plotted against visual ranking as shown in Figure 4-4, it was
found that none of the print samples have any significant correlation. As shown in Figure
4-4, print samples from similar batches do not have any significant change in print
density and samples from HP 2600 series generally have a higher print density value
than the other 2 printer series. This means that paper type does not affect print density
and print density does not play a role in affecting the visual appearance of print, unlike
print mottle (i.e. the nonuniformity in print density) which will be discussed in the
following section.
4.3.3
In agreement with the previous literature, print mottle was found to be one of the
objective print quality tests that have the most effect on the subjective judgment of a
print. In order to determine which mottle range correlates best to the human eye, print
mottle was plotted against visual ranking for the following size ranges: >10mm, 1 10mm, 0.1 - 1mm, and <0.1mm.
56
In Figure 4-5, Figure 4-6, and Figure 4-7, the x-axis shows the visual ranking data
whereby 1 corresponds to the best rated sample with best print quality while 10
corresponds to the worst rated sample with the worst print. All three figures show that
the size range of 0.1 - 1 mm is best correlated to visual ranking for printed samples from
HP 4700 and HP 9500 series.
Figure 4-5. Impact of Print Mottle on Visual Ranking for HP 2600 Print Samples
Figure 4-6. Impact of Print Mottle on Visual Ranking for HP 4700 Print Samples
57
Figure 4-7. Impact of Print Mottle on Visual Ranking for HP 9500 Print Samples
Another size range worth noting was 1 - 10 mm because the correlation between print
mottle and visual ranking is relatively high for all 3 printers. However, in this section, only
the size range of 0.1 - 1mm was analysed for further correlations because the print
samples in this range had the highest mottle value (print mottle is dominated by this
range).
Figure 4-8. Impact of Print Mottle (0.1 1mm) on Visual Ranking for all 3 Printers
58
Since the human eye is most sensitive to spatial variations (i.e. print mottle) within the
size range of 0.1 - 1mm, a plot correlating print mottle at this size range versus visual
ranking for all 3 printers was produced as shown in Figure 4-8. From Figure 4-8, it could
be seen that there is a positive correlation between print mottle and visual ranking.
Figure 4-8 shows that samples printed using HP 9500 have the best correlation to print
mottle in the 0.1 - 1mm range whereas samples printed in the HP 4700 series have the
worse correlation.
Print mottle versus print microgloss nonuniformity was then correlated based on the 0.1 1mm size range as shown in Figure 4-9. This figure shows that the different printed
samples of similar base sheets have very similar mottle values but different microgloss
non-uniformity (labeled numbers signify the different paper types). It was also observed
that the print mottle and microgloss nonuniformity varies from paper to paper when the
printed samples of similar printers are compared.
Figure 4-9. Impact of Print Mottle (0.1 1mm) on Print Microgloss Nonuniformity
There is an increasing trend line for samples printed using the HP 2600 and HP 9500
series (i.e. paper with higher mottle typically has a higher print nonuniformity). This
shows that the uneven print density caused by uneven toner distribution deteriorates the
59
Figure 4-10. Impact of Gloss Mottle on Visual Ranking for HP 2600 Print Samples
60
Figure 4-11. Impact of Gloss Mottle on Visual Ranking for HP 4700 Print Samples
Figure 4-12. Impact of Gloss Mottle on Visual Ranking for HP 9500 Print Samples
In comparison to print mottle, gloss mottle was less correlated to visual ranking and all 3
printers showed similar mottle trends (i.e. gloss mottle is dominant in the 0.1 - 1mm size
range, similar to that of print mottle). When comparing all 4 frequency ranges for the 3
printers, it was noted that all four ranges have almost similar but weak correlation to
visual ranking. Hence, it can be concluded that gloss mottle does play a role in affecting
61
print quality regardless of the mottle size (i.e. macro or microgloss). However, its effect is
not as significant as that of print mottle.
4.3.4
Effects of Roughness
HP 2600
HP 4700
HP 9500
Rq
Rsk
Rku
Rq
Rsk
Rku
Rq
Rsk
Rku
7.23
-0.11
3.74
11.06
-1.69
4.43
10.43
-1.32
1.94
7.39
-1.04
2.64
7.99
-0.16
2.51
9.06
-1.40
4.03
5.87
-1.74
4.19
5.50
-1.57
2.93
6.91
0.37
2.09
1.69
-0.26
2.19
3.60
-1.64
4.84
3.99
-0.30
2.35
5.55
-0.34
3.94
4.87
-0.15
2.49
3.70
1.22
1.77
3.80
-1.74
4.88
4.14
-0.50
3.09
2.73
-1.53
4.00
2.71
-2.02
8.02
2.35
-1.72
4.59
2.94
0.45
2.96
2.45
-0.64
3.19
3.23
-1.56
4.34
2.76
-0.16
2.69
2.09
-0.08
2.29
4.17
-0.76
4.86
2.07
-0.01
1.75
10
5.76
-1.54
3.41
6.07
-1.53
2.79
4.57
-1.61
3.06
In general, a sample with a negative skewness value has fewer bumps or peaks above
the mean surface (i.e. relatively more valleys). Samples with a low kurtosis value are
relatively more randomly distributed in surface heights, whereas samples with high
kurtosis tend to have a significant number of high and low extreme surface heights. From
this observation, it could be noted that even though the paper type influences print
roughness, it does not significantly affects the skewness and kurtosis values. Different
regions of a similar printed sample could provide completely contradictory skewness and
kurtosis values; hence, skewness and kurtosis should be considered as localized
roughness parameters that depend greatly on individual print and not the paper or
printer type.
63
Table 4-4. Correlation as Measured by R2 between Print Mottle and Paper Roughness
Measured using Different Methods on Samples Printed with Different Laser Printers
Method
Printer
HP 2600
HP 4700
HP 9500
Stylus
0.52
0.52
0.49
PPS
0.6
0.6
0.7
WYKO
0.42
0.82
0.65
From Table 4-4, it could be seen that print mottle has a high correlation with paper
roughness measured using the PPS method as opposed to the Stylus method. However,
print mottle is not affected by the printer type and all three methods produce very similar
trend lines. Although PPS produced better results, the instrument was not available at
the point of analysis. WYKO, on the other hand, does not pick up good print roughness
points due to the strong absorbance of light by the black prints. Hence, Stylus was
chosen for this study. It should be noted that paper roughness measured from WYKO
and Stylus were highly correlated. Both have Print and paper roughness measurements
done by Stylus profilometry were used to perform a correlation analysis against print
mottle (see Figure 4-14 and 4-15).
According to Figure 4-14, print mottle in general increases when paper roughness
increases. When comparing the three series of printed samples, it was found that
samples printed using HP 9500 had the steepest slope while samples printed using HP
4700 had the gentlest slope. This meant that HP 9500 is the most sensitive printer to the
paper type and its roughness among all three printers. Therefore, a significant change in
paper roughness does not cause as large a change in print mottle for samples printed
using HP 4700 as similar paper samples printed using HP 2600 and HP 9500.
The dependence of print mottle on the printed area roughness (100% coverage) and the
unprinted area roughness (paper roughness) of similar paper types was examined (see
Figure 4-14 and 4-15). It was found that print mottle increases with both printed
roughness and paper roughness regardless of the printer. It was hypothesized that some
areas were not fully covered with toner even though the samples printed to have 100%
coverage (see Figure 4-16 (b)).
64
Figure 4-14. Impact of Print Mottle (0.1 1mm) on Paper Roughness (Stylus)
Figure 4-15. Impact of Print Mottle (0.1 1mm) on Print Roughness (Stylus)
To validate this hypothesis, Figure 4-16 (a) and (b) show SEM images of an unprinted
and printed area of the same paper, correspondingly. Figure 4-16 (b) shows some areas
that are not covered with toner, thus revealing the underlying fibers of the paper. Since
Stylus is a contact surface profiler, the unfused toner particles will lead to a greater
surface roughness as the stylus tip travels from the highest point of the unfused area to
the bottom gap of the overlapping fibers.
65
Figure 4-16: (a) SEM Image of Paper Sample #9, (b) SEM Image of 100% Black
Coverage on Paper Sample #9 using HP 9500 Printer
Although print roughness of the samples was greater than the unprinted paper
roughness, both Figures 4-14 and 4-15 produce very similar trend line and slopes.
Figure 4-15 shows better correlation to print mottle as compared to the paper roughness
for HP 2600 and HP 9500. On the other hand, the correlation for HP 4700 decreased
from 0.52 to 0.43. Therefore, it can be concluded that both paper and print roughness
play a role in affecting print mottle.
66
Figure 4-19. Uncoated Paper corresponding to (a) Best Rated Sample and (b) Worse
Rated Sample in HP 9500 Series
68
(Refer to Section 4.5). In addition, the correlation produced from printed samples
seemed to be stronger than the unprinted samples. Paper samples have a small
roughness range between 4 to 7 microns (See Figure 4-18), whereas the printed
samples have a wider roughness range (2 to 12 microns). Hence, it was hypothesized
that if the paper is rougher, the addition of toner onto the paper will only make it rougher
due to the uneven toner penetration into the pores and uneven toner fusing due to the
nonuniform heat distribution between the fuser roll, toner, and paper itself.
Figure 4-21. 100% Black Coverage corresponding to (a) Best Rated Sample at
100X Magnification, (b) Best Rated Sample at 500X Magnification, (c) Worst Rated
Sample at 100X Magnification and (d) Worst Rated Sample at 500X Magnification in
HP 9500 Series
Since the fibers of the paper corresponding to the poorly rated samples are not evenly
spaced as seen in Figure 4-19 (b), more and larger patches could be seen after printing
as shown in Figure 4-21 (c). On the other hand, the 100% black coverage image of the
best rated sample shows smaller patches that are more uniformly distributed across the
print (Refer to Figure 4-21 (a)). Due to the uneven fiber network of the paper
69
corresponding to the poorly rated sample, the toner particles tend to be trapped in
between the larger gaps of the overlapping fibers and heat transfer between the toner
particles trapped in the underlying fibers and the fuser roll tend to be poorer. Hence,
more unfused toner particles can be observed from the SEM image in Figure 4-21 (d).
Conversely, since the fibers of the paper corresponding to the best rated sample tend to
be finer and more evenly distributed, most of the toner particles are not trapped below
the fiber layers. Therefore, there is better contact between the toner particles and the
fuser roll. This in turn decreases the amount of unfused toner particles and thus, the
sample tends to look better and less mottled after printing as illustrated in Figure 4-21
(a).
4.3.5
4.4
To determine the critical paper parameters that have an effect on xerographic print
quality, partial least squares (PLS) analysis was performed using the input raw data
shown in Table 4-5.
PLS has the ability to analyze data with strongly correlated and numerous X-variables
while simultaneously model and analyze several Ys (response or output parameters)
together, which has the advantage to give a simpler overall picture than one separate
model for each Y-variable [79]. The 10 different uncoated paper acts as the number of
70
observation points, paper parameters signify the input X-variables, and subjective print
quality; i.e. visual ranking of the 3 different print batches, acts as the output Yi variables.
Table 4-5. PLS Raw Data for Paper versus Print Quality
N (No. of Observations)
Output (Visual
Ranking, Print Mottle)
B - Brightness (%)
C - Caliper (mm)
D - Density (g/cm3)
E - Fiber (Hardwood %)
F - Fluorescence IP
G - Gloss 75 (%)
H - Microgloss
I - Microgloss Nonuniformity
J - HST Sizing (s)
Y1 = HP 2600
Y2 = HP 4700
Y3 = HP 9500
K - Opacity (%)
L - Porosity Gurley (s)
M - PPS Roughness (mm)
N - Youngs Modulus (1000 lb/in2)
4.4.1
Before analyzing the data, it is important to ensure that the Y-variables are correlated.
Hence, principal component analysis (PCA) was performed on the Y-matrix. Since the
principal component for the visual ranking matrix is 1, a single PLSR model with all Ys
can be derived as the 3 Y variables are correlated. Therefore, PLS was performed on
71
the X and Y matrixes and as shown in Figure 4-22, two principle components were
obtained from this model.
Figure 4-22. Principal Component Analysis for Paper versus Visual Ranking
In PLS, R2 and Q2 stand for the goodness of fit and predictive ability respectively. The
higher the R2 and Q2 value, the better fitted is the model; however, it should be noted
that R2 will always increase as the number of principal component increases but Q2 will
start to decrease once predictability of the model decreases. Hence, a trade-off between
R2 and Q2 (difference between R2 and Q2 should be less than 0.2 - 0.3) is required to
obtain the optimal number of principal components and in this case, only two principal
components are required to explain the model. This means that the X-variables are
highly correlated and the first and second components can explain 93.2% and 3.4% of
the model respectively.
Due to the numerous X-variables and observations present, it is necessary to ensure
that the data does not contain any outliers that will affect the overall model predictability.
Hence, a score plot was made as shown in Figure 4-23. In this plot, each observation is
given a pair of scores (i.e. t[1] and t[2]) that corresponds to the value of the principal
component for that observation [21, 79]. Figure 4-23 shows that none of the samples fall
outside the Hotellings T2 95% boundary; hence, it is a good data set. It should be noted
that the paper parameters for the different samples cover a relatively tight range.
72
Figure 4-23. Score Scatter Plot for Paper versus Visual Ranking
In order to have a graphical representation of the effect of each paper parameters (each
X-variable is assigned weights: w*c[1], w*c[2]) on the principal component and the visual
ranking of the 3 different printers, a loading plot is produced as shown in Figure 4-24.
The blue scatter points in Figure 4-24 correspond to the 14 different paper parameters
used in this analysis and the description of each variable can be found in Table 4-5.
Since PC[1] explains most of this model (93.2%), the variables are first analyzed along
the x-axis (i.e. w*c[1]).
Figure 4-24. Scatter Loading Plot for Paper versus Visual Ranking
Figure 4-24 shows the 3 Y-variables cluster around the same area. This further proves
that the Y-variables are highly correlated and hence, paper effects on print quality do not
73
depend on the printer types (i.e. given the same paper quality, it will produce similar print
effect using different printers). Since the X-variables: basis weight, brightness, caliper,
density, fiber hardwood %, fluorescence, gloss 75, microgloss, opacity, and porosity are
clustered on the extreme left of the plot while the Y-variables are on the extreme right, it
can be concluded that those X-variables are negatively correlated to the Y-variables.
This means that an increase in the above mentioned X-variables would lead to a
decrease in visual ranking, which increases print quality. On the other hand, X-variable:
PPS roughness is positively correlated to visual ranking of the 3 printers. This means
that an increase in paper roughness will lead to an increase in visual ranking and a
decrease in print quality. Other X-variables: microgloss nonuniformity, HST sizing, and
youngs modulus are less correlated to visual ranking for the first principal component.
In order to obtain quantitative information about the correlation of these paper
parameters to visual ranking, a coefficient plot is needed as shown in Figure 4-25. The
coefficient plot shows the regression model consisting of the PLS regression coefficients
mean-centered and scaled to a unit variance [21, 79]. Other coefficient plots illustrating
the 2 individual principal components with the different Y-variables can be found in
Appendix E. From these plots, the coefficients obtained can be used to explain the
extent of correlation of each X-variable on the Y-variables as shown in the loading plot.
Figure 4-25. Coefficient Plot of Y-Variable HP 2600 for Paper versus Visual Ranking
Due to the large number of coefficient plots obtained, it is hard to determine the overall
influence of each individual paper parameters on all 3 printers. Hence, in order to
74
determine which X-variable has the highest influence on the response Y-variables, a
variable importance plot is needed as shown in Figure 4-26 and 4-27.
Figure 4-26. Variable Importance Plot of PC[1] for Paper versus Visual Ranking
Figure 4-27. Variable Importance Plot of PC[2] for Paper versus Visual Ranking
The VIP score is the weighted sum of squares of the PLS weights (i.e. w*c[1] or w*c[2]),
taking into account the amount of explained Y-variance in each dimension [21]. Any
variables with VIP scores less than 0.7 are considered to have no significance on the
response Y-variables while those with scores greater than 1.0 have strong influence on
visual ranking, which is a subjective form of print quality [21].
75
As shown in Figures 4-26 and 4-27, the five most important paper parameters that have
an effect on visual ranking include brightness, opacity, basis weight, gloss 75, and PPS
roughness, while the paper parameters that do not have a significant influence on visual
ranking include youngs modulus, HST sizing, and microgloss nonuniformity. Since the
error bars for some of the paper parameters are large, the paper parameters of
importance have similar impact on visual ranking and should not be ranked in order of
importance. It should also be noted that these paper parameters are highly correlated
because only 1 principal component was present when the five most important paper
parameters were correlated against visual ranking. It should be noted that all the optical
properties of paper included in this analysis have a strong effect on visual ranking. As
mentioned in Section 2.2.2, optical properties of paper were shown to play a major role
in affecting print quality in inkjet printing [17, 35]. Based on the results of this study, it can
now be concluded that these properties also have an effect on xerographic print quality.
When optimizing the paper parameters, it is important not to exclude any of the
parameters present in this model because the elimination of any parameters will cause a
significant change in the entire model as the paper parameters are highly correlated.
4.4.2
PLS was performed using similar X-variables as mentioned above using print mottle as
the output variable. The Y-variables in this analysis refer to print mottle or power
spectrum of the 3 different printers at different frequency ranges (i.e. 1 - 5, 5 - 45, 45 450, 450 - 1025). Before analyzing the model, PCA was performed on the Y matrix to
ensure that they are correlated. It was found that Q2 for the overall Y matrix is 0.44;
hence, the correlation between the different frequency ranges of print mottle is weak.
When PLS was performed on the X and Y matrixes, the model could not be produced
and exceeds the maximum allowable principal components (max. of 6 components is
generated). Hence, PLS was performed on the individual frequency ranges and it was
found that print mottle corresponding to a frequency range (1 - 5) produces a negative
Q2 value whereas other frequency ranges produced positive Q2 values. Therefore, data
from the frequency range of 1 - 5 (i.e. >10mm) was excluded in this analysis and a Q2
value of 0.89 was obtained for the new overall Y matrix.
76
Figure 4-28. Principal Component Analysis for Paper versus Print Mottle
Six principle components were obtained from the PLS model (see Figure 4-28). This
indicates that the X and Y variables are not highly correlated. It could be seen from
Figure 4-28 that the Q2 value for component 3 is lower than that of component 2;
whereas components 4 - 6 are higher than those of component 3. However, the first and
second components can explain 73.5% and 8.9% of the model respectively; hence, in
this analysis, emphasis will be placed on the first component.
Figure 4-29. Scatter Loading Plot for Paper versus Print Mottle
77
As shown in Figure 4-29, the blue scatter points correspond to the 14 different paper
parameters used in this analysis and the red scatter points correspond to the different
frequency ranges (5 - 45, 45 - 450, 450 - 1025) of the different printers. Since PC[1]
explains most of this model (73.5%), the variables are first analyzed along the x-axis (i.e.
w*c[1]).
Figure 4-29 shows that the Y-variables of all 3 frequency ranges corresponding to HP
4700 and HP 9500 cluster around the same area above the x-axis, whereas the Yvariables corresponding to HP 2600 cluster below the x-axis. Therefore, it can be
concluded that print mottle obtained from HP 2600 have a negative correlation to those
from HP 4700 and HP 9500. The X-variables that are located on the opposite side of the
plot as opposed to the Y-variables are similar to those produced from the visual ranking
plot, which means that those variables are also negatively correlated to print mottle
produced from all 3 printers.
Figure 4-30. Variable Importance Plot of PC[1] for Paper versus Print Mottle
When comparing Figure 4-24 and 4-29, it was found that although microgloss
nonuniformity does not have a good correlation to visual ranking, it is more correlated to
print mottle, whereas fiber (hardwood %) does not have a significant effect on print
mottle. In order to determine the paper parameters that have a high influence on print
mottle, a variable importance plot is produced as shown in Figure 4-30. From this plot, it
is evident that microgloss nonuniformity, youngs modulus, and HST sizing is less
78
significant to print mottle whereas the five most important paper parameters are similar
to those for visual ranking. However, it should be noted that the order of importance is
dissimilar.
4.5
Figure 4-31. Impact of Different Paper Samples Printed using Three Different
Printers on Visual Ranking
79
Figure 4-32. Plot of HP 4700 and HP 9500 Ranking vs. HP 2600 Ranking
Figure 4-32 shows that there is a strong correlation between the visual ranking results
conducted in HP 4700 and HP 9500 series versus those from the HP 2600 series. This
meant that samples with similar paper properties printed using the different printers
would have almost similar rankings when compared against other samples within each
batch with different paper types. This reconfirms the PLS analysis made in Section 4.4.
In the next section, microscopic images of the best and worse rated samples from the
three batches of print samples were examined and relate to print quality. The different
print patterns and the difference in toner sizes and coverages can be illustrated from
these microscopic images.
4.5.1
In order to have a visual comparison between the best and worst rated print samples
from the different printers, optical images of the print samples were captured and are
shown in Figures 4-33, 4-34, and 4-35. From Figure 4-33, it could be seen that the
different printers have different print patterns. Samples printed using HP 9500 seemed to
have the best visual appearance due to the more even toner coverage whereas samples
from HP 4700 series revealed more fibers and do not seem to be properly covered with
toner.
When similar samples with 40% coverage were analyzed at a higher magnification as
shown in Figure 4-34, it was found that the toner particles are not properly fused in
80
samples from the HP 4700 series printer and the toner particles are generally smaller.
Hence, there is a possibility that there is lesser contact between the toner particles and
the fuser roll. In addition, since the toner particles are smaller, the same percentage of
coverage would mean that less toner mass is present and this might lead to the poor
print quality.
Besides the difference in printer type, the difference in paper type also has an effect on
the visual print quality. As shown in Figure 4-33, the worse rated samples from all three
series have larger and more uncovered patches than the corresponding best rated
samples from similar series. Since softwood fibers tend to be wider, more gaps would be
formed after printing; hence, the increase in hardwood % would enhance the
appearance of the printed images.
Figure 4-33. Optical Microscopic Images of the Worse Rated 100% Black Samples
Corresponding to (a) HP 2600, (b) HP 4700, and (c) HP 9500 series and the Best
Rated Samples for (d) HP2600, (e) HP 4700, and (f) HP 9500 at 10X Magnification
When comparing the toner patterns between the different printers as shown in Figure 435, it was found that even though the samples were printed with 40% coverage, HP
2600 seemed to have more toner particles on the paper samples than those in HP 9500.
This might be due to the toner transfer problem. Since the toner particles seemed to be
larger for HP 2600 than HP 4700 and HP 9500, as evident in Figure 4-34, there might be
81
greater contact between the toner particles, the fuser roll and paper itself. This in turn
increases the dielectric charges of the toner particles and thus increases the toner
transfer efficiency.
Figure 4-34. Optical Microscopic Images of the Worse Rated 40% Black Samples
Corresponding to (a) HP 2600, (b) HP 4700, and (c) HP 9500 series and the Best Rated
Samples for (d) HP2600, (e) HP 4700, and (f) HP 9500 at 50X Magnification
Figure 4-35. Optical Microscopic Images of the Worse Rated 40% Black Samples
Corresponding to (a) HP 2600, (b) HP 4700, and (c) HP 9500 series and the Best
Rated Samples for (d) HP2600, (e) HP 4700, and (f) HP 9500 at 10X Magnification
82
In addition to the toner charge issue, another factor that might have contributed to the
difference in toner transfer is the uneven grayness. This means that even though the
printers were preset to release toner particles that fill up 40% of the paper, the different
printers might have a different released amount and some toner particles might have a
larger spreading angle or wettability factor which contributes to a higher and faster
penetration to drying rate during fusing [54].
Figure 4-36. Microgloss Images of Paper Corresponding to (a) Best Rated Sample and
(b) Worst Rated Sample in HP 9500 series and 100% Black Coverage of (c) Best Rated
Sample and (d) Worst Rated Sample in HP 9500 series
Another factor that contributes to the poor visual quality of the printed samples is the
presence of white spots as shown in Figure 4-36 and 4-37. During microgloss analysis,
it was found that the print images captured have traces of white spots. In order to ensure
these white spots are not saturated images due to overexposure, EDX was performed
on these samples as shown in Figure 4-37 and 4-38.
83
Figure 4-38. EDX Plot Showing Presence of Calcium in White Spot Tested
An energy dispersive X-ray analysis was performed on one of the white spots shown in
Figure 4-37 and the spectrum in Figure 4-38 showed the presence of calcium and
oxygen. Hence, there is likely that the spots were composed of filler particles that stick to
the fuser roll and paper during printing or that the toner layer is insufficient to cover the
underlying particles in the paper. This suggests that besides paper properties, print
properties such as insufficient toner layer and inadequate fuser roll heat and pressure
also can lead to print quality degradation.
84
CHAPTER 5
5.1
CONCLUDING REMARKS
Conclusions
Both paper and printer type have an effect on the quality of xerographic prints.
However, paper plays a major role in affecting xerographic print quality.
The six most important paper parameters (of equal importance) that have a
strong effect on print quality (visual ranking and print mottle) are brightness,
opacity, basis weight, gloss 75o, roughness, and density. These parameters are
highly dependent on each other and a change in one of these parameters will
lead to a significant change in the effect of other paper parameters on print
quality. Hence, there is no perfect printing paper that will produce prints with the
best quality because there has to be a compromise between the different paper
parameters.
All of the optical properties of paper included in this analysis showed a strong
correlation to visual ranking and print mottle due to its strong dependence on the
structure and composition of other paper parameters.
85
Print gloss mottle was found to affect print quality regardless of the mottle size
(i.e. macro or microgloss). However, its effect is not as significant as that of print
mottle.
Paper samples with higher softwood fiber percentage (i.e. broader and wider
fibers) and uneven toner coverage will result in an increase in surface roughness,
which contributes to a poorer visual appearance. This is because toner particles
tend to be trapped in between the larger gaps of the overlapping fibers and heat
transfer between the toner particles trapped in the underlying fibers and the fuser
roll tend to be poorer.
The difference in printer characteristics such as smaller toner particle size, poor
toner coverage and high print speed also result in the poor visual qualities of
printed samples with similar base sheet properties.
5.2
Since the results presented in this study corresponds mainly to the 100% black
prints, similar analysis should also be performed on other color samples to
confirm the effects of paper properties on print quality.
86
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92
APPENDICES
Appendix A Microgloss OPTIMASTM 6.0 Program
93
mG=mG.^2;
psG=psG+mG;
ccc=ccc+1;
end
psG=psG/ccc; %average power spectrum
fr=[1 5 45 450 1025];
totalG=zeros(1,4);
for i=1:4
totalG(i) = sum(psG(fr(i):fr(i+1)));
end
disp('Average power spectrum for 4 frequency ranges for the green color is:')
disp(totalG)
%Blue Channel
B1=ones(1024,1025);
MeanB=mean2(B);
MeanBimage=MeanB*B1;
Mean0imageB=B-MeanBimage;
n=length(Mean0imageB); % 1025
nfft=2^(nextpow2(length(Mean0imageB)));%2048
psB=zeros(1,1025);
ccc=0;
NumUniquePts = ceil((nfft+1)/2);%1025
for i = 1:10:n
FFTB = fft(Mean0imageB(i,:),nfft);
FFTB2 = FFTB(1:NumUniquePts);
mB=abs(FFTB2);
mB=mB/length(Mean0imageB);
mB=mB.^2;
psB=psB+mB;
ccc=ccc+1;
end
psB=psB/ccc; %average power spectrum
fr=[1 5 45 450 1025];
96
totalB=zeros(1,4);
for i=1:4
totalB(i) = sum(psB(fr(i):fr(i+1)));
end
disp('Average power spectrum for 4 frequency ranges for the blue color is:')
disp(totalB)
%Grayscale image
RGB=imread('HMCopyPlus1.tif');
GL=rgb2gray(RGB);
GL=im2double(GL);
GL1=ones(1024,1025);
MeanGL=mean2(GL);
MeanGLimage=MeanGL*GL1;
Mean0image=GL-MeanGLimage;
n=length(Mean0image); % 1025
nfft=2^(nextpow2(length(Mean0image)));%2048
psGL=zeros(1,1025);
ccc=0;
NumUniquePts = ceil((nfft+1)/2);%1025
for i = 1:10:n
FFTGL = fft(Mean0image(i,:),nfft);
FFTGL2 = FFTGL(1:NumUniquePts);
mGL=abs(FFTGL2);
mGL=mGL/length(Mean0image);
mGL=mGL.^2;
psGL=psGL+mGL;
ccc=ccc+1;
end
psGL=psGL/ccc; %average power spectrum
fr=[1 5 45 450 1025];
totalGL=zeros(1,4);
for i=1:4
totalGL(i) = sum(psGL(fr(i):fr(i+1)));
97
end
disp('Average power spectrum for 4 frequency ranges for the grayscale image is:')
disp(totalGL)
From the above algorithm, an example of the power spectrum data of the grayscale
image obtained from the MATLABTM program is as follows:
Average power spectrum for 4 frequency ranges for the grayscale image is:
1.0e-003 *
0.0389
0.0443
0.5075
0.2065
This data means that at frequency range of 1 to 5 (>10mm), the power spectrum is
0.0389E-3. Other frequency ranges include 5 to 45 (1 to 10mm), 45 to 450 (0.1 to 1mm),
and 450 to 1025 (<0.1mm).
98
ranges as follows: 1 - 2 (>10mm), 2 - 11 (1 to 10mm), 11 - 106 (0.1 to 1mm), and 106 513 (<0.1mm) and the power spectrums obtained signify gloss mottle.
Image=imread('image 1 - 1800.tif');
Image=im2double(Image);
%info=imfinfo('HMCopyPlus_2.tif')
Image1=ones(612,612);
MeanImage=mean2(Image);
MeanImageImage=MeanImage*Image1;
Mean0Image=Image-MeanImageImage;
n=length(Mean0Image) % 1025
nfft=2^(nextpow2(length(Mean0Image)));%2048
psImage=zeros(1,513);
ccc=0;
NumUniquePts = ceil((nfft+1)/2)%1025
for i = 1:10:n
FFTImage = fft(Mean0Image(i,:),nfft);
FFTImage2 = FFTImage(1:NumUniquePts);
mImage=abs(FFTImage2);
mImage=mImage/length(Mean0Image);
mImage=mImage.^2;
psImage=psImage+mImage;
ccc=ccc+1;
end
psImage=psImage/ccc; %average power spectrum
fr=[1 2 11 106 513];
totalImage=zeros(1,4);
for i=1:4
totalImage(i) = sum(psImage(fr(i):fr(i+1)));
end
disp('Average power spectrum for 4 frequency ranges for the grayscale image is:')
disp(totalImage)
99
100
4. The second condenser lens forms the electrons into a thin, tight, coherent beam and
is usually controlled by the "fine probe current knob".
5. A user selectable objective aperture further eliminates high-angle electrons from the
beam.
6. A set of coils then "scan" or "sweep" the beam in a grid fashion (like a television),
dwelling on points for a period of time determined by the scan speed (usually in the
microsecond range).
7. The final lens, the Objective, focuses the scanning beam onto the part of the
specimen desired.
8. When the beam strikes the sample (and dwells for a few microseconds) interactions
occur inside the sample and are detected with various instruments.
9. Before the beam moves to its next dwell point these instruments count the number of
interactions and display a pixel on a CRT whose intensity is determined by this
number (the more reactions the brighter the pixel).
10. This process is repeated until the grid scan is finished and then repeated, the entire
pattern can be scanned 30 times per second.
101
Paper
Gloss 75o
Paper Microgloss
Avg
Std
Paper Microgloss
Nonuniformity
Avg
Std
HM Copy Plus
6.2
861.1
9.8
35.8
2.4
HP Office Riverdale
7.1
859.2
3.5
42.0
2.9
HP Office C35
5.8
859.5
7.4
39.5
0.7
HM Laser Print Ti
10.5
972.5
13.0
48.9
1.8
Premium Multipurpose
7.4
900.7
6.2
37.0
1.8
HP Multipurpose C35
7.1
900.3
7.1
35.7
1.8
HM Color Copy Ti
10.8
978.0
5.5
42.9
1.5
HP Color Laser Ti
10.9
915.3
17.6
42.2
2.0
HP Premium Choice Ti
11.2
902.1
9.2
40.8
1.0
LaserJet Saillat
7.7
846.0
5.5
31.5
0.9
Table D-2. Print Gloss, Microgloss, & Nonuniformity for HP2600 Print Samples
Paper Samples
(HP 2600)
Print
Gloss 75o
Avg
Std
Print Microgloss
Nonuniformity
Avg
Std
Print Microgloss
HM Copy Plus
24.7
335.2
13.8
101.3
5.4
HP Office Riverdale
21.7
281.4
13.0
96.9
2.5
HP Office C35
20.5
287.7
8.0
102.4
3.3
HM Laser Print Ti
27.7
316.2
9.5
74.9
6.7
Premium Multipurpose
27.3
325.2
8.8
85.2
3.9
HP Multipurpose C35
23.4
331.5
28.2
95.5
9.6
HM Color Copy Ti
21.0
238.1
7.5
52.4
2.0
HP Color Laser Ti
27.7
317.3
6.1
77.7
3.8
HP Premium Choice Ti
29.6
360.5
17.8
88.8
5.4
LaserJet Saillat
23.0
281.8
5.2
92.2
1.8
102
Table D-3. Print Gloss, Microgloss, & Nonuniformity for HP4700 Print Samples
Paper Samples
(HP 4700)
Print
Gloss 75o
Avg
Std
Print Microgloss
Nonuniformity
Avg
Std
Print Microgloss
HM Copy Plus
18.1
246.1
3.7
77.9
4.2
HP Office Riverdale
17.4
246.8
7.7
80.1
7.1
HP Office C35
14.9
227.3
7.8
84.5
3.7
HM Laser Print Ti
23.0
287.5
8.6
73.0
2.4
Premium Multipurpose
24.2
283.5
7.7
79.1
4.1
HP Multipurpose C35
20.7
261.9
9.0
79.8
2.7
HM Color Copy Ti
27.0
306.3
10.1
76.2
2.3
HP Color Laser Ti
26.5
318.1
13.1
79.1
3.6
HP Premium Choice Ti
25.3
309.5
9.8
80.2
4.7
LaserJet Saillat
18.8
260.5
4.6
92.2
4.1
Table D-4. Print Gloss, Microgloss, & Nonuniformity for HP9500 Print Samples
Paper Samples
(HP 9500)
Print
Gloss 75o
Avg
Std
Print Microgloss
Nonuniformity
Avg
Std
Print Microgloss
HM Copy Plus
18.2
265.3
5.3
71.1
3.4
HP Office Riverdale
15.5
240.4
7.9
71.4
5.7
HP Office C35
16.2
240.4
6.9
75.2
7.1
HM Laser Print Ti
18.6
247.5
7.6
48.4
1.5
Premium Multipurpose
17.2
232.7
12.1
51.6
5.5
HP Multipurpose C35
16.4
223.7
12.9
53.6
4.8
HM Color Copy Ti
17.9
235.2
10.4
43.6
2.6
HP Color Laser Ti
19.7
259.9
6.6
50.0
2.2
HP Premium Choice Ti
15.5
204.6
8.8
40.2
4.1
LaserJet Saillat
15.1
217.3
4.7
59.0
1.8
103
Table D-5. Paper & Print Roughness (Rq) for Different Paper & Print Samples
Paper Roughness (
m)
Paper Samples
WYKO
STYLUS
HP 4700
Avg
Std
Avg
Std
Avg
Std
HM Copy Plus
5.44
0.8
5.54
1.8
7.23
HP Office Riverdale
5.69
0.6
6.47
1.8
7.39
5.7
7.99
3.0
9.06
7.1
HP Office C35
5.39
0.5
5.34
1.1
5.87
1.1
5.50
2.9
6.91
2.5
HM Laser Print Ti
4.05
0.4
4.82
2.6
1.69
0.1
3.60
0.3
3.99
1.5
Premium Multipurpose
5.68
0.8
5.32
2.7
5.55
0.8
4.87
1.1
3.70
1.2
HP Multipurpose C35
5.03
0.8
4.36
1.6
3.80
0.1
4.14
1.3
2.73
0.1
HM Color Copy Ti
4.05
0.6
4.25
1.1
2.71
0.1
2.35
0.6
2.94
1.7
HP Color Laser Ti
4.21
0.5
4.14
0.9
2.45
0.6
3.23
0.8
2.76
1.2
0.5
4.87
1.5
2.09
0.1
4.17
0.9
2.07
1.0
LaserJet Saillat
0.5
5.56
1.9
5.76
1.5
6.07
1.5
4.57
1.6
4.83
Avg
Std
HP 9500
Avg
Std
HP 2600
HP 4700
HP 9500
Avg
Std
Avg
Std
Avg
Std
HM Copy Plus
1.62
0.02
1.35
0.01
1.38
0.00
HP Office Riverdale
1.59
0.01
1.34
0.01
1.34
0.01
HP Office C35
1.58
0.02
1.32
0.01
1.33
0.02
HM Laser Print Ti
1.65
0.01
1.36
0.01
1.35
0.01
Premium Multipurpose
1.62
0.03
1.34
0.01
1.34
0.01
HP Multipurpose C35
1.61
0.00
1.31
0.02
1.36
0.01
HM Color Copy Ti
1.56
0.01
1.33
0.02
1.38
0.01
HP Color Laser Ti
1.63
0.02
1.32
0.01
1.37
0.00
HP Premium Choice Ti
1.62
0.02
1.29
0.01
1.36
0.01
LaserJet Saillat
1.59
0.00
1.36
0.01
1.39
0.00
104
As mentioned in Section 3.3.2, the power spectrum obtained from each frequency range
corresponds to the print mottle of a particular wavelength or size. Frequency range of 1 5, 5 - 45, 45 - 450, and 450 - 1025 corresponds to wavelength in the range of >10mm, 1
- 10mm, 0.1 - 1mm, and <0.1mm respectively.
Table D-7. Power Spectrum for HP2600 Print Samples (Grayscale)
Paper Samples
(HP 2600)
1-5
Avg
Std
5 - 45
Avg
Std
45 - 450
Avg
Std
450 - 1025
Avg
Std
HM Copy Plus
HP Office Riverdale
HP Office C35
HM Laser Print Ti
Premium Multipurpose
HP Multipurpose C35
HM Color Copy Ti
HP Color Laser Ti
HP Premium Choice Ti
LaserJet Saillat
1-5
Avg
Std
5 - 45
Avg
Std
45 - 450
Avg
Std
450 - 1025
Avg
Std
HM Copy Plus
HP Office Riverdale
HP Office C35
HM Laser Print Ti
Premium Multipurpose
HP Multipurpose C35
HM Color Copy Ti
HP Color Laser Ti
HP Premium Choice Ti
LaserJet Saillat
105
1-5
Avg
Std
5 - 45
Avg
Std
45 - 450
Avg
Std
450 - 1025
Avg
Std
HM Copy Plus
HP Office Riverdale
HP Office C35
HM Laser Print Ti
Premium Multipurpose
HP Multipurpose C35
HM Color Copy Ti
HP Color Laser Ti
HP Premium Choice Ti
LaserJet Saillat
For gloss mottle, the power spectrum obtained from each frequency range corresponds
to the gloss mottle of a particular wavelength or size. Frequency range of 1 - 2, 2 - 11, 11
- 106, and 106 - 612 corresponds to wavelength in the range of >10mm, 1 - 10mm, 0.1 1mm, and <0.1mm respectively.
Table D-10. Power Spectrum for HP2600 Gloss Samples (Grayscale)
Paper Samples
(HP 2600)
1-2
Avg
Std
2 - 11
Avg
Std
11 - 106
Avg
Std
106 - 612
Avg
Std
HM Copy Plus
HP Office Riverdale
HP Office C35
HM Laser Print Ti
Premium Multipurpose
HP Multipurpose C35
HM Color Copy Ti
HP Color Laser Ti
HP Premium Choice Ti
LaserJet Saillat
106
1-2
Avg
Std
2 - 11
Avg
Std
11 - 106
Avg
Std
106 - 612
Avg
Std
HM Copy Plus
HP Office Riverdale
HP Office C35
HM Laser Print Ti
Premium Multipurpose
HP Multipurpose C35
HM Color Copy Ti
HP Color Laser Ti
HP Premium Choice Ti
LaserJet Saillat
1-2
Avg
Std
2 - 11
Avg
Std
11 - 106
Avg
Std
106 - 612
Avg
Std
HM Copy Plus
HP Office Riverdale
HP Office C35
HM Laser Print Ti
Premium Multipurpose
HP Multipurpose C35
HM Color Copy Ti
HP Color Laser Ti
HP Premium Choice Ti
LaserJet Saillat
107
Figure E-1. Coefficient Plot of PC[1] and Y-Variable HP 4700 and HP 9500
108
Figure E-2. Coefficient Plot of PC[2] and Y-Variable HP 2600, 4700 and 9500
109
110
Figure E-5. WYKO Images of Paper Corresponding to (a) Worst Rated Sample and (b)
Best Rated Sample in HP 9500 series and 100% Black Coverage of (c) Worst Rated
Sample and (d) Best Rated Sample in HP 9500 series
In Figure E-5, WYKO analysis performed on the uncoated paper also shows that the
paper corresponding to the best rated sample has more uniformly covered fibers, similar
to that obtained from the SEM images. In addition, the best rated sample has a lower
roughness value than the worst rated sample. When the 100% black samples were
analyzed, small patches of toner particles can be seen on the best rated sample while
large patches and fibers can be detected on the worst rated sample. It was also noted
that the roughness value for the printed samples are lower than that of the base paper.
Hence, this reconfirms that besides print roughness, paper roughness also has a strong
effect on xerographic print quality.
111
112
Figure F-1. 3D Topographic Maps Illustrating the Print Surface of the 10 Different Paper
Samples Printed Using 3 Different Printers
113