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Fly ash, known also as pulverized-fuel ash, is the ash precipitated electrostatically or
mechanically from the exhaust gases of coal-fired power station; it is the most common artificial
pozzolana. The fly ash particles are spherical and have a very high fineness: the vast majority of
particles have a diameter between less than 1m and 100m, and the specific surface of fly ash
is usually between 250 and 600 m2/kg. The high specific surface of fly ash means that the
material is readily available for reaction with calcium hydroxide. The specific surface of fly ash
is not easy to determine because, in the air permeability test, the spherical particles pack more
closely than the irregularly shaped particles of cement so that the resistance of fly ash to air flow
is greater.
The fly ash may affect the colour of the resulting concrete, the carbon in the ash making it
darker. This may be important in the case of appearance, especially when concrete with and
without fly ash are placed side by side.
Class-C fly ash, that is, high lime ash originating from lignite coal. Such ash occasionally have a
lime content as high as 24%. High lime ash has some cementitious (hydraulic) properties of its
own but, because its lime will combine with the silica and alumina portions of the ash, there will
be less amount of these compounds to react with the lime liberated by the hydration of cement.
The carbon content is low, the fineness is high, and the colour is light. However, the MgO
content can be high, and some of the MgO as well as the lime can lead to deleterious expansion.
present at the surface of the fly ash particles. The retardation may be
advantageous when concreting in hot weather; otherwise, an accelerator may be needed. Only
initial setting is delayed, the time interval between setting and final stiffening being unaffected.
propagation, and stiffness. The resulting system of capillary pores is better able to retain water
which can be available for long term hydration.
The glass content in the fly ash strongly affects its reactivity. In the case of Class C fly ash, the
lime content is also a factor influencing reactivity. However, for knowing the performance tests
are necessary; tests with the actual Portland cement to be used are preferable.
The beneficial influence of fly ash upon water demand does not extend beyond a fly ash content
20% by mass. As excessive content of fly ash is nit beneficial from the point of view of strength
development either. The limiting content is probably around 30% by mass of the total
cementitious material, as shown.
As for the physical properties of the concrete other than strength, it appears that creep and
shrinkage are not fundamentally affected by the use of fly ash.