RE TNORM Disposal in KY (399) - FairmontBrineRadchem

#=CL#
Pace Analytical Services, Inc.

1638 Roseytown Road - Suites 2,3,4
Greensburg, PA 15601
(724)850-5600
LIMS USE: FR - RICK QUINN

LIMS OBJECT ID: 30150255
June 16, 2015
Rick Quinn
Waste Management
1488 Dawson Drive
Suite 102
Bridgeport, WV 26330
RE: Project: Fairmont Brine - Sludge Pit Cl

Pace Project No.: 30150255
Dear Rick Quinn:
Enclosed are the analytical results for sample(s) received by the laboratory on June 09, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Timothy Reed
timothy.reed@pacelabs.com
Project Manager
Enclosures
cc: Joni Edgells-Smith, Waste Management
REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 31
#=CP#

(724)850-5600
CERTIFICATIONS
Project:
Fairmont Brine - Sludge Pit Cl
Pace Project No.:
30150255
Pennsylvania Certification IDs

1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ACLASS DOD-ELAP Accreditation #: ADE-1544
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California/TNI Certification #: 04222CA
Colorado Certification
Connecticut Certification #: PH-0694
Delaware Certification
Florida/TNI Certification #: E87683
Guam/PADEP Certification
Hawaii/PADEP Certification
Idaho Certification
Illinois/PADEP Certification
Indiana/PADEP Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: 90133
Louisiana DHH/TNI Certification #: LA140008
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: PA00091
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification
Missouri Certification #: 235
Montana Certification #: Cert 0082

Nebraska Certification #: NE-05-29-14
Nevada Certification
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New Mexico Certification
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Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
South Dakota Certification
Tennessee Certification #: TN2867
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Utah/TNI Certification #: PA014572014-4
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West Virginia DHHR Certification #: 9964C
Wisconsin/PADEP Certification
Wyoming Certification #: 8TMS-Q

Page 2 of 31
#=SS#

(724)850-5600
SAMPLE SUMMARY
Project:
Pace Project No.:
30150255
Lab ID
Sample ID
30150255001
Matrix
Date Collected
Date Received
Solid
06/08/15 09:25
06/09/15 15:45

Page 3 of 31
#=SA#

(724)850-5600
SAMPLE ANALYTE COUNT

Project:
Pace Project No.:
30150255
Lab ID
Sample ID
30150255001
Method
Analysts
EPA 6010B
RAC
Analytes
Reported
Laboratory
11
PASI-PA
EPA 7470A
RAC
PASI-PA
EPA 8270C
DJL
18
PASI-PA
EPA 8260B
CLG
13
PASI-PA
ASTM D2974-87
TAW
PASI-PA
EPA 901.1
MAH
10
PASI-PA
EPA 1010
DEH
PASI-PA
EPA 160.4
DEH
PASI-PA
EPA 9045C
DEH
PASI-PA
EPA 9071B
DLH
PASI-PA
EPA 9095A
DEH
PASI-PA
SW-846 7.3.4.2
KAS
PASI-PA
EPA 9012A
BMS
PASI-PA

Page 4 of 31
#=AR#

(724)850-5600
ANALYTICAL RESULTS
Project:
Pace Project No.:
30150255
Sample: Fairmont Brine - Sludge Pit

Lab ID: 30150255001
Collected: 06/08/15 09:25 Received: 06/09/15 15:45 Matrix: Solid
Cl
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
6010 MET ICP, TCLP
Qual
Analytical Method: EPA 6010B Preparation Method: EPA 3005A

Leachate Method/Date: EPA 1311; 06/11/15 15:23 Initial pH: 7.92; Final pH: 4.9
Arsenic
Barium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Strontium
Zinc
7470 Mercury, TCLP
ND
ND
ND
ND
ND
ND
0.12
ND
ND
65.9
0.21
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0.050
1.0
0.050
0.050
0.050
0.050
0.10
0.10
0.050
0.50
0.20
0.0045
0.00080
0.00055
0.00073
0.0020
0.0036
0.0017
0.0046
0.00082
0.0052
0.0027
1
1
1
1
1
1
1
1
1
10
1
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/12/15 14:03
06/15/15 15:35
06/15/15 15:35
06/15/15 15:35
06/15/15 15:35
06/15/15 15:35
06/15/15 15:35
06/15/15 15:35
06/15/15 15:35
06/15/15 15:35
06/15/15 16:43
06/15/15 15:35
7440-38-2
7440-39-3
7440-43-9
7440-47-3
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-24-6
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A

Mercury
8270 MSSV TCLP
ND
ug/L
1.0
0.022
06/12/15 13:23 06/15/15 09:57 7439-97-6
Analytical Method: EPA 8270C Preparation Method: EPA 3535A

1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,5-Trichlorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
80
74
56
83
89
90
%
%
%
%
%
%
500
100
100
100
500
2000
2000
100
5000
500
5000
100
9.0
35.3
7.9
13.5
15.1
16.8
39.9
13.0
45.3
17.6
21.9
21.7
38-129
49-105
10-101
48-121
51-128
64-115
1
1
1
1
1
1
1
1
1
1
1
1
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
106-46-7
121-14-2
87-68-3
118-74-1
67-72-1
95-48-7
1
1
1
1
1
1
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 09:35
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
06/15/15 16:49
4165-60-0
321-60-8
1718-51-0
13127-88-3
367-12-4
118-79-6
98-95-3
87-86-5
110-86-1
95-95-4
88-06-2
M1
Analytical Method: EPA 8260B Leachate Method/Date: EPA 1311; 06/11/15 18:34
192
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
50.0
5000
50.0
1000
0.16
2.4
0.22
0.13
1
1
1
1
06/12/15 14:26
06/12/15 14:26
06/12/15 14:26
06/12/15 14:26
71-43-2
78-93-3
56-23-5
108-90-7

Date: 06/16/2015 05:39 PM
Page 5 of 31
#=AR#

(724)850-5600
ANALYTICAL RESULTS
Project:
Pace Project No.:
30150255

Lab ID: 30150255001
Collected: 06/08/15 09:25 Received: 06/09/15 15:45 Matrix: Solid
Cl
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
8260 MSV TCLP
Chloroform
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture
1010 Flashpoint,Closed Cup
Flashpoint
160.4 Total Volatile Solids
Total Volatile Solids
9045 pH Soil
pH at 25 Degrees C
9071 Oil and Grease/TPH
Oil and Grease
9095 Paint Filter Liquid Test
Free Liquids
735S Reactive Sulfide
Sulfide, Reactive
9012 Cyanide, Total
Cyanide
Qual
Analytical Method: EPA 8260B Leachate Method/Date: EPA 1311; 06/11/15 18:34
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
98
105
102
%
%
%
500
50.0
50.0
50.0
50.0
50.0
0.19
0.36
0.26
0.29
0.33
0.20
1
1
1
1
1
1
06/12/15 14:26
06/12/15 14:26
06/12/15 14:26
06/12/15 14:26
06/12/15 14:26
06/12/15 14:26
1
1
1
06/12/15 14:26 17060-07-0

06/12/15 14:26 2037-26-5
06/12/15 14:26 460-00-4
06/15/15 17:41
06/10/15 14:30
10.0
06/10/15 14:37
1.0
06/09/15 23:23
84-124
79-118
84-113
67-66-3
107-06-2
75-35-4
127-18-4
79-01-6
75-01-4
Analytical Method: ASTM D2974-87

55.0
0.10
0.10
Analytical Method: EPA 1010

>200
deg F
60.0
Analytical Method: EPA 160.4

10.2
% (w/w)
10.0
Analytical Method: EPA 9045C

5.9
Std. Units
1.0
Analytical Method: EPA 9071B Preparation Method: EPA 9071B

26900
mg/kg
222
24.9
06/12/15 12:00 06/15/15 08:00
1.0
1.0
06/10/15 15:00
22.1
06/10/15 18:00
Analytical Method: EPA 9095A

FAIL
Analytical Method: SW-846 7.3.4.2

ND
mg/kg
22.1
Analytical Method: EPA 9012A Preparation Method: EPA 9012A

ND
mg/kg
1.1
0.17
06/15/15 18:00 06/15/15 21:47 57-12-5
M1,R1

Date: 06/16/2015 05:39 PM
Page 6 of 31
#=QC#

(724)850-5600
QUALITY CONTROL DATA

Project:
Pace Project No.:
30150255
QC Batch:
MERP/6597
Analysis Method:
EPA 7470A
QC Batch Method:
EPA 7470A
Analysis Description:
7470 Mercury TCLP
Associated Lab Samples:

METHOD BLANK:
30150255001
906820
Matrix: Water
30150255001
Parameter
Units
Mercury
Blank
Result
ug/L
LABORATORY CONTROL SAMPLE:

Parameter
ug/L
MATRIX SPIKE SAMPLE:

Parameter
ug/L

Parameter
Mercury
SAMPLE DUPLICATE:
06/15/15 09:12
Spike
Conc.
LCS
Result
LCS
% Rec
1.0
30149653002
Result
Spike
Conc.
% Rec
Limits
100
Qualifiers
85-115
1.0 U
MS
Result
2.5
MS
% Rec
2.6
% Rec
Limits
104
Qualifiers
80-120
906825
Units
30149957001
Result
ug/L
0.000022U mg/L
Spike
Conc.
MS
Result
2.5
MS
% Rec
2.8
% Rec
Limits
111
Qualifiers
80-120
906822
Parameter
Units
Mercury
ug/L
SAMPLE DUPLICATE:
1.0
Qualifiers
906823
Units
Mercury
ND
Analyzed
906821
Units
Mercury
Reporting
Limit
30149653002
Result
Dup
Result
1.0 U
RPD
Max
RPD
ND
Qualifiers
20
906824
Parameter
Mercury
Units
ug/L
30149957001
Result
0.000022U
mg/L
Dup
Result
RPD
ND
Max
RPD
Qualifiers
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Date: 06/16/2015 05:39 PM
Page 7 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
MPRP/15754
Analysis Method:
EPA 6010B
QC Batch Method:
EPA 3005A
6010 MET TCLP

METHOD BLANK:
30150255001
906876
Matrix: Water
30150255001
Parameter
Blank
Result
Units
Arsenic
Barium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Strontium
Zinc
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Spike
Conc.
Units
Arsenic
Barium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Strontium
Zinc
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Arsenic
Barium
Cadmium
Chromium
Copper
Lead
Nickel
0.050
1.0
0.050
0.050
0.050
0.050
0.10
0.10
0.050
0.050
0.20
Analyzed
Qualifiers
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
06/15/15 15:56
906877
Parameter
Parameter
Reporting
Limit
LCS
Result
.5
.5
.5
.5
.5
.5
.5
.5
.25
.5
.5
0.49
.49J
0.51
0.52
0.49
0.50
0.50
0.50
0.25
0.49
0.53
906879
Units
30149653002
Result
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0.050 U
0.61J
0.050 U
0.00077J
0.0088J
0.013J
0.0055J
LCS
% Rec
% Rec
Limits
99
98
103
105
98
99
101
101
100
99
106
Qualifiers
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
906880
MS
Spike
Conc.
MSD
Spike
Conc.
.5
.5
.5
.5
.5
.5
.5
MS
Result
.5
.5
.5
.5
.5
.5
.5
0.53
1.1
0.53
0.49
0.51
0.51
0.45
MSD
Result
MS
% Rec
0.54
1.2
0.53
0.50
0.51
0.51
0.46
106
108
106
99
100
99
89
MSD
% Rec
107
110
107
100
101
99
90
% Rec
Limits
Max
RPD RPD
75-125
75-125
75-125
75-125
75-125
75-125
75-125
0
1
1
2
1
0
1
Qual
20
20
20
20
20
20
20

Date: 06/16/2015 05:39 PM
Page 8 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
Parameter
Selenium
Silver
Strontium
Zinc

Parameter
906879
Units
30149653002
Result
mg/L
mg/L
mg/L
mg/L
0.0063J
0.050 U
0.15
0.038J
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
SAMPLE DUPLICATE:
.5
.25
.5
.5
.5
.25
.5
.5
MS
Result
0.56
0.27
0.65
0.52
MSD
Result
MS
% Rec
0.56
0.27
0.66
0.53
MSD
% Rec
110
107
101
96
111
109
103
98
% Rec
Limits
Max
RPD RPD
75-125
75-125
75-125
75-125
1
2
1
2
Qual
20
20
20
20
30149957001
Result
0.0049J
0.77J
0.00055U
0.0012J
0.0020U
0.0036U
0.0042J
0.0094J
0.00082U
1.9
0.0073J
Spike
Conc.
MS
Result
.5
.5
.5
.5
.5
.5
.5
.5
.25
.5
.5
MS
% Rec
0.56
1.3
0.57
0.51
0.53
0.51
0.46
0.59
0.29
2.4
0.50
% Rec
Limits
112
107
113
101
107
103
92
117
117
113
100
Qualifiers
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
906878
Parameter
Units
Arsenic
Barium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Strontium
Zinc
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
SAMPLE DUPLICATE:
MSD
Spike
Conc.
906882
Units
Arsenic
Barium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Strontium
Zinc
906880
MS
Spike
Conc.
30149653002
Result
0.050 U
0.61J
0.050 U
0.00077J
0.0088J
0.013J
0.0055J
0.0063J
0.050 U
0.15
0.038J
Dup
Result
Max
RPD
RPD
.0047J
.6J
ND
ND
.0083J
.011J
.0066J
.0056J
ND
0.15
.039J
Qualifiers
20
20
20
20
20
20
20
20
20
20
20
906881
Parameter
Arsenic
Barium
Cadmium
Units
mg/L
mg/L
mg/L
30149957001
Result
0.0049J
0.77J
0.00055U
Dup
Result
RPD
ND
.78J
ND
Max
RPD
Qualifiers
20
20
20

Date: 06/16/2015 05:39 PM
Page 9 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
SAMPLE DUPLICATE:
906881
Parameter
Chromium
Copper
Lead
Nickel
Selenium
Silver
Strontium
Zinc
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
30149957001
Result
0.0012J
0.0020U
0.0036U
0.0042J
0.0094J
0.00082U
1.9
0.0073J
Dup
Result
Max
RPD
RPD
ND
ND
ND
.005J
.01J
ND
1.9
.0075J
Qualifiers
20
20
20
20
20
20
20
20

Date: 06/16/2015 05:39 PM
Page 10 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
MSV/23797
Analysis Method:
EPA 8260B
QC Batch Method:
EPA 8260B
8260 MSV TCLP

METHOD BLANK:
30150255001
906715
Matrix: Water
30150255001
Parameter
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
Benzene
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Toluene-d8 (S)

Parameter
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
Benzene
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Toluene-d8 (S)

Parameter
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
Benzene
Units
Blank
Result
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
95
103
102
50.0
50.0
5000
50.0
50.0
1000
500
50.0
50.0
50.0
84-124
84-113
79-118
Analyzed
Qualifiers
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
06/12/15 11:26
906716
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
Spike
Conc.
LCS
Result
200
200
200
200
200
200
200
200
200
200
LCS
% Rec
213
195
215J
241
234
233J
209J
230
228
207
% Rec
Limits
107
98
108
120
117
116
105
115
114
104
88
101
105
Qualifiers
58-126
66-124
69-126
69-123
52-133
72-121
63-123
62-131
66-125
58-131
84-124
84-113
79-118
906750
Units
ug/L
ug/L
ug/L
ug/L
30149813001
Result
ND
ND
ND
ND
Spike
Conc.
MS
Result
200
200
200
200
179
189
190J
181
MS
% Rec
% Rec
Limits
90
95
95
91
Qualifiers
58-126
66-124
69-126
69-123

Date: 06/16/2015 05:39 PM
Page 11 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
906750
Parameter
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Toluene-d8 (S)
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
Benzene
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Toluene-d8 (S)
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
Parameter
30149813001
Result
Units
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
906751
30150424001
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Spike
Conc.
MS
Result
200
200
200
200
200
200
MS
% Rec
197
178J
181J
187
182
172
% Rec
Limits
98
89
91
93
91
86
105
103
99
Qualifiers
52-133
72-121
63-123
62-131
66-125
58-131
84-124
84-113
79-118
906752
MS
Spike
Conc.
200
200
200
200
200
200
200
200
200
200
MSD
Spike
Conc.
200
200
200
200
200
200
200
200
200
200
MS
Result
223
241
226J
236
259
238J
232J
224
238
191
MSD
Result
MS
% Rec
151
151
159J
150
165
150J
147J
149
150
154
112
120
113
118
130
119
116
112
119
95
103
98
102
MSD
% Rec
75
75
79
75
83
75
73
74
75
77
116
100
99
% Rec
Limits
Max
RPD RPD
58-126
66-124
69-126
69-123
52-133
72-121
63-123
62-131
66-125
58-131
84-124
84-113
79-118
39
46
45
44
40
45
21
30
30
30
30
30
30
30
30
30
30
Qual
R1
R1
R1
R1
R1
R1

Date: 06/16/2015 05:39 PM
Page 12 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
OEXT/24026
Analysis Method:
EPA 8270C
QC Batch Method:
EPA 3535A
8270 TCLP MSSV

METHOD BLANK:
30150255001
907395
Matrix: Water
30150255001
Parameter
Units
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Terphenyl-d14 (S)
METHOD BLANK:
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
%
%
%
907400
Blank
Result
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
82
74
88
85
83
58
500
5000
100
100
2000
2000
100
100
500
100
5000
500
64-115
49-105
51-128
38-129
48-121
10-101
Analyzed
Qualifiers
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
06/15/15 10:48
Matrix: Water
30150255001
Parameter
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
%
Blank
Result
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
80
74
89
83
500
5000
100
100
2000
2000
100
100
500
100
5000
500
64-115
49-105
51-128
38-129
Analyzed
Qualifiers
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28
06/15/15 11:28

Date: 06/16/2015 05:39 PM
Page 13 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
METHOD BLANK:
907400
Matrix: Water
30150255001
Parameter
Phenol-d6 (S)
Terphenyl-d14 (S)
%
%
83
56
Spike
Conc.
Units
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Terphenyl-d14 (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
%
%
%
1,4-Dichlorobenzene
2,4-Dinitrotoluene
3&4-Methylphenol(m&p
Cresol)
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
Reporting
Limit
48-121
10-101
Analyzed
Qualifiers
06/15/15 11:28
06/15/15 11:28
907396
Parameter
Parameter
Blank
Result
Units
LCS
Result
500
500
500
500
500
1000
500
500
500
500
500
500
LCS
% Rec
357J
437J
419
409
411J
853J
322
246
347J
433
512J
139J
907398
% Rec
Limits
71
87
84
82
82
85
64
49
69
87
102
28
82
71
86
83
82
52
Qualifiers
49-85
63-117
61-110
51-113
64-109
64-113
43-95
33-80
44-93
61-126
40-111
10-63
64-115
49-105
51-128
38-129
48-121
10-101
907399
MS
Spike
Conc.
MSD
Spike
Conc.
Units
30150255001
Result
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
500
500
500
500
500
1000
500
500
500
500
500
1000
395J
448J
433
415
418J
849J
417J
477J
471
451
454J
927J
79
90
87
83
81
85
83
95
94
90
89
93
49-85
63-117
61-110
51-113
64-109
64-113
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
ND
ND
ND
ND
ND
ND
500
500
500
500
500
500
500
500
500
500
500
500
367
287
301J
429
562J
108J
389
330
322J
461
603J
132J
73
57
60
86
112
22
90
78
66
64
92
121
26
97
43-95
33-80
44-93
61-126
40-111
10-63
64-115
Max
RPD RPD
8
8
6
14
7
Qual
46
38
36
43
33
33
49
62
53
38
46 M1
51

Date: 06/16/2015 05:39 PM
Page 14 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
Parameter
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Terphenyl-d14 (S)
Units
907398
30150255001
Result
907399
MS
Spike
Conc.
MSD
Spike
Conc.
MS
Result
MSD
Result
MS
% Rec
%
%
%
%
%
77
90
84
84
69
MSD
% Rec
80
96
90
91
84
% Rec
Limits
Max
RPD RPD
Qual
49-105
51-128
38-129
48-121
10-101

Date: 06/16/2015 05:39 PM
Page 15 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
PMST/5395
Analysis Method:
ASTM D2974-87
QC Batch Method:
ASTM D2974-87
Dry Weight/Percent Moisture

SAMPLE DUPLICATE:
30150255001
907855
Parameter
Units
Percent Moisture
SAMPLE DUPLICATE:
30149555001
Result
Dup
Result
20.2
Max
RPD
RPD
20.7
Qualifiers
20
907856
Parameter
Percent Moisture
Units
%
30149555004
Result
23.8
Dup
Result
Max
RPD
RPD
14.5
48
Qualifiers
20 D6

Date: 06/16/2015 05:39 PM
Page 16 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
WET/28683
Analysis Method:
EPA 1010
QC Batch Method:
EPA 1010
1010 Flash Point, Closed Cup

METHOD BLANK:
30150255001
905329
Matrix: Water
30150255001
Parameter
Blank
Result
Units
Flashpoint
deg F
SAMPLE DUPLICATE:
Reporting
Limit
>200
60.0
Analyzed
Qualifiers
06/10/15 14:30
905330
Parameter
Flashpoint
30150184001
Result
Units
deg F
>200
Dup
Result
RPD
Max
RPD
Qualifiers
>200

Date: 06/16/2015 05:39 PM
Page 17 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
WET/28679
Analysis Method:
EPA 160.4
QC Batch Method:
EPA 160.4
160.4 Total Volatile Solids

METHOD BLANK:
30150255001
905316
Matrix: Solid
30150255001
Parameter
SAMPLE DUPLICATE:
Blank
Result
Units
% (w/w)
Reporting
Limit
ND
10.0
Analyzed
Qualifiers
06/10/15 14:37
905317
Parameter
30150256001
Result
Units
% (w/w)
76.7
Dup
Result
Max
RPD
RPD
79.5
Qualifiers
20

Date: 06/16/2015 05:39 PM
Page 18 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
WET/28670
Analysis Method:
EPA 9045C
QC Batch Method:
EPA 9045C
9045 pH

SAMPLE DUPLICATE:
30150255001
904979
Parameter
pH at 25 Degrees C
30150256001
Result
Units
Std. Units
8.3
Dup
Result
Max
RPD
RPD
8.3
Qualifiers
10

Date: 06/16/2015 05:39 PM
Page 19 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
WET/28732
Analysis Method:
EPA 9071B
QC Batch Method:
EPA 9071B
9071 ASE, Oil and Grease/TPH

METHOD BLANK:
30150255001
907040
Matrix: Solid
30150255001
Parameter
Blank
Result
Units
Oil and Grease
mg/kg
ND
Spike
Conc.
Units
Oil and Grease
mg/kg
Oil and Grease
98.6
Analyzed
Qualifiers
06/15/15 08:00
907041
Parameter
Parameter
Reporting
Limit
LCS
Result
1590
1530
907042
Units
30150383001
Result
mg/kg
358
LCS
% Rec
% Rec
Limits
96
Qualifiers
85-115
907043
MS
Spike
Conc.
1630
MSD
Spike
Conc.
1630
MS
Result
2080
MSD
Result
MS
% Rec
2040
106
MSD
% Rec
104
% Rec
Limits
Max
RPD RPD
85-115
Qual
20

Date: 06/16/2015 05:39 PM
Page 20 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
WET/28682
Analysis Method:
EPA 9095A
QC Batch Method:
EPA 9095A
9095 PAINT FILTER LIQUID TEST

SAMPLE DUPLICATE:
30150255001
905328
Parameter
Units
30150223001
Result
PASS
Free Liquids
Dup
Result
RPD
Max
RPD
Qualifiers
PASS

Date: 06/16/2015 05:39 PM
Page 21 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
WETA/20267
Analysis Method:
SW-846 7.3.4.2
QC Batch Method:
SW-846 7.3.4.2
734S Reactive Sulfide

METHOD BLANK:
30150255001
905434
Matrix: Solid
30150255001
Parameter
Blank
Result
Units
Sulfide, Reactive
mg/kg
SAMPLE DUPLICATE:
Reporting
Limit
ND
Analyzed
10
Qualifiers
06/10/15 18:00
905672
Parameter
Sulfide, Reactive
30149951001
Result
Units
mg/kg
9.9U
Dup
Result
RPD
ND
Max
RPD
Qualifiers
20

Date: 06/16/2015 05:39 PM
Page 22 of 31
#=QC#

(724)850-5600

Project:
Pace Project No.:
30150255
QC Batch:
WETA/20310
Analysis Method:
EPA 9012A
QC Batch Method:
EPA 9012A
9012 Cyanide

METHOD BLANK:
30150255001
907831
Matrix: Solid
30150255001
Parameter
Blank
Result
Units
Cyanide
mg/kg
ND
Spike
Conc.
Units
Cyanide
mg/kg
Cyanide
0.60
Analyzed
Qualifiers
06/15/15 21:47
907832
Parameter
Parameter
Reporting
Limit
LCS
Result
5
5.2
907833
Units
30150255001
Result
mg/kg
ND
LCS
% Rec
% Rec
Limits
103
Qualifiers
90-110
907834
MS
Spike
Conc.
5.6
MSD
Spike
Conc.
5.3
MS
Result
4.9
MSD
Result
MS
% Rec
3.9
73
MSD
% Rec
57
% Rec
Limits
Max
RPD RPD
90-110
22
Qual
20 M1,R1

Date: 06/16/2015 05:39 PM
Page 23 of 31
#=ARR#

(724)850-5600
ANALYTICAL RESULTS - RADIOCHEMISTRY

Project:
Pace Project No.:
30150255

Cl
PWS:
Lab ID: 30150255001
Collected: 06/08/15 09:25
Site ID:
Sample Type:
Received: 06/09/15 15:45
Matrix: Solid
Results reported on a "dry-weight" basis

Parameters
Method
Antimony-124
EPA 901.1
Cobalt-60
EPA 901.1
Iridium-192
EPA 901.1
Potassium-40
EPA 901.1
Radium-226
EPA 901.1
Radium-228
EPA 901.1
Scandium-46
EPA 901.1
Silver-110M
EPA 901.1
Thorium-232
EPA 901.1
Uranium-238
EPA 901.1
Act Unc (MDC) Carr Trac
Units
0.000 0.674 (2.037)

C:NA T:NA
0.000 0.565 (1.683)
C:NA T:NA
0.000 0.634 (1.680)
C:NA T:NA
26.630 19.036 (17.130)
C:NA T:NA
1453.500 200.780 (44.630)
C:NA T:NA
303.750 40.774 (7.817)
C:NA T:NA
1.268 1.784 (1.774)
C:NA T:NA
2.381 1.567 (1.549)
C:NA T:NA
162.200 392.170 (478.000)
C:NA T:NA
94.336 17.406 (17.780)
C:NA T:NA
Analyzed
CAS No.
Qual
pCi/g
06/15/15 16:51 14683-10-4
pCi/g
06/15/15 16:51 10198-40-0
pCi/g
06/15/15 16:51 14694-69-0
pCi/g
06/15/15 16:51 13966-00-2
pCi/g
06/15/15 16:51 13982-63-3
pCi/g
06/15/15 16:51 15262-20-1
pCi/g
06/15/15 16:51 13967-63-0
pCi/g
06/15/15 16:51 14391-76-5
pCi/g
06/15/15 16:51 7440-29-1
pCi/g
06/15/15 16:51

Page 24 of 31
#=QCR#

(724)850-5600
QUALITY CONTROL - RADIOCHEMISTRY

Project:
Pace Project No.:
30150255
QC Batch:
RADC/24797
Analysis Method:
EPA 901.1
QC Batch Method:
EPA 901.1
901.1 Gamma Spec

METHOD BLANK:
906067

Parameter
Antimony-124
Cobalt-60
Iridium-192
Potassium-40
Radium-226
Radium-228
Scandium-46
Silver-110M
Thorium-232
Uranium-238
30150255001
Matrix: Solid
30150255001
Act Unc (MDC) Carr Trac
0.000 0.033 (0.159) C:NA T:NA
0.003 0.106 (0.135) C:NA T:NA
0.042 0.058 (0.097) C:NA T:NA
0.028 1.455 (1.615) C:NA T:NA
0.454 1.910 (2.506) C:NA T:NA
0.093 0.172 (0.554) C:NA T:NA
0.000 0.015 (0.131) C:NA T:NA
0.043 0.073 (0.080) C:NA T:NA
0.000 23.005 (78.470) C:NA T:NA
0.000 0.888 (1.950) C:NA T:NA
Units
Analyzed
pCi/g
pCi/g
pCi/g
pCi/g
pCi/g
pCi/g
pCi/g
pCi/g
pCi/g
pCi/g
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
06/11/15 13:35
Qualifiers

Page 25 of 31
#=QL#

(724)850-5600
QUALIFIERS
Project:
Pace Project No.:
30150255
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Act - Activity
Unc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval).
Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval)
(MDC) - Minimum Detectable Concentration
Trac - Tracer Recovery (%)
Carr - Carrier Recovery (%)
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-PA
Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
D6
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
M1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1
RPD value was outside control limits.

Date: 06/16/2015 05:39 PM
Page 26 of 31
#=CR#

(724)850-5600
QUALITY CONTROL DATA CROSS REFERENCE TABLE

Project:
Pace Project No.:
30150255
Analytical Method
Analytical
Batch
Lab ID
Sample ID
QC Batch Method
QC Batch
30150255001
EPA 3005A
MPRP/15754 EPA 6010B
ICP/14949
30150255001
EPA 7470A
MERP/6597
EPA 7470A
MERC/6295
30150255001
EPA 3535A
OEXT/24026 EPA 8270C
MSSV/7735
30150255001
EPA 8260B
MSV/23797
30150255001
ASTM D2974-87
PMST/5395
30150255001
EPA 901.1
RADC/24797
30150255001
EPA 1010
WET/28683
30150255001
EPA 160.4
WET/28679
30150255001
EPA 9045C
WET/28670
30150255001
EPA 9071B
WET/28732
30150255001
EPA 9095A
WET/28682
30150255001
SW-846 7.3.4.2
WETA/20267
30150255001
EPA 9012A
WETA/20310 EPA 9012A
EPA 9071B
WET/28733
WETA/20313

Date: 06/16/2015 05:39 PM
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Page 28 of 31
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RE TNORM Disposal in KY (399) - FairmontBrineRadchem

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#=CL#

Pace Analytical Services, Inc.

LIMS USE: FR - RICK QUINN

June 16, 2015

RE: Project: Fairmont Brine - Sludge Pit Cl

REPORT OF LABORATORY ANALYSIS

Pace Analytical Services, Inc.

Fairmont Brine - Sludge Pit Cl

Pace Project No.:

Pennsylvania Certification IDs

Montana Certification #: Cert 0082

REPORT OF LABORATORY ANALYSIS

Pace Analytical Services, Inc.

Fairmont Brine - Sludge Pit Cl

Pace Project No.:

Fairmont Brine - Sludge Pit Cl

REPORT OF LABORATORY ANALYSIS

Pace Analytical Services, Inc.

SAMPLE ANALYTE COUNT

Fairmont Brine - Sludge Pit Cl

Pace Project No.:

Fairmont Brine - Sludge Pit Cl

REPORT OF LABORATORY ANALYSIS

Pace Analytical Services, Inc.

Fairmont Brine - Sludge Pit Cl

Pace Project No.:

Sample: Fairmont Brine - Sludge Pit

Analytical Method: EPA 6010B Preparation Method: EPA 3005A

Analytical Method: EPA 7470A Preparation Method: EPA 7470A

06/12/15 13:23 06/15/15 09:57 7439-97-6

Analytical Method: EPA 8270C Preparation Method: EPA 3535A

REPORT OF LABORATORY ANALYSIS

Date: 06/16/2015 05:39 PM

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

Fairmont Brine - Sludge Pit Cl

Pace Project No.:

Sample: Fairmont Brine - Sludge Pit

06/12/15 14:26 17060-07-0

Analytical Method: ASTM D2974-87

Analytical Method: EPA 1010

Analytical Method: EPA 160.4

Analytical Method: EPA 9045C

Analytical Method: EPA 9071B Preparation Method: EPA 9071B

06/12/15 12:00 06/15/15 08:00

Analytical Method: EPA 9095A

Analytical Method: SW-846 7.3.4.2

Analytical Method: EPA 9012A Preparation Method: EPA 9012A

06/15/15 18:00 06/15/15 21:47 57-12-5

REPORT OF LABORATORY ANALYSIS

Date: 06/16/2015 05:39 PM

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

QUALITY CONTROL DATA

Fairmont Brine - Sludge Pit Cl

Pace Project No.:

7470 Mercury TCLP

Associated Lab Samples:

Associated Lab Samples:

LABORATORY CONTROL SAMPLE:

MATRIX SPIKE SAMPLE:

MATRIX SPIKE SAMPLE:

REPORT OF LABORATORY ANALYSIS