Professional Documents
Culture Documents
US005591489A
United States Patent [191
[11]
Patent Number:
5,591,489
Dragner et a].
[45]
Date of Patent:
Jan. 7, 1997
4,628,071
Morgan et a1.
....
Kiehlbauch et a1.
. . . ..
... .. .
. . . ..
523/201
5,081,166
1/1992
5,118,533
523/201
5,122,568
6/1992
DePierne et a].
.. . . ..
. . . ..
524/824
5,139,614
8/1992
DePierne et a1.
.. . . . .
. . . ..
162/135
5,149,729
814528
l/l990
4,916,171
4,894,397
6/1969
Canada .
OTHER PUBLICATIONS
References Cited
U.S. PATENT DOCUMENTS
[57]
ABSTRACT
2,230,240
2,583,274
2,606,891
8/1952 Rowland
3,048,501
8/1962
3,244,655
..... .. 260/29.6
3,297,657
l/1967
. . . . . ..
260/78.5
Miller et a1.
Gray et a1.
.. . . ... .
.... .. .._ .
. . . . . . ..
260/78.5
427/391
.......... .. 4271391
260/26.9 RW
4,258,104
3/1981
Lee et a1.
4,279,964
7/1981
Heller ............ ..
427/364
4,397,984
427/391
4,410,673
. . . .....
427/391
. . . . . . . . . . ..
427/391
5,591,489
1
BACKGROUND
This invention relates to surface treatment of paper or
SUMMARY
Brie?y, the present invention provides a process for
surface sizing paper or paperboard. This process involves
applying a surface sizing composition comprising a mixture
30
printer printing.
For many years the paperrnaker has had only a few types
of size press sizes from which to choose. Ammonium salts
of half esters of maleic acid copolymerized with styrene and
salts of acrylic acid polymerized with styrene are two types
tribute to poor or erratic performance as a surface modi?er. 45 factant containing systems such as destabilization of the
face.
50
foaming agents.
65
5,591,489
3
sulfonic acid and the like may also be used. The acid number
of the alkali soluble, acid containing copolymers is at least
100 and generally from 100 to 400, preferably from 190 to
250. The weight average molecular weight of the alkali
toner adhesion.
65
5,591,489
5
EXAMPLE 1
EXAMPLE In
seconds to 46 seconds.
EXAMPLE II
25
EXAMPLE IV
40
placed on the sized surface. The contact angle of the drop ten
seconds after application to the surface is 90+/l when
measured using a contact angle goniometer. The ten second
the reaction at 83+/2 C. and additional monomer and 50 contact angle on a surface of paper sized with a commer
cially feasible amount (1.6 lb./ton) of a styrene/maleic acid
initiator are continuously added to the reactor via positive
half amide, half butyl ester size is also 90+/1. The contact
angle of water on a surface treated with only starch is
EXAMPLE V
60
65
5,591,489
7
so the starch: size ratio- of 8023.5. No foamlng 0f the Stzc 5 Those familiar with the art will realize that adjustments may
press sohmori m the mp or m the feed tahk 1S observe?
part of the pilot machine run conditions are kept the same as 10 of the desired PickhP- The She?ts are dried in forced air at
approximately cut
20
Starch
Pickup
Size
38 3:2:
21:56 H
Contact
Penetration
Angle (deg)
Time (sec)
85 1b: starch
_
SMA
_
EXAMPLE VII
900
Sj
218
starch at the size press. This also shows that the size in
35 trimmed
EXAMPLE IX
printing and other important properties on standard 81/z"><11" 40 26212635153132;gliiesttfgmtcggzl 231C216; 05321152?
sheets. 220 grams of acid thinned hydroxyethylated dent
'
p p
EXAMPLE X
Size
Example II
SMAE
SAA
Color
Bleed*
Drying
Time
Seconds
Black
Ink
Wicking*
Toner
Adhesion
Percent
Toner
Crack
Width
Contact
Angle,
Degrees
Penetration
Time,
seconds
8
6
6
1
1s.
12
8
7
6
98
93
92
1.0
1.21
1.1
86
98
93
123
164
144
5,591,489
-continued
Size
Color
Bleed*
Drying
Time
Seconds
Black
Ink
Wicking*
Toner
Adhesion
Percent
Toner
Crack
Width
Contact
Angle,
Degrees
Penetration
Time,
seconds
SAM
85
87
132
*These tests are compared visually under 5% magni?cation to test standard and then are rated on
a scale with 1 = very poor and 10 = best possible.
EXAMPLE XI
EXAMPLE XV
EXAMPLE XII
EXAMPLE XHI
Contact
Time
Angle
168 sec.
48 sec.
86
64
Foam Volumes
35
40
EXAMPLE XIV
SMAE
SMAE
Example II
Example III
Example 11
Two Hours
130
130
0
0
0
110
80
0
0
0
0.40%
0.15%
1.0%
0.4%
0.15%
One-Half Hour
45
results were:
Foam Volumes
10% Example 11
1% SMAE
1% SAA
1% Example II
One-Half Hour
Two Hours
Three Hours
60
40
50
0
5O
0
60
10
3O
160
0
140
O
100
65
5,591,489
11
12
acrylate.
6. Process of claim 4 wherein the vinyl polymer further
comprises a crosslinking monomer.
7. Process of claim 4 wherein the alkali soluble, acid
containing copolymer has a weight average molecular
weight of from about 5000 to 10,000.
8. Process of claim 7 wherein the microemulsion of vinyl
polymer has a particle size of 99% less than 0.1 microns.
9. Process of claim 8 wherein the surface sizing compo
sition comprises a solids weight ratio of vinyl polymer
10
containing copolymer.