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College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, PR China
College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310014, PR China
Received 18 December 2006; received in revised form 17 January 2007; accepted 18 January 2007
Abstract
Non-porous hollow fibers were used as more excellent structured packing over normal packing in the distillation of methanolwater system. Due to
their special geometry, a column with hollow fibers could easily work 310 times higher above the limit where flooding usually occurs in conventional
cases. A small height of transfer units at 8 cm and the overall mass-transfer coefficient Kx based on the liquid-side at 2.3 105 mol/cm2 s were
obtained experimentally. Compared with theoretical estimation from earlier studies, it was found that the liquid side was mostly responsible for the
total resistance of mass transfer, which was similar to the conventional distillation process at low concentration, although mass transfer resistance
in the membrane and the vapor could not be negligible.
2007 Elsevier B.V. All rights reserved.
Keywords: Hollow fibers; Distillation; Methanolwater system; Mass transfer coefficient
1. Introduction
One of the main challenges in designing and operating conventional distillation is to maximize the mass transfer rate by
producing as much interfacial area as possible. Although conventional distillation have been workhorses of the chemical
industry for decades, an important disadvantage is the interdependence of the two fluid phases to be contacted, which
sometimes leads to many difficulties such as emulsions, foaming, unloading and flooding. For devices with moving internals,
successful operation relies on how to minimize the bubble or
droplet size of the dispersed phase and maximize the number of
bubbles or droplets, see Kister and BennettKovak [1,2]. Usually
the separation is hard to control and causes lower efficiency. An
alternative separation technology that overcomes these disadvantages and also offers substantially more interfacial area than
conventional cases is the membrane contactor, as described by
YangCussler, AlanHwang, KelleharFair and Obuskovic et
al. [36].
In this work, non-porous hollow fibers (with a 5 m polydimethylsiloxane coating) were used as special structured
packing in the distillation of methanolwater solutions. Such
Corresponding author at: College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, PR China.
Tel.: +86 571 88320863; fax: +86 571 88320863.
E-mail address: guoliangz@zjut.edu.cn (G. Zhang).
1383-5866/$ see front matter 2007 Elsevier B.V. All rights reserved.
doi:10.1016/j.seppur.2007.01.016
144
(1)
where AG and AL are the area of the vapor and the liquid, G and L
are the molar vapor and liquid fluxes in the column, respectively.
As constant molar overflow is also assumed, these flows are
independent of their position. Under these conditions, balances
on methanol in both vapor and liquid give the familiar operating
line:
y=x
(2)
dx
Kx a(x x )
dz
(3)
NTU
Kx a
x2 (dx/(x x ))
where l is the length of the column. The number of transfer units
(NTU) is a measure of the difficulty of the separation. From
this equation, the value of experimental overall mass-transfer
coefficient can be found, and the height of transfer units (HTU),
which is a measure of the efficiency of the column, can also be
worked out by:
L
l
=
.
HTU =
NTU
Kx a
(5)
From Eq. (4), the value of NTU changes with the fluid
mechanics and the overall mass transfer coefficient based on the
liquid-side. This mass transfer coefficient is complicated and
can be shown theoretically as:
1
cL
1
1
1
=
=
+
+
KL
Kx
kL
HkG
HkM
(6)
[7]. For the high liquid flow above the flooding limit, the Graetz
number is given as:
Gz =
d 2 vL
DL l
(7)
145
Table 1
Properties of different structured packings
Module packing
Size (mm)a
Void fraction,
25 (number of fibers)
50 (number of fibers)
50 50 4.5
8 8 1.5
0.85
0.71
0.81
0.64
659
1587
93
570
1073
4434
175
2174
(10)
(11)
Using these relations and Eq. (4), the NTUs can be obtained
experimentally as below and use for comparison with the estimates given by theory:
0.1 < x 0.3,
NTU = 0.3985(0.4828 + ln(0.5346 x) ln(0.0802 + x))
(12)
0.3 < x < 0.9,
NTU = 1.5553(ln(3.1033 + x) ln(0.9893 x) 1.5968)
(13)
4. Results and discussion
Fig. 1. Scheme of distillation in hollow fiber. The module was run at total reflux.
Liquid flowed through the lumens of the fibers, while vapor flowed counter
currently outside the fibers.
146
Fig. 2. Distillate concentration vs. heat rate. When heat rate increased, concentration of distillate at the top of the column decreased. , distillate at the top of
module; , feed at the bottom of module.
Fig. 3. Hollow fibers operates above flooding. A column with hollow fibers
could operate at fluxes 310 times higher above the normal flooding limit.
Fig. 4. The height of transfer units (HTU) vs. vapor velocity. While vapor
velocity changed, the height of mass transfer varied in the range of 836 cm,
representing a higher efficiency than conventional packings.
147
Fig. 5. The reciprocal of the number of transfer units (1/NTU) vs. liquid flow.
A linear relationship between 1/NTU and the liquid flow is predicted, showing
the experimental data fitted theoretical estimation well.
Table 2
Estimates of mass-transfer coefficient with hollow fiber modules in different systems
Mass-transfer coefficient in
Separation system
Methanol (vL = 1.65 cm/s)a
kL = 11 104 cm/s
kG = 4.1 cm/s
H = 2.9 103
kM = 1 cm/s
kL = 8 104 cm/s
kG = 6.0 cm/s
H = 1.0 103
kM = 1 cm/s
36 cm
60 cm
Flow velocity.
148
F = uG G
(14)
Fig. 7. Mass-transfer coefficients for hollow fiber modules. Both the Sherwood
and Graetz numbers were based on the fiber diameter. , Experimental Sherwood number which the liquid side dominates; and solid line, calculated
Sherwood number based on Leveque correlation.
correlation. The gap turned to be smaller when the Graetz number was low. Although the Leveque correlation was theoretical
strong for laminar flow through circular tube, the results of this
experiment tended to give a higher parameter than 1.62, which
was similar to the former empirical value of Sieder and Tate
[3,20]. Since the fibers used in this experiment was organic, the
random fiber packing might be uneven along the module length
and the fiber tube could be a tortuous path after heating and solvating. Under these circumstances, how to increase the packing
interfacial area as large as possible and how to keep the shape
of fibers and module flow path in the operation was very important. The geometry change of hollow fiber membrane especially
under the high temperature and solvation effect should be paid
more attention in the following research.
5. Conclusion
The distillation in the hollow fibers showed excellent performances over conventional structured packing for the separation
of methanol/water solutions. Since the wall of the hollow fibers
was non-porous but highly permeable, they could define the
flows very well but did not compromise the mass transfer.
The vapor and liquid flows were largely independent of the
normal constraints of fluid mechanics, therefore the modules
could be operated successfully at conditions, which normally
caused severe operational problems such as emulsions, foaming,
unloading and flooding. Further, the minimum HTU of only 8 cm
at the lowest vapor velocity of 116 cm/s (KL,exp = 0.001 cm/s)
represented a higher separation efficiency, while the largest HTU
of 36 cm at the highest flow of 223 cm/s (KL,exp = 0.0016 cm/s)
was only a mediocre value which could be given by conventional packing. All these results demonstrated more productive
and higher efficient separations in hollow fibers.
149
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