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a,*
,
Abstract
Diamond-like carbon (DLC) lms have been deposited on glass substrates using radio-frequency (r.f.) plasma deposition method. c-ray, ultraviolet (UV) ray and neutron beam were used to irradiate the DLC lms. Raman spectroscopy and infrared (IR) spectroscopy were used to characterize the changing characteristics of SP3 CH bond and
hydrogen content in the lms due to the irradiations. It showed that, the damage degrees of the c-ray, UV ray and
neutron beam on the SP3 CH bonds are dierent. Among them, the damage of c-ray on the SP3 CH bond is the
weakest. When the irradiation dose of c-ray reaches 10 104 Gy, the SP3 CH bond reduces about 50% in number.
The square resistance of the lms is reduced due to the irradiation of UV ray and this is caused by severe oxidation of
the lms. Compared with that of the as-deposited one, the IR transmittance of the lms irradiated by both c-ray and
neutron beam is increased to some extent. By using the results on optical gap of the lms and the fully constrained
network theory, the hydrogen content in the as-deposited lms is estimated to be 1025 at.%.
2002 Elsevier Science B.V. All rights reserved.
Keywords: Diamond-like carbon lms; c-ray irradiation; Neutron irradiation; Ultraviolet ray irradiation; Raman spectroscopy; SP3 C
H bond; Infrared transmittance
1. Introduction
Much work has been done on the synthesis of
diamond thin lms during the last 20 years and great
progress has been made. However, the preparation
and processing conditions of the lms are hard to
master and are still far from wide applications in
industry. The properties of diamond-like carbon
q
This research was supported by the aeronautics science
foundation of China (no: 98G51124).
*
Corresponding author. Tel.: +86-759-238-2059; fax: +86757-6581272.
E-mail address: liuga@pub.zhanjiang.gd.cn (G. Liu).
0168-583X/02/$ - see front matter 2002 Elsevier Science B.V. All rights reserved.
PII: S 0 1 6 8 - 5 8 3 X ( 0 2 ) 0 1 3 8 0 - 0
108
G. Liu et al. / Nucl. Instr. and Meth. in Phys. Res. B 197 (2002) 107113
10
0
11
2
12
4
13
6
14
8
15
10
Table 2
The irradiation dose of neutron beams
Sample number
Irradiation dose
(1012 n/cm2 )
20
0
21
1.4
22
2.3
23
7.2
Table 3
The irradiation conditions for UV ray
Sample number
Irradiation time of
UV ray (min)
30
0
31
10
32
60
33
150
34
270
G. Liu et al. / Nucl. Instr. and Meth. in Phys. Res. B 197 (2002) 107113
This evident color change implies that the structure and optical property of the lms have been
changed by the irradiation.
Raman spectroscopy has been used for characterizing the DLC lms. Two strong CH peaks
around wave numbers of 2934 and 2871 cm1 are
observed, as shown in Fig. 1. Both peaks can be
attributed to SP3 CH2 asymmetric [6] and SP3 CH3
symmetric stretching vibrational mode [7], respectively. With the increase of irradiation dose,
the intensities of the two peaks reduce, indicating
the stretching vibrations of both bonds become
weak due to the irradiation. Based on the theory
that the Raman peaks should be symmetrical in
shape [8], we noticed that some peaks are overlapped in the spectra. Detailed observation showed
that, another two peaks, centered at about 2855
and 2960 cm1 also appear in the spectra in spite
of their weak intensities. According to the references [9,10], the appearance of the two peaks at
2855 and 2960 cm1 is reasonable and they are
attributed to SP3 CH2 symmetric stretching vibrational mode and SP3 CH3 asymmetric stretching
vibrational mode, respectively. Because all these
four peaks are related to SP3 stretching vibrational
mode, so the relative areas of the peaks can be
considered as identication of stretching vibra-
109
Sample number
Optical gap eV
10
11
12
13
14
15
0.90 1.01 1.01 1.02 1.06 1.06
110
G. Liu et al. / Nucl. Instr. and Meth. in Phys. Res. B 197 (2002) 107113
Eg 0:55X2 0:95
:
2:2
G. Liu et al. / Nucl. Instr. and Meth. in Phys. Res. B 197 (2002) 107113
Table 5
Relation between the lms thickness or refractive index and
neutron irradiation dose
Sample number
Refractive index (n)
)
Thickness d
200 (A
20
2.15
9300
21
2.20
10500
22
2.25
9600
23
2.30
10920
111
112
G. Liu et al. / Nucl. Instr. and Meth. in Phys. Res. B 197 (2002) 107113
Table 6
Change of square resistancedue to UV photon irradiation
Sample number
Square resistance q
(1012 X)
30
4.5
31
6.0
32
4.6
33
3.6
34
2.5
G. Liu et al. / Nucl. Instr. and Meth. in Phys. Res. B 197 (2002) 107113
113
the lms, causing the reduction of lm resistance with the increase of irradiation time.
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