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Introduction
The rare earth elements (REEs) are usually defined as the
14 lanthanides, from lanthanum (atomic number Z557)
to lutetium with (Z571) plus yttrium (Z539) as shown in
Table 1. The prevailing industry practice is to exclude
scandium even though it may be included in some
chemistry texts. By virtue of its instability, promethium
(Pm) effectively does not occur in nature. Y has a similar
concentration to La and Nd though behaves geochemically like a heavy rare earth element (e.g. Dy).
The term rare earth element is commonly abbreviated
to REE and their oxides to REO. To avoid confusion,
it is wise in reporting REE resources to define whether
yttrium is included and to report REO values rather
than REE. In this paper, REO includes yttrium oxide
and TREO refers to the total sum of the REO.
A commonly used subdivision of the REE consists of
the light REE (LREE) or LREO and the heavy REE
(HREE) or HREO. Common industry usage, which is
quite arbitrary, is to define the LREE as consisting of
La, Ce, Pr, Nd and Sm and the HREE as Eu, Gd, Tb,
Dy, Ho, Er, Tm, Yb, Lu plus Y. This grouping may vary
with the LREE extended to include Eu and even Gd.
1
2
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Atomic number
Symbol
Atomic weight
Yttrium
Lanthanum
Cerium
Praseodymium
Neodymium
Samarium
Europium
Gadolinium
Terbium
Dysprosium
Holmium
Erbium
Thulium
Ytterbium
Lutetium
39
57
58
59
60
62
63
64
65
66
67
68
69
70
71
Y
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
88.91
138.91
140.12
140.91
144.24
150.36
151.96
157.25
158.93
162.50
164.93
167.26
169.93
173.04
174.97
22
30
64
7.1
26
4.5
0.88
3.8
0.64
3.5
0.8
2.3
0.33
2.2
0.32
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Assaying
The assay method of choice is typically inductively
coupled plasma mass spectrometry (ICP-MS) based on
an alkali fusion followed by acid dissolution. Alkali
fusion is the preferred primary digestion step in order to
ensure total results. Extra elements of interest such as
Hf, Nb, Sn, Ta, Th, U, W and Zr in addition to the REE
may be obtained for an incremental cost. Some laboratories offer REE packages that include these elements.
Concentrations that report in excess of the quoted
maximum range will require re-assay by a more appropriate method. Depending on the style of mineralisation,
consideration should be given to assaying Fe, Mn, P and
S which are generally determined by inductively coupled
plasma optical emission spectrometry (ICP-OES).
Complete packages of major, minor, trace and REE
are offered by commercial laboratories and have the
advantage of providing the ability to characterise the
geochemistry of various rock and ore-types. Additionally, such packages are useful when projects reach
the stage when measures of acid-consumption and acidgeneration may be required as part of the waste-rock
and ore characterisation. Metallurgical processing and
Chondrite-normalised graphs are useful tools for identifying assaying issues in addition to the usual QA/QC
procedures that should involve blind relevant standards,
coarse and fine blanks and check assays at a second
laboratory. The geochemical similarity of the REE
results in high correlation coefficients and scatter plots
defining near-perfect straight lines. However, it can be
difficult to efficiently examine thousands of assay results
for the 15 REE for internal consistency. The factors of
Sun and McDonough (1989) have been used for the
example in Fig. 2 which clearly shows some internally
anomalous REE patterns. The focus is to identify
particular REE that display aberrant behaviour which
can then be referred to the laboratory for checking.
Positive and negative anomalies for Ce and Eu may be
expected in nature due to their variable oxidation states.
The absolute abundances are not critical but rather
the relationships within the REE. In this example, Tb
and Tm show suspicious elevations compared to
neighbouring REE and there is an obvious decline in
precision towards lower concentrations.
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7.98
11.7
7.9
6
3
0.050.2
4.2
2.6
0.029
1.59
1.38
2.4
1.08
1.74
0.061
2.26
4.54
4.19
14.0
0.16
3.23
2.56
3.12
0.41
0.41
0.21
16.7
9.7
23.9
48
17
10?
2.52
47
805
109
160
2.56
956
4.90
187
195
21.6
42
0.67
59.3
13.4
38.4
7.18
23.9
19.8
36.2
42.5
29.3
220
278
214
61
73.2
35.9
7.8
6.48
Mountain Pass
Mt Weld
Mt Weld
Bayan Obo
Mianning
S China IO Clays
Kangkankunde
Nolans
Charley Ck
Nechalacho Basal
Nechalacho Basal
Hoidas Lake
Kvanefjeld
Cummins Range
Milo
Ngualla
Ngualla
(Ngualla
Steenkampskraall
Eco Ridge
Bear Lodge
Bear Lodge
Bear Lodge
Kipawa
Kipawa
Hastings
Zandkopsdrift
Ashram
Ashram
Strange Lake
Strange Lake
Norra Karr
Dubbo Zirconia
Dubbo Zirconia
Olserum
Browns Range
956
557
4180
2585
1819
329
548
323
48
48
1468
1135
1888
288
510
?
107
92
235
1735
2212
61
10 325
85
113
4407
982
1800
94
95
433
983
224
98
81
76
TREO/kt
1.0
1.25
1.25
0.5
0.5
0.4
1.5% (Nb2O5zZrO2zTREO)
1.5% (Nb2O5zZrO2zTREO)
0.4
0.15
5.0
4.0, 7.0
2.5
?
?
?
3.5
1.0
$Value
$Value
$Value
1.5
150 ppm U3O8
1.0
0.03
1.0
3.0
3.0
1.0
$Value
1.5
1.5
1.0, 1.5
0.2
0.2
0.15% Nb2O5
COG (%TREO)
IF
MI
F
I
F
F
MI
OR
IF
IF
OR
OR
MIF
ME
ME
ME
F
MIF
IF
MI
F
MI
IF
F
F
MIF
OR
MIF
MIF
IF
MI
F
OR
MI
OR
IF
Category
E
FS
FS
PEA
PEA
PEA
FS
FS
E
E
P
P
P
P
P
P
E
FS
E
FS
FS
E, PEA
FS
E
E
FS
FS
FS
PEA
FS
PEA
PEA
FS
E
E
E
Status
REO
REO
REO
REO
REO
REO
ZrO2
ZrO2
REO
REO
REO
REO
REO
REO
REO
HREO
REO
REO
REO
REO
REO
REO
U3O8
REO
REO
REO
REO
REO
REO
U3O8
REO
REO
REO
HREO
HREO
Nb2O5
Target
Fluorite
Fluorite
Zr, Nb, Hf
Zr, Nb, Hf
Zr, Hf
REO, Ta, Hf
REO, Ta, Hf,
Zr
REO
Zr, Nb, Ta
Zr, Nb, Ta
P2O5
REO and Zn
P2O5 U3O8
P2O5 U3O8
Nb
Byproducts
HB
C
C
C
AP
AP
A
A
A
C
C
C
I/MV
CON
AI
AI
AI
A
A
CS
C
CS
CS
C
C
IO
C
C
A
A
A
AP
ALK
C
Type
Ref.
*Abbreviations for Deposit are IO5ionic clays, Category: OR5Ore Reserve; ME5Mineral Endownment; M5Measured, I5Indicated and F5Inferred resources; Status, E5exploration; FS5feasibility study,
PEA5Preliminary Economic Assessment; P5production). Resources include any quoted reserves. Type, C5carbonatite, IO5ionic clay, A5alkaline intrusive, AP5alkaline intrusive/pegmatite,
CS5supergene over carbonatite, I/MV monazite vein in granitic intrusives, CON5conglomerate, HB5hydrothermal breccia.
2.25
1.9
1.9
0.93
0.85
0.54
0.75
0.9
0.61
0.74
TREO/%
Tonnes/Mt
Deposit
Density
Obtaining a sufficient number of density measurements is
especially important in deposits affected by significant
weathering. Deposits such as Mt Weld and Ngualla have
Resource estimation
There are no special issues relating to the mechanics of
the estimation of REEs which appear similar in
mineralisation style to primary and supergene enriched
copper deposits. A typical process starts with the
estimation of TREO along with LREO and HREO to
provide an indication of the ratio of HREO to TREO.
Byproducts with possible value or relevance such as
Nb2O5, Ta2O5, ZrO2 and P2O5 should be estimated but
not reported unless there is evidence that they will add
value. Deleterious elements such as Th and U should be
estimated, reported and discussed. Understanding their
deportment and distribution should be a priority.
Leaching conditions
Monazite xenotime/churchite
Apatite
Eudialyte, bastnaesite, ionic clays
Uranium processing
Columbite/tantalite
Zircon
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3 Conict between populations of blocks and composites due to over-domaining left hand Y-axis is the block count and
the right hand Y-axis is the number of underlying composites upon which the estimate is based. The X-axis shows
the grade of the variable being estimated (in this case WO3)
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Tonnage/year
Major applications
Ce carbonate, oxide
5200
La carbonate, oxide
Ce/La and Ce/La/Pr
carbonate, oxide
Nd/Pr oxide, Nd oxide
and Pr oxide
SEGzHeavy Rare Earths
Total
2700
8000
5400
960
22 000
Lighting, Magnets
*(Lynas Corporation, 2014); FCC5fluid cracking catalysts; NiMH5nickel metal hydride where M is Nd/Pr; UV cut is ultra-violet
transmissivity inhibition in polished glass; tonnage/year is a Lynas projection.
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4 Mt Weld Drill holes (solid dots), location of pit over CLD and outline of Measured and Indicated Resources
A corollary of this discussion is that the quotation of inground value should never be attempted in the public
sphere and is likely to be misleading and inaccurate.
Equally hazardous is the use of forward projected
prices. For example, in March 2011, Lynas (2011, p. 5)
forecast a 2014 TREO price between approximately
US$90/kg and US$130/kg for the Mt Weld mineralisation compared with the March 2014 quarter (notional
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Case-study: Mt Weld
The Mt Weld carbonatite in the Eastern Goldfields of
Western Australia and its thick, complex regolith, lie
123
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Max
Block
dimensions No. of blocks
East
455 200
456 300
10
North 6 806 340
6 807 420
10
RL
301.5
448.5 3
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Conclusions
The significant growth in exploration activities directed
at delineating rare earth resources has resulted in a
plethora of low grade deposits that, in general, have
grades that fall well below even the lower reporting cutoff grades of the only two Western producers, Mountain
Pass and Mt Weld. Early in the evaluation process there
should be a study of the phase distribution of the REE
to help understand the recoverability and ease of processing of the various ore types. The value of a deposit will be
governed by both the distribution of the individual REE
and the host minerals. It is likely that relatively soluble
ionic clay type deposits are far more widespread than is
currently realised. Although of lower grade, these may
prove considerably more attractive than higher grade
deposits containing REE-bearing minerals that require
aggressive leaching conditions and high capital costs.
Acknowledgements
Valuable improvements to the text were contributed by
Luke Burlet, Malcolm Hancock and Helen Waldron
who also helped with the details on INAA. Chris
Griffith (ANSTO) contributed Table 4 and Rupert
Osborne provided Fig. 2. Katherine Courtney helped
with Table 3. The comments of the two reviewers, Dr
M. Absalov and Dr S. Jowitt, substantially improved the
manuscript. Careful lithological modelling by Gary
Brabham in 2002 contributed to the close reconciliations.
Deposit references
Alkane Resource Ltd. 2011. Projects. Retrieved 2014 May 1, from
Dubbo Zirconia Project Overview: http://www.alkane.com.au/
index.php/projects/current-projects/dubbo
Arafura Resources Limited. 2012, June. Resources & reserves.
Retrieved 2014 May 1, from http://www.arafuraresources.com.
au/our-projects/nolans/resources-reserves.html
References
Abzalov, M. Z. 2006. Localised Uniform Conditioning (LUC): a new
approach for direct modelling of small blocks, Math. Geol., 38,
(4), 393411.
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Avalon Rare Metals Inc. 2013, August 15. Project Fact Sheet.
Retrieved 2014 May 22, from Nechalacho: http://www.avalonrar
emetals.com/_resources/nechalacho/Resource_Update_August_
2013.pdf
Chakhmouradian, A. and Wall, F. 2012. Rare earth elements.
Elements, 323400.
Commerce Resources Corp. 2012, March 6. Ashram Project. Retrieved
2014 May 1, from http://www.commerceresources.com/s/Ashram.asp
Crossland. 2012, May 15. INITIAL INDICATED RESOURCE OF 387
MILLION TONNES. Retrieved 2014 May 5, from Crossland.
Frontier Rare Earths, n.d. Zandkopsdrift Rare Earths Project.
Retrieved 2014 May 1, from http://www.frontierrareearths.com/
projects/zandkopsdrift
GBM Resources Ltd, 2012, August 12. GBM Resources. Retrieved
May 6, 2014, from http://www.gbmr.com.au/aurora/assets/user_
content/GBM%20ARpt%202012%20LR.pdf
Greenland Minerals and Energy Ltd, 2012. Northern Ilimaussaq
Specialty Metal. Retrieved 2014 May 1, from http://www.ggg.gl/
projects/kvanefjeld-rees-uranium-zinc/mineral-resources/
Hastings Rare Metals Limited, 2011. JORC Resource. Retrieved 2014
May 1, from http://www.hastingsraremetals.com/projects/hast
ings-project/jorc-resource/#!prettyPhoto
Lynas Corporation, 2014, April 1. Announcements/2014/Operations
%20Update%20April%202014_CLEAN%20final%20-%20correction.pdf. Retrieved 2014 May 13, from https://www.lynascorp.com
Lynas Corporation, 2014, March. http://www.lynascorp.com/
Presentations/2014/Lynas%20Asian%20Metals%20Presentation%
20for%20Website%20020414.pdf. Retrieved 2014 May 13, from
http://www.lynascorp.com
Molycorp, Inc., 2012, April 10. Molycorp. Retrieved 2014 May 5. http://
www.molycorp.com/wp-content/uploads/Molycorp-Year-End-Reivew2012.pdf
Navigator Resources Limited, 2014. Cummins Range Resources.
Retrieved 2014 May 1, from http://www.navigatorresources.com.
au/Projects/Cummins-Range-(REE)/Resources
Northern Minerals, 2014, February. http://northernminerals.com.au/
browns-range/mineral-resource/. Retrieved 2014 May 15, from
Northern Minerals.
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