CL-Chapter 09-Electrochemistry : Nernst Equation and Equilibrium Contant, K

PST
Name: ______________________________
__________

Group : ____________________

WORKSHEET 1 :
Based on the standard electrode potential given:
Ag+(aq) + e Ag(s)

E = +0.80 V ------(A)

Cu2+(aq) + 2e Cu(s)

E = +0.15 V ------(B)

Sn2+(aq) + 2e Sn(s)

E = 0.14 V ------(C)

Ni2+(aq) + 2e Ni(s)

E = 0.25 V ------(D)

Fe2+(aq) + 2e Fe(s)
Q
1

Task
A&C

or

Eo Ag+| Ag = +0.80 V

E = 0.44 V ------(E)

Calculate the Ecell at 25 C if the [Ag+] =0.01M and [Sn2+] =1.0 M.

Step 1 Write the equation for the spontaneous reaction (half-cell equation)

Step 2 Write the overall equation

Step 3 Calculate the Eocell

Step 4 Calculate the Ecell at 25 using Nernst Equation

A&B

Calculate the Ecell at 25 C if the [Ag+] =0.01M and [Cu2+] =0.1 M.

Tutorial :

CL-Chapter 09-Electrochemistry : Nernst Equation and Equilibrium Contant, K

PST

C&D

Calculate the Ecell at 25 C if the [Sn2+] =0.01M and [Ni2+] =0.1 M.

E&C

Calculate the Ecell at 25 C if the [Fe2+] =0.01M and [Sn2+] =0.01 M.

CL-Chapter 09-Electrochemistry : Nernst Equation and Equilibrium Contant, K

PST

WORKSHEET 2 :
Calculate the equilibrium constant, K for the following reaction using standard reduction
potential(SRP) at 25oC
Q

Task

Zn(s) + 2H+(aq)
H2(g)

Zn2+ (aq) +

Sn(s) + Pb2+(aq)

Pb(s)

2Sn2+ (aq) +

Ce4+(aq) + Au(s)

Au3+(aq)

Ce3+(aq) +

CL-Chapter 09-Electrochemistry : Nernst Equation and Equilibrium Contant, K

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Ni(s) | Ni2+ (aq, 1M) || Sn2+ (aq, 1M) |

Sn (s)

Zn(s) | Zn2+ (aq, 1M) || H+ (aq, 1M) | H2(g)

|Pt (s)

CL-Chapter 09-Electrochemistry : Nernst Equation and Equilibrium Contant, K

PST

WORKSHEET 3

Quiz

Name: ______________________________ Group : ____________________ Tutorial : __________

Given standard potential electrod :
Sn2+(aq) + 2e Sn(s)

Ni2+(aq) + 2e Ni(s)

E = 0.14 V
E = 0.25 V

a. Calculate the Ecell at 25 C if the [Sn2+] =0.01M and [Ni2+] =0.1 M.

b. Calculate the equilibrium constant, K for the following reaction at 25oC

CL-Chapter 09-Electrochemistry : Nernst Equation and Equilibrium Contant, K

PST