The objectives of coal flotation as a major fine coal cleaning method is
reduction of the content of mineral matter in coal; this increases calorific value of thermal coals and, in the case of metallurgical coals, improves the reactivesto-inerts ratio in the feed to a coke-making plant. Reduction of mineral matter also translates into lower content of sulfur and reduces the impact of coal utilization on the environment. Coal organic matter may be quite hydrophobic, but this strongly depends on coal rank, and while bituminous coals (metallurgical coals) are very hydrophobic, lower rank sub-bituminous coals and anthracites(thermal coals) are not. This translates into extremely easy flotation of bituminous coals and very difficult flotation of sub-bituminous coals [4]. As is shown in Figure 1, the separation of coal organic matter from inorganic matter can be achieved either via forward flotation or via reverse flotation. Since bituminous coals are hydrophobic and float easily the forward flotation is a common practice. But since sub-bituminous coals, and also the coals stored in old tailings ponds, are difficult to float the reverse flotation may be quite an attractive option in such cases. The reverse flotation of coal has recently been shown to be possible [5]. There are fundamental differences between the forward and reverse coal flotation. In the case of the forward flotation, the clean coal is recovered as a froth product that is made hydrophobic with the use of various flotation reagents. In the case of reverse flotation, the clean coal product is what is ending up in the flotation tailings; this product is kept as hydrophilic as possible to make its flotation impossible. While these differences may not seem to be very significant they are extremely important when these products are utilized to make a coal-water fuel.