s1_2014-2015

rv\

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<->,
TEST 1
CHM s20 (PHYSICAL CHEMISTI(Y II)
Name :

Date:

Group :
Fundamental constant:
Gas constant(R) = 8.3l4 J K-r mol-I
QIIESTION 1

Give examples of both a system doing work on its surroundings and a system losing heat to its
(4 marks)
surroundings.Describe what happensto the energy of the system in each case.

,f o,

s Tlo cyw,edl
I'd,o't q"4.

. 4 e l*s 4

urarM

a-.,

lf

oI

L)cq

t'rrr*ne\f^

,,*//e

a.. fofu

f* f*A'V
"/tfu
l.npn"de

ot

"f

dPt>r2 utYk

/tl*tr

TP

dt ik

Ttaen-'J

ft^
ot

A-ol

V0n4<r

s4l'r-rer./r'rdnns.

*fre,n-/?+ ift

QUESTION 2
The hot iron at 50.0'C is placed into 500.0 g of water at25.0 "C. If the iron loses 5.1 x 103J of heat,
determine what will be the final temperature of the water and the iron. Give one reason to support your
(5 marks)
answer. (Cowater:4.18J/gK or75.3 J/molK)

= mcAT
1
It

ri
q)

!. AT ' 2'+ k

.fetw7"rafuRTAe' f'nd
f/*
0
o T c 7.4 c
3eo-69
u, ilf k
*

;fl*

i,o n

wfll

ptft /rt- i>r-n

/q<

x 4T

+ . ig !

5' t flDf=5 ""Ax

A"of

o-nd ,/A.

tenz f;>t*l /^^/ctufun"

"f

t-R

i^ n

attd

y'Le ,oap

CD

u.r.l.^ N{ll
ar\4 4f*
u'q./</ NrY V*'h'b $zfe

re

h-,'f.

af *4t

s1_2014-2015
QUESTTON3
In the presenceofa spark,nitrogenandoxygenreactto form nitrogenoxide.

Nz(e) +

Oz(g) +

2No (e)

CalculateAFf for thereactionfrom the following data:

0r

a0

IJN,
|.'3
2N02

R wut e

trzNz(g) +

Oz(g) +

NOz(g)

AH": +33.2kJ/mol

NO (g) +

lt2o,z(g)--*

NOzG)

AHo= -57.1kJimol

tt)+

o rr!)-,

9)

"p,alfrn

?)
ZN o
rg) * (2,0 z

a H= *ZS^2 /zV/na"I X 2
t 6 e' v t4 n o t
.)

cp /

0z

a)
Y:g

Ngz

Naqt+)XV

lv'rJ, +

Nyt

*Noq)n'Fy
'e',p

(5 marks)

, * urL,

\Z

All = -f 57, I

ryiloi

x'2

= * lt+l.Z kJ/n, I

u
/5H '- + &, V !-r/no I
o

6H ' + ll +,1 Pf/na I

4U" t +tflo. 6 l<T/-ot

s1_2014-2015
QUESTION 4
Calculatechangeof enthalpy(AH) (in unit J) and the changeof internalenergy(AU) (in unit J) for the
transformationof one mole of an ideal gasfrom 27.0 "C and 1.00atm to 227 "C and 17.0atm if molar
(9 marks)
heatcapacityat constantpressure(Cp,.): 20.9 + 0.042Tin unitsof JK-rmol-r.

AI J =a C 7 , n A T

AH=lr
ltl

\
O

c D, ^r lT

ll

"Ti
,5ooK

=l

c ?o'1 t aotle7) ol7

" 3oaK

t+ f 1 5 o o (

- -l n.1r ]to o * *
L

TI
fL ',o+2r
l'llt

-3*K

aoil ( 5oo"

= tu,1 X CS oo-Veo) T +
= ( 2 r c r a t* . r l o o ) J +
? 79-/FJ

ffi" $ o

J TooK

- 3oo^)r 0)

;J

X. -7,ry f-to'f, *

AH =AufnR,T

0)

c . 4 4 eAH-rrRT

Tygia' J

-a

TSti'O d

:= 58-T-7'Z
I

Itpol
| 6 &z,g

x 8.gt 4 x{tnul'

,lD o k

ro

1\

x F:s.*{ to3,{:4,
.

n._r

4,*

s1_2014-2015
QUESTTONs
Definethe termsof the following:
(2 marks)

ClausiusinequalitY

i)

,3 usd /- e/L^,AlL"l
q vy-fanr*t*S oA*7o.

ry$*

in

Cter^.hW A)

>.
"ls !3
T

Third law of thermodynamic

7Ac

*bf/

fu U -ro t& '

ot nf-+,

(2 marks)

cys4tu<

"f &aff4

t.l+lerr<l

CD

7-?

*t T-Q, in q f-Fd

iii)

incr"ol*"

^"a ff^*ok* ./n"+ ftu

c",'^$rfaf utTt fi* krdLd /o,.",.

ii)

"^ty;
,**/,v,

W*il

ut/toVy

ftrz

7tl't

ry

y't*- *futf

or iant arc i\

dll ttt *''

a'4 '\
f

cx-b+vruq

tL

oP: o

,f--t**.d

c*f<)

(1 mark)

Entropy

A^Xrt' ft,/;z-l d-rq,,r/x" or /h-'*"fauiz

d'f"[/'|a"

s,t'*.b+-'.-"'lo{ef*,|}r>*t
@
, Enf,-py n /4* 47,*
# dit'"-,Lr.. ;v1
t f h.u
wdrv'-d
Ao'424to "-r/y;t '
1t"s7cl fu
Y'P

^ TA*lo+g
T h u*o

*nalw,t2

Arl^

dzfin/,>

nt

hq /,7"-

-rryy-

? 4
/t 4Df47d
/\, ft,- e'f-^/ /" tJuzt wr"l
-Lfl.
c-,,,'tb "kr>\/.i by rc/>uy 'i* Zr*"ib
e,h"-lr>J,y
"f
,rf ^
*Ty
Cf,r.rf
+ 'MJJ ) ^5 /up,4-a-t " 1*+.4t
'
'A
ptsc;+t,

s1_2014-2015
QUESTTONs
Calculatethe changeof entropyof system(AS.r.),the changeof entropyof surroundings
(AS.,,) andthe
whenthe volumeof 85.0g of CO initiallyat 298K and 1.00barincreases
totalchangeof entropy(AS,o,),
by a factor ofthree in
'

i)

an adiabatic reversible expansion

ii)

an expansionagainstexternalpressure(P"o.-a):0

Statewhethereachprocess(i and ii) is spontaneous.

(12marks)

(Mco:28.01g mol-r1

i)

qd)qbqln
^

Af,

t"t

Fapr*ilfe

A.l

t=

euqanPl*.

4 u'3-)r,,
A!/

Athtr{ =7*

T
'%Jrr
Oty-o

lu-^&

A(S*r=o

i.-"-,'';-*
7="

=o

4 f/*=
Tl*

/{,--f*

^t r y + A LY

pl'<q

;f p/

T/* y/*,

Widervt,

eTuflr\;un

fp-vecft/e

q.c<- rd

qlLd krtYz'>unanVt

4*r*

ii ) ar1 zxy*r*nrt
W
h)=-p.AV'

./

CJ%ffre'wol)

Ua--o

Lrct

lTa l U)-O

6S swi
I

AS =

br/=Z=o

"n

LrV
VL

CI b<-*a

o t hr 3 oSrrr* 4 f
7^z

l2^ur1 r)

x t, 7v [mol'k' * /ns

2F'olf unl'
4

A Stur=

tr' 03-

/,

3,c3 nal x J.tZJaula/.J- eVZ J-ko

=o

= 27,7.7pq7s = 27- /7Ik

fon..rws

-f

{f