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    I am not a frigging robot

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    I am not a frigging robot

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    © All Rights Reserved
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    13 views13 pages

    Assignment Answers 2

    Uploaded by

    Jerry Jose
    I am not a frigging robot

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 13
    aR F for BCC. Consider the BCC ai 1. This problem calls for a demonstration of the relationship call shown below Using the triangle NOP And thon for triangle WP, (NO)? ~ (OP)? + Py But J 1D = AK, R boing the atomic rains. Also, OP = a. Therefore, (aR? oe ak B 2. We are esked to show that the atomic packing factor for BCC is 0.68, The atomic packing factor is dys JOP +O? + (DF ~ 0.1347 am) (YB) ~ 03300 am ‘And, rom Equation 33 afi eens Besa D 8. 1m oadar wo compute tbe faction of atom sts tht are vacant Equation Aaataed inthe problem, 0,-0.9 eVistom Ths, copper at 1357 K, we must employ . 0.90 <¥V/atom | [Gar wom TR 456x104 1. Determination of tho number of vacancies par cubie meter in gold at 900°C (1173 K) requis he ization of Equations 2 follows: ta Bh Me tig Ge 6028 «10 ator mi (iB gies) | 0.98 eV /atom ror *b Gara evan RTE 23524 1018 cnr} =259 5 1024 3 uL i This pat of problem asks that we compute the number af grains per square inch for an ASTM ain size of 6 ata magnification of 100x. All we nod dois solv forthe parameter Nin Equation inasmuch = 26-132 grincin i Now ite necessary o compute the vale of N for no magnification, In endo o solve this problem it it nocessary to use Equation oon ‘whore Nyy ~ the number oF gains per square inch at magnifition MZ, end a isthe ASTM grain size number. Without any magnification, Mf inthe above equation i 1, an therefor, And solving for ¥, N= 320,000 grain a ‘The volume of che pce is taken as unity. ‘Thus from 1 Solidification time & ——————, i (Sarface are)? ‘The respective surface areas are as follows, Spheres Cabe: Grinder Ve ath =2ryr=(t)", Lye da? + 2eth= 6» bo( st) = 5.54 ‘The respective solidification times are therefore Iyhen = 0.043G, fae = 0.028C, fyi = 0.0330. Hence, the cube-shaped piece will solidify the fastest, and the spherical piece wil solidify the slowest. 13. {This problem asks us to consider s specimen of ie that is at -15°C and 10 atm prassure, 2. Moling occu, (changing pressure) 2s, moving vertically (gpwad) ths temperature, we cos the tee Liqud phase boundary “This oocurs at appreximaaly 1,000 atm; thus, the pressure of the specimen must be raised fom 10 1,00 atm, . In cwer to deterine the pressure at which sublimation uccus al his temperate, we move veticlly onavard ion 10 an unt we crass the e-Vapurplsebounday of Figu This iersection occurs at approximately 0.003 aim We ae asked to specify the value of F for Gibbs phase cule at poins A, B, and C on the pressure temperature diagram for HO (Figure 9.38). Gibbs phase rae in general frm is PLF=C>N Fortis system, the number of components, C, is 1, whereas N, the numberof noncompesiional variables, is 2~iz temperature and pressure. Thus, the phase rule nw becomes PHPH1t2=3 ‘where P is the numberof phases present at equilibria, At point A, only a single (quid) phase is present (ic, P~ 1), or Fo3-PH3 ‘which means that oth emperstre an pressure ate necessary to define the system, Atpoint B whichis onthe phase Boundary betwsen liquid and vapor phases, twa phases are im equilibria Prd-2-l Or that we need 10 specify he value of ether temperature or pressure, which determines the value ofthe other (pressure or temperature). And, finally, at point C, three phases are present—viz ce I vapor, and liquid—and the numberof degrees ‘of fredam is era ince P-3-P-3-3-0 ‘Thus, point € sam invari point in this case triple pont), and we have no choice inthe selection of externally controllable variables inorder o define the system, 14. This problem states that ice homogeneously mucleates at ~40°C, and that we ate to calculate the

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