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AC:JrA

CRIMICA SINICA 1990,

48, 365-371

III. (SPFO)
(CTAB)

ESR NMR SPFO-CTAB

. CTAB SPFO
. SPFO CTAB .

(SPFO 07F15000Na)
C1: So(III) EOAB( 6B)-SPFO-TPB( )~

105L.mol-1.om-1)C1\ Al(III)-EOAB-SPFO-OTAB
(pH5.08x=660n 8tJonm =2 .58 x 105L.mol- 1 .om- 1) .
(pH5.76 max = 643 e~3 =2.72 X

SPFO-c-Sf( ).

Al(III)

EOAB-SPFO-OT AB. ESR NMR


SPF O-OTAB Sf SPFO OTAB '~.

1 6- 3 (DPH) SPFO

OTAB . DPH p

;.
. Ohaopadhyay DPH
CSJ

DPH DPH

DPH .
JlIJ

PBS():

0.15mol.L-1NaOl,

pH 7 .2. DPH(Sigma ): 1

2x10- 3 mol.L-1Hs P0 4

x 10- s mol.L-l .

PBS 2 X 10-6 mol.L-l 15min.

850

10m . 359 m e 430nm; 5nm;

:.
:

10 mL 1 mL 2 x

10-6 mol. L -1 DPH

PBS

25 0 lh .
llS8 4 7 . II 1989 8 ( 5. .

.366.

ACJrA

CH MICA

SINICA lYIN

DPH

1 DPH ^ex = 385 nm, ^em = 443 nm

. CTAB( 2 b) SPF-CTAB ( 2u:


359nm 430nm

DPH
( 2 0)
. DPH
.

4.0

3.0

"

'"

2.

c
1. 0

200
2
~

400

420
/nm

440

460

300

'AAn

L=?

4HNom

---AHU

"hd

AU

600

DPH CTAB CTAB-SPFO

a. 2x10- 8 mol.L-l OTAB 2 X 10-8 mol. L-l SPFO;


b. 2xl0-3 mol.L-1 0TAB; C. 90% (w/w) Dioxane;
d. DPH: 2x10- 7 mol.L-1 mol.L-l

DPH PBS .

DPH: 2xl0-6 mol.L-l

3 Dioxane-HIIO DPH

.DPH

. d

120

E41.

8 d DPH

p d 20 DPH

..

90

.3

60

40

DPH

. 2 DPH CTAB
SPFO-CTAB

30

DPH .

o
3

20

40
60
80
Dioxane(%. w/w)

100

Dioxane-H~O DPH

-CTAB

ex359nm em430nm

DPH

OTAB DPH pH3-9.5 . pH-7


DPH PBS (pH7.2) .

4 DPH C'l'AB

SPFO-.OTAB . SPF-CTAB

CTA:B DPH
OTAB . Al(III) - EOAB-SPF-OT AB

ACJrA CBIMICA SIKICA 19

20
4

40

60

t/min

80

100

.387.

120

DPH

0
ex 859 m em 430 nm , 25

1-2.5x10-s mol.L-lCTAB , ::1 X10- 7 mol.L-lDPB;


mol.L-lCTAB , 1. 25x10- 8 mol.L-l
SPFO , 2X10-7 mol.L-lDPB;
8-2 X10-8 mol. L-l CTAB; 2 X 10-7 mol. L-l DPR

2.5x10- 8

DPH

ex 359nm , ^" 430nw; 25


CTAB: 2.5X10- 8 mol.L-l; SPFO:
1. 25x10- 8 mol.L-l; DPB: 2X10- 7 mo].L-l
0

Al (III) - EOAB-OT AB .

6 DPH

I ; I1.

0.30

P 25 50min

P DPH
.

25 0 1h
20

SPF -O TAB
DPH 6 OTAB
5xl0- 4 4x lO- s mol.L-l

CSPll'O:CTAB CSPll'O:
CCTAB 1:1 P

-OTAB NaOA<rOTAB

DPH 6.

6 NaOAo
OTAB P
. SPFO OTAB
SPFO -F E

.
-OTAB
-H OTAB

CZICCT

CTAB SPFO

NaOAo DPH

DPB:

::1 X 10-7 mol. L-l" 359

nm.

A.m 430 nm, 25 1h


0

COTAB ,mol.L-l
1-5x LO-4
2-1x10- 3
3-2x10-S
4-4 xl0- S
5-4 X 10-8
6-1xl0-S
7-2xl0-8
-4: xl0-'

SPFO;
SPFO;
SPFO;
SPFO;
NaOA

.. 888.

ArA

CHIMICA SINICA 1990

. NaOAc

CTAB .

ESR
(ES.""
ESRi
. ESR ESR
C6J

5NS(5-DOXYL-saric acid) SPFO-CTAB

p .
5NS SPFO-CTAB ESR

1 (:)( 10
6J
1

?
z6.51o[(r

e ;

. p ;.

.
b

Ilr.

5NS(SYVA ) :

Bruker ESR ER 200D-SRC

2 X 10-.{ mol. L-1

100L 2x10- mol.L- 1 5NS


4

1mL 3
p
12h ESR .

'1

.&.

,/

'1

5NS

Dioxane-H.20 ESR .

Vpjane:VHO'

100:0 0:100 5NS ESR

323-

LL

.,

J1J ESR . 5NS.


d

v- -

7 5NS ESR
a.

Sx10-Smol.L-~

OTA.tl

b.1 ;-Bmol.210TAE

X 10-4

mo 1. L-l 8PF;

::ZZEZE.
5 N8: 2 x 10-5 mol. L-l

ESR
7c 5NS ESR

. (1 % 5NS
. C'l'AB SPFO-CTAB (
'7 a b) ( 7 5NS ESR

5NS CTAB SPFO-CTAB


p p

5NS 'l7c . SPFO-OTAB 5NS CTAB


5NS

C02H

ACTA CHIMICA 8INICA 1990

11e .

.389.

SPFO E52

OTAB .
OTAB .
NaOAo SPFO OTAB OTAB

5NS 11c . SPFO OTAB


.

SPFO-OTAB SPFO OTAB


ESR SPFO-OTAB -OTAB NaOAo
DTAB OTAB lHNMR SPFO 19F NMRi. JEOL
FX90

Q Fourier

lH

19F

lH TMS p (HMO)

F113 (OF2 0l. OF0l2) . 8 9.

'li

cf{ctzh-(ctzvcF24f0

ONa

-10

20

-30
4/ppm

-40

50

-' "_J

CT AB--SPFO 19FNMR

8PFO: 0.025mol.L-l;
'AB: a. 0; b. 2.5x10-'mol.L. 1. 25x10- 8 mol.L
d. 2.5xl0- 8 mol.L-l;5 X 10-8 mol. L-l

8 0.025 mol. L -l.SPFO OTAB SPFO 19FNMR

(OFlI);. I SPFO OTAB


.
SPFO U Xl0- 3 mol.L- 1 0TAB 9) OTAB lHNMR

SPFO CSP.i'O :COTAB=O. 3: 1 OTAB lHNMR .

NaOAo SPFO.

OTAB

'TAB lHNMR . SPFO OTAB

.a70.

ACTA OHIMICA SINICA 1990

k'

_j

..
-N(CH

a
3.0

2.0

1.1.)

8/ppm

CTAB-SPFO lHNMR

CTAB: 5 X10-3 mol. L-l;


PFO: a. 0; b. 5x10-5 mol.L-l; C. 2.5x10- 4mol.L-1;
d. 5XIO-4mol.L-l; e. lxlO- 8 mol.L-l; f. 1. 5xIO-s mol.L-t

NaOAc .

OTAB SPFO
SPFO OTAB 3

OTAB p 3 .
.

[1]

1990 8 ( 7

t: 2]

1989, 8( 5.
[3 J Ohattopadhyay, A.; London. E" Anal. Bioch87Tl. , 1984, 189, 408.
[4 J Akhada, Y. DieZectric Prerties 01 Biry SoZution , Oxford, Pergaman
[5J 1984(1) , 1.
(6] " 4". 1980.

Pr:

N. Y.,

11

p. 285.

ArA

.371.

CHIMICA 8INICA 1990

Application of Specific Surfactant in Micelle Specphotome'y

IU. The

Microenvironmen1 Proper;ies of e

Sodiu Perfluorooctanoae

(SPFO) and

Mixed Micelle of

Cylrimehylammo:ium

Bromide (CTAB)
Li, Min Zheng, Yong-Xi.
(Depf emist'1' Tsight(J Umve'1'S Beij-'g)

Abstra o1i
Our previo rep

or
have
ind

ia
$
ed
hat A
l(

E
IH

o
r
So(
m

))-EOAB(Erihrome
zurol
B)-SPFO-OTAB(pH=5
)8
ystem
i8 a SUp

erB

siv

'e reaion s
for il19

rophorio deermination of alnminium (or andium). Inhis s he


o
properies of he SPFO-OT AB mixed mioo11e micrnvironme were udied usg
flnoresn prooo elron spin rnanoo (ESR) in laooled hniqne and nuolear
m.agne renan(NMR) k'py. The DPH (1 , 6-phenyl-1 3, 5-hexatriene)
norInoo proOO reveals a low elootrio const a in e SPFO-CT AB millar re.
The degr of polarization(P value) of DPH iS inoreased in SPF-OTAB mixed mille
inabing a change of he milIar 're microviSity. ESR using 5NS (5-DOXYLaric acid) laOOl chniqne also revea1she iDcrease of microvsi of he mixed
i11e. As shown by 1H NMR and 19F NMR experien SPFO and OTABhaveformoo
a mixed miool1e and he flnorocar bon chain of SPFO h a rog interactjoD wibh
the hydrarbon chain of OT AB, indica ting a nnmber of SPFO flnorla:J." bon chaiD
pene'&sine intrior of OT AB ioo.6.