LEMBAR PERHITUNGAN

1. Menghitung Kebutuhan Reagen

Densitas
a. Kalibrasi volume picnometer
m pikno kosong=29,752 gr

m pikno kosong+ aquadest=79,66 gr

m aquadest=79,6629,752=49,908 gr
aquadest=0,996
Vpikno=

gr
ml

49,908 gr
=50,1 ml
gr
0,996
ml

b. Asam asetat
m pikno kosong+ asamasetat =82,168 gr

m asamasetat =82,16829,752=52,416 gr
asam asetat=
c. Etanol

52,416 gr
gr
=1,046
50,1ml
ml

m pikno kosong+ etanol=72,314 gr

m etanol=72,31429,752=42,562 gr
etanol=
d. HCl

42,562 gr
gr
=0,84
50,1 ml
ml

m pikno kosong+ HCl=87,663 gr

m HCl=87,66329,752=57,911 gr
HCl=

57,911 gr
gr
=1,155
50,1 ml
ml

Kebutuhan NaOH (0,41 N)

m 1000
N=

kadar
Mr
V
0,41=

m 1000

0,98
40 500

m NaOH =8,36 gr

Kebutuhan Katalis HCl (0,2 N)

m 1000
N=

kadar valensi
Mr
V
0,2=

m
1000

0,25 1
36,5 250

m HCl=7,3 gr
=

m
v

v HCl=

7,3 gr
=6,32 ml
gr
1,155
ml

Kebutuhan Etanol dan Asam Asetat

V total
= V asetat + V etanol + V katalis

V asetat + V etanol

= 250 6,32 ml

V asetat + V etanol

= 243,68 mL

Mol asam asetat : etanol = 1 : 3

x V x kadar
x V x kadar
3
asetat=
etanol
BM
BM
3

[
[

1,046 x V x 0,98
0,84 x V x 0,96
asetat=
etanol
60
46

0,05125 V asetat

0,0175 V etanol

V asetat

0,341 V etanol

V etanol + V asam asetat

243,68 ml

V etanol + 0,341 V etanol

243,68 ml

V etanol

181,72 ml

V asam asetat

61,96 ml

2. Menghitung Konsentrasi asam asetat sisa (CA) dalam konversi asam asetat (XA)
CH3COOH + C2H5OH CH3COO C2H5 + H2O
A
B
C
D

M assa asam asetat= V %kadar

Massa asamasetat =1,046

gr
61,96 ml 0,9 8
ml

Massa asamasetat =63,51 gr

CAo =

gr 1000 63,51 1000

x
=
x
=4,234 mol/l
BM V ( ml )
60
250

M assa asam asetat= V %kadar

Massa asamasetat =0,84

gr
181,72 ml 0,96
ml

Massa asamasetat =146,54 gr

CBo =

gr 1000 146,54 1000

x
=
x
=12,743 mol /l
BM V ( ml )
46
250

CA=

( VxN ) NaOH (Vsampel x N katalis HCl) ( V x 0,4 1 )(5 x 0,2)

=
=0,082 V 0,2
V sampel
5

X A =1

CA
CA 0

Variabel 1 ( T =45 )
t (menit)

Volume
NaOH (ml)

CA

XA

64.3

5.0726

-0.19806

11

50.1

3.9082

0.076949

22

43.5

3.367

0.204771

33

34.7

2.6454

0.375201

44

31.8

2.4076

0.431365

C A =C A 0 ( 1 X A ) =C A 0C A 0 X A =4,234 ( 1X A )
C B=C B 0 C A 0 X A =12,7434,234 X A
CC =C A 0 X A
C D =C A 0 X A
M=

C B 0 12,743
=
=3.007 6
C A 0 4,234

r A=

d C A
C C D
=k 1 x C A x C B C
dt
K

C Ao x

dCA
C C D
=k 1 C A x C B c
dt
K

C Ao x

d XA
( C Ao x X A ) x ( C Ao x X A )
=k 1 C Ao ( 1X A ) x ( C BoC Ao x X A )
dt
K

d XA
C Bo
C Ao2 x X A2
C Ao x
=k 1 C Ao ( 1X A ) x C Ao
XA
dt
C Ao
K

( (

))

d XA
C Bo
X A2
2
C Ao x
=k 1 x C Ao x ( 1X A ) x
XA
dt
C Ao
K

) )

dXA
C Bo
X A2
=k 1 x C Ao x ( 1 X A ) x
X A
dt
C Ao
K

dXA
X 2
=k 1 x C Ao x ( 1 X A ) x ( M X A ) A
dt
K

Pada saat Kesetimbangan

K=

CC x C D
( C Ao x X A ) x (C Ao x X A )
=
C A x C B C Ao x ( 1 X A ) x (C Bo( C Ao x X A ) )

Konstanta Kesetimbangan saat t = 44 menit

X A2
0.4312
K=
=
=0.127
( 1 X A ) x ( M X A ) ( 10.431 ) x (3.007 60.431)

Mencari Nilai XA
dXA
X A2
=k 1 x C Ao x ( 1X A ) x ( M X A )
dt
K

dXA
X 2
=k 1 x 4,234 x ( 1X A ) x ( 3.007 6 X A ) A
dt
0.127

dXA
=k 1 x 4,234 x ( X A24.007 6 X A +3.007 67,874 X A2 )
dt
dXA
=k 1 x 4,234 x (6.874 X A 24.007 6 X A +3.007 6 )
dt
dXA
=k 1 x (29,1045 X A 216,968 X A +12,734 )
dt
dXA
=k 1 x29,1045 ( X A 2+ 0,583 X A 0,4375 )
dt
XA

t
d XA
1
=k 1 dt
2
29,1045
0 ( X A +0,583 X A 0,4375 )
0
XA

0.034
0

d XA

( X A2 +0,583 X A 0,4375 )

=k 1 x t

Dimana,
XA

0.034
0

dXA
( X A 0,4313 ) ( X A + 1,0143 )

A
B
+
=0.034
( X A 0,4313 ) ( X A +1,0143 )

A ( X A +1,0143 ) + B ( X A 0,4313 )
A
B
+
=
( X A 0,4313 ) ( X A +1,0143 )
( X A 0,4313 )( X A +1,0143 )
A + B=0
1,0143 A0, 4313 B=1

A=0,692

B=0,69 2

Sehingga Menjadi,

XA

XA

0,692
0,692
0.034
d X A +
dX A = k 1 x t
0 ( X A 0,4313 )
0 ( X A +1,0143 )

( Xa+1,0143 )
ln

Xa
0.034 (0,692) {[ln ( Xa0,4313 ) ]0
0,4313
ln ( Xa0,4313 )ln

( Xa+1,0143 )ln ( 1,0143)

ln

0,048 {

0,048 ln

( Xa0,4313 )
( Xa+1,0143 )
ln
=k 1 x t
(0,4313 )
( 1,0143 )

[
[(

0,048 ln

0,048 ln

)]

(( (

Xa0,4313 ) ( Xa+1,0143 )

=k 1 x t
( 1,0143 )
0,4313 )

)]

( Xa0,4313 )
(1,0143)

=k 1 x t
(0,4313 )
( Xa+1,0143 )

0,048 x ln

( Xa0,4313 ) ( 1,0143 )
=k 1 x t y=mx
(0,4313 )( Xa+1,0143 )

t(x)

XA

x.y

x2

-0.198063297

-0.13233

11

0.076948512

-0.07867

-0.8654

121

22

0.204770902

-0.06025

-1.3255

484

33

0.375200756

-0.03498

-1.1542

1089

44

0.431365139

-0.02549

-1.1217

1936

11

m=

K=

0.33171

n . xy x y
n . x ( x )
2

4.4667

36

30

( 5 4.4667 )(110 0.33171)

3 mol
=2,3396 x 10
2
menit
( 5 3630 )(110 )

k1
k 2,3396 x 103
mol
k2 = 1 =
=1,842 x 102
k2
K
0.127
menit

Variabel 2 ( T =5 5 )
t (menit)

Volume NaOH (ml)

Ca

Xa

47.1

3.6622

0.135049598

11

37.8

2.8996

0.315162966

22

30.7

2.3174

0.452668871

33

26.8

1.9976

0.528200283

44

26.1

1.9402

0.541757204

Pada saat Kesetimbangan

K=

CC x C D
( C Ao x X A ) x (C Ao x X A )
=
C A x C B C Ao x ( 1 X A ) x (C Bo( C Ao x X A ) )

Konstanta Kesetimbangan saat t = 44 menit

X A2
0.5422
K=
=
=0,2601
( 1 X A ) x ( M X A ) ( 10.542 ) x (3.007 60.542)

Mencari Nilai XA
dXA
X A2
=k 1 x C Ao x ( 1X A ) x ( M X A )
dt
K

dXA
X A2
=k 1 x 4,234 x ( 1X A ) x ( 3.007 6 X A )
dt
0,2601

dXA
=k 1 x 4,234 x ( X A24.007 6 X A +3.007 63,845 X A 2)
dt
dXA
=k 1 x 4,234 x (2,845 X A2 4.007 6 X A +3.007 6 )
dt
dXA
=k 1 x (12,04 X A 216,968 X A +12,734 )
dt
dXA
=k 1 x12,04 ( X A2 +1,409 X A 1,057 )
dt
XA

t
d XA
1
=k 1 dt
2
12,04
0 ( X A +1,409 X A 1,057 )
0
XA

0,083
0

d XA

( X A2 +1,409 X A 1,057 )

=k 1 x t

Dimana,
XA

0,083
0

d XA
( X A 0,542 ) ( X A +1, 951 )

A
B
+
=0.034
( X A 0,542 ) ( X A +1,951 )
A ( X A + 1,951) + B ( X A0,542 )
A
B
+
=
( X A 0,542 ) ( X A +1,951 )
( X A 0,542 ) ( X A +1,951 )
A + B=0

1,951 A0, 542 B=1

A=0,401

B=0,401

Sehingga Menjadi,
0,083

XA

XA

, 401
0,401
d X A +
dX A = k 1 x t
X 00,542
)
0 (
0 ( X A +1,951 )
A

( Xa+ 1,951 )
ln

Xa
0,083(0,401){[ln ( Xa0,542 ) ]0
0,542
ln ( Xa0,542 ) ln

( Xa+1 , 9513 )ln ( 1,951)

ln

0,033 {

0,033 ln

( Xa0,542 )
( Xa+1,951 )
ln
=k 1 x t
(0,542 )
( 1,951 )

[(
[(

)]

0,033 ln

( Xa0,542 ) ( Xa+1,951 )

=k 1 x t
(0,542 )
( 1,951 )

0,033 ln

( Xa0 ,542 )
(1,951)

=k 1 x t
(0,542 )
( Xa+1,951 )

)]

0,033 x ln

m=

K=

( Xa0,542 ) (1,951 )
=k 1 x t y =mx
(0,542 ) ( Xa+1,951 )

t(x)

XA

x.y

x^2

0.135049598

-0.07017

11

0.315162966

-0.04429

-0.487153421

121

22

0.452668871

-0.02163

-0.475769057

484

33

0.528200283

-0.00621

-0.205080033

1089

44

0.541757204

-0.135893336

1936

-0.00309
-

110

0.14538

1.303895847

n . xy x y
n . x 2 ( x )

363

( 5 1.303895847 )(110 0.14538)

mol
=1,566 x 103
2
menit
(5 3630 )(110 )

k1
k 1,566 x 103
mol
k2 = 1 =
=1,23 x 102
k2
K
0.127
menit