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Continuous phase
Matrix/Binder
Dispersed phase
Reinforcement/Filler
Interphase
An interfacial region
between matrix and reinforcement
Interfacial region
The interfacial area is essentially equivalent to the
surface area of dispersed phase in a composite.
2
Thostenson et al. Composites Science and Technology, 65, 2005, 491-516.
Interfacial region
The primary considerations
Wetting of the dispersed phase by the matrix
The type of bonding between the dispersed
phase and the matrix
Wetting
The ability of a liquid to spread on a solid surface
SV SL LV cos
contact angle
Wetting
The contact angle is a measure of wettability
The magnitude of depends on:
Time and temperature of contact,
Interfacial reactions,
Electronic configurations,
Surface roughness.
Complete wetting
=0
SV ( LV SL )
<90
( for 0 900 )
=90
>90
2
SV graphite 70 mJ m 2 LV polyester 35 mJ m
SV polyethylene 31 mJ m 2
LV metals ~ 800 mJ m 2
=180
4
Hull and Clyne, An introduction to composite materials, Cambridge press 2010.
Types of interfaces
Coherent interface
Semicoherent interface
A partial matching of lattice planes on the two sides of the interface.
Incoherent interface
No matching of lattice planes on the two sides of the interface.
Interface bonds
By Molecular entanglement
By electrostatic attraction
By interdiffusion of elements
By chemisorption
By mechanical keying/bonding
Interface bonding
Degree of interfacial bonding determines toughness of
overall composite
For ductile matrix (metals and polymers) composites
A high degree of dispersed phase-matrix bonding is preferred.
A crack initiating in the brittle dispersed phase tends to be blunted
when it reaches the ductile matrix even the bonding is strong.