CR91EventShelbyCounty,AL

PreliminaryAirMonitoringSummary
September17,201605:0017:00

Preparedby
CenterforToxicologyandEnvironmentalHealth,L.L.C.(CTEH)
OnBehalfofColonialPipeline

Introduction
OnSeptember9,2016,theCenterforToxicologyandEnvironmentalHealth,L.L.C.(CTEH)initiatedairmonitoring
insupportofresponseeffortstothegasolinereleaseinShelbyCounty,AL.Thisreportpresentstherealtimeair
monitoringdatarecordedfromSeptember17201605:00toSeptember17,201617:00CDT.

RealTimeAirMonitoring1
Realtime air monitoring was conducted to evaluate the potential airborne presence of gasolineassociated
constituents,ifany,duringresponseoperations. Allinstrumentationwascalibratedatleastonceperdayorper
manufacturers recommendations. Target analytes were measured as total volatile organic compounds (VOCs),
oxygen, benzene, and flammability as the percent of the lower explosive limit (LEL) using remote telemetering
RAESystemsAreaRAEs,handheldinstrumentssuchasRAESystemsMultiRAEPro/PlusandUltraRAEs,aswellas
Gasteccolorimetricdetectiontubes.

Duringthismonitoringperiod,twoLEL,sixbenzene,and21VOCactionlevelexceedanceswererecordedduring
workeractivitymonitoring,includinginstantaneousVOCandbenzenereadingswhichwererecordedabovethe
actionlevel.Whennecessary,workersegressedtheareainaccordancewiththeapprovedsamplingandanalysis
plan.

Table1,below,presentstheresultsofrealtimeairmonitoringusinghandheldinstruments.Mapsoftheincident
sitelocationandlocationsofhandheldrealtimeairmonitoringreadingsareprovidedinAppendixI.

Real-time air monitoring refers to the use of hand-held instruments that provide near-instantaneous readings of an airborne chemical concentration without the need for
laboratory analysis.

2016-09-18 Page 2 of 6

Table1:HandHeldRealTimeAirMonitoringSummary1
September17,201605:00toSeptember17,201617:00
LocationCategory

Countof
Detections

RangeofDetections2,3

UltraRAE

35

0.51.9ppm

MultiRAEPlus

58

<1%

MultiRAEPro

46

<1%

MultiRAEPlus

20.920.9%

MultiRAEPro

20.920.9%

MultiRAEPlus

57

1.71.7ppm

MultiRAEPro

57

16

0.2159ppm

UltraRAE

11.0511.05ppm

MultiRAEPro

425%

MultiRAEPro

1512ppm

Instrument

Benzene
%LEL
WorkerActivity
Monitoring

Countof
Readings

Analyte

O2

VOCs
Benzene
SiteCharacterization LEL
VOC
1Please

Note: The data displayed in the above table has not undergone complete QC analysis and is presented in a preliminary format.
2Maximum detections preceded by the < symbol are considered non-detections below the instrument limit of detection (LoD) value to the right.
3Numbers are the raw values, no correction factors have been applied.

Duringthismonitoringperiodremotetelemeteringequipmentrecorded5445detectionsofVOCsabovetheCTEH
establishedactionlevelof30ppmand45detectionsofLELabovetheCTEHestablishedactionlevelof10%(3%as
rawvaluesonLELsensors).

Table2(below)summarizesremotetelemeteringAreaRAEdataforthismonitoringperiod.Forthisreportingperiod
AreaRAEmonitoringdatamaycontaindriftevents2.AppendixIandAppendixIIincludelocationmapsandgraphs
forremotetelemeteringdata,respectively.4

Drift is defined as any interference in the PIDs or electrochemical sensors ability to accurately report the concentration of a chemical in the atmosphere. Humidity, rapid
temperature changes, and compromised batteries are examples of common sources of drift.

2016-09-18 Page 3 of 6

Table2:RemoteTelemeteringRealtimeAirMonitoringSummary1,3
September17,201605:00toSeptember17,201617:00
Unit

LocationDescription

AR01

2ACompressors

AR03

WestofRelease
Site/NearStopple1

AR04

2AFracTankStaging

AR05

2ARecovery

AR06

EastofRelease
Site/NearStopple2

AR07

2BRecovery

AR08

MainStagingAreaFrac
Tanks

AR09

ReleaseSite

AR10

Onpathbetween
Recovery2Aand
Recovery2B.

AR11

MainStagingEntrance
EastofTRGcheckpoint

AR13

TRGCheckpoint2
accesstostopple1,
Recovery2Aand2A
FracTankStagingArea.

AR14
1Please

Cabofexcavatorat
releasesite

Countof
Readings
2372
2372
2372
2489
2489
2489
2476
2476
2476
2527
2527
2527
2319
2319
2319
2485
2485
2485
2503
2503
2503
2514
2514
2514
2177
2177
2177
2090
54
2090
2006
2006

Countof
Detections
0
2372
2012
0
2453
1608
0
2476
909
3
2527
1687
0
2319
616
0
2485
1317
0
2503
2500
0
2514
525
0
2101
0
0
54
107
0
2006

VOC

2006

2005

0.11.5ppm

LEL
O2
VOC

2534
2534
2534

0
2534
2534

<1%
20.920.9%
0.659ppm

Analyte
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2

RangeofDetections2
<1%
20.920.9%
0.1300.2ppm
<1%
20.920.9%
0.14.6ppm
<1%
20.920.9%
0.16.8ppm
1.33.1%
20.921.4%
0.198.8ppm
<1%
20.920.9%
0.163.6ppm
<1%
20.921.2%
0.112.2ppm
<1%
20.420.9%
0.1109.5ppm
<1%
20.920.9%
0.171.1ppm
<1%
20.921.3%
<0.1ppm
<1%
20.920.9%
0.10.4ppm
<1%
20.920.9%

note: The data displayed here has not undergone complete QA/QC analysis and is presented in a preliminary format.
detections preceded by the < symbol are considered at the limit of detection (LoD) value to the right.
3LEL and VOC values are raw values, correction factors have not been applied.
2Maximum

2016-09-18 Page 4 of 6

AppendixI:
SiteLocation,HandHeldRealTime
AirMonitoringLocation,and
RemoteTelemeteringAirMonitoring
LocationMaps

2016-09-18 Page 5 of 6

CR-91 Event
Site Location

Project: 108465
Client: Colonial Pipeline
Location: Shelby County, AL

S
"

0 25 50

100

150

200 Miles

n
!

W
W aa ll kk ee rr
S
S tt .. C
C ll aa ii rr

JJ ee ff ff ee rr ss oo nn

T
T uu ss cc aa ll oo oo ss aa

S
"

Co

T
Taa ll ll aa dd ee gg aa
C
C ll aa yy

B
B ii bb bb
C
C hh ii ll tt oo nn
PROJECTION SYSTEM: UTM16

S
"

C
C oo oo ss aa

COORDINATE SYSTEM: WGS84

t
on
m
al
Co

S
"

Release Site
Stopple

Rd

91

Rd

0.15

0.3 Miles

Main Staging SIte

2B Frac Tank Staging Area

ArtificialPath

2B Recovery Site Staging Area

n
!

Underflow Dam

Creek/Stream
Print Date: 9/13/2016

Radio-telemetering Real-time Air Monitoring Station Locations

CR-91 Event 9/17/2016

10

)
"

Project: 108465
Client: Colonial Pipeline
Location: Shelby County, LA

07
)
"

01
)
"

04
)
"

05
)
"

03
)
"

06
)
09 "
)
"
S
"

11
)
"

13
)
"
Co

Rd

91

t
on
m
l
oa

Rd

Legend
08
)
"
0

500

PROJECTION SYSTEM: UTM Zone 16

1,000
Feet
COORDINATE SYSTEM: WGS84

)
"
S
"

Radio-telemetering Station
Release Site
Ponds

Creek/Stream
Print Date: 9/17/2016

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nua
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7/
2
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0
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oR

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P
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:10
8465
Cl
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oni
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pel
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L
oc
a
t
i
on:
S
hel
byCount
y
,
AL

Rd

Legend
S
"

Release Site

Real-Time Reading Location

ArtificialPath

0 250 500

1,000 1,500 2,000 2,500 3,000 3,500

Feet

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

COORDINATE SYSTEM: WGS84

Creek/Stream
Ponds

Print Date: 9/17/2016

Ma
nua
l
l
yL
og
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dRe
a
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T
imeRe
a
ding
s|Be
nze
ne
CR9
1E
v
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nt|09
/
1
7/
2
0
1
60
5:
0
0 0
9
/
17
/
2
01
617
:
0
0

P
r
oj
e
c
t
:10
8465
Cl
ie
nt
:Col
onia
l
P
ipel
ine
L
oc
a
t
ion:
S
hel
by Count
y,
AL

S
"

Legend
S
"

Co

250

500

1,000

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

1,500

2,000
Feet

COORDINATE SYSTEM: WGS84

Rd

91

Release Site
Rd

t
ArtificialPath
on

m
al
CoCreek/Stream

Ponds

Real-Time Benzene Reading (PPM)

<0.1
0.05 - 0.25
0.26 - 0.49
> 0.50

Print Date: 9/17/2016

Ma
nua
l
l
y
L
og
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di
ng
s| L
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CR9
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nt| 09
/
1
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2
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60
5:
0
0 0
9
/
17
/
2
01
617
:
0
0

P
r
oje
c
t
:10
8465
Cl
i
e
nt
:Col
oni
a
l
P
i
pel
i
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L
oc
a
t
i
on:
S
hel
byCount
y
,
AL

S
"

Co

Rd

91

t
on
lm
a
Co

Rd

Legend
S
"

Release Site
ArtificialPath

Creek/Stream
Ponds

Real-Time LEL Reading (%)

<0.1
1 - 10

0 250 500

1,000

1,500

2,000

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

2,500

3,000
Feet

COORDINATE SYSTEM: WGS84

11 - 30
>30

Print Date: 9/17/2016

Ma
nua
l
l
yL
og
g
e
dRe
a
l
T
i
meRe
a
di
ng
s|VOC
CR9
1E
ve
nt|09
/
1
7/
2
0
1
60
5:
0
0 0
9
/
17
/
2
01
617
:
0
0

S
"
R
Co

1
d9

t
on
lm
a
Co

P
r
oj
e
c
t
:10
8465
Cl
i
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nt
:Col
oni
a
l
P
i
pel
i
ne
L
oc
a
t
i
on:
S
h el
by Count
y,
AL

Rd

Legend
S
"

Release Site

ArtificialPath
Creek/Stream
Ponds

Real-Time VOC Reading (PPM)

<0.1
0.1 - 29.9

250 500

1,000

1,500

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

2,000

2,500

3,000
Feet

COORDINATE SYSTEM: WGS84

30.0 - 299.9
>300.0

Print Date: 9/18/2016

AppendixII:
RemoteTelemeteringAirMonitoring
Graphs

2016-09-18 Page 6 of 6

Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|VOC
CR91Event|9/
17/
201605:
00t
o9/
17/
201616:
59

AR01/2ACompr
essor
s

PPM

Uni
t/L
oc
at
i
on
200
100

AR04/2AFr
acSt
agi
ng

PPM

0
200
100

AR05/Rec
over
y2A

PPM

0
200
100

AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2

PPM

0
200
100

AR07/Rec
over
y2B

PPM

0
200
100

AR08/Mai
nSt
agi
ngAr
eaFr
acTanks

PPM

0
200
100

AR09/Rel
easeSi
t
e

PPM

0
200
100

AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B

PPM

0
200
100

AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt

PPM

0
200
100

AR13/TRGChec
kpoi
nt2

PPM

0
200
100

AR14/Cabofexc
avat
oratr
el
ease
si
t
e

PPM

0
200
100
0
9/
17/
201605:
00

9/
17/
201607:
00

9/
17/
201609:
00

9/
17/
201611:
00
Dat
e/Ti
me

VOCr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
t
i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.

9/
17/
201613:
00

9/
17/
201615:
00

9/
17/
201617:
00

Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|LEL
CR91Event|9/
17/
201605:
00t
o9/
17/
201616:
59
Uni
t/L
oc
at
i
on

6
AR01/2ACompr
essor
s

4
2

6
AR04/2AFr
acSt
agi
ng

4
2

6
AR05/Rec
over
y2A

4
2

AR07/Rec
over
y2B

AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2

4
2

6
4
2

6
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks

4
2

6
AR09/Rel
easeSi
t
e

4
2

AR11/Mai
nSt
agi
ngEnt
r
anc
eEast
ofTRGc
hec
kpoi
nt

AR13/TRGChec
kpoi
nt2

AR10/Onpat
hbet
weenRec
over
y
2AandRec
over
y2B

4
2

6
4
2

6
4
2

6
%

AR14/Cabofexc
avat
oratr
el
ease
si
t
e

4
2
9/
17/
201605:
00

9/
17/
201607:
00

9/
17/
201609:
00

9/
17/
201611:
00
Dat
e/Ti
me

L
ELr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
t
i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.

9/
17/
201613:
00

9/
17/
201615:
00

9/
17/
201617:
00

Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|Oxygen
CR91Event|9/
17/
201605:
00t
o9/
17/
201616:
59
Uni
t/L
oc
at
i
on

AR01/2ACompr
essor
s

20
10
0

AR04/2AFr
acSt
agi
ng

20
10
0

AR05/Rec
over
y2A

20
10
0

AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2

20
10
0

AR07/Rec
over
y2B

20
10
0

AR08/Mai
nSt
agi
ngAr
eaFr
acTanks

20
10
0

AR09/Rel
easeSi
t
e

20
10
0

AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B

20
10
0

AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt

20
10
0

AR13/TRGChec
kpoi
nt2

20
10
0

AR14/Cabofexc
avat
oratr
el
ease
si
t
e

20
10
0
9/
17/
201605:
00

9/
17/
201607:
00

9/
17/
201609:
00

9/
17/
201611:
00
Dat
e/Ti
me

9/
17/
201613:
00

9/
17/
201615:
00

9/
17/
201617:
00