Internal Colonial Pipeline Documents

CR91EventShelbyCounty,AL
PreliminaryAirMonitoringSummary
September17,201605:0017:00
Preparedby
CenterforToxicologyandEnvironmentalHealth,L.L.C.(CTEH)
OnBehalfofColonialPipeline
Introduction
OnSeptember9,2016,theCenterforToxicologyandEnvironmentalHealth,L.L.C.(CTEH)initiatedairmonitoring
insupportofresponseeffortstothegasolinereleaseinShelbyCounty,AL.Thisreportpresentstherealtimeair
monitoringdatarecordedfromSeptember17201605:00toSeptember17,201617:00CDT.
RealTimeAirMonitoring1
Realtime air monitoring was conducted to evaluate the potential airborne presence of gasolineassociated
constituents,ifany,duringresponseoperations. Allinstrumentationwascalibratedatleastonceperdayorper
manufacturers recommendations. Target analytes were measured as total volatile organic compounds (VOCs),
oxygen, benzene, and flammability as the percent of the lower explosive limit (LEL) using remote telemetering
RAESystemsAreaRAEs,handheldinstrumentssuchasRAESystemsMultiRAEPro/PlusandUltraRAEs,aswellas
Gasteccolorimetricdetectiontubes.
Duringthismonitoringperiod,twoLEL,sixbenzene,and21VOCactionlevelexceedanceswererecordedduring
workeractivitymonitoring,includinginstantaneousVOCandbenzenereadingswhichwererecordedabovethe
actionlevel.Whennecessary,workersegressedtheareainaccordancewiththeapprovedsamplingandanalysis
plan.
Table1,below,presentstheresultsofrealtimeairmonitoringusinghandheldinstruments.Mapsoftheincident
sitelocationandlocationsofhandheldrealtimeairmonitoringreadingsareprovidedinAppendixI.
Real-time air monitoring refers to the use of hand-held instruments that provide near-instantaneous readings of an airborne chemical concentration without the need for
laboratory analysis.
2016-09-18 Page 2 of 6
Table1:HandHeldRealTimeAirMonitoringSummary1
September17,201605:00toSeptember17,201617:00
LocationCategory
Countof
Detections
RangeofDetections2,3
UltraRAE
35
0.51.9ppm
MultiRAEPlus
58
<1%
MultiRAEPro
46
<1%
MultiRAEPlus
20.920.9%
MultiRAEPro
20.920.9%
MultiRAEPlus
57
1.71.7ppm
MultiRAEPro
57
16
0.2159ppm
UltraRAE
11.0511.05ppm
MultiRAEPro
425%
MultiRAEPro
1512ppm
Instrument
Benzene
%LEL
WorkerActivity
Monitoring
Countof
Readings
Analyte
O2
VOCs
Benzene
SiteCharacterization LEL
VOC
1Please
Note: The data displayed in the above table has not undergone complete QC analysis and is presented in a preliminary format.
2Maximum detections preceded by the < symbol are considered non-detections below the instrument limit of detection (LoD) value to the right.
3Numbers are the raw values, no correction factors have been applied.
Duringthismonitoringperiodremotetelemeteringequipmentrecorded5445detectionsofVOCsabovetheCTEH
establishedactionlevelof30ppmand45detectionsofLELabovetheCTEHestablishedactionlevelof10%(3%as
rawvaluesonLELsensors).
Table2(below)summarizesremotetelemeteringAreaRAEdataforthismonitoringperiod.Forthisreportingperiod
AreaRAEmonitoringdatamaycontaindriftevents2.AppendixIandAppendixIIincludelocationmapsandgraphs
forremotetelemeteringdata,respectively.4
Drift is defined as any interference in the PIDs or electrochemical sensors ability to accurately report the concentration of a chemical in the atmosphere. Humidity, rapid
temperature changes, and compromised batteries are examples of common sources of drift.
2016-09-18 Page 3 of 6
Table2:RemoteTelemeteringRealtimeAirMonitoringSummary1,3
September17,201605:00toSeptember17,201617:00
Unit
LocationDescription
AR01
2ACompressors
AR03
WestofRelease
Site/NearStopple1
AR04
2AFracTankStaging
AR05
2ARecovery
AR06
EastofRelease
Site/NearStopple2
AR07
2BRecovery
AR08
MainStagingAreaFrac
Tanks
AR09
ReleaseSite
AR10
Onpathbetween
Recovery2Aand
Recovery2B.
AR11
MainStagingEntrance
EastofTRGcheckpoint
AR13
TRGCheckpoint2
accesstostopple1,
Recovery2Aand2A
FracTankStagingArea.
AR14
1Please
Cabofexcavatorat
releasesite
Countof
Readings
2372
2372
2372
2489
2489
2489
2476
2476
2476
2527
2527
2527
2319
2319
2319
2485
2485
2485
2503
2503
2503
2514
2514
2514
2177
2177
2177
2090
54
2090
2006
2006
Countof
Detections
0
2372
2012
0
2453
1608
0
2476
909
3
2527
1687
0
2319
616
0
2485
1317
0
2503
2500
0
2514
525
0
2101
0
0
54
107
0
2006
VOC
2006
2005
0.11.5ppm
LEL
O2
VOC
2534
2534
2534
0
2534
2534
<1%
20.920.9%
0.659ppm
Analyte
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
VOC
LEL
O2
RangeofDetections2
<1%
20.920.9%
0.1300.2ppm
<1%
20.920.9%
0.14.6ppm
<1%
20.920.9%
0.16.8ppm
1.33.1%
20.921.4%
0.198.8ppm
<1%
20.920.9%
0.163.6ppm
<1%
20.921.2%
0.112.2ppm
<1%
20.420.9%
0.1109.5ppm
<1%
20.920.9%
0.171.1ppm
<1%
20.921.3%
<0.1ppm
<1%
20.920.9%
0.10.4ppm
<1%
20.920.9%
note: The data displayed here has not undergone complete QA/QC analysis and is presented in a preliminary format.
detections preceded by the < symbol are considered at the limit of detection (LoD) value to the right.
3LEL and VOC values are raw values, correction factors have not been applied.
2Maximum
2016-09-18 Page 4 of 6
AppendixI:
SiteLocation,HandHeldRealTime
AirMonitoringLocation,and
RemoteTelemeteringAirMonitoring
LocationMaps
2016-09-18 Page 5 of 6
CR-91 Event
Site Location
Project: 108465
Client: Colonial Pipeline
Location: Shelby County, AL
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Creek/Stream
Print Date: 9/13/2016
Radio-telemetering Real-time Air Monitoring Station Locations

CR-91 Event 9/17/2016
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Location: Shelby County, LA
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AppendixII:
RemoteTelemeteringAirMonitoring
Graphs
2016-09-18 Page 6 of 6
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|VOC
CR91Event|9/
17/
201605:
00t
o9/
17/
201616:
59
AR01/2ACompr
essor
s
PPM
Uni
t/L
oc
at
i
on
200
100
AR04/2AFr
acSt
agi
ng
PPM
0
200
100
AR05/Rec
over
y2A
PPM
0
200
100
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
PPM
0
200
100
AR07/Rec
over
y2B
PPM
0
200
100
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
PPM
0
200
100
AR09/Rel
easeSi
t
e
PPM
0
200
100
AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B
PPM
0
200
100
AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt
PPM
0
200
100
AR13/TRGChec
kpoi
nt2
PPM
0
200
100
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
PPM
0
200
100
0
9/
17/
201605:
00
9/
17/
201607:
00
9/
17/
201609:
00
9/
17/
201611:
00
Dat
e/Ti
me
VOCr
eadi
ngsar
eat
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uer
epr
esent
at
i
onofat
mospher
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cc
ondi
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i
ons(
appr
opr
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or
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i
onf
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shavebeenappl
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edt
of
i
el
dval
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.
9/
17/
201613:
00
9/
17/
201615:
00
9/
17/
201617:
00
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|LEL
CR91Event|9/
17/
201605:
00t
o9/
17/
201616:
59
Uni
t/L
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at
i
on
6
AR01/2ACompr
essor
s
4
2
6
AR04/2AFr
acSt
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4
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AR05/Rec
over
y2A
4
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AR07/Rec
over
y2B
AR06/EastofRel
easeSi
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e/
Near
St
oppl
e2
4
2
6
4
2
6
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
4
2
6
AR09/Rel
easeSi
t
e
4
2
AR11/Mai
nSt
agi
ngEnt
r
anc
eEast
ofTRGc
hec
kpoi
nt
AR13/TRGChec
kpoi
nt2
AR10/Onpat
hbet
weenRec
over
y
2AandRec
over
y2B
4
2
6
4
2
6
4
2
6
%
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
4
2
9/
17/
201605:
00
9/
17/
201607:
00
9/
17/
201609:
00
9/
17/
201611:
00
Dat
e/Ti
me
L
ELr
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uer
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esent
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cc
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ons(
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.
9/
17/
201613:
00
9/
17/
201615:
00
9/
17/
201617:
00
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|Oxygen
CR91Event|9/
17/
201605:
00t
o9/
17/
201616:
59
Uni
t/L
oc
at
i
on
AR01/2ACompr
essor
s
20
10
0
AR04/2AFr
acSt
agi
ng
20
10
0
AR05/Rec
over
y2A
20
10
0
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
20
10
0
AR07/Rec
over
y2B
20
10
0
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
20
10
0
AR09/Rel
easeSi
t
e
20
10
0
AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B
20
10
0
AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt
20
10
0
AR13/TRGChec
kpoi
nt2
20
10
0
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
20
10
0
9/
17/
201605:
00
9/
17/
201607:
00
9/
17/
201609:
00
9/
17/
201611:
00
Dat
e/Ti
me
9/
17/
201613:
00
9/
17/
201615:
00
9/
17/
201617:
00
CR-91 Event Shelby County, AL

Preliminary Air Monitoring Summary
September 18, 2016 05:00
Prepared by
Center for Toxicology and Environmental Health, L.L.C. (CTEH)
On Behalf of Colonial Pipeline
Introduction
On September 9, 2016, the Center for Toxicology and Environmental Health, L.L.C. (CTEH) initiated air monitoring
in support of response efforts to the gasoline release in Shelby County, AL. This report presents the real-time air
monitoring data recorded from September 17 2016 17:00 to September 18, 2016 05:00 CDT.
Real-Time Air Monitoring1

Real-time air monitoring was conducted to evaluate the potential airborne presence of gasoline-associated
constituents, if any, during response operations. All instrumentation was calibrated at least once per day or per
RAESystems AreaRAEs, hand-held instruments such as RAESystems MultiRAE Pro/Plus and UltraRAEs, as well as
Gastec colorimetric detection tubes.
During this monitoring period, two LEL and six VOC action level exceedances were recorded during worker activity
monitoring, including instantaneous VOC and benzene readings which were recorded above the action level. When
necessary, workers egressed the area in accordance with the approved sampling and analysis plan.
Table 1, below, presents the results of real-time air monitoring using hand-held instruments. Maps of the incident
site location and locations of hand-held real-time air monitoring readings are provided in Appendix I.
2016-09-18 Page 2 of 6
Table 1: Hand-Held Real-Time Air Monitoring Summary1

September 17, 2016 17:00 to September 18, 2016 05:00
Location Category
Count of
Readings
Count of
Detections
Range of Detections2,3
Gastec #121L
<0.05 ppm
UltraRAE
73
10
0.05 - 0.3 ppm
MultiRAE Plus
55
<1 %
MultiRAE Pro
149
3-6%
MultiRAE Pro
20.9 - 20.9 %
MultiRAE Plus
47
0.1 - 9 ppm
MultiRAE Pro
159
57
0.1 - 638 ppm
%LEL
MultiRAE Pro
4-8%
VOC
MultiRAE Pro
125 - 352.8 ppm
Analyte
Benzene
Worker Activity
Monitoring
%LEL
O2
VOCs
Site Characterization
Instrument
1Please
detections preceded by the < symbol are considered non-detections below the instrument limit of detection (LoD) value to the right.
2Maximum
During this monitoring period remote telemetering equipment recorded 7851 detections of VOCs above the CTEH
established action level of 30 ppm and 11 detections of LEL above the CTEH established action level of 10% (3% as
raw values on LEL sensors).
Table 2 (below) summarizes remote telemetering AreaRAE data for this monitoring period. For this reporting period
AreaRAE monitoring data may contain drift events2. Appendix I and Appendix II include location maps and graphs
for remote telemetering data, respectively. 4
2016-09-18 Page 3 of 6
Table 2: Remote Telemetering Real-time Air Monitoring Summary1,3

Unit
Location Description
AR01
2A Compressors
AR04
2A Frac Tank Staging
AR05
2A Recovery
AR06
East of Release
Site/Near Stopple 2
AR07
2B Recovery
AR08
Main Staging Area Frac

Tanks
AR09
Release Site
AR10
On path between
Recovery 2A and
Recovery 2B.
AR11
Main Staging Entrance

East of TRG checkpoint
AS12
Boom Site #2
AR13
TRG Checkpoint 2 access to stopple 1,

Recovery 2A and 2A
Frac Tank Staging Area.
AR14
Cab of excavator at
release site
Count of
Readings
8382
8382
8382
7315
7315
Count of
Detections
38
8382
6867
0
7315
Range of Detections2
1.1 - 4.9 %
20.9 - 20.9 %
0.1 - 276.5 ppm
<1 %
20.9 - 20.9 %
VOC
LEL
O2
VOC
LEL
O2
7315
8464
8464
8464
7397
7397
7315
0
8464
1908
0
7397
0.2 - 105.4 ppm

<1 %
20.9 - 20.9 %
0.1 - 24.5 ppm
<1 %
20.9 - 21.4 %
VOC
LEL
O2
VOC
LEL
O2
7397
8368
8368
8368
7242
7242
4208
0
8368
3779
0
7242
0.1 - 123.7 ppm

<1 %
20.9 - 20.9 %
0.1 - 14.8 ppm
<1 %
20.9 - 20.9 %
VOC
LEL
O2
VOC
LEL
O2
7242
8382
8382
8382
8380
8380
7242
0
8382
8382
0
8380
0.5 - 736.4 ppm

<1 %
20.9 - 20.9 %
4.8 - 166.7 ppm
<1 %
20.9 - 20.9 %
VOC
LEL
O2
VOC
LEL
VOC
8380
8398
8398
8398
2380
2380
5279
0
8398
0
0
1
0.1 - 123.5 ppm

<1 %
20.9 - 20.9 %
<0.1 ppm
<1 %
0.3 ppm
LEL
O2
8390
8390
0
8390
<1 %
20.9 - 20.9 %
VOC
8390
8390
0.3 - 2.1 ppm
LEL
O2
VOC
7815
7815
7815
0
7815
7815
<1 %
20.9 - 20.9 %
0.7 - 30.1 ppm
Analyte
LEL
O2
VOC
LEL
O2
1Please
2Maximum
2016-09-18 Page 4 of 6
Appendix I:
Site Location, Hand-Held Real-Time
Air Monitoring Location, and
Remote Telemetering Air Monitoring
Location Maps
2016-09-18 Page 5 of 6
CR-91 Event
Site Location
Project: 108465
S
"
0 25 50
100
150
200 Miles
n
!
W
W aa ll kk ee rr
S
S tt .. C
C ll aa ii rr
T
S
"
Co
T
C
C ll aa yy
B
B ii bb bb
C
C hh ii ll tt oo nn
S
"
C
C oo oo ss aa
t
on
m
al
Co
S
"
Release Site
Stopple
Rd
91
Rd
0.15
0.3 Miles
Main Staging SIte
ArtificialPath
n
!
Underflow Dam
Creek/Stream

CR-91 Event 9/18/2016
Project: 108465
12
)
"
07
04
)
"
05
)
"
01
)
"
)
10 "
)
"
06
0S
9"
)
)
"
)
"
14
11
)
"
13
)
"
500
08
)
"
1,000
Feet
Co
Rd
91
t
on
m
l
a
Co
Rd
Legend
)
"
S
"
Release Site
Ponds
Creek/Stream
Ma
nua
l
l
y
L
og
g
edRe
a
l
T
i
meRe
a
di
ngL
oc
a
t
i
ons
CR91E
v
ent| 09/
17/
201617:
00 09/
17/
201605:
00
S
"
d
oR
91
tR
on
m
l
a
Co
P
r
ojec
t
:
108465
Cl
i
ent
:
Col
oni
a
l
Pi
pel
i
ne
L
oc
a
t
i
on:S
hel
byCount
y
,
AL
Legend
S
"
250 500
1,000
1,500

2,000
2,500
Feet
Release Site

ArtificialPath
Creek/Stream
Ponds
Ma
nua
l
l
yL
og
g
edRe
a
l
T
imeRe
a
ding
s|Be
nze
ne
CR91E
v
ent|09/
17/
201617:
00 09/
17/
201605:
00
S
"
d
oR
91
tR
on
m
l
a
Co
P
r
oj
ec
t
:
108465
Cl
ient
:
Col
onia
l
Pipel
ine
L
oc
a
t
ion:S
hel
by Count
y,
AL
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
0.05 - 0.25
250 500
1,000
1,500

2,000
2,500
3,000
Feet
0.26 - 0.49
> 0.50
Ma
nua
l
l
y
L
og
g
edRe
a
l
T
i
meRe
a
di
ng
s| L
E
L
CR91E
v
ent| 09/
17/
201617:
00 09/
17/
201605:
00
S
"
d
oR
91
tR
on
m
l
a
Co
P
r
ojec
t
:
108465
Cl
i
ent
:
Col
oni
a
l
Pi
pel
i
ne
L
oc
a
t
i
on:S
hel
byCount
y
,
AL
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
1 - 10
250 500
1,000
1,500

2,000
2,500
Feet
11 - 30
>30
Ma
nua
l
l
yL
og
g
edRe
a
l
T
i
meRe
a
di
ng
s|VOC
CR91E
v ent|09/
17/
201617:
00 09/
17/
201605:
00
S
"
R
Co
d9
tR
on
lm
a
Co
P
r
oj
ec
t
:
108465
Cl
i
ent
:
Col
oni
a
l
Pi
pel
i
ne
L
oc
a
t
i
on:S
h el
by Count
y,
AL
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
0.1 - 29.9
250 500
1,000
1,500

2,000
2,500
3,000
Feet
30.0 - 299.9
>300.0
Appendix II:
Graphs
2016-09-18 Page 6 of 6
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|LEL
CR91Event|9/
17/
201617:
01t
o9/
18/
201604:
59
Uni
t/L
oc
at
i
on
30
AR01/2ACompr
essor
s
20
10
0
30
AR04/2AFr
acSt
agi
ng
20
10
0
AR05/Rec
over
y2A
30
20
10
0
30
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
20
10
0
30
AR07/Rec
over
y2B
20
10
0
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
30
20
10
0
AR09/Rel
easeSi
t
e
30
20
10
0
AR10/Onpat
hbet
weenRec
over
y
2AandRec
over
y2B
30
20
10
0
AR11/Mai
nSt
agi
ngEnt
r
anc
eEast
ofTRGc
hec
kpoi
nt
30
20
10
0
AR12/Boom Si
t
e#2
30
20
10
0
AR13/TRGChec
kpoi
nt2
30
20
10
0
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
30
20
10
0
9/
17/
201617:
00
9/
17/
201619:
00
9/
17/
201621:
00
9/
17/
201623:
00
Dat
e/Ti
me
L
ELr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
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i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.
9/
18/
201601:
00
9/
18/
201603:
00
9/
18/
201605:
00
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|VOC
CR91Event|9/
17/
201617:
01t
o9/
18/
201604:
59
Uni
t/Loc
at
i
on
PPM
600
AR01/2ACompr
essor
s
400
200
0
AR04/2AFr
acSt
agi
ng
PPM
600
400
200
0
AR05/Rec
over
y2A
PPM
600
400
200
0
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
PPM
600
400
200
0
AR07/Rec
over
y2B
PPM
600
400
200
0
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
PPM
600
400
200
0
AR09/Rel
easeSi
t
e
PPM
600
400
200
0
AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B
PPM
600
400
200
0
AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt
PPM
600
400
200
0
AR12/Boom Si
t
e#2
PPM
600
400
200
0
AR13/TRGChec
kpoi
nt2
PPM
600
400
200
0
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
PPM
600
400
200
0
9/
17/
201617:
00
9/
17/
201619:
00
9/
17/
201621:
00
9/
17/
201623:
00
Dat
e/Ti
me
VOCr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
t
i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.
9/
18/
201601:
00
9/
18/
201603:
00
9/
18/
201605:
00
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|Oxygen
CR91Event|9/
17/
201617:
01t
o9/
18/
201604:
59
Uni
t/L
oc
at
i
on
AR01/2ACompr
essor
s
20
10
0
AR04/2AFr
acSt
agi
ng
20
10
0
AR05/Rec
over
y2A
20
10
0
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
20
10
0
AR07/Rec
over
y2B
20
10
0
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
20
10
0
AR09/Rel
easeSi
t
e
20
10
0
AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B
20
10
0
AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt
20
10
0
AR13/TRGChec
kpoi
nt2
20
10
0
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
20
10
0
9/
17/
201617:
00
9/
17/
201619:
00
9/
17/
201621:
00
9/
17/
201623:
00
Dat
e/Ti
me
9/
18/
201601:
00
9/
18/
201603:
00
9/
18/
201605:
00

September 18, 2016 17:00
Prepared by
Introduction

During this monitoring period, eight benzene, five LEL and nine VOC action level exceedances were recorded during
worker activity monitoring, including instantaneous VOC and benzene readings which were recorded above the
action level. When necessary, workers egressed the area in accordance with the approved sampling and analysis
plan.
1
2016-09-18 Page 2 of 6

Location Category
Count of
Readings
Count of
Detections
108
18
0.05 - 300 ppm
Gastec #101L
<5 ppm
Gastec #102L
<1 ppm
MultiRAE Plus
33
<1 %
MultiRAE Pro
183
4 - 20 %
Gastec #122
<1 ppm
Gastec #122L
<0.5 ppm
MultiRAE Plus
37
13
0.1 - 17.1 ppm
MultiRAE Pro
183
51
0.1 - 1900 ppm
Xylene
Gastec #123
<1 ppm
LEL
MultiRAE Pro
<1 %
VOC
MultiRAE Pro
<0.1 ppm
Benzene
UltraRAE
5 - 100 ppm
%LEL
MultiRAE Pro
11 - 56 %
VOC
MultiRAE Pro
6.5 - 1250 ppm
Analyte
Instrument
Benzene
UltraRAE
Gasoline
Hexane
%LEL
Worker Activity
Monitoring
Toluene
VOCs
Community
1Please
detections preceded by the < symbol are considered non-detections below the instrument limit of detection (LoD) value to the right.
2Maximum
2
2016-09-18 Page 3 of 6

Unit
AR01
2A Compressors
AR04
AR05
2A Recovery
AR06
East of Release
Site/Near Stopple 2
AR07
2B Recovery
AR08

Tanks
AR09
Release Site
AR10
On path between
Recovery 2A and
Recovery 2B.
AR11

AR12
Boom Site #2
AR13

Recovery 2A and 2A
AR14
Cab of excavator at
release site
Count of
Readings
5258
5258
5258
8133
8133
Count of
Detections
95
5258
4691
0
8133
1.2 - 5 %
20.9 - 21.6 %
0.1 - 423.8 ppm
<1 %
20.9 - 20.9 %
VOC
LEL
O2
VOC
LEL
O2
8133
6301
6301
6301
8290
8290
5171
0
6301
2491
0
8290
0.1 - 57.6 ppm

<1 %
20.9 - 20.9 %
0.1 - 45.1 ppm
<1 %
20.9 - 21.9 %
VOC
LEL
O2
VOC
LEL
O2
8290
8070
8070
8070
8119
8119
2655
0
8070
4976
0
8119
0.1 - 46 ppm
<1 %
20.9 - 20.9 %
0.1 - 78.6 ppm
<1 %
20.5 - 21.3 %
VOC
LEL
O2
VOC
LEL
O2
8119
8354
8354
8354
8133
8133
5755
0
8354
4560
0
8133
0.1 - 35.6 ppm

<1 %
20.7 - 20.9 %
0.1 - 118.1 ppm
<1 %
20.4 - 20.9 %
VOC
LEL
O2
VOC
LEL
VOC
8133
6485
6485
6485
6428
0
6485
0
0.1 - 157.2 ppm

<1 %
20.9 - 20.9 %
<0.1 ppm
2740
<1 %
LEL
O2
2740
8100
8100
27
0
8100
0.1 - 0.1 ppm

<1 %
20.9 - 21.3 %
VOC
8100
4109
0.1 - 0.9 ppm
LEL
O2
VOC
4054
4054
4054
0
4054
99
<1 %
20.9 - 20.9 %
0.1 - 5.6 ppm
Analyte
LEL
O2
VOC
LEL
O2
1Please
2Maximum
2016-09-18 Page 4 of 6
Appendix I:
Location Maps
2016-09-18 Page 5 of 6

CR-91 Event 9/18/2016
Project: 108465
12
)
"
07
04
)
"
05
)
"
01
)
"
)
10 "
)
"
06
0S
9"
)
)
"
)
"
14
11
)
"
13
)
"
500
08
)
"
1,000
Feet
Co
Rd
91
t
on
m
l
a
Co
Rd
Legend
)
"
S
"
Release Site
Ponds
Creek/Stream
CR-91 Event
Site Location
Project: 108465
S
"
0 25 50
100
150
200 Miles
n
!
W
W aa ll kk ee rr
S
S tt .. C
C ll aa ii rr
T
S
"
Co
T
C
C ll aa yy
B
B ii bb bb
C
C hh ii ll tt oo nn
S
"
C
C oo oo ss aa
t
on
m
al
Co
S
"
Release Site
Stopple
Rd
91
Rd
0.15
0.3 Miles
Main Staging SIte
ArtificialPath
n
!
Underflow Dam
Creek/Stream
Ma
nua
l
l
y
L
og
g
e
dRe
a
l
T
i
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di
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a
t
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ons
CR91E
v
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nt| 09/
18/
201605:
00 09/
18/
201617:
00
S
"
Co
Rd
91
t
on
lm
a
Co
P
r
oje
c
t
:10
8465
Cl
i
e
nt
:Col
oni
a
l
Pi
pe
l
i
ne
L
oc
a
t
i
on:
S
hel
byCount
y
,
AL
Rd
Legend
S
"
Release Site

ArtificialPath
250 500
1,000
1,500

2,000
2,500
Feet
Creek/Stream
Ponds
Ma
nua
l
l
yL
og
g
e
dRe
a
l
T
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a
ding
s|Be
nze
ne
CR91E
v
e
nt|09/
18/
201605:
00 09/
18/
201617:
00
S
"
Co
Rd
91
t
on
alm
o
C
P
r
oj
e
c
t
:10
8465
Cl
ie
nt
:Col
onia
l
Pipe
l
ine
L
oc
a
t
ion:
S
hel
by Count
y,
AL
Rd
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
250
500
1,000
1,500

2,000
2,500
Feet
0.05 - 0.25
0.26 - 0.49
> 0.50
Ma
nua
l
l
y
L
og
g
e
dRe
a
l
T
i
meRe
a
di
ng
s| L
E
L
CR91E
v
e
nt| 09/
18/
201605:
00 09/
18/
201617:
00
S
"
R
Co
1
d9
t
on
lm
a
Co
P
r
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c
t
:10
8465
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i
on:
S
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Rd
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
250 500
1,000
1,500

2,000
2,500
3,000
Feet
1 - 10
11 - 30
>30
Ma
nua
l
l
yL
og
g
e
dRe
a
l
T
i
meRe
a
di
ng
s|VOC
CR91E
ve
nt|09/
18/
201605:
00 09/
18/
201617:
00
S
"
d
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t
on
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C
P
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8465
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L
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on:
S
h el
by Count
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AL
Rd
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
0.1 - 29.9
250 500
1,000
1,500

2,000
2,500
3,000
Feet
30.0 - 299.9
>300.0
Appendix II:
Graphs
2016-09-18 Page 6 of 6
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|VOC
CR91Event|9/
18/
201605:
00t
o9/
18/
201616:
59
Uni
t/Loc
at
i
on
PPM
300
AR01/2ARec
over
y
200
100
0
PPM
300
AR04/2AFr
acTankSt
agi
ngAr
ea
200
100
0
PPM
300
AR05/2ACompr
essor
s
200
100
0
300
PPM
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
200
100
0
PPM
300
AR07/2B Rec
over
y
200
100
0
PPM
300
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
200
100
0
PPM
300
AR09/Rel
easeSi
t
e
200
100
0
AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt
PPM
300
200
100
0
300
PPM
AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B
200
100
0
PPM
300
AR12/Boom Si
t
e#2
200
100
0
PPM
300
AR13/TRGChec
kpoi
nt2
200
100
0
300
PPM
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
200
100
0
9/
18/
201605:
00
9/
18/
201607:
00
9/
18/
201609:
00
9/
18/
201611:
00
Dat
e/Ti
me
VOCr
eadi
ngsar
eat
r
uer
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esent
at
i
onofat
mospher
i
cc
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i
ons(
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ec
or
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or
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i
edt
of
i
el
dval
ues)
.
9/
18/
201613:
00
9/
18/
201615:
00
9/
18/
201617:
00
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|Oxygen
CR91Event|9/
18/
201605:
00t
o9/
18/
201616:
59
Uni
t/L
oc
at
i
on
AR01/2ARec
over
y
20
10
0
AR04/2AFr
acTankSt
agi
ngAr
ea
20
10
0
AR05/2ACompr
essor
s
20
10
0
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
20
10
0
AR07/2B Rec
over
y
20
10
0
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
20
10
0
AR09/Rel
easeSi
t
e
20
10
0
AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B
20
10
0
AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt
20
10
0
AR13/TRGChec
kpoi
nt2
20
10
0
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
20
10
0
9/
18/
201605:
00
9/
18/
201607:
00
9/
18/
201609:
00
9/
18/
201611:
00
Dat
e/Ti
me
9/
18/
201613:
00
9/
18/
201615:
00
9/
18/
201617:
00
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|LEL
CR91Event|9/
18/
201605:
00t
o9/
18/
201616:
59
Uni
t/L
oc
at
i
on
10
AR01/2ARec
over
y
5
0
10
AR04/2AFr
acTankSt
agi
ngAr
ea
5
0
10
AR05/2ACompr
essor
s
5
0
10
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
5
0
10
AR07/2B Rec
over
y
5
0
10
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
5
0
10
AR09/Rel
easeSi
t
e
5
0
10
AR10/Onpat
hbet
weenRec
over
y
2AandRec
over
y2B
5
0
10
AR11/Mai
nSt
agi
ngEnt
r
anc
eEast
ofTRGc
hec
kpoi
nt
5
0
10
AR12/Boom Si
t
e#2
5
0
10
AR13/TRGChec
kpoi
nt2
5
0
10
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
5
0
9/
18/
201605:
00
9/
18/
201607:
00
9/
18/
201609:
00
9/
18/
201611:
00
Dat
e/Ti
me
L
ELr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
t
i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.
9/
18/
201613:
00
9/
18/
201615:
00
9/
18/
201617:
00

September 19, 2016 05:00
Prepared by
Introduction

During this monitoring period, four benzene, one LEL and 13 VOC action level exceedances were recorded during
worker activity monitoring, including instantaneous VOC and benzene readings which were recorded above the
action level. When necessary, workers egressed the area in accordance with the approved sampling and analysis
plan.
1
2016-09-19 Page 2 of 6

Location Category
Count of
Detections
UltraRAE
76
32
0.05 - 6.6 ppm
MultiRAE Plus
27
<1 %
MultiRAE Pro
163
7-7%
MultiRAE Plus
26
11
0.4 - 12.8 ppm
Instrument
Benzene
%LEL
Worker Activity
Monitoring
VOCs
Count of
Readings
Analyte
MultiRAE Pro
176
118
0.1 - 440 ppm
Xylene
Gastec #123
<1 ppm
Benzene
UltraRAE
6 - 160 ppm
%LEL
MultiRAE Pro
4-8%
VOC
MultiRAE Pro
0.9 - 4999.9 ppm4
1Please
4VOC sensor upper detection limit for the MultiRAE Pro is 5000 ppm.
2
2016-09-19 Page 3 of 6

Unit
AR01
2A Compressors
AR04
AR05
2A Recovery
AR06
East of Release
Site/Near Stopple 2
AR07
2B Recovery
AR08

Tanks
AR09
Release Site
AR10
On path between
Recovery 2A and
Recovery 2B.
AR11

AR12
Boom Site #2
AR13

Recovery 2A and 2A
AR14
Cab of excavator at
release site
Count of
Readings
2761
2761
2761
2761
2761
Count of
Detections
22
2761
2672
0
2761
1.1 - 4 %
20.9 - 20.9 %
0.1 - 302.1 ppm
<1 %
20.9 - 21.3 %
VOC
LEL
O2
VOC
LEL
O2
2761
2743
2743
2743
2814
2814
2581
0
2743
2681
0
2814
0.1 - 70.9 ppm

<1 %
20.9 - 20.9 %
0.1 - 63.7 ppm
<1 %
20.9 - 22 %
VOC
LEL
O2
VOC
LEL
O2
2814
2827
2827
2827
2747
2747
2631
0
2827
2336
0
2747
0.1 - 87 ppm
<1 %
20.9 - 20.9 %
0.1 - 23.4 ppm
<1 %
20.9 - 21.3 %
VOC
LEL
O2
VOC
LEL
O2
2747
2740
2740
2740
2784
2784
2024
12
2740
1906
0
2784
0.1 - 44.2 ppm

1.2 - 4.9 %
20.5 - 20.9 %
0.1 - 107.9 ppm
<1 %
20.9 - 21.2 %
VOC
LEL
O2
VOC
LEL
VOC
2784
2726
2726
2726
2503
2503
2760
0
2726
973
0
301
0.1 - 99.9 ppm

<1 %
20.9 - 20.9 %
0.1 - 18.4 ppm
<1 %
0.1 - 1.5 ppm
LEL
O2
2684
2684
0
2684
<1 %
20.9 - 20.9 %
VOC
2684
1114
0.1 - 13.1 ppm
LEL
O2
VOC
2739
2739
2739
0
2739
2607
<1 %
20.9 - 20.9 %
0.1 - 55.5 ppm
Analyte
LEL
O2
VOC
LEL
O2
1Please
2Maximum
2016-09-19 Page 4 of 6
Appendix I:
Location Maps
2016-09-19 Page 5 of 6
CR-91 Event
Site Location
Project: 108465
S
"
0 25 50
100
150
200 Miles
n
!
W
W aa ll kk ee rr
S
S tt .. C
C ll aa ii rr
T
S
"
Co
T
C
C ll aa yy
B
B ii bb bb
C
C hh ii ll tt oo nn
S
"
C
C oo oo ss aa
t
on
m
al
Co
S
"
Release Site
Stopple
Rd
91
Rd
0.15
0.3 Miles
Main Staging SIte
ArtificialPath
n
!
Underflow Dam
Creek/Stream

CR-91 Event 9/18/2016
Project: 108465
12
)
"
07
04
)
"
05
)
"
01
)
"
)
10 "
)
"
06
0S
9"
)
)
"
)
"
14
11
)
"
13
)
"
500
08
)
"
1,000
Feet
Co
Rd
91
t
on
m
l
a
Co
Rd
Legend
)
"
S
"
Release Site
Ponds
Creek/Stream
Appendix II:
Graphs
2016-09-19 Page 6 of 6
Ma
nua
l
l
y
L
og
g
e
dRe
a
l
T
i
meRe
a
di
ngL
oc
a
t
i
ons
CR91E
v
e
nt| 09/
18/
201617:
00 09/
19/
201605:
00
S
"
R
Co
1
d9
t
on
lm
a
Co
P
r
oje
c
t
:10
8465
Cl
i
e
nt
:Col
oni
a
l
Pi
pe
l
i
ne
L
oc
a
t
i
on:
S
hel
byCount
y
,
AL
Rd
Legend
S
"
Release Site

ArtificialPath
250 500
1,000
1,500

2,000
2,500
Feet
Creek/Stream
Ponds
Ma
nua
l
l
yL
og
g
e
dRe
a
l
T
imeRe
a
ding
s|Be
nze
ne
CR91E
v
e
nt|09/
18/
201617:
00 09/
19/
201605:
00
S
"
R
Co
1
d9
t
on
alm
o
C
P
r
oj
e
c
t
:10
8465
Cl
ie
nt
:Col
onia
l
Pipe
l
ine
L
oc
a
t
ion:
S
hel
by Count
y,
AL
Rd
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
250 500
1,000
1,500

2,000
2,500
Feet
0.05 - 0.25
0.26 - 0.49
> 0.50
Ma
nua
l
l
y
L
og
g
e
dRe
a
l
T
i
meRe
a
di
ng
s| L
E
L
CR91E
v
e
nt| 09/
18/
201617:
00 09/
19/
201605:
00
S
"
R
Co
1
d9
t
on
lm
a
Co
P
r
oje
c
t
:10
8465
Cl
i
e
nt
:Col
oni
a
l
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i
ne
L
oc
a
t
i
on:
S
hel
byCount
y
,
AL
Rd
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds
<0.1
250 500
1,000
1,500

2,000
2,500
Feet
1 - 10
11 - 30
>30
Ma
nua
l
l
yL
og
g
e
dRe
a
l
T
i
meRe
a
di
ng
s|VOC
CR91E
ve
nt|09/
18/
201617:
00 09/
19/
201605:
00
S
"
R
Co
1
d9
t
on
alm
o
C
P
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e
c
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8465
Cl
i
e
nt
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oni
a
l
Pi
pe
l
i
ne
L
oc
a
t
i
on:
S
h el
by Count
y,
AL
Rd
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
0.1 - 29.9
250 500
1,000
1,500

2,000
2,500
Feet
30.0 - 299.9
>300.0

September 17, 2016 05:00
Prepared by
Introduction

During this monitoring period, four benzene and six VOC action level exceedances were recorded during worker
activity monitoring, including instantaneous VOC and benzene readings which were recorded above the action
level. When necessary, workers egressed the area in accordance with the approved sampling and analysis plan.
1
2016-09-17 Page 2 of 6

Location Category
Count of
Readings
Count of
Detections
UltraRAE
35
0.5 - 1.9 ppm
MultiRAE Plus
58
<1 %
MultiRAE Pro
46
<1 %
MultiRAE Plus
20.9 - 20.9 %
MultiRAE Pro
20.9 - 20.9 %
MultiRAE Plus
57
1.7 - 1.7 ppm
MultiRAE Pro
57
16
0.2 - 159 ppm
Benzene
UltraRAE
11.05 - 11.05 ppm
LEL
MultiRAE Pro
4 - 25 %
VOC
MultiRAE Pro
1 - 512 ppm
Analyte
Instrument
Benzene
%LEL
Worker Activity
Monitoring
O2
VOCs
1Please
2
2016-09-17 Page 3 of 6

Unit
AR01
2A Compressors
AR03
West of Release
Site/Near Stopple 1
AR04
AR05
2A Recovery
AR06
East of Release
Site/Near Stopple 2
AR07
2B Recovery
AR08

Tanks
AR09
Release Site
AR10
On path between
Recovery 2A and
Recovery 2B.
AR11

AR13
AR14

Recovery 2A and 2A
Cab of excavator at
release site
Count of
Readings
2624
2624
2624
26
26
Count of
Detections
62
2624
2427
0
26
1.1 - 8.9 %
20.9 - 21.3 %
0.1 - 1408.5 ppm
<1 %
20.9 - 21.5 %
VOC
LEL
O2
VOC
LEL
O2
26
2453
2453
2453
630
630
16
0
2453
1904
0
630
0.2 - 38.5 ppm

<1 %
20.9 - 20.9 %
0.1 - 63.7 ppm
<1 %
20.9 - 21.5 %
VOC
LEL
O2
VOC
LEL
O2
630
1993
1993
1993
2583
2583
386
164
1993
1642
0
2583
0.1 - 117.5 ppm

1.2 - 4.2 %
20.9 - 22.2 %
0.1 - 100.4 ppm
<1 %
20.9 - 21.1 %
VOC
LEL
O2
VOC
LEL
O2
2583
2651
2651
2651
1499
1499
1012
44
2651
288
2
1499
0.1 - 142.6 ppm

1.2 - 22.3 %
20.9 - 21.3 %
0.1 - 947.5 ppm
1.5 - 3.9 %
20.5 - 20.9 %
VOC
LEL
O2
VOC
LEL
O2
1499
2603
2603
2603
1976
1976
1292
0
2603
2572
0
1976
0.1 - 131.6 ppm

<1 %
20.9 - 20.9 %
0.1 - 343.2 ppm
<1 %
20.9 - 21.2 %
VOC
LEL
O2
1976
1214
1214
0
0
1214
<0.1 ppm
<1 %
20.9 - 21.5 %
VOC
1214
1.3 - 1.3 ppm
LEL
O2
VOC
1443
1443
1443
0
1443
1443
<1 %
20.5 - 20.9 %
1.7 - 149.4 ppm
Analyte
LEL
O2
VOC
LEL
O2
1Please
2Maximum
2016-09-17 Page 4 of 6
Appendix I:
Location Maps
2016-09-17 Page 5 of 6
CR-91 Event
Site Location
Project: 108465
S
"
0 25 50
100
150
200 Miles
n
!
t
on
lm
a
Co
n
!
3
2
W
W aa ll kk ee rr
S
S tt .. C
C ll aa ii rr
T
S
"
Co
Co
S
"
T
C
C ll aa yy
B
B ii bb bb
C
C hh ii ll tt oo nn
C
C oo oo ss aa
t
on
m
al
Co
Rd
Rd
91
91
Rd
S
"
Rd
0
Release Site
Stopple
Main Staging SIte
n
!
0.25
0.5 Miles
Right of Way
ArtificialPath
Underflow Dam
Creek/Stream

CR-91 Event 9/17/2016
10
)
"
Project: 108465
07
)
"
01
)
"
04
)
"
05
)
"
03
)
"
06
)
09 "
)
"
S
"
11
)
"
13
)
"
Co
Rd
91
t
on
m
l
oa
Rd
Legend
08
)
"
0
500
1,000
Feet
)
"
S
"
Release Site
Ponds
Creek/Stream
Ma
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l
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L
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a
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a
di
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oc
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i
ons
CR9
1E
v
e
nt| 09
/
1
6/
2
0
1
61
7:
0
0 0
9
/
17
/
2
01
605
:
0
0
P
r
oje
c
t
:10
8465
Cl
i
e
nt
:Col
oni
a
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i
pel
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on:
S
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byCount
y
,
AL
S
"
Co
Rd
91
t
on
m
al
Co
Rd
Legend
S
"
Release Site

ArtificialPath
250
500

1,000
Feet
Creek/Stream
Ponds
Ma
nua
l
l
yL
og
g
e
dRe
a
l
T
imeRe
a
ding
s|Be
nze
ne
CR9
1E
v
e
nt|09
/
1
6/
2
0
1
61
7:
0
0 0
9
/
17
/
2
01
605
:
0
0
P
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:10
8465
Cl
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onia
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L
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S
hel
by Count
y,
AL
S
"
Legend
S
"
Release Site
d
ArtificialPath
tR
n
o
Creek/Stream
lm
a
Co
Ponds
91
Real-Time
Rd
Co
<0.1
Benzene Reading (PPM)
0.05 - 0.25
0
250
500

1,000
Feet
0.26 - 0.49
> 0.50
Ma
nua
l
l
y
L
og
g
e
dRe
a
l
T
i
meRe
a
di
ng
s| L
E
L
CR9
1E
v
e
nt| 09
/
1
6/
2
0
1
61
7:
0
0 0
9
/
17
/
2
01
605
:
0
0
P
r
oje
c
t
:10
8465
Cl
i
e
nt
:Col
oni
a
l
P
i
pel
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L
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a
t
i
on:
S
hel
byCount
y
,
AL
S
"
Legend
S
"
Co
Rd
91
t
on
m
al
Co
Rd
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
1 - 10
250
500

1,000
1,500
Feet
11 - 30
>30
Ma
nua
l
l
yL
og
g
e
dRe
a
l
T
i
meRe
a
di
ng
s|VOC
CR9
1E
ve
nt|09
/
1
6/
2
0
1
61
7:
0
0 0
9
/
17
/
2
01
605
:
0
0
S
"
R
Co
1
d9
t
on
lm
a
Co
P
r
oj
e
c
t
:10
8465
Cl
i
e
nt
:Col
oni
a
l
P
i
pel
i
ne
L
oc
a
t
i
on:
S
h el
by Count
y,
AL
Rd
Legend
S
"
Release Site
ArtificialPath
Creek/Stream
Ponds

<0.1
0.1 - 29.9
250 500
1,000
1,500

2,000
2,500
3,000
Feet
30.0 - 299.9
>300.0
Appendix II:
Graphs
2016-09-17 Page 6 of 6
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|LEL
CR91Event|9/
16/
201617:
00t
o9/
17/
201604:
59
Uni
t/L
oc
at
i
on
AR01/2ACompr
essor
s
60
40
20
AR03/WestofRel
easeSi
t
e/
Near
St
oppl
e1
0
60
40
20
AR04/2AFr
acSt
agi
ng
0
60
40
20
AR05/Rec
over
y2A
0
60
40
20
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2
0
60
40
20
AR07/Rec
over
y2B
0
60
40
20
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks
0
60
40
20
AR09/Rel
easeSi
t
e
0
60
40
20
AR10/Onpat
hbet
weenRec
over
y
2AandRec
over
y2B
0
60
40
20
AR11/Mai
nSt
agi
ngEnt
r
anc
eEast
ofTRGc
hec
kpoi
nt
0
60
40
20
AR13/TRGChec
kpoi
nt2
0
60
40
20
AR14/Cabofexc
avat
oratr
el
ease
si
t
e
0
60
40
20
0
9/
16/
201617:
00
9/
16/
201619:
00
9/
16/
201621:
00
9/
16/
201623:
00
Dat
e/Ti
me
L
ELr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
t
i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.
9/
17/
201601:
00
9/
17/
201603:
00
9/
17/
201605:
00
Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|Oxygen
CR91Event|9/
16/
201617:
00t
o9/
17/
201604:
59
Uni
t/Loc
at
i
on
AR01/2ACompr
essor
s
20
10
0
AR03/WestofRel
easeSi
t
e/
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Health and Safety Best Practices Guides

Petroleum Spill Responses (Draft Final)
Created: August 13, 2015, Version 1.0
Page 1 of 3
Hazard Summary (See specific Safety Data Sheets for more information)
Health Hazards: May be fatal if swallowed and enters airways. May cause genetic defects. May cause cancer. Causes
skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness.
Physical Hazards: Fire and explosive hazards. Heat Stress Hazards. Slip, Trip and Fall Hazards.
Signs and Symptoms of Exposure (See SDS for more information)
Short-term over-exposures to this material may cause irritation to skin and eyes, headache, dizziness, nausea,
vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation.
Long term inhalation over-exposures to this material may cause cancer. Contains material that may cause heritable
genetic damage. Contains material that may cause damage to the blood and blood forming organs.
Emergency Actions (See SDS for more information)
First-aid measures general: If exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation: Remove to fresh air and keep in a position comfortable for breathing. In case of
irregular breathing or respiratory arrest provide artificial respiration.
First-aid measures after skin contact: Wash immediately with water for 15 minutes. Remove affected clothing and
wash all exposed skin area with mild soap and water, followed by warm water rinse.
First-aid measures after eye contact: Rinse immediately and thoroughly with water, hold eyelids open for 15 minutes.
First-aid measures after ingestion: Immediately call a POISON CONTROL CENTER and/or 911. Rinse mouth.
Air Monitoring/Sampling Equipment
Equipment (Linked to ERTG QSG)
Notes
MultiRAE Pro
PID only detects VOCs with an Ionization Potential (IP) <10.6; also H2S, CO,
%O2, and %LEL. See RAE Systems Technical Note TN-106 for information on
PID use and correction factors.
Non-specific, FID will detect total VOCs. PID will detect VOCs w/ an IP
TVA 1000
<10.6
Draeger Chip Management System (CMS) Estimated 10% - 20% margin of error.
Draeger Tubes
Estimated 25% margin of error.
UltraRAE 3000
Use Benzene-specific separation tube for Benzene monitoring.
Analytical methods:
1. Oil Mist - NIOSH 5026
Personnel Sampling:
2. Benzene NIOSH 3700
1. GilAir Sample Pump
3. VOCs NIOSH 2549
2. SKC Sample Pump
4. Hydrocarbons NIOSH 1500
Will also need a DryCal Calibrator and appropriate sampling media
Exposure Limits
Contaminant
10
IDLH
OSHA Exposure Limits
10
Benzene
Butane
Carbon Monoxide
500ppm
1600ppm (10%LEL)
1200ppm
TWA: 1 ppm, STEL: 5ppm

-TWA: 35ppm, Ceiling: 200ppm
Diesel Fuel
600ppm (10%LEL)
--
Ethyl Benzene
Gasoline
Hydrogen Sulfide
800ppm (10%LEL)
-100ppm
TWA: 100ppm
-Ceiling: 20ppm
Kerosene (Jet Fuel)
700ppm (10%LEL)
--
20ppm
Ceiling: 5ppm
Nitrogen Dioxide
ACGIH Exposure Limits
12
Explosive
10
Range
TWA: 0.5ppm, STEL: 2.5ppm 1.2-7.8%

STEL: 1000ppm
1.6-8.4%
TWA: 25ppm
12.5-74%
3
TWA: 100mg/m /~11ppm
0.6-7.5%
(total hydrocarbon vapor)
TWA: 20ppm
0.8-6.7%
TWA: 300ppm, STEL: 500ppm 1.4-7.6%
TWA: 1ppm, STEL: 5ppm
4.0-44.0%
3
TWA: 200 mg/m /~29ppm
0.7-5.0%
(total hydrocarbon vapor)
TWA: 0.2ppm
--
9.24 eV
10.63 eV
--
PID
Correction
11
Factors
0.47
---
Mixture
0.7
8.76 eV
Mixture
10.46 eV
0.65
0.9-1.0
3.3
Mixture
0.6-1.0
--
--
Ionization
10
Potential
Health and Safety Best Practices Guides - Petroleum Spill Responses (Draft Final)
Contaminant
Oil Mist
Pentane
Petroleum
Distillates
Sulfur Dioxide
Toluene
Xylenes
10
IDLH
Page 2 of 3
OSHA Exposure Limits
2500
3
mg/m /~149ppm
1500ppm (10%LEL)
Action Levels:
Contaminant/Hazard
Fire or Explosion Hazard
Oxygen Deficient or Rich
Atmosphere
ACGIH Exposure Limits
12
Explosive
10
Range
Ionization
10
Potential
PID
Correction
11
Factors
TWA: 5 mg/m /~0.3ppm
--
--
Mixture
--
TWA: 1000ppm
1000ppm
1.5-7.8%
10.34 eV
8.4
TWA: 500ppm
--
1.1-5.9%
Mixture
--
1100ppm (10%LEL)
100ppm
500ppm
900ppm (10%LEL)
10
TWA: 5ppm
STEL: 0.25ppm
TWA: 200ppm, Ceiling: 300ppm
TWA: 20 ppm
TWA: 100ppm
TWA: 100ppm, STEL: 150ppm
-1.1-7.1%
0.9-7.0
--8.82 eV
0.45
8.44 8.56 eV 0.39-0.40
Action
Leave the work zone and implement engineering controls. Engineering controls used in
a potentially explosive atmosphere must be rated explosion proof.
Exceed an OSHA or ACGIH

Exposure Limit
Leave the work zone and implement engineering controls. Don Level C PPE. Replace
cartridges at the end of each work shift and/or based on manufacturers
recommendations. Do not reenter the work zone if LEL levels are still >10%.
Oxygen Deficient
Atmosphere and/or Exceed
the Maximum Use
Concentration of Respirator
Leave the work zone and implement engineering controls.

Don Level B PPE. Do not reenter the work zone if LEL levels are still >10%.
Personal Protection Equipment

Safety Toe/Shank Work Boots, Safety Glasses, Flame Resistant Coveralls (as needed), Work Gloves (as needed), Hard
Hat (as needed), High-Vis Vest (as needed), Hearing Protection (as needed), personal flotation device (as needed),
Chest waders (as needed)
Safety Toe/Shank Work Boots or HAZMAT Boots, Appropriate Chemical Protective Suit, Flame Resistant Coveralls (as
Level C:
needed), Full Face APR with Appropriate Cartridges, Appropriate Chemical Protective Gloves, Work Gloves (as
needed), Hard Hat (as needed), High-Vis Vest (as needed), Hearing Protection (as needed)
Safety Toe/Shank Boots or HAZMAT Boots, Appropriate Chemical Protective Suit, Flame Resistant Coveralls (as
Level B:
needed), and Chemical Protective Gloves, SCBA, Work Gloves (as needed), Hard Hat (as needed), Hearing Protection
(as needed)
NOTE: Always review the PPE permeation rates for the specific compounds involved. Saranex (Tychem SL), Polyethylene Coated
Suits (Tychem QC) and Nitrile Gloves may not always be appropriate for petroleum responses. The following are permeation rates
for equipment carried by ERRPB. Always confirm this information with SDS or Specific Manufacturer
Permeation Rates are in Minutes, unless otherwise noted.
imm.: Chemical moves through suit, glove or boot material immediately. Blank Cells - No testing data available.
Level D:
Chemical Name
Crude oil
Diesel fuel
Ethanol
Fuel oil
Chemical Protective Suits

Chemical Protective Gloves
Boots
DuPont DuPont DuPont DuPont DuPont North Ansell North North Ansell Tingley Onguard
Physical Tychem Tychem SL Tychem Tychem Tychem Silver Barrier Viton Butyl Solvex HAZPROOF Boot
State
QC
- Saranex
BR
Responder
TK Shield
Nitrile
Cover
Liquid
imm.
>480
>480
>480
>480
Liquid
imm.
48
>480
>480
>480
Liquid
>480
>480
>480 >480
>480 240
Excellent
Liquid
imm.
>480
>480
Gasoline
Liquid
imm.
>480
>480
>480
170
>480
Poor
Kerosene and Jet Fuel
Liquid
58
>480
>480
>480
>480
>360
Poor
The online version of this Health and Safety Quick Start Guide supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of
this document can be found at http://epaosc.org/hsmanualregion4.
Health and Safety Best Practices Guides - Petroleum Spill Responses (Draft Final)
Page 3 of 3
Decontamination
Dry removal of PPE following standard contamination control techniques is typically appropriate. Wash hands and face
with soap and water after exiting the contaminate reduction zone. Use a degreasing solution to decontaminate
waders, chemical protective boots, tools and equipment.
Special Considerations
Light ends (e.g. pentanes, butanes, benzene, xylenes, toluene, and ethyl benzene) often volatilize during the first
few days of the response as the oil weathers. Do not underestimate the explosive hazards of the light ends.
Exposure to carcinogens should be as low as reasonably achievable. Implement engineering controls even if air
monitoring indicates respiratory protection is not required.
Additional health and safety considerations and controls are needed during In-situ Burning Operations. See SOG #
P103 for additional information.
Resources/References:
1. OSHA Compendium of Oil Spill Safety Data Sheets (includes SDSs for dispersants and DECON agents)
2. Other SDS: Benzene, Ethyl Benzene, Toluene, Xylene
3. Emergency Response and Removal Operations Job Hazard Analysis
4. Emergency Response, Removal and Prevention Health and Safety Standard Operating Guidelines
5. Emergency Response, Removal and Prevention PPE Selection Guides
6. OSHA PPE Matrix for Oil Spill Response
7. NIOSH Respiratory Protection Recommendations Deepwater Horizon Response
8. Emergency Response Air Monitoring Guidance Tables (EPA ERTG, 2012, Version 3)
9. Hazard Evaluation Flow Chart for Unknowns (EPA ERTG, 2005, Version 6)
10. NIOSH Pocket Guide to Chemical Hazards
11. RAE Systems Technical Note TN-106
12. American Conference of Governmental Industrial Hygienist TLVs and BEIs
13. SCOTT Safety SureLife Cartridge Calculator
14. MSA Emergency Response Application (Respirator Cartridge Calculator)
The online version of this Health and Safety Quick Start Guide supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of
this document can be found at http://epaosc.org/hsmanualregion4.
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHl!>IGTON, D.C. 20460
SEP 1 6 2016
The Honorable Terry McAuli!Tc
The Honorable No1h:in Deni
Go\cn1or of the Common,vcaltJ1 of Virginill
GO\'Cn1or of Gcorgiu
Slllle Cllpitol
Third Floor
Richmond. Viri;inia 232 19
203 S1111e Capi1ol

Atlan1a. Goorgin 30334
I00 Stale Circle

Annopolis. M11rylund 21401
The Honorable Pot McCrory

Go,cmorof North C:i.rolina
OJ1icc o f the Govcn1or
20301 Moil Servi Ccnlcr
Rnlcigli. Nonh Ctuolinn 27699
The Honorabk Phil Bryant

GO\'<m<>r ofMissi!<Sippi
P.O. Box 139
J:ickoon. Mississippi 39205
The I lonornbk Bill Hoslrun

c;o,cmor ofTe.nnesSt."C
Tennessee Stale Cnpitol
Na:-:hvillc. Tennessee 37243
The flonomblc Robert J. Bentley
The I lonomble Jack Morkcll

Governor o f Dela\\'nt~
Lcgisfa1ive I loll
l)over. l)elawarc 19901
The llonor>blc l.nJT)' Hogan

Governor of tvfarylcutd
Go,emor of J\lnb.1n1a
S101e Capitol
600 Dexter Avenue
Mon11,>omery. Alabama 36130

The lfonombk Nikki R. Holey
Governor of Soulh Cnrolinn
1205 Pendle1on Sired
Columbia. South Carolina 29201
The Honor>blc Muriel Bowser
Mayor of 1hc Ois1rict of Columbia

1350 Pcnnsylvnnio ,\\'cnue N\\1
Sui1e3 16
Wushing1on. D.C. 20004
Re:
The llonorJblc Mt1U Devin

Governor of Keotuck)'
700 Cnpilol Avenue. Suile 100

Fmnkfon. Kentuck)' 40601
111c Honorable Chris Chris:1il:

Go"cmor of Ne\v Jersey
1110 S101e Mouse
P.O. Box 001
rrcnton, Nev Jersey 08625
September 2016 Fuel Wahcr Concerning Rcfonnufated Gosoline in

Aln\slp1r1. Dcl3\\"3re. Gcao;jp. .Krnluck''. Mnryl?nd. Mississippj. Ne''' Jergy. N2rth
Carolin>'. South Coro1jn;1. Tennessee-. Viri;:inin.11nd the Dis1rict ofCol11mbi~
Ocnr Governors and Mnyor Bo\\'Scr:
- ""'1'-
--An!Ut.fUM.) Nlf
n.tye.i9Cl ....y<JtUe .._,,,... .. 111v.,.~..,.01 e.._~t..i. ,~ tW..h.~'1"C'f. ~nC~O',...
,_Roo:)clM P.,...
l have received requests for a waiver under the Clean Air Act (CAA) lo add ress a fuel supply emergency
caused by a failure in a segment of the Colonial Pipeline in Alabama. As you know, regulations
promulgated under the CAA require gasoline sold in certain areas of Delaware. Maryland. New Jersey.
Virginia. and the District of Columbia to meet reformulated gasoline (RFG) requirements. These areas
are referred to as the Affected RFG Covered Areas.' The RFG regulations at 40 C.F.R. 80.78(a)(7)
also prohibit any person in Alabama, Delaware. Georgi~ Kentucky, Maryland. Mississippi. New Jersey.
North Caro lina. South Carolina, Tennessee, Vi rginia. and the District of Colum bia from combining any
reformulated blendstock for oxygenate blending (RBOB) with any other gasoline, blendstock. or
oxygenate. except for the oxygenate of the type and amount specified by the refiner that produced the
RBOB. RBOB is combined with its specified oxygenate to produce RFG.
The pipeline failure affects Lhc petroleum distribution system in the Affected RFG Covered Areas and
has resulted in significant supply shortages of RFG to these areas. which are projected to remain over
the next several days. Additionally, the pipeline fa ilure has also caused supply shortages of conventi onal
gasoline (CG) in other non-RFG areas where RBOB could be supplied by other pipelines to produce
RFG, if the RBOB could be commingled with CG or other gasoline blendstocks.
The U.S. Environmental Protection Agency, in consultation with the U.S. Department of Energy. has
evaluated the impact of the fuel d istribution system disrnption on fuel supply in the Aftected RFG
Covered Areas. Based on this evaluation, the EPA has determined. and DOE concurs. that it is necessary
to take the followi ng action to minimize or prevent further disruption of an adequate supply of gasoli ne
to consumers in these areas.
1 have determined that an ..ex treme and unusual fuel supply circumstance' exists that w111 prevent the
d istri bution of an adequate supply of gasoline to consu mers. CAA 211 (c)(4)(C)( ii )(I), 42 U .S.C.
7545(c)(4)(C)(ii)(l). This extreme and unusual fuel circumstance is the result of a pipeline fai lure, an
event that cou ld not reasonably have been foreseen or prevenced. and is not anributable to a lack of
prudent planning on the pan of suppliers of the fuel to these areas. CAA 211 (c)(4)(C)(ii)(II). 42 U.S.C .
7545(c)(4)(C)(ii)(ll). Furthermore. I have determined that it is in the public interest to grant thi s
waiver and that this waiver applies to the smallest geograph ic area necessary to add ress the fuel supply
circumstances. CAA 211 (c)(4)(C)(ii)(Ill) and (iii)(I), 42 U.S .C. 7545(c)(4)(C)(ii)(III) and (i ii)(I).
Therefore, to minimize or prevent further gasoline supply disruptions. I am issuing this waiver of the
fede ral RFG requirements in the Affected RFG Covered Areas. Under this waiver. the EPA will allow
regulated parties to sell CG in the Affected RFG Covered Areas. Additionally, I am waiving the
provisions at 40 C.F .R. 80. 78(a)(7) that prohibit any person from combining any RFG blendstock for
oxygenate blend ing with any other gasol ine. blendstock. or oxygenate, unless certain conditions are met.
This waiver covers the prohibitions at 40 C.F.R. 80.78(a)(7). and applies to the District of Columbia,
1
Delmvare Ccm111ies: New Castle, Kent, and Sussex.
Mmyland Counties: Anne Arundel. Baltimore County and City. Calvert. Carroll. Charles. Cecil. Fredrick. Hartford. Howard.
Kent, Montgomery, Prince George's, and Queen Anne's.
New Jersey Counties: Atlantic, Bergen, Burlington. Camden. Cape May, Cumberland, Essex, G loucester, Hudson,
Hunterdon, Mercer, Middlesex, Monmouth. Morris, Ocean, Passaic, Salem. Somerset, Sussex, Union, and Warren.
Virginia Cities: Fairfax, Falls Church, Alexandria, Manassas, Manassas Park. Hopewell, Richmond. Colonial Heights.
Hampton. Chesapeake. Newpon News. Norfolk, Poquoson. Portsmouth, SuITolk. Virginia Beach. and Williamsburg:
Virginia Counties: Stafford. Fairfax. Loudoun. Arlington. Prince William, Charles Cit}. Chesterfield, Hanover. Henrico.
James Ciry. and York.
District ofColumbia: All Areas.
the States of Alabama, Delaware, Georgia, Kentucky, Maryland, Mississippi, New Jersey, North
Carolina, South Carolina, Tennessee, and the Commonwealth of Virginia.
This waiver is effective immediately and will continue through October 6, 2016. After October 6, 2016,
refiners and importers may not produce or import gasoline that does not meet the RFG standards for
distribution in the Affected RFG Covered A!eas. However, any CG for use in the Affected RFG
Covered Areas that is in the distribution system on October 6, 2016, may be distributed and sold until
the supply is depleted . CG that is in the possession of parties other than retailers and wholesale
purchaser-consumers must meet the RFG requirements by no later than November 6, 2016. Retailers and
wholesale purchaser-consumers may continue selling or dispensing CG until their supplies are depleted .
The EPA will continue to work with the DOE and affected states to monitor the impact of the pipeline
failure on the fuel supply situation. Should conditions warrant, this waiver may be modified, terminated
or extended, as appropriate.
If you have questions you may call me, or your staff may call Phillip Brooks at (202) 564-0652.
Sincerely,
cc: The Honorable Dr. Ernest Moniz

Secretary of Energy
Surface Water Sample Results

Location
Date
Ecological Screening Value (Acute)1
Ecological Screening Value (Chronic)1
Consumption of Fish2
TPH (GRO) Benzene Toluene

(mg/L)
(g/L)
(g/L)
Ethylbenzene
(g/L)
Total-Xylene
(g/L)
Location Notes
9/16/2016
9/17/2016
9/18/2016
9/19/2016
9/16/2016
9/17/2016
9/18/2016
9/19/2016
9/16/2016
9/17/2016
9/18/2016
9/19/2016
9/16/2016
9/17/2016
9/18/2016
9/19/2016
9/16/2016
9/17/2016
9/18/2016
9/19/2016
9/16/2016
9/17/2016
9/18/2016
9/19/2016
NE
114
NE
0.86
0.68
0.5
0.75
0.74
0.44
0.79
0.69
0.1U
0.1U
0.1U
0.1U
0.1U
0.1U
0.1U
-
700
160
15.47
100
76
56
85
86
48
92
80
1.0U
1.0U
1.0U
1.0U
1.0U
1.0U
1.0U
-
560
62
8,722.74
150
110
80
130
130
65
140
120
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
-
550
61
1,244.44
1.3
1.2
0.89 J
1.2
1.4
0.76 J
1.2
1.2
1.0U
1.0U
1.0U
1.0U
1.0U
1.0U
1.0U
-
240
27
NE
150
120
92
130
130
83
140
130
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
-
9/16/2016
9/17/2016
9/18/2016
9/19/2016
9/16/2016
9/17/2016
9/18/2016
9/19/2016
0.1U
0.1U
0.07 J
0.1U
0.1U
1.0U
1.0U
1.0U
1.0U
1.0
5.0U
5.0U
5.0U
5.0U
5.0U
1.0U
1.0U
1.0U
1.0U
1.0U
5.0U
5.0U
5.0U
5.0U
5.0U
PP-SW-14
9/16/2016
9/17/2016
9/18/2016
9/19/2016
0.064 J
0.1U
0.1U
0.1U
1.0U
1.0U
1.0U
1.0U
5.0U
5.0U
5.0U
5.0U
1.0U
1.0U
1.0U
1.0U
5.0U
5.0U
5.0U
5.0U
Cahaba River at confluence of Peel Creek and

Cahaba River
9/16/2016
9/17/2016
9/18/2016
9/19/2016
0.67
-
80
-
120
-
1.0
-
120
-
Pond 3 drainage pipe
PP-SW-02
PP-SW-03
PP-SW-03D
PP-SW-04
PP-SW-07
PP-SW-09
PP-SW-12
PP-SW-13
PP-SW-15
Page 1 of 2
Pond 3 inside the weIr
Pond 3 outside the weIr
Pond 3 outside the weIr
Peel Creek, upstream of confluence with Pond

3 drainage feature
Cahaba River upstream
Cahaba River downstream
Downstream of conlfuence with Pond 3 and

additional drainage feature upstream of
sample location PP-SW-13
Downstream of conlfuence with Pond 3
drainage feature
Pelham Pipeline Spill

September 22, 2016
Surface Water Sample Results

Location
Date
Ecological Screening Value (Acute)1
Ecological Screening Value (Chronic)1
Consumption of Fish2
PP-SW-16
PP-SW-174
9/16/2016
9/17/2016
9/18/2016
9/19/2016
9/16/2016
9/17/2016
9/18/2016
9/19/2016
TPH (GRO) Benzene Toluene

(mg/L)
(g/L)
(g/L)
NE
114
NE
0.1U
1,600
700
160
15.47
1.0U
2,200
560
62
8,722.74
5.0U
8,000
Ethylbenzene
(g/L)
Total-Xylene
(g/L)
550
61
1,244.44
1.0U
1,600
240
27
NE
5.0U
14,000
Location Notes
Cahaba River approximately 4.75 miles

downstream of the Cahaba/Peel Creek
confluence
Pond 2
Notes:
1
2
3
4
ADEM
CPC
D
EPA
GRO
J
mg/L
NE
PP
SSS
SW
TPH
U
g/L
-
BOLD
Ecological screening values were provided by EPA SSS in an email dated September 16, 2016.
ADEM provided State comparison criteria for the protection of human health in the water in an email dated September 19, 2016.
On September 17, 2016, CPC installed a plug in the 6-inch pipe to help reduce the potential of petroleum impacted water being released to Peel Creek.
Pond 2 was not sampled until September 19, 2016 because product previously covered the majority of the pond and prevented sampling access due to health and safety
concerns related to hazardous atmospheres.
Alabama Department of Environmental Management
Colonial Pipeline Company
Duplicate
U.S. Environmental Protection Agency
Gasoline range organics
The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample.
milligrams per liter
Not established
Pelham pipeline
Scientific Support Section
Surface water
Total petroleum hydrocarbons
The analyte was analyzed for, but was not detected at or above the associated value (reporting limit).
micrograms per liter
The sample at the associated location was not collected on that particular date.
Constituent exceeds the chronic ecological screening value
Constituent exceeds the consumption of fish screening value.
Constituent exceeds the both the chronic and acute ecological screening value as well as the consumption of fish screening value.
Constituent detected above the laboratroy reporting limit
Page 1 of 2
Pelham Pipeline Spill

September 22, 2016
Pond 2, Pond 3, and Peel Creek Surface Water Sample Locations
PP-SW-15
PP-SW-03
PP-SW-12
PP-SW-04
PP-SW-13
PP-SW-02
PP-SW-17
September 22, 2016

Surface Water Samp lin g
Split Sample Locations

Retention Ponds
Hydrography
Colonial Pipeline
Cahaba River MP
Water Features
Cahaba River
0
0
0.0375
0.05
1:4,514
0.075
0.1
0.15 mi
0.2 km
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS,

USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS
User Community
Esri, HERE, DeLorme, MapmyIndia, OpenStreetMap contributors
U.S. EPA Region IV
Esri, HERE, iPC | USDA FSA, DigitalGlobe, Microsoft | Copyright 2015 TRG The Response Group, LLC | Esri, HERE, DeLorme, iPC |
Cahaba River Surface Water Sample Locations
PP-SW-07
PP-SW-14
PP-SW-09
PP-SW-16
September 22, 2016

Retention Ponds
Hydrography
Colonial Pipeline
Water Features
Cahaba River MP
Cahaba River
0.3
0.5
1:36,112
0.6
1
1.2 mi
2 km
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS,

USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS
User Community
Esri, HERE, DeLorme, MapmyIndia, OpenStreetMap contributors
U.S. EPA Region IV
Esri, HERE | Copyright 2015 TRG The Response Group, LLC | USDA FSA, DigitalGlobe, Microsoft, CNES/Airbus DS | Esri, HERE, DeLorme |

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CR91EventShelbyCounty,AL

COORDINATE SYSTEM: WGS84

Main Staging SIte

2B Frac Tank Staging Area

2B Recovery Site Staging Area

Radio-telemetering Real-time Air Monitoring Station Locations

PROJECTION SYSTEM: UTM Zone 16

Real-Time Reading Location

1,000 1,500 2,000 2,500 3,000 3,500

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Print Date: 9/17/2016

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Real-Time Benzene Reading (PPM)

Print Date: 9/17/2016

Real-Time LEL Reading (%)

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Print Date: 9/17/2016

Real-Time VOC Reading (PPM)

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Print Date: 9/18/2016

CR-91 Event Shelby County, AL

Real-Time Air Monitoring1

Table 1: Hand-Held Real-Time Air Monitoring Summary1

0.05 - 0.3 ppm

0.1 - 638 ppm

125 - 352.8 ppm

Table 2: Remote Telemetering Real-time Air Monitoring Summary1,3

2A Frac Tank Staging

Main Staging Area Frac

Main Staging Entrance

TRG Checkpoint 2 access to stopple 1,

0.2 - 105.4 ppm

0.1 - 123.7 ppm

0.5 - 736.4 ppm

0.1 - 123.5 ppm

0.3 - 2.1 ppm

COORDINATE SYSTEM: WGS84

Main Staging SIte

2B Frac Tank Staging Area

2B Recovery Site Staging Area

Radio-telemetering Real-time Air Monitoring Station Locations

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Real-Time Reading Location

Print Date: 9/18/2016

Real-Time Benzene Reading (PPM)

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Print Date: 9/18/2016

Real-Time LEL Reading (%)

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Print Date: 9/18/2016

Real-Time VOC Reading (PPM)

PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

Print Date: 9/18/2016