Chapter9ChemicalBondingI:BasicConcepts

Student:___________________________________________________________________________

2.

Whichofthesecompoundsismostlikelytobeionic?
A.
B.
C.
D.
E.

4.

6.

GaAs
SrBr2
NO2
CBr4
H2O

Whichofthesepairsofelementswouldbemostlikelytoformanioniccompound?
A.
B.
C.
D.
E.

ClandI
AlandK
ClandMg
CandS
AlandMg

Whichofthesecompoundsismostlikelytobecovalent?
A.
B.
C.
D.
E.

KF
CaCl2
SF4
Al2O3
CaSO4

8.

Completethisstatement:Coulomb'slawstatesthatthemagnitudeoftheforceofinteractionbetweentwo
chargedbodiesis
A.
B.
C.
D.

directlyproportionaltotheproductofthechargesonthebodiesanddirectlyproportionaltothe
distanceseparatingthem.
directlyproportionaltotheproductofthechargesonthebodies,andinverselyproportionaltothe
squareofthedistanceseparatingthem.
inverselyproportionaltothechargesonthebodies,anddirectlyproportionaltothesquareofthe
distanceseparatingthem.
directlyproportionaltothesumofthechargesonthebodies,andinverselyproportionaltothesquare
ofthedistanceseparatingthem.

10. TheLewisdotsymbolfortheS2ionis
A.
B.
C.
D.

E.

12. TheLewisdotsymbolforthecalciumionis
A.
B.
C.
D.

E.

14. Whichoftheseionicsolidswouldhavethelargestlatticeenergy?

A.
B.
C.
D.
E.

SrO
NaF
CaBr2
CsI
BaSO4

16. Whichofthesesolidswouldhavethehighestmeltingpoint?

A.
B.
C.
D.
E.

NaI
NaF
MgO
MgCl2
KF

18. Calculatetheenergychangeforthereaction
K(g)+Br(g)K+(g)+Br(g)
giventhefollowingionizationenergy(IE)andelectronaffinity(EA)values

A.
B.
C.
D.
E.

1,092kJ/mol
95kJ/mol
95kJ/mol
1,092kJ/mol
1,187kJ/mol

20. UsetheBornHabercycletocalculatethelatticeenergyofLiCl(s)giventhefollowingdata:
H(sublimation)Li=155.2kJ/mol
I1(Li)=520kJ/mol
Bondenergy(ClCl)=242.8kJ/mol
EA(Cl)=348kJ/mol
Hf(LiCl(s))=408.8kJ/mol
A.
B.
C.
D.
E.

40kJ/mol
40kJ/mol
736kJ/mol
857kJ/mol
1,553kJ/mol

22. Whichoftheseelementshasthegreatestelectronegativity?
A.
B.
C.
D.
E.

Na
As
Ga
Cs
Sb

24. Whichoftheseelementshasthegreatestelectronegativity?

A.
B.
C.
D.
E.

Se
Sb
K
Ga
Fe

26. Whichoftheseelementshasthegreatestelectronegativity?
A.
B.
C.
D.
E.

Mg
Ga
Si
Ba
Pb

28. Whattypeofchemicalbondholdstheatomstogetherwithinawatermolecule?
A.
B.
C.
D.

Ionicbond
Nonpolarcovalentbond
Polarcovalentbond
Coordinatecovalentbond

30. Whichofthesebondswouldhavethegreatestpolarity(i.e.,highestpercentioniccharacter)?
A.
B.
C.
D.

E.

32. Thecovalentbondwiththegreatestpolaritywouldforminwhichoftheseatompairs?
A.
B.
C.
D.
E.

34. Inwhichofthesepairsofatomswouldthebondhavethegreatestpercentioniccharacter(i.e.,most
polar)?
A.
B.
C.
D.

E.

36. Classify
A.
B.
C.

the

bondinCH3OHasionic,polarcovalent,ornonpolarcovalent.

ionic
polarcovalent
nonpolarcovalent

38. Classify
A.
B.
C.

the

bondinCaCl2asionic,polarcovalent,ornonpolarcovalent.

ionic
polarcovalent
nonpolarcovalent

40. ThenumberofloneelectronpairsintheN2moleculeis___.
A.
B.
C.
D.
E.

1
2
3
4
5

42. Thetotalnumberofbondingelectronsinamoleculeofformaldehyde(H2CO)is
A.
B.
C.
D.
E.

3.
4.
6.
8.
18.

44. TheLewisstructureforCS2is:
A.
B.
C.

D.

46. WhichoftheseLewisstructuresisincorrect?

A.
B.

C.

D.
E.

48. Thenumberofresonancestructuresforthesulfurdioxidemoleculethatsatisfytheoctetruleis
A.
B.
C.
D.
E.

1.
2.
3.
4.
noneofthese.

50. Howmanyresonancestructuresarethereforthecyclobutenemolecule(C4H6;thefourcarbonatomsare
arrangedinaring)?
A.
B.
C.
D.
E.

1
2
3
4
noneofthese

52. Howmanycovalentbondswillanitrogenatomusuallyform?

A.
B.
C.
D.
E.

1
2
3
5
8

54. WhatistheformalchargeontheoxygenatominN2O(theatomicorderisNNO)?

A.
B.
C.
D.
E.

0
+1
1
2
+2

56. Theformalchargeonthesulfuratomintheresonancestructureofsulfurdioxidewhichhasonesingle
bondandonedoublebondis
A.
B.
C.
D.
E.

0.
+1.
1.
+2.
2.

58. WhatistheformalchargeonthesinglybondedoxygensintheLewisstructureforthecarbonateion?

A.
B.
C.
D.
E.

2
1
0
+1
+2

60. Nitrousoxide,N2O,issometimescalled"laughinggas".Whatistheformalchargeonthecentralnitrogen
atominthebestLewisstructurefornitrousoxide?(TheatomconnectivityisNNO.)
A. 2
B. 1
C. 0
D. +1
E. +2
62. IntheLewisstructureoftheiodateion,IO3,thatsatisfiestheoctetrule,theformalchargeonthecentral
iodineatomis
A.
B.
C.
D.
E.

+2.
+1.
0.
1.
2.

64. Forwhichofthesespeciescanyoudrawtworesonancestructures?
A.
B.
C.
D.
E.

CH2O
ClNO2
H2O
CH4
H2S

66. Forwhichofthesespeciesisthebestdescriptionofthebondingprovidedbytwoormoreequivalent
resonancestructures?

A.
B.
C.
D.
E.

HCO2
SCN
CNO
N3
CO2

68. WhichofthesesubstanceswilldisplayanincompleteoctetinitsLewisstructure?

A.
B.
C.
D.
E.

CO2
Cl2
ICl
NO
SO2

70. Whichofthesecompoundsdoesnotfollowtheoctetrule?
A.
B.
C.
D.
E.

NF3
CF4
PF5
AsH3
HCl

72. Whichresponseincludesallthemoleculesbelowthatdonotfollowtheoctetrule?
(1)H2S(2)BCl3(3)PH3(4)SF4
A.
B.
C.
D.
E.

(2)and(4)
(2)and(3)
(1)and(2)
(3)and(4)
(1)and(4)

74. Whichofthesemoleculeshasanatomwithanexpandedoctet?

A.
B.
C.
D.
E.

HCl
AsCl5
ICl
NCl3
Cl2

76. ThestructuresofC2H4andC2H5OHare

TheenthalpychangeduetothereactionofonemoleofC2H4withwatertoformC2H5OHcanbeestimated
by
A.
B.
C.
D.
E.

BE(C=C)2BE(CC)BE(CO).
BE(C=C)+BE(OH)2BE(CC)BE(CO).
BE(CO)+BE(CC)BE(OH)BE(C=C).
BE(OH)+BE(C=C)BE(CH)BE(CO)BE(CC).
BE(CH)+BE(CO)+BE(CC)BE(OH)BE(C=C).

78. Estimatetheenthalpychangeforthecombustionofonemoleofacetylene,C2H2,toformcarbondioxide
andwatervapor.
BE(CH)=456kJ/mol
BE(CC)=962kJ/mol
BE(O=O)=499kJ/mol
BE(C=O)=802kJ/mol
BE(OH)=462kJ/mol
A.
B.
C.
D.
E.

1759kJ/mol
+653kJ/mol
+1010kJ/mol
1010kJ/mol
155kJ/mol

80. UsebondenergiestoestimatetheenthalpychangeforthereactionofonemoleofCH4withchlorinegasto
giveCH3Clandhydrogenchloride.
BE(CH)=414kJ/mol
BE(CCl)=326kJ/mol
BE(HCl)=432kJ/mol
BE(ClCl)=243kJ/mol

A.
B.
C.
D.
E.

101kJ/mol
106kJ/mol
+331kJ/mol
+106kJ/mol
+101kJ/mol

82. Usethebondenthalpydatagiventoestimatetheheatreleasedwhen50.0gofpropanegas,C3H8,burnsin
excessoxygentoyieldcarbondioxideandwatervaporat25C.
BE(CC)=347kJ/mol
BE(C=OinCO2)=799kJ/mol
BE(CH)=414kJ/mol
BE(OH)=460kJ/mol
BE(O=O)=498.7kJ/mol

A.
B.
C.
D.
E.

1360kJ
2240kJ
2370kJ
1540kJ
1970kJ

84. Thestandardenthalpyofformationofammoniaat25Cis46.3kJ/mol.EstimatetheNHbondenthalpyat
thistemperature.
(Given:BE(NN)=941.4kJ/mol,BE(HH)=436.4kJ/mol)

A.
B.
C.
D.
E.

383kJ/mol
475kJ/mol
360kJ/mol
391kJ/mol
459kJ/mol

Chapter9ChemicalBondingI:BasicConceptsKey
2.B

4.C

6.C

8.B

10.B

12.D

14.A

16.C

18.C

20.D

22.B

24.A

26.C

28.C

30.D

32.E
34.D

36.B

38.A

40.B

42.D

44.C

46.E
48.B

50.D

52.C

54.C

56.B
58.B

60.D

62.A

64.B

66.A

68.D

70.C

72.A

74.B

76.D

78.D

80.A

82.B

84.D