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A P-graph Approach to Bioenergy

System Planning Under


Environmental Footprint
Constraints

Kathleen B. Aviso, Ph.D.


Chemical Engineering Department, De La Salle University Manila

Exceeding the Limits


Atmospheric CO2 levels now
exceed 400 ppm

(Rockstrom et al., 2009)

Global GHG emissions continue


to grow, fuelled by economic and
demographic trends
Climate change has complex
links with other issues e.g.,
biodiversity loss, water stress,
land use
The transport sector contributes
to 13% of the global GHG
emissions in 2004 (IPCC, 2007)
54th Annual Meeting of the Philippine Economic Society
Novotel Manila, Araneta Center
November 8, 2016

Biofuels
Biofuels are being considered as
alternative fuel to reduce the generation of
GHGs
Biofuel feedstocks are typically
agricultural products which require more
land and water than their traditional
counterparts
Reliance on biofuels may strongly be
influenced by the impacts of climate
change
The environmental impact of biofuel
systems should be evaluated throughout
the supply chain
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Biofuel Scenario in the Philippines


Demand for diesel is 8B liters per year in 2014
Demand for gasoline is 5B liters per year
Enactment of the Biofuels Act in 2006 aims to
reduce the countrys dependence on imported
fossil fuels and to reduce GHGs
National Biofuels Program mandates a 2%
biodiesel blend for diesel and 10% ethanol blend
for gasoline
Coconut is the main feedstock for biodiesel
production in the country
In 2013, insect damage (coco lisap) affected 50
70% of coconut farms in Batangas
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Related Work

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Input-Output Analysis:
Historical Perspective
Wassily Leontief received the Sveriges
Riksbank Prize in Economic Sciences in
Memory of Alfred Nobel 1973
"for the development of the input-output
method and for its application to important
economic problems"

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S-1

Final Outputs

Resource Inputs

A Three-Sector Input-Output
System Wastes and Pollutants

S-2

S-3

System Boundary

Supply chains may be modelled similar to IO systems


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P-graph Methodology

Process graph or p-graph is a graph theoretic method developed for


process network synthesis (Friedler et al., 1992, 1993)
P-graph utilizes 3 algorithms to identify the optimal network
structure
MSG maximal structure generation
SSG solution structure generation
RM1
ABB advanced branch and bound
OPERATING UNIT
RM2

P-graph is a graphical representation of


matrix calculations such as MILP
Provides near optimal solutions
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8

P1

Recent applications of P-graph


Application

Authors

Vehicle maintenance scheduling

Adonyi et al. (2013)

Industrial symbiosis networks

Aviso et al., (2015a)

Allocation of in economic systems during crises

Aviso et al., (2015b)

Planning of CO2 capture and storage systems

Chong et al. (2014)

Planning of building evacuation during emergencies

Garcia-Ojeda et al. (2012)

Planning of supply chains in the Energy-Water-Food


Nexus

Heckl et al. (2015b)

Open-structure biomass networks


Renewable energy systems for cities

Lam et al. (2013)


Maier and Narodoslawsky (2014)

Biomass supply chains with consideration of


occupational safety
Operation of polygeneration plants under abnormal
conditions
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in urbanof
infrastrcuture
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Ng et al. (2015)
Tan et al. (2014)
Tan et al. (2015)

Case Study

10

The case study considers the production of biodiesel and


bioethanol
Corn and sugarcane are considered as feedstock for
bioethanol production while coconut is used for
biodiesel production
Agricultural feedstock require land and water resources
Environmental impacts considered include CO2 emission,
water use and land use
There is a desired productivity level for the biofuels
There are desired limits to the environmental impact
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Case Study

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(adapted from Tan et al., 2009)


Parameters

Lower Limit

Upper Limit

Biodiesel Prodn
(in million kg)

140

700

Based on2% and 10%


projected 2008 diesel
demands

Ethanol Prodn
(in million kg)

250

500

Based on 5% and 10%


gasoline demand

Land use
(in hectares)

1,000,000

Based on 10% of total


Phil. agricultural land
area

Water footprint
(in million tons)

10,000

Carbon footprint
0
800
(in thousand
tons)
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Remarks

Based on land use


footprint and annual
rainfall of 1000 mm
Based on 80% reduction
relative to emissions
avoided for 10% fuel
displacement

Case Study

(Adapted from Tan et al., 2009)

The A matrix represents the


technology matrix
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The B54matrix
contains
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environmental
interventions
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12

Case Study

(Adapted from Tan et al., 2009)

Phases in the production process


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are represented
as ofprocess
units
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Case Study

(Adapted from Tan et al., 2009)

Phases in the production process


are represented as process units
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Material,
energy
and
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streams
are represented
as nodes
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Case Study

(Adapted from Tan et al., 2009)

Phases in the production process


are represented as process units
Material, energy and product
streams are represented as nodes
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Center
Environmental
footprints
are
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also represented as nodes
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P-graph representation of
supply chain

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17

Feasible Networks

Structure 1

Structure 2

Structure 3
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Feasible Networks

Structure 4

Structure 5

Structure 6
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Optimization Model

s.t.

s.t.

A technology matrix
B environmental intervention matrix
x - capacity of processes
y - flow of economic goods
yL lower
ofMeeting
y, yU
upper
limitEconomic
of y Society
54thlimit
Annual
of the
Philippine
Z environmental
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Araneta Center
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ZU upper
limit 8,of2016
environmental impact

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Optimal Network: Minimized


Environmental Impact

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21
Biodiesel Production

Ethanol production
utilizes both sugarcane
and corn as feedstock
material
The strategies differ in
relative capacity levels of
process units
Bioethanol
Production
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Maximize Biofuel Production


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Summary of Possible Strategies


Parameters

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Limit

Min EI

Max BD

Max BE

Biodiesel
Prodn (in
million kg)

140 - 700

140

348.43

140

Ethanol Prodn
(in million kg)

250 500

250

255.46

295.06

0 1,000,000

451,548

606,906

531,589

0 10,000

2,634

3,903.69

3016.42

Land use
(in hectares)
Water footprint
(in million tons)

Carbon
0 - 800
168.14
342.73
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footprint
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(in 000 tons)November 8, 2016

178.51

Conclusions and Future Work


A P-graph model for bioenergy system planning was
developed
P-graph is able to identify various pathways for
implementing a strategy
It is possible to identify a strategy which maximizes
economic production and also recognizes
environmental impact constraints and targets
Future work may focus on developing multi-objective
optimization models in P-graph, considering more
detailed supply chains and additional feedstock
alternatives and environmental impacts
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Thank you
for comments and questions you may email at
Kathleen.aviso@dlsu.edu.ph

Further Reading

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Aviso, K.B. (2013) Design of robust water exchange networks for ecoindustrial symbiosis. Process Safety and Environmental Protection (in
press, dx.doi.org/10.1016/j.psep.2012.12.001).
Aviso, K. B., Tan, R. R., Culaba, A. B, Foo, D. C. Y. and Hallale, N. (2011)
Fuzzy optimization of topologically constrained eco-industrial resource
conservation networks with incomplete information. Engineering
Optimization, 43: 257 279.
Aviso, K. B., Tan, R. R. and Culaba, A. B. (2010) Designing Eco-Industrial
Water Exchange Networks Using Fuzzy Mathematical Programming. Clean
Technologies and Environmental Policy, 12, 353 362.
Aviso, K. B., Tan, R. R., Culaba, A. B. and Cruz, J. B. (2010) Bi-Level
Fuzzy Optimization Approach for Water Exchange in Eco-Industrial Parks.
Process Safety and Environmental Protection 88: 31 40.
54th Annual Meeting of the Philippine Economic Society
Novotel Manila, Araneta Center
November 8, 2016

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