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Abstract
The discrete element method-large eddy simulation (DEM-LES) is used to model coal combustion at the particle level in a bubbling
%uidized bed. The gas phase is modelled as a continuum and the solid phase is modeled by DEM. Chemical reactions consist in the
heterogeneous reactions of char with O2 , CO, CO2 , NO, and N2 O, and in the homogeneous reactions involving CO, O2 , NO, and N2 O.
The colliding particleparticle heat transfer is based on the analysis of the elastic deformation of the spheres during their contact. The
model predicts the e9ects of the particle heterogeneous %ow structure on the thermal characteristics of coal particles when heating and
burning, and the gaseous emissions from a %uidized sandcoal binary mixture. The heating rates are 1627 and 432 K=s for, respectively,
0.8 and 2:0 mm diameter coal particles fed into the %uidized bed. The instantaneous contribution of the collision heat transfer is weak,
less than 5.0% of the total power exchanges (coal combustion, radiation, convection and collision) during the heating and 1.5% during
the combustion. The temperature of the coal particles exceeds the bed temperature, which is in qualitative agreement with experimental
data from literature. The e9ects of the diameter of coal particles, of the bed temperature, and of the inlet gas velocity on the thermal
characteristics are also studied.
? 2004 Elsevier Ltd. All rights reserved.
Keywords: Fluidized bed; Coal combustion; Pollutant formation; Temperature of coal particle; Numerical simulation
1. Introduction
When a solid fuel, such as coal, municipal solid waste
or biomass, is fed into a %uidized bed combustor, each particle undergoes several processes which can occur sequentially or simultaneously, including drying, volatile evolution
(and combustion), char combustion (or gasiDcation). The
solid fuel combustion is greatly in%uenced by the %uidized
bed hydrodynamics, fuel properties, oxygen supply and bed
temperature (Palchonok et al., 1997).
Proposed models to predict the performance of %uidized bed coal combustors have been extensively reviewed
(Adanez and Abanades, 1992). Most of them are based on
the 2-phase theory of %uidization, in which the %uidized bed
consists in a bubble phase and an emulsion phase. However,
2-phase models are unable to predict the gas back-mixing
and the recycle peak in solids mixing. Computational %uid
Corresponding author. Tel.: +33-4-68-30-7758;
fax: +33-4-68-30-2940.
E-mail address: %amant@imp.cnrs.fr (G. Flamant).
0009-2509/$ - see front matter ? 2004 Elsevier Ltd. All rights reserved.
doi:10.1016/j.ces.2004.01.070
4206
= k0 exp
(Vpyrol
Vpyrol )N ;
(1)
dt
RTpc
where N is the order of the reaction, Vpyrol is the mass fraction
(2)
C
[CN] + NO
N2 O + C:
(C)
D 1
NO + C
2 N2 + CO:
(D)
kE 1
CO
2
N2 + CO2 :
(E)
F
N2 O + C
N2 + CO:
(F)
G
1
N2 ON
2 + 2 O2 :
(G)
H
N2 O + CON
2 + CO2 :
(H)
CO + 12 O2 CO2 :
(I)
4207
The reaction rates of these homogeneous and heterogeneous reactions are summarized in Table 1.
2.5. Conservation of mass fractions of species
The mass balance for the gas species i (CO2 , CO, N2 O,
NO, H2 O and O2 ) is:
@(f Y i ) @(f u f; j Y i )
+
@t
@xj
@Y
@
t
i
f Di +
+ "i ;
=
@xj
! @xj
(3)
(1
4=3
;
+ (1 (22 )=G2
(6)
(21 )=G1
(7)
4208
Table 1
Reactions included in the model
Reaction
Catalyst
Reaction rate
(mol m3 s1 )
Kinetic constant
(s1 )
Heat release
(J mol1 )
Reference
(A)
Heterogeneous
RA = k A C O 2
Char
Char
R B = kB CO 2
RC = kC CNO
4:04 105
(2=( + 2))
Negligible
Negligible
(B)
(C)
(D)
Char
RD = kD CNO
kD =
(E)
(F)
(G)
(H)
Char
Homogeneous
Homogeneous
Char
RE = kE CNO
RF = k F C N 2 O
RG = kG CN2 O
RH = kH CN2 O
0:159fp exp(6255=Tpc );
Tpc 6 973 K
555:6fp exp(14193=Tpc );
Tpc 973 K
Negligible
Negligible
Negligible
Negligible
Negligible
Homogeneous
RI = kI CCO
2:82 105
exp(20130=Tf )
1 = 7:93 exp(2:48CCO =CO2 )
Table 2
Di9usion coeQcients of H2 O; CO2 , CO, N2 O, NO and O2 (Massman, 1998; Canu, 2001)
Gas
H2 O
CO2
CO
N2 O
NO
O2
CoeQcient (104 m2 s1 )
0.2178
0.1381
0.1807
0.1436
0.1729
D O2 = DN 2 O (
WN2 O 0:5
)
WO2
Note: (1) The given values are at D(0, 1) (Tf0 = 273:15 K and p0 = 1:013 105 Pa). (2) Di9usion coeQcients can be expressed as Di (Tf ; p) =
T
where Tp02 ; Tp01 are the temperatures of the particles before collision, vpn is the normal relative velocity, pi is the
particle density, Cpi is the heat capacity of the particle, +i
is the particle thermal conductivity.
For particlewall contact, the temperature and properties
of the second particle are replaced by those of the wall.
Table 3 lists the thermophysical properties of air, sand, and
coal.
2.6.2. Particlegas convective heat transfer
For calculating the particlegas heat convection Qc , the
correlation of Ranz (1952) was adopted to determine the
heat transfer coeQcient hp . Then
Qc = hp Ap (Tp Tf );
(8)
(9)
dTp
= Qcomb Qc Qr Qcoll ;
dt
(10)
4209
Table 3
Thermophysical properties of air, coal and sand (in SI system units)
For air (Flamant et al., 1993)
Density
f (Tf ) =
7
i=1
Wi Ymi
Thermal conductivity
SpeciDc thermal capacity
2=3
Dynamic viscosity
For char (Tripathi et al., 2002)
Thermal conductivity
SpeciDc thermal capacity
1=2
+ps = 1:87
Cps = 860
(11)
3. Results
3.1. Heating stage of coal
Fig. 1 shows the variations of the heating rate and of
the temperature of coal particles with time. The heating
rate decreases with time, and the temperature of coal particles increases. At very early stage, the heating rate is much
2000
1200
1600
1000
1200
800
dc = 0.8 mm
800
dc = 2.0 mm
600
Temperature / K
When coal is fed into a hot %uidized bed, each coal particle
undergoes heating and combustion stages. It takes several
seconds to burn out, depending on the coal particle diameter,
oxygen concentration, %uidizing velocity, etc. However, the
simulation showed that most coal particles %oat and burn at
the bed surface after 1:5 s (see Part I). To study the e9ect of
the particle heterogeneous %ow structure on the coal combustion, heating and combustion are artiDcally separated,
i.e. the initial coal particle temperature is set as 423.15 and
1123:15 K, respectively, then %uidization begins.
p
RTf
400
400
0
0.0
0.5
1.0
Time / s
1.5
2.0
4210
3.0x10-4
2.0x10-4
(2)
(1)x10
1.0x10-4
1.0x10-7
8.0x10-8
800
(3)
(2)
2.0x10-8
1.0
1.5
2.0
200
0.0
0.5
2.5
1.0
1.5
Time / s
2.0
2.5
Fig. 3. Coal pyrolysis during the heating stage (dc0 = 1:5 mm).
Time / s
1800
3200
1600
2400
Sample 1
1600
1400
Sample 2
800
1200
Heating rate/K.s-1
Temperature /K
Fig. 2. Contributions of the di9erent power exchanges for all the coal
particles during the heating stage (dc0 = 1:5 mm).
higher for small particles (the heating rates are 1627, 621,
and 432 K=s for coal diameter of 0.8, 1.5, and 2:0 mm,
respectively). Moreover, the temperature and heating rate
of coal particles increase with the gas inlet velocity because of the higher gasparticle convective heat transfer
(Eq. (8)). After 2 s for a given particle diameter, the temperature range of the coal particles is very narrow. For
example, it ranges from 1137.2 to 1140:6 K for 0:8 mm
coal particles and from 875.7 to 881:6 K for 2:0 mm coal
particles. The simulation shows that it is reasonable to
separate the heating and burning stages. The larger the
coal particle diameter, the lower the temperature of coal
particles after 2 s. The mean temperatures of coal particles are 1133:0 K (0:8 mm); 989:0 K(1:5 mm)m and
878:0 K (2 mm), respectively.
Fig. 2 plots the instantaneous contributions of the four
power exchanges, i.e., heat of coal combustion, radiation,
convection and collision, for the whole set of coal particles.
The heat of combustion is small due to the very low temperature of coal particles, and so does the heat of collision in
comparison to the contributions of radiation and convection,
which are about ten-fold bigger. The collision heat transfer
%uctuates and it decreases with time because of the discontinuous coalsand particle collisions and because of the decreasing temperature di9erence between coal and sand. The
instantaneous contribution of collision ranges from 0% to
2.6%. The maximum contributions increase with the coal
particle diameter (2.0% and 3.4% for 0.8 and 2:0 mm, respectively) and the inlet gas velocity (4.2% for 0:6 m=s).
Fig. 3 plots an example of coal pyrolysis and combustion
during the heating stage (particle diameter is 1:5 mm). The
volatiles release very quickly (less than 2 s). The maximum
release rate of CO2 is at the very early stage (about 0:25 s)
whereas it is about 1 s for CO and the curve is more %at.
There are two peaks for the CO2 release because the release
rate depends on the coal temperature and its heating rate, but
also on the time. The burning point of coal is about 800 K.
400
(1)
0.0
0.5
600
4.0x10-8
0.0
0.0
1000
6.0x10-8
(4)x10
(3)
1200
CO (1)
CO2 (2)
Temperature of coal particle (3)
4.0x10-4
0
1000
0.0
0.5
1.0
1.5
2.0
Time / s
Fig. 4. Variations of the temperature and heating rate of coal particles
with time during the combustion (dc0 = 1:5 mm).
4.0x10-4
combustion (1)
radiation (2)
convection (3)
collision (4)
3.0x10-4
(1)
2.0x10-4
(2)
(4)x20
1.0x10-4
(3)
0.0
0.0
0.5
1.0
Time / s
1.5
2.0
750
Time =1 s
Time =2 s
Excess temperature / K
600
450
164.0 K
300
72.7 K
4211
150
10
15
Series of particle number
20
on the coal particle, the absolute values for the same heat
transfer mode may vary up to almost tenfold.
The temperature of coal particles is always higher than
the bed temperature (Fig. 6). The maximum excess temperature is 105:0 K at 1 s, it reaches 614:0 K at 2 s. The
mean excess temperature increases with time, whereas the
bed temperature remains almost constant. The mean excess
temperatures are 72.7 and 164:0 K at 1 and 2 s, respectively.
The standard deviation of the temperature of coal particles
is 17.6 at 1 s and it increases to 141.2 at 2 s, which indicates
that the temperature of coal particles can vary strongly, and
the range widens strongly with time: It is 58:3 K at 1 s, and
559:0 K at 2 s. This big temperature di9erence results from
the di9erent routes followed by the coal particles, where the
O2 concentration, the gas velocity, the in%uence of other
coal particles, : : : may vary deeply.
Fig. 7 shows the distributions of the gas species at 1 s
in the %uidized bed. The O2 concentration is higher at the
The contributions of radiation and convection are comparable whatever the diameter and the contribution of collision
decreases slightly with the diameter (the maximum contributions are 1.1% for dc0 =0:8 mm and 0.8% for dc0 =2:0 mm).
So, the heat transfer due to particle collisions is always very
weak during the coal combustion.
Fig. 9 shows that the coal particle temperature is much
higher than the bed temperature. The di9erence ranges between 93.0 and 142:0 K for the three diameters of coal particles after 2 s. The maximum excess temperature is 274.0,
614.0 and 229:0 K for the diameter of 0.8, 1.5 and 2:0 mm,
respectively. The mean temperature and the excess temperature of coal particles are the highest when the diameter
of coal is 1:5 mm. The simulation shows that the heating
rate of coal particle does not vary inversely to the diameter
during the combustion stage, contrary to the heating stage.
Radiation and convection heating transfers, which increase
with the diameter, dominate during the heating. However,
the heat of combustion is larger during combustion; it depends mainly on the coal temperature and on its diameter,
but also on O2 and H2 O concentrations.
The combustion rate per unit mass is the same whatever
the particle diameter when the temperature of coal particle
is low ( 1400 K) then a di9erence exists, which increases
4212
CO
O2
0.023
0.11
0.023
0.05
0.10
0.11
0.10 0.11
0.07
0.09
0.10
0.10
0.07
0.14
0.130.14
0.09
0.0230.11
0.05
0.16
0.09
0.05
0.05
0.18 0.21
0.22
0.19
0.07
0.11
0.16
CO2
N2O
NO
0.16
0.18
1.4E-5
8E-6
0.18
0.16
1.6E-5
9E-6
0.14
9E-6
2.3E-5
0.12
0.10
0.060.08
2.3E-5
0.04
0.020
9E-6
1.4E-5
1.8E-5
2.7E-5 1.4E-5
2.3E-5
9E-6
2.7E-5
4.5E-6
0.08
3.2E-5
1.8E-5
1.8E-5
2.4E-5
3.2E-5
3.2E-5
4E-53.2E-5
1.6E-5
8E-6
4.8E-5
1.8E-5
2.4E-5
1.6E-5
2.4E-5
2.3E-5
0.24
CO concentration (mg.m-3)
0.20
O2
0.16
0.12
CO2
10
8
3x104
0.08
2x104
0.04
N2O
1x104
0.00
CO
0.0
0.5
1.0
Time / s
1.5
600
4x104
NO
700
12 5x104
Excess temperature / K
Fig. 7. Instantaneous gas species (O2 ; CO2 , CO, NO, and N2 O) distributions (mass fraction, time = 1:0 s).
Tmean = 142.0 K
Tmean = 164.0 K
Tmean = 93.0 K
500
400
300
200
2.0
100
0
0
10
15
20
3000
3.0
2500
2.5
2000
2.0
1500
1.5
4213
280
1000
500
1.0
dc0= 1.5 mm
dc0 = 0.8 mm
0.5
0.0
Excess temperature / K
240
Time / s
200
160
120
80
Temperature / K
Fig. 10. Temperature of coal particles versus combustion rate and time.
72
40
0
10
15
Series of particle number
20
0.6 m/s
0.4 m/s
Excess temperature / K
68
4. Discussion
64
60
56
52
10
15
20
Much e9ort has been devoted to measure the temperature of burning coal particles in %uidized bed combustors
(LaNauze et al., 1987; Linjewile et al., 1994; Joutsenoja
et al., 1999). All authors observed that the coal particle
temperature is much higher than the bed temperature. For
example, Linjewile et al. (1994) found that the average temperature of petroleum coke particle exceeded the bed temperature by 60360 K. Joutsenoja et al. (1999) showed that
the average char particle temperature exceeded the bed temperature by about 100200 K, whereas the maximum char
particle temperature was nearly 600 K above the bed temperature. Although our simulation conditions (e.g. the particle number, particle size distribution, simulation time, etc.)
are di9erent from their operating conditions because of the
computer capacity limitations, the temperature of coal particles is in qualitative agreement with these experimental data.
They agreement is better than with the results of Rong and
Horio (1999) who simulated char combustion in a bubbling
%uidized bed. They found that the maximum temperature of
char particles was about 50 C 5 C higher than the average bed temperature, which is much lower than the experimental measurements. Their model seems to overestimate
the particleparticle heat conduction.
5. Conclusions
Coal combustion was numerically studied at the particle
level in a bubbling %uidized bed. The mathematical model
is based on the discrete element method (DEM) model with
heat transfer and chemical reactions. The model predicts the
e9ects of the particle heterogeneous %ow structure on the
thermal characteristics of coal particles when heating and
4214
Notation
A; B; C; D
Ap
Cf
CH2 O
CNO
CN 2 O
CCO
CO 2
Cp
dp
Di
EA
fp
G
Gi
hp
kA ; kB ; : : : ; kJ
k0
m
mp
N
Qc
Qcoll
Qcomb
Qr
r
R
RA ; RB ; : : : ; RJ
t
Tb
Tf
Tp
TR
u f
umf
vpn
Vpyrol
Vpyrol
Wi
Yi
Ymi
Greek letters
(i
Rt
RT
Rx
Ry
&p
+f
+p
t
f
p
!
!S B
Subscripts
c
s
0
coal
sand
initial
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4215