SET-3

Series ONS
U .

Code No.

U .

56/3/C

U U U-S -cU
U

Roll No.

Candidates must write the Code on the

title page of the answer-book.

U - cU 16
- U U U U U-S -cU U
U - 26
U M U ,
- 15 U - U q
10.15 10.15 10.30 U - U
U -S U U
Please check that this question paper contains 16 printed pages.
Code number given on the right hand side of the question paper should be written
on the title page of the answer-book by the candidate.
Please check that this question paper contains 26 questions.
Please write down the Serial Number of the question before attempting
it.
15 minute time has been allotted to read this question paper. The question paper
will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will
read the question paper only and will not write any answer on the answer-book
during this period.

U (h)
CHEMISTRY (Theory)

70

Time allowed : 3 hours

56/3/C

Maximum Marks : 70
1

P.T.O.


(i)

(ii)

(iii)

10 -U U

(iv)

11

(v)

23

(vi)

24

(vii)

, U U UU

-U U
2

26

22 -U U
U U

-U U

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 5 are very short answer questions and carry 1 mark each.

(iii) Questions number 6 to 10 are short answer questions and carry 2 marks each.
(iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each.
(v)

Question number 23 is a value based question and carry 4 marks.

(vi) Questions number 24 to 26 are long answer questions and carry 5 marks each.
(vii) Use log tables, if necessary. Use of calculators is not allowed.

56/3/C

1.

U SU U ?

What is the reason for the stability of colloidal sols ?

2.

U U U U

Give an example each of a molecular solid and an ionic solid.

3.

Pb(NO3)2

U U U U UU U U mU

Pb(NO3)2 on heating gives a brown gas which undergoes dimerization on

cooling ? Identify the gas.

4.

C4H9Br U

SN1

Write the structure of an isomer of compound C4H9Br which is most reactive

towards SN1 reaction.

5.

.....

Write the IUPAC name of the given compound :

56/3/C

P.T.O.

6.

CoCl3.6NH3 AgNO3
AgCl
(i)

(ii)

.....

When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of

AgCl are precipitated per mole of the compound. Write

7.

8.

(i)

Structural formula of the complex

(ii)

IUPAC name of the complex

(i)

U (A) (B)
KH (U SU) U U ?

(ii)

U , U
?

(i)

Gas (A) is more soluble in water than Gas (B) at the same temperature.
Which one of the two gases will have the higher value of KH (Henrys
constant) and why ?

(ii)

In non-ideal solution, what type of deviation shows the formation of

maximum boiling azeotropes ?

U
(i)

(ii)

BrF3

2
XeF4

(i)

Fe31

(ii)

XeF4

56/3/C

SbF5

SO2

?
4

Write the structures of the following :

(i)

BrF3

(ii)

XeF4
OR

What happens when :

9.

(i)

SO2 gas is passed through an aqueous solution Fe31 salt ?

(ii)

XeF4 reacts with SbF5 ?

U U
(i)

-U

(ii)

Write the chemical equations involved in the following reactions :

10.

(i)

Hoffmann-bromamide degradation reaction

(ii)

Carbylamine reaction

hv

H2 1 Cl 2
2HCl

U5k
(i)

U U

(ii)

hv
For a reaction : H2 1 Cl 2
2HCl

Rate5k
(i)

Write the order and molecularity of this reaction.

(ii)

Write the unit of k.

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P.T.O.

11. (a)
(b)

[Fe(H2O)6]31 U, U U S
(.. Fe526)
[Pt(en)2Cl2]21 c

(a)

For the complex [Fe(H 2O)6 ]31, write the hybridization, magnetic
character and spin of the complex. (At. number : Fe526)

(b)

Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]21 which

is optically inactive.

12. (i)

SU U U U

(ii)

U ?

(iii)

UU U U U U U

(i)

Write the structural difference between starch and cellulose.

(ii)

What type of linkage is present in Nucleic acids ?

(iii) Give one example each for fibrous protein and globular protein.
13. (i)

UU U U ?

(ii)

(iii)

U U S
UU, ,

(i)

What is the role of Sulphur in the vulcanization of rubber ?

(ii)

Identify the monomers in the following polymer :

(iii) Arrange the following polymers in the increasing order of their

intermolecular forces :
Terylene, Polythene, Neoprene
56/3/C

14.

MU U
(i) U
(ii) 1- U
(iii) 2-U U-2-

(i)

(ii)

(iii)
How do you convert :
(i) Chlorobenzene to biphenyl
(ii) Propene to 1-iodopropane
(iii) 2-bromobutane to but-2-ene
OR
Write the major product(s) in the following :
(i)

(ii)

(iii)

56/3/C

P.T.O.

15.

(i)

U-U

(ii)

(iii)

UU U U

(CH3)3 N

(CH3)2 NH

Give reasons for the following :

(i)

Aniline does not undergo Friedal-Crafts reaction.

(ii)

(CH3)2 NH is more basic than (CH3)3 N in an aqueous solution.

(iii) Primary amines have higher boiling point than tertiary amines.

16.

(a)

(b)

(c)

56/3/C

(i) CHCl 1 aq.NaOH

H
(ii)

C6H52OH
1

Write the final product (s) in each of the following reactions :

(a)

(b)

(c)

17.

(i) CHCl 1 aq.NaOH

H
(ii)

C6H52OH
1

U
(i) SO2 TeO2
(ii) U UU
(iii) I2 ICl

Give reasons :
(i) SO2 is reducing while TeO2 is an oxidizing agent.
(ii) Nitrogen does not form pentahalide.
(iii) ICl is more reactive than I2.
18.

MgSO4 (M5120 g mol21) 4 g 100 g

U , U MgSO4
U
(Kb 50.52 K kg mol21)

Calculate the boiling point of solution when 4 g of MgSO4 (M5120 g mol21)

was dissolved in 100 g of water, assuming MgSO4 undergoes complete
ionization.
(Kb for water50.52 K kg mol21)
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P.T.O.

19. (i)

UcU

(ii)

c U ?

(iii)

U U U c U ?

(i)

Name the method of refining of nickel

(ii)

What is the role of cryolite in the extraction of aluminium ?

(iii) What is the role of limestone in the extraction of iron from its
oxides ?

20.

U
(i)

(ii)

(iii)

Define the following terms :

(i)

Lyophilic colloid

(ii)

Zeta potential

(iii) Associated colloids

21.

U c U
C2H5Cl(g) C2H4(g) 1 HCl(g)
Time/sec

UU /atm

0.30

300

0.50

U SU U
(
56/3/C

log 250.301, log 350.4771, log 450.6021)

10

For the first order thermal decomposition reaction, the following data were
obtained :
C2H5Cl(g) C2H4(g) 1 HCl(g)
Time / sec

Total pressure / atm

0.30

300

0.50

Calculate the rate constant

(Given : log 250.301, log 350.4771, log 450.6021)

U b.c.c. cU
7.5g cm23 300 g U ?

22. 500pm

An element crystallizes in a b.c.c. lattice with cell edge of 500pm. The density
of the element is 7.5g cm23. How many atoms are present in 300 g of the
element ?

23.

S U U U U U
M U U
U U . . UU
UUU U . UU . U
U U UU U
U . U U U
U

U U U
(i)

. ( ) ?

(ii)

UU ? U

(iii)

UU ? U

56/3/C

11

P.T.O.

Due to hectic and busy schedule, Mr. Singh started taking junk food in the
lunch break and slowly became habitual of eating food irregularly to excel in
his field. One day during meeting he felt severe chest pain and fell down.
Mr. Khanna, a close friend of Mr. Singh. took him to doctor immediately.
The doctor diagnosed that Mr. Singh was suffering from acidity and prescribed
some medicines. Mr. Khanna advised him to eat home made food and change
his lifestyle by doing yoga, meditation and some physical exercise. Mr. Singh
followed his friends advice and after few days he started feeling better.
After reading the above passage, answer the following :
(i)

What are the values (at least two) displayed by Mr. Khanna ?

(ii)

What are antacids ? Give one example.

(iii) Would it be advisable to take antacids for a long period of time ? Give
reason.

24. (a)

U
(i)

Mn S17 U
S14

(ii)

Cr21

(iii) Cu21
(b)

Zn21

U
(i)

(ii)

56/3/C

2MnO2 1 4KOH 1 O2

Cr2O722 1 14H1 1 6I2

12


3d

Sc

Ti

Cr

Mn Fe

Co

Ni

Cu Zn

U
(i)

S U

(ii)

(iii)

(iv)

(a)

Account for the following :

13

13

S ?

S U ?

(i)

Mn shows the highest oxidation state of17 with oxygen but with
fluorine it shows the highest oxidation state of 14.

(ii)

Cr21 is a strong reducing agent.

(iii) Cu21 salts are coloured while Zn21 salts are white.
(b)

Complete the following equations :

(i)
(ii)

2MnO2 1 4KOH 1 O2

Cr2O722 1 14H1 1 6I2

OR
The elements of 3d transition series are given as :
Sc

Ti

Cr

Mn Fe

Co

Ni

Cu Zn

Answer the following :

(i)

Write the element which shows maximum number of oxidation states.

Give reason.

(ii)

Which element has the highest m.p ?

(iii) Which element shows only 13 oxidation state ?

(iv) Which element is a strong oxidizing agent in 13 oxidation state and
why ?
56/3/C

13

P.T.O.

25. (a)

(b)

(c)

H ,Pd2BaSO

H N2OH

(i)

2
4 A
2
CH3COCl
B

(ii)

CH3 MgBr

1. CO2
A
2. H3O1

PCl

5 B

(i)

C6H52COCH3 U C6H52CHO

(ii)

CH3COOH U HCOOH

CH3CHO, CH3COOH, CH3CH2OH

(a)

-U U

(b)

S

C6H5COCH3, CH32CHO, CH3COCH3

(c)

, ?

(d)

1. (i2Bu) AlH

CH3CH2CH5CH2CH2CN 2.
H2O

(e)

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C3H6O

A U B NaOH U I2, U
U B U A
A U B
14

(a)

(b)

(c)

Write the structures of A and B in the following reactions :

H ,Pd2BaSO

H N2OH

(i)

2
4 A
2
CH3COCl
B

(ii)

CH3 MgBr

PCl

1. CO2
A
2. H3O1

5 B

Distinguish between :
(i)

C6H52COCH3 and C6H52CHO

(ii)

CH3COOH and HCOOH

Arrange the following in the increasing order of their boiling points :

CH3CHO, CH3COOH, CH3CH2OH
OR

(a)

Write the chemical reaction involved in Wolff-Kishner reduction.

(b)

Arrange the following in the increasing order of their reactivity towards

nucleophilic addition reaction :
C6H5COCH3, CH32CHO, CH3COCH3

(c)

Why carboxylic acid does not give reactions of carbonyl group ?

(d)

Write the product in the following reaction

1. (i2Bu) AlH

CH3CH2CH5CH2CH2CN 2.
H2O

(e)

56/3/C

A and B are two functional isomers of compound C3H6O. On heating with

NaOH and I2, isomer B forms yellow precipitate of iodoform whereas
isomer A does not form any precipitate. Write the formulae of A and B.
15

P.T.O.

26. (a)

298K

E8cell

2Al(s)1 3Cu21(0.01M) 2Al31 (0.01M) 1 3Cu(s)

(b)

: Ecell 5 1.98 V

A U B E8

U U
U ? [E8(Fe21/Fe)520.44V]

E8(A21/A)522.37V : E8 (B21/B)520.14V

(a)

0.001 mol L21 3.90531025 S cm21

U U U U (a) U

CH3COOH

l0 (H1)5349.6 S cm2 mol21 U l0 (CH3COO2)540.9 S cm2 mol21

(b)

lU U l U
E8cell s U ?

(a)

Calculate E8cell for the following reaction at 298K :

2Al(s)1 3Cu21(0.01M) 2Al31 (0.01M) 1 3Cu(s)
Given : Ecell 5 1.98 V

(b)

Using the E8 values of A and B, predict which is better for coating the
surface of iron [E8(Fe21/Fe)520.44V] to prevent corrosion and why ?
Given : E8(A21/A)522.37V : E8 (B21/B)520.14V
OR

(a)

The conductivity of 0.001 mol L 21 solution of CH 3 COOH is

3.90531025 S cm21. Calculate its molar conductivity and degree of
dissociation (a).
Given l0 (H1)5349.6 S cm2 mol21 and l0 (CH3COO2)540.9 S cm2 mol21

(b)

56/3/C

Define electrochemical cell. What happens if external potential applied

becomes greater than E8cell of electrochemical cell ?

16