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Molarity redirects here. It is not to be confused with denoted by a capital letter M (pronounced molar), someMolality or Morality.
times preceded by an SI prex to denote sub-multiples,
For the comic strip, see Molarity (comic strip).
for example:
mol/m3 = 103 mol/dm3 = 103 mol/L = 103
Molar concentration, also called molarity, amount
M = 1 mmol/L = 1 mM.
concentration or substance concentration, is a measure of the concentration of a solute in a solution, or of
any chemical species, in terms of amount of substance in The words millimolar and micromolar refer to mM
3
6
a given volume. A commonly used unit for molar con- and M (10 mol/L and 10 mol/L), respectively.
centration used in chemistry is mol/L. A solution of concentration 1 mol/L is also denoted as 1 molar (1 M).
3 Related quantities
Denition
Molar concentration or molarity is most commonly ex- The conversion to number concentration Ci is given by:
pressed in units of moles of solute per litre of solution.
For use in broader applications, it is dened as amount
of solute per unit volume of solution, or per unit volume Ci = ci NA
available to the species, represented by lowercase c:[1]
where NA is the Avogadro constant, approximately
6.0221023 mol1 .
c=
n
N
C
=
=
.
V
NA V
NA
=
c
i
i
i
which can appear in Ostwalds law of dilution.
xj Mj
xi = ci
ci Mi
2 Units
where M is the average molar mass of the solution,
In the International System of Units (SI) the base unit for is the density of the solution and j is the index of other
molar concentration is mol/m3 . However, this is imprac- solutes.
tical for most laboratory purposes and most chemical lit- A simpler relation can be obtained by considering the toerature traditionally uses mol/dm3 , or mol dm3 , which tal molar concentration namely the sum of molar concenis the same as mol/L. These traditional units are often trations of all the components of the mixture.
1
6 EXAMPLES
xi =
3.4
ci
ci
=
c
ci
Mass fraction
ci =
ci,T0
(1 + T )
where ci,T0 is the molar concentration at a reference temperature, is the thermal expansion coecient of the
mixture.
Mi
wi = ci
3.5
Molality
b2 =
c2
c2 M2
6 Examples
Example 1: Consider 11.6 g of NaCl dissolved in 100 g
of water. The nal mass concentration (NaCl) will be:
(NaCl) = 11.6 g / (11.6 g + 100 g) = 0.104
g/g = 10.4 %
The density of such a solution is 1.07 g/mL, thus its volume will be:
bi =
c
i
ci Mi
Properties
4.1
4.2
Sum
of
products
molar
concentrations-partial molar volumes To create the solution, 11.6 g NaCl are placed in a
ci Vi = 1
4.3
Dependence on volume
Molar concentration depends on the variation of the volume of the solution due mainly to thermal expansion. On Likewise, the concentration of solid hydrogen (molar
mass = 2.02 g/mol) is:
small intervals of temperature the dependence is :
3
c(H2 ) = 88 g/L / (2.02 g/mol) = 43.7 mol/L
The concentration of pure osmium tetroxide (molar mass
= 254.23 g/mol) is:
c(OsO4 ) = 5.1 kg/L / (254.23 g/mol) = 20.1
mol/L.
Example 4: A typical protein in bacteria, such as E. coli,
may have about 60 copies, and the volume of a bacterium
is about 1015 L. Thus, the number concentration C is:
C = 60 / (1015 L)= 61016 L1
The molar concentration is:
c = NCA = 61016 L1 / (61023 mol1 ) = 107
mol/L = 100 nmol/L
Formal concentration
References
External links
Molar Solution Concentration Calculator
Experiment to determine the molar concentration of
vinegar by titration
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10.1
10.2
Images
File:Reference_ranges_for_blood_tests_-_by_molarity.png
Reference_ranges_for_blood_tests_-_by_molarity.png License:
Hggstrm.
10.3
Content license
Source:
https://upload.wikimedia.org/wikipedia/commons/b/b8/
Public domain Contributors: Own work Original artist: Mikael