Analytical Chemistry

c. 0.02564 M

d. 0.03846 M

1. Which of the following precipitate are hardest to

filter?
a. isomorphous
b. gelatinous
c. crystalline
d. curdy precipitates

8. Brix scale is the hydrometer scale for:

a. gasoline
b. sugar solution
c. liquefied propane gas
d. water

2.What is the color of methyl orange at ph = 8?

a. red
b. yellow
c. colorless
d. blue

9. A 0.010 F weak acid is 4.17 ionized. What is the ionization

constant?
a.1.74 x 10-5
b.3.6 x 10-5
-4
c. 1.2 x 10
d. 1.2 x 10-5

3. Which of the following conditions would induce

precipitation?
a. high temperature b. dilute solns
c. low ph
d. all of the above

10. What is the most commonly used reagent in the

standardization of acids?
a. K2SO4
b. Borax
c. BaCl2
d. Na2CO3

4. What is the density of 7.16M H2SO4 which is 50.11

% (w/w)?
a. 1.4 g/l
b. 7.4 g/l
c. 1.4 g/ml
d. 7.14 x 10-4 g/l

11. What is the practical method of coagulation?

a. increasing T
b. agitating/stirring
c. digestion
d. all of the above

5. Which of the following has the highest purity?

a. primary Std.
b. USP reagent
c. ACS reagent
d. CP reagent

12. A 0.0722 M acid has pH of 3.11, what is the Ka of the acid?

a. 4.2 x 10-6
b.8.35 x 10-6
-7
c. 8.35 x 10
d. 4.2 x 10-7

6. What is the color of litmus paper in acid?

a. blue
b. red
c. orange
d. colorless

13. What weight. in grams of KMnO4 needed to form a 250 ml

solution of 0.10 M?
a. 47.5
b. 2.75
c. 3.95
d. 89.5

7. Calculate the molar analytical concentration of solute

when 2.5 gram of KH (IO3)2 is dissolved and diluted to
500 ml. (MW KH (IO3)2 = 390 g/mol)
a. 0.00641 M
b. 0.01282 M

14. In a redox reaction, you need:

a. a strong OA & WA
b. a strong RA & a weak OA
c. a strong OA & a strong RA
d. a weak OA & weak RA
15. Sixteen grams of a mixture of sodium & potassium
is neutralized with 40 moles of H2SO4. How many
grams of potassium is present in the mixture?
a. 5.01 g
b. 2.93 g
c.10.96 g
d. 5.04 g
16. Twenty milliliter of a 0.125 M HCl is mixed with
25 mL of 0.120 M NH3. What is the resulting pH of the
mixture?
a. 0.055
b. 1.26
c. 7.52
d. 8.50
17. What is the color of phenolphthalein at
pH = 10?
a. colorless
b. blue
c. red
d. yellow
18. What is the color of Bromcresol green at
pH = 9?
a. colorless
b. yellow
c. red
d. blue types

19. Which of the following types of precipitimetry is used as a

direct method for halide determination?
a. Mohr method
b. Volhard method
c. Fajans method
d. none of the above
20. What is the titrant used in Mohr method?
a. AgNO3
b. KSCN
c. K4Fe ( CN)6
d. KCN
21. What is the indicator used in Fajans method of
precipitimetry?
a. methylorange
b. phenolputhalein
c. Bromcresol green
d. Sodium fluoresclinate
22. A certain solution is known to contain a compatible
combination of two of the following substance: HCl, Na2HPO4,
H3PO4, NaOH, Na3PO4. Titration of a sample with 0.510 N
HCl, using methyl orange, requires 28.1 mL of the acid. With
the mass of the sample & phenolphthalein indicator, 17.1 mL of
the HCl is required. What components are present & how many
grams of each are in the sple taken?
a. NaH2PO4 = 0.32 g, NaOH = 0.17 g
b. NaOH = 0.51 g, NaH2PO4 = 0.71 g
c. Na3PO4 = 0.921 g, NaOH = 0.12 g
d. HCl = 0.5 g, H3PO4 = 0.19 g