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1.
2.
Reversible reaction: a reaction which can go both ways.
3.
Equilibrium: is the point when the [reactants] and [products] becomes constant.
4.
Equilibrium is reached when no more changes can be observed. SQ1
5.
Equilibrium is recognized by constancy of macroscopic properties in a closed system at
constant temperature. SQ2
6.
Macroscopic properties are observable properties or measurable properties like pressure,
concentration, color, size, volume and mass.SQ3 and SQ4
7.
Closed system is a system containing a closed amount of matter. SQ5
8.
At equilibrium: two opposite processes occur at the same rate.
9.
Each set of equilibrium concentrations is called an equilibrium position.
10.
Steady state: indicates a situation where macroscopic properties are constant but
equilibrium does not exist as the system is not closed e.g a blue Busen burner flame.
BQ1
11. Equilibrium in physical changes: Solubility of iodine SQ7, Vapor pressure of water SQ8
12. Equilibrium in chemical reactions: NO2-N2O4 system SQ9
13. Equilibrium is dynamic in nature since at equilibrium two microscopic processes are
occurring in opposite direction at the same rate resulting in no observable macroscopic
changes.
BQ2 and 3
Extra Question: What does each of the following symbols stand for? (g), (l), ()
Keq = [][]
27. Concentrations of solids and liquids are NOT included in the equilibrium expression.
These values are constant and are incorporate in the value of Keq directly. . SQ19-23, CT8
28. Temperature and the nature of solvent are the only values which determine the value of
the equilibrium constant.
SQ25
29. There is only one equilibrium constant for a particular system at a particular temperature
but there are an infinite number of equilibrium positions
30. Significance of value of K
SQ26-29
K>1
system consists mostly of products
equilibrium lies to the right
reaction goes to completion
Example
B2 (g) 2 B (g)
K<1
system consists mostly of reactants
equilibrium lies to the left
reaction does not occur to a significant
effect but the reverse reaction occurs.
Example
A2 (g) 2 A (g)