CNASGL02

Guidance on Statistic Treatment of

Proficiency Testing Results and
Performance Evaluation

CNAS-GL022006

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1
1.1 CNAS

1.2 CNAS CNAS

ISO/IEC 43-11997
GB/T15483.1IDT
APLAC PT001
APLAC PT002
NATA
ISO 57251994 1-6

3
3.1
3.1.1

a
b
c
d
3.1.2

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CNAS-GL022006

2 18

a)
b)
c)
d) /

e)
f)

3.1.3 4.1.2 a)(

)

3.2
3.2.1

a
b
c/

e) 4.2.3
3.2.2

3.2.3

:
a)
b)
3.2.4 BIPM IEC
IFCCISOIUPAC OIML

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CNAS-GL022006

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3.2.5
a

ISO5725-2
b

3.2.6
a

3.3
3.3.1
3.3.1.1
3.3.1.2

3.3.1.3

- SD
- CV RSD
-
3.3.1.4
a D = x X x X
b

D
100 %
X

c
d Z
Z =

x X
s

S / X S
X S

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CNAS-GL022006

4 18

Z =

(x X )
0.7413IQR

IQR

e En
En =

LAB

x REF

2
2
U LAB
+ U REF

x LAB x REF U LAB

U REF
3.3.1.5
a

(x X ) ISO5725-4
b
c

e Z

3.4
3.4.1

Youden Mandel h -

a
-
-z
-
-
b
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CNAS-GL022006

5 18

-
- Z
-
3.4.2
a Z
x 2
b

3.5
3.5.1
a

b
c Z
Z 2
2< Z <3

Z 3

En 1

En > 1

En

- 80%90% 95%
- 90%
3.5.2

3.5.3 Z

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CNAS-GL022006

6 18

-
-
-

/
3.5.4 En
C

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CNAS-GL022006

7 18

A:

A.1

CNAS
B

A.4A.5 A.6
A.2
A.3

A.2

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8 18

A.5

68%
95%99%

A.3

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CNAS-GL022006

9 18

A.4

IQR ( CV )

IQR
IQR

N
N
X

[(N + 1)] N
2

(X [N 2 ]+ X [(N 2 )+ 1]) N 9 5
2

N 10 5 6
IQR IQR 0.7413

Q Q
1

Q Q IQR = Q Q
1
3
3
1
IQR = IQR 0.7413
CV CV =

IQR
100%

X [1] X [N ]
X [N ] X [1]

IQR

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10

18

A.8 A
B
0.7413

A.5

Z
Z

IQR Z
Z ZB Z ZW
A B A IQR
A IQR( A)
B A
Z Z

Z=

A A
IQRA

A B ZB ZW S

S = A + B / 2

D =A B/ 2

D +-

S D
IQR(D )
IQR Z

Z
Z ZB Z ZW

ZB =

S S
IQRS

ZW =

D D
IQRD

Z A.8 Z
Z ZB ZW 3
Z
Z 2< Z <3,

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11

18

Z
ZB 3
ZB -3
ZW 3
X Z Z

A.6

Z
A.8 Z
Z ZB ZW

CuZB
14
5
4
3
2
1
ZB 0
-1
-2
-3
-4
-5

05

11
13

03

09

15

08

07

04

10

17

12

18
01
06

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12

18

CuZW
5
04

3
1

10

01

14

12

05

08

18

ZW
-1
-3

11

17

13

15

09

07

06

03

-5

95%

Cu

Cu(A )%

Cu(B )%
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18

Z 3 99% 95%

5%
5%
Z 2 -2

(1)

(2)

A.7

Z A.8

A.8

Cu

A B
wCu/%
0.927
0.952
0.977
0.995
0.915
0.962
B

01
03
04
05
06
07

2006 06 01

wCu/%
0.857
0.886
0.888
0.921
0.852
0.900
B

ZB

ZW

1.2615
1.2997
1.3188
1.3548
1.2495
1.3166

-3.05
-0.68
0.51
2.74*
-3.79
0.37

0.0495
0.0467
0.0629
0.0523
0.0445
0.0438

0.35
-0.12
2.58*
0.82
-0.47
-0.59

Cu-1
Cu-1
Cu-1
Cu-2
Cu-1
Cu-2

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CNAS-GL022006

14

08
09
10
11
12
13
14
15
17
18

0.966
0.950
0.969
0.949
0.961
0.940
1.02
0.956
0.960
0.943

0.891
0.889
0.901
0.904
0.890
0.888
0.950
0.898
0.912
0.864

1.3131
1.3004
1.3223
1.3103
1.3089
1.2926
1.3930
1.3110
1.3237
1.2777

16

16

16

16

0.958

0.891

1.3106

0.0474

IQR

0.0143

0.0106

0.01612

0.00603

1.49

1.19

1.23

12.72

0.915

0.852

1.2495

0.0318

1.020

0.950

1.3930

0.0629

0.105

0.098

0.1435

0.0311

CV
%

0.15
-0.63
0.73
-0.02
-0.11
-1.12
5.11
0.02
0.81
-2.04*

0.0530
0.0431
0.0481
0.0318
0.0502
0.0368
0.0495
0.0410
0.0339
0.0559

0.93
-0.71
0.11
-2.58*
0.47
-1.76
0.35
-1.06
-2.23*
1.40

18

Cu-1
Cu-1
Cu-1
Cu-1
Cu-1
Cu-1
Cu-1
Cu-1
Cu-1
Cu-1

Z 3* 2 Z 3

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CNAS-GL022006

15

18

B.1

B.2

En
En

B.3

En
En
En =

x
U

LAB
2
LAB

REF

2
+ U REF

x LAB -

REF

U LAB -

U REF -

U LAB U REF 95%

En En-1 +1 En 1
B

Z
, En
En

,
En
En En 1
En
B

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16

18

1 En
4 6
1

DC

U95

-1

-0.45

0.89

-3

-0.95

1.41

0.5

1.5

0.28

-2.5

-1.12

En

B.4

En
B

B.5

B.3

1Volt DC
6

xLAB-xREF(V)

4
2
0
-2
-4

2
REF

4
5

1
6

-6
-8

,
En

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CNAS-GL022006

17

18

C.1

4.3.1.4 En

C.2
1. En

En
En =

x
U

LAB
2
LAB

REF

2
+ U REF

x LAB -

REF

U LAB -
U REF -
U LAB U REF 95%

En 1
En

2. CD

r R

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18

18

ISO5725-6 CD
CD =

(2 . 8 R ) (2 . 8 r ) n n 1

1
2

y y
0
0

CD

3.

En CD

Z
Z =

LAB

REF

x LAB -

REF

-
Z 1

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