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(1)

(2)

(3)

(4)

(5)

(6)


(1)

(2)

(3)

(4)

(5)

(6)

(anodic aluminum oxide, AAO) (anodic titanium


oxide, ATO)AAO
AAO60nm-
ATO
ATO
ATO0o


(1)

(2)

(3)

(4)

(5)

(6)


AAO
AAO
AAO1040nm40
100nm100500nm

H2O
2Al3+ + 3H2O Al2O3 + 6H+

Al2O3

2Al + 3O2- Al2O3 + 6e-

Al

AAO

AAO

AAO
Electro-polish; EP

95%

70 vol.%

45 V

6min

(70%)

15 vol.%

(99%) 15 vol.%

12

AAO

10 vol.%

18V

1
0~ 40 nm

3 wt.%

40V

2
5

4
0~ 100 nm

1 vol.%

195V

1
0
0~ 500 nm

AAO
AAO

()

92.2 vol.

(;)

1.8 wt.

(85)

6 vol.

()

95 vol.%

85%

5 vol.%


15 wt.%

35%

8 vol.%

AAO(3 wt.%)
AAO
99.7% (#1070)

(a)AAO

50nm
1010 pore/cm2

(c)
AAO

(cup)
50nm

(b)
AAO

(barrier layer)
(d) (low
magnification)

AAO

AAO
(a)
(b)
AAO
AAO

(a)

(b)

AAO
AAO
(pore widening)

10nm 20nm 40nm 50nm 70nm


90nm250nm300nmAAO
AAO

AAO

AAO
10nm

50nm

250nm

20nm

70nm

300nm

40nm

90nm

450nm

AAO(10 vol.%,18V,25oC)
(10m/hr)
1hr,16
m

4hr,43
m

2
h
r
,
2
5
m

5
h
r
,
5
1m

3
h
r
,
3
2
m

6
h
r
,
7
8m

AAO(3wt.% ,40V,25oC)
6m/hr

1hr,8
m

5hr,40
m

3
h
r
,
2
3
m

4
h
r
,
2
6
m

1
0
h
r
,
6
0m

1
9
h
r
,
1
1
4m


(1)

(2)

(3)

(4)

(5)

(6)

-
(noble)

-
-
(Au-Si eutectic)
(MEMS, micro-electro mechanical
systems) -
(field emission)

-(Au-Si)


(a)

(b)

2.3wt%Si
-Au

2.8wt%Si
-Au

Au

Au-Si

Au-Si
25m

(c)

4.0wt%Si
-Au

25m

(
mat
rix)

Si

(pre
cip
ita
tio
n)(a)
(
Auric
h
)
(
b
)(c)

Au-Si

(S
i-ri
ch
)
25m

-SEM
(a)

(b)

15m

(c)

2m

(a)SEMSi
Au(b)SEMSi
AuSi-Au
EDS
SiAuSi-Au
Au-Si
(c)EDS

SEM

TEM

100 nm

-AAO
SEM

-TEM


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(2)

(3)

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(5)

(6)

ATO
Electro-polish; EP

42 vol.%

32 V

6min

(70%)

5 vol.%

(99%) 53 vol.%


(1)450oC3hr

(2)
0.5 vol.%. (HF) + 10 vol.%
(H2SO4) + 88.8 vol.% (H2O)
18V20min
0.3m
(3)0.58 wt.% (KF) + 13.8 wt.%
(NaHSO42H2O) + 5.9 wt.% (C6H5Na3O7
2H2O)25V
(1~10m)

0
.
5vo
l.%
0.5%20V3
SEM100nm
0.3
m
(a)

(b)

(a)

(b)

SEMTiO2
0.58wt.%+13.8wt.% +5.9wt.%
25V
6SEM

(a)

(
a
)

(b)

(
b
)

(c)

(
c
)

(d)

(
d
)

(a)1010~1011 /cm2

(b) 100 nm

(c) 3m

(d)


ATO
ATO
ATO
(etching)

ATO Compact TiO
TiO Tube
2

ATO
(a)

(b)

(c)

(d)

(a) (b) (c) (d)

ATO
TiO2 tube grows on the Ti substrate
Compact TiO2 covers on the TiO2 tube

Semi-TiO2 tube grows on the Ti substrate

pHATO

0.83m/hr2.5m/hr

7
0
6
0

25oC

pH=6.4

5
0
Thickness /m)

ATO

pH

25pH
ATO
ATO
pHpH
1.44.7ATO

0.4m
2.8mpH
5.25.56.4ATO
0.42m/hr

4
0
3
0
pH=5.5

2
0

pH=5.2

1
0
pH=4.7

0
0

pH=1.4

1
2

1
6

Time /hr

2
0

2
4

2
8

ATOpH=5.5, 25V, 25, 17

(a)

(a) 20, 5.7m

(b)

(c)

(c) 50, 35.4m

(b) 25, 21.3m

ATOpH=6.4, 60V, 25, 15

(b)

(a)

(a) 0.25%, 18.4m

(b) 0.5%, 33.2m

ATO
ATO

(a
)

(b
)

(a)30V

(b)60V

ATO
ATO

(a
)

(b
)

(a)30V, 100nm

(b)60V, 210nm

Ti-TiO2
2~3 nm
TiO2

(TiOx)

TiO2SEM
TiO2SEM (a)
TiO2(pattern)
(barrier layer)450oC3
Ti-ATO(b)
(TiOx)
(a)

(b)

Ti

TiO2

(a)TiO2

TiOx

TiO2

(
b
)T
i
O
x
T
i
T
i
O2

SEM

(~3nm)(TiO2)

450oC3hr
TiO2
(a)

(a)

(b)

(b)

SEM

TiO2 100nm109
pores/cm2

ATO
0o 180o
(self-cleaning)
(lotus effect)
180o
(anatase)
0o

180o0o
(a)

(a)

180o

(b)

(b)

0o

(a)

60.6o

(b)

51.5o

(c)

23.1o

(d)

0o

(a)TiO2 (b)0 min


(c)10 min (d)20 min
0o

o)
0


(1)

(2)

(3)

(4)

(5)

(6)

N3
N3(Dye Sensitized Solar CellDSSC)
400nm530nm

HOOC

HOOC

COOH

N
N
SCN

Ru
N
NCS

N3 dye

COOH

1
.
4
5

0
.
3
5

1
.
1
5

0
.
2
5

Absorbance

Absorbance

(a), (b)TiO2
450oC
0.9m
400nm800nm
387nmTiO2

0
.
8
5

0
.
0
5

0
.
5
5

0
.
2
5
3
0
0

0
.
1
5

0
.
0
5
4
0
0

5
0
0

6
0
0

7
0
0

8
0
0

Wavelength/ nm

(a)TiO2

3
0
0

4
0
0

5
0
0

6
0
0

7
0
0

8
0
0

Wavelength/ nm

(b) N3 dyeTiO2(0.9m)

N3 dye

N3 dye3.2m ATO4
16

N3 dye1.5m3.2m
ATO


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()

-
-(20nm)

()

TiO2

pH
ATO
ATO

()
TiO2TiO2
TiO2
2 mW/cm220 min
-51.5o 0o

-0o

()


(SCI)
1Jin-Shyong Lin , Yu-Chying Chen ,Eric Wei-Guang Diau and Tzeng-Feng Liu
Soc.,2004
Aggregation of Zinc Protoporphyrin in Anodized Aluminum Oxide(AAO) Nanoporous
Environments ( SCI )
Journal of the Chinese Chemical Society
2Jin-Shyong Lin ,Yu-Chying Chen, Chien-Chon Chen, Liyang Luo ,Eric Wei-Guang
Diau and Tzeng-Feng Liu
Soc.,2006
Fluoresecence Dynamics of Zinc Protoporphyrin in Solution and inside Anodized
Aluminum Oxide(AAO) Nanotube ( SCI )
Journal of the Chinese Chemical Society
3Jin-Shyong Lin, Chien-Chon Chen, Eric Wei-Guang Diau*, Tzeng-Feng Liu
Dec.2007
Fabrication and Characterization of Eutectic Gold-Silicon (Au-Si) Nanowires (SCI)
(Dec.2007Accepted)
Journal of Materials Processing Technology


1
, ,,2004.
2
, ,,2005.
3
, , ,, -(111),
,2006.
4
, , ,, ,,,2006
5
, , , ,,, 11
,,,2006


6
,,,,,,
,24-25, ,2006
7
Meng-Hung Lin, Wei-Ming Chiu, Hua-Chiang Wen, Jin-Shyong Lin, Tzu-Chin
Chang, Chang-Pin Chou, Mechanical Properties,of Carbon nanotube/
biodegradable Plastic Poly(lactic acid, PLA) Composites, Symposium on Nano
Device Technology ,May. 9-15, Hsinchu, Taiwan, (2007).
8
Meng-Hung Lin, Jin-Shyong Lin, and Chien-Chon Chen, Indentation Behaviour
of Bi-Sn Nanowire on Anodic Aluminum Oxide Matrix,Nanotechnology and
Micro System Association, Aug. 30-31, Taichung, Taiwan ,2007.


9
, , , , ,
,, 30-31,,,2007.
10
, , , , ,
,,30-31,,,2007.
11
, , , , ,
,,
16-17,,,2007.
12
, , , ,
,,16-17,,,2007.


13
, , , , ,
,,16-17,,,2007.
14
Jin-Shyong Lin, Jia-Sheng Huang, Jun-Liang Chen, Chien-Chon
Chen, Modification of Anodic Aluminum Oxide Template Pore Size by
ChemicalEtching and Electron Beam Deposition Methods
15
,,,,,",
16
,,,,"",
,16-17,,,2007.
17
, , , , ,"
",,,,2007

2( )

3()

4

5

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