Professional Documents
Culture Documents
January
29, 1976
LAWRENCE
I.IVERMORE
LABORATORY
Pages
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UC-90C
LAWRENCEI_IVERMORE LABORATORY
UniversityofCa~fomia
Livermore,Calilornia 94550
UCRL-52004
January
29,
1976
Contents
List of "l:].].ustratlons
AhstracC .
Introduction
Cenclus:Lons
Soviet Methods o~ Under,round Coal Gas:l.icat~on
52
-ill-
List of Illustrations
Fig. No.
Page
i0
I]
12
].3
14
beds.
15
]6
[[7
].8
i0
"].9
ii
20
].2
2"I.
22
23
16
24
17
25
Effect of the speciflc inflow rate of water into the gaslficatlon zones on the chemlcal cemposltion of gas obtained by
under~round conl ~aslfieotion.
18
26
Mean air flow and heat content by months for Mas generator
No. 5a-b.
27
-iV-
T:Itie
Fig. No.
19
Page
29
23.
30
22
Arrangement at foot
3]
23
32
24
33
coal.
26
Kholmogorsk.
27
28
36
sub.41denco.
29
37
38
30
39
31
32
40
33
var:[ous coals.
34
1.inkingdis taoce.
35
Chauge in the characteristic parameters of channeling by burnthrough w~.th the use of the pcrmeabillty of the coal seam,
4~
Podmoskovnaya stntlon.
-v-
No.
Title
Page
36
45
37
46
38
47
39
48
4O
49
41
42
50
Calculated chanp.,e "in the cost nf 1 b[cal in the gas ;it place of
productJ.ou ~or Kuzl~ass conditons as a fun~:tion of the power
of the Pndze~4az station.
51
-vi-
underground
as developed
in
coal
the
gasifi-
USSR since
to surmount
~tese problems.
Introduction
coal,
peak in
B~cause
follows:
(i)
(pyrolysis),
(2)
(3)
underground gasifica-
Und~.~row,d
effort.
-2-
Coal C~iI~a~:4on.
In
we briefly
Conclusions
The Soviet
fication
underground
coal
gasi-
done
of mud.
|.ntrusion
):ate
as well
ae to maximize
or coal ~ype.
_II.12~.I
\ SurfaceArea Reactorwith
.~li_)d~!
Pcrmuab~_~l
i ty -- Highpermeability
2.5 arm.
An advantage ~[ these low operating
tlon.
water supply.
the
of the channel
spacing.
~te Soviet d~slgns place the
as liquids.
plpe life.
spacing:
drops.
down.
on an intermittent basis to
i00 ft thick.)
supply
-6-
swelling coals.
composition that is
quite constant in
long.
Fig.
basins
-10-
Donbass
(DonetsBasln)
(Anthracite 1933)
(Oldest pff 1933)
(Experimental1~.35)
(Underconstructwon1960)
Shakhta
L~slchansk
Gorlovka
Kamensl~
Lislchansk
Coal characterlsHcs
1. Bffumlnous (6-16% ash~ 25-35%volaHles~~15%H20
1-5%sulfur)
~ 10"
2. 10.
Steeply di~ng (20-60)
3. Thin seams(0.4-1.5 m) as deep as 400
10
4. 4500-5000kcal/kg (8000-9000Btu/Ib) coal in the seam
Gas~flcatloncharacteristics
I. 800-I 000kca I/m3 (90-I 12 Btu/scf) 10.
1,5 x 108 m3/yr (I ,5xi09 Btu/day) in 1959
2. I0,
Economics
I. 55 rpls./1000 m3 (I .56 rpl=/1000 scf) in 195910.
Kuzbass(Kuznets Basin)
Lenin plt
Yuzhno-Ablnsk
Stal insk
(1933)
(Podzemgaz
staHon 1955)
(Underconstruction 1960)
Yuzhno-Ablnsk
Coal characterlsHcs
I. O10.
Bffumlnous (4-10%ash,20-30%volatiles~ 5-8%1"12
11.
Steeply
dipping (55-700)
2.
3. 23 seams2-9 mthlck 11 .
10
4. 5000-6000kcal/kg (9~ 000-10,800Btu/Ib) coal in the seam
Gasification characteristics
1. 1000kcal/m3 10.
(I 12 Btu/scf)
2. 3.9x 108 m3/yr (4.1 x 109 Btu/day) in 196511.
Economics
I, 29.5 rpls,/1000 m3 (0.8 rpls/1000 scf) ~n first quarter of 195910.
Fig.2.
Dataon Lis:l.chansk
and Yuzhno-Abinsk,
l~eimporCantpolnCshereare
~batbotharenshavesteeplydippingbedsand biCuml.nous
Lis:I.cllansk
has muahthinnerseamsthanYuzhno-Abinsk.
~0
Podmoskovnyl(MoscowBasin)
Krutova mine
Podmoskovla
station
Shatskaya
Tula
Coal characteristics
1. 10.
Lignite (Hard brown coal, 27-60%ash,17-27%volatile, 20-30%H20)
2. Horizontal.
Roof is loam-sand-loam
(plastic), descendsuniformly and compactsbed
3. 12.
2-4 m thick, 40-60 m deep
4. 12
2000-5000kcal/kg (3600-9000Btu/Ib) for dry coal
5. 10.
Gasification
I. 700-900kcal/m3 I0.
(79-101 Btu/scf)
2. 4.6 x 108 m3/yr.
Economics
I. 36.3 rpls/1000 m3 (1 rpl/1000 scf) in 195910.
Da~aon Podmoskovla
and Angren,The J.mportmtt
poJ.n~shereare tha~"
both~reashavehorizon~al
bedsand ll.gnJ.~e
coal(browncoal),but
~ ~ s ~ 7 ~ I 0 ~ 12~ 1 3
Podmoskov~.a
hasmucht]lJ.nne~coalseams
~han
Angren.
-12-
(a)
]?ig. 4.
-13-
LISICHANSI(AYA
PODZEMGAZSTATION
PODMOSKOVNAYA
PODZEMGAZSFATION
Fig. 5,
-14-
, . ..
t- =nject=on
r~Gas
f
~
removal
.....~ ,~
- ;,...::~ _-"
~..~..~ _
~:..
.~.!~~..
~;~.,,.~-
Coal seam
].ig.
6.
~~
~a~if~cation
region
-15-
Gasremoval
i
I
Water
~ig,
7.
r-InJection
Injection
/-Gas removal
~/InjecHon
II
(a)
Water
5300m3/hr
3
3000m;~hr
2500 m /hr
I
I
I
75
50
25
Directionof motion
of the gasphase,.~-m
F:l.g. 8.
1 O0
-17-
LinlCa~e.seffected wlt.h
h~ghpressure a=r
Pig. 9.
-18-
Gasremoval
2 air injection
J
Strata cracking
and subsiding
Void
Reaction
Strata subsiding
into burnt out
(recently brought,nto
*~/ use as illustrated)
/.
Original end of
gasification bore
Use of two air injection holes :Ln a steeply s.l.op:Lng seam. The
Soviets commonly encountered severe gas leakage to the surface
through cracks created by subsidence. ThJ.s fisure shows part of the
solution employed to solve ~his problem, swhich was to bulldo~e clay
into the cracks that reached the surface.
In add/.tion, the system
was operated at the lowest possible pressure consistent with required
production flow rates (injection pressure about 3 arm).**
-19-
Gasremovalholes
drilled ~n seam.
Vertical flrst-stage
air ~njecHonholes
)irected drill holes
to form
linkage path
Fig. 11.
-20-
Blast-lnjectlon
holes
Gasremoval
holes
Inclined-horlzontal
llnklng holes
Connectingchannel
~g.
12.
-21-
1200
7-9 m3/hr
800
m3/hr
3-5 m3/hr
400
0-1 m3/hr
0
o
Yi~,. 13.
I
2
I
~
I
~
4
6
Gaslflcatlonrate -- tons of caal/hr
10
-22-
1400
1000
0-1 m3/hr
1-3 m3/hr
:3-5 m3/hr
6OO
r m3/hr
7-9m3/hr
(Water inflow)
200I
~
I
~
4
6.
Gasification intensity mtons of coal/hr
Fig. 14.
I
8
10
-23-
120C
/~~/-~---
--
800
400
u2
!
,!
I
l~.Lg, 15.
~ 1 m3 of water/ton
of coal gasified
I
3.0
I
I
I
6.0
9.0
Seamthickness-- m
I
12
I
15
Effect of seam thickness and the specific water inflow into gas:Lflcation zones en the calorlfle value of F.,as e.btained by underground
gas~fication. Both water intrusion rate. aud coal. seam thie.kness can
have a strong effect en the hea~ing value of the product gas, The.
effoe.t of the water intrusion rate was discussed earlier, 5ut this
figure also illustrates the effee.t of se.em thickness. [[.t can be
saen that the heatin~ value of the product zas falls off dramatically
as the. coa.1, seam ~,ete thinner than 1 to 2 m. This is clue to thinner
seams losing n ].arMe.r ~rae.tlon of heat to the surrounding fo~natlon.
1%o. h~.~her heat losses result in lowwr f].ame, frout temperatures,
which in ~urn shifts ~he CO/CO2 equilibrium l:owards tile production
ef more CO2. The i- to 2-m limita~ion "In coal. seam thickness has
very ~.mportnnt implications. Most of the coal I.n the eastern part
of the U.S. lles in seams less than 2 m thick, whil.e most of tile coal
in the. western U.S. is in ~h:|cker seams.
-24-
1200
o
o
o
o
8OO
~
~Oo~
o
o
o
o
400
I
I
I
2
I
3
I
4
I
5
o
o
-25-
2-m seamthickness
20
.-------
16
C 02 _
12
8
CO
20--
CH
4
8.5-m seamthickness
16-12--
H2
8--
CO
CH4 4-O~
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
-26-
Hourly
meanair
Month-
year
flow Im3/h)
Heat content
of gas
lkcal/m31
Nov. --
1962
3460
1280
Dec. --
1962
7000
1304
dan.
--
1963
8030
1291
Feb.
-- 1963
8760
1260
Mar.
--
1963
8400
1264
Apr.
--
1963
9850
1238
7600
1260
Average
Fig. 18.
Mean air flow and heat content by months for gas generator No. 5a-b.
This table shows the stability of product gas heating value that was
achieved over a 6-mo period. The blast flow rate was used as a means
sk,2
of controllingthe heating value at Yuzhno-Abin
-27-
3.
Calor~flc value oF the gas Q = 1300, to 1196 kcal/m
Gas leakage = 10%.
3.
Gas water content = 290 g/m
"2
Relative
blast intensity = 17 m3/hr - m
I.
2.
3.
4.
5.
6.
7.
8.
9.
~,
-28-
60
I
~
N
2
CH
4
o
20
25
"l"
35
30
40
60
02 confent of blas~" ~ %
20.
blast, on the basis of operate.on of underground gas generator No.
of Gorlovskaya Podzomgaz station. The Soviets axperlment~d
slvely with enriching d~e air blast with oxygen; some results from
Podmoekovla are presented hera. Similar experiments a~ Lis~.chan8k
showed sgnlfleant1~ different produc~ gas concentrations, because
"cnndJ.t~ons of opara~on of the gas.l.flcst:Lonchannel.s~ were differeat.I~ One J.nteresting point ~.s that the C02/C0 ratio did not change
s~gnifieantly with ~nercasing oxygen eoncent~a1on in the blas~.
SJ.nee the combustion zone would be hotter with increased 02 eoneenLratlon ~n the b%as, ~he insensitivity of the CO~/CO ratio would
have to be explained by reactions taking place in the cooler zones
further downstream, ~e product gas eomposltlon is probably dominated by the shift reaction, CO + 1120 = CO2 + 112, ~is is consistent
with the increasing 112 concentration.
-29-
Product
gaSmanifold
I ~-
225
75-~ 75~,
75
~.j
I Producing gas
I75
Row 2 I
Linking
Manifold
Row 3
Row 4
Dr|lllng
m.
C
--0-
and
I preparing
Row5
Boreholes
Fig. 21.
-30-
Future B Ih~e
Stage !
Drill holes 3,4 & 5 ~n ~A~ llne.
Apply H.P, a~r toA.4. Establish
llnk to (say) A.3.
e to be at 25 rn CRSeach.way
H.P. a~r
Stage !!
Ignite A.3 as induce fire zone
in line A.3 -A.4. Apply H.P. air
teA.5 to link teA.4.
F Fire zone
-Air
Sta.qe! ! !
LInk and induce fire zones
A.2-A.3,
A.6-A.5~ A,1-A.2~efc.
,
"1--I
1
H.P. air
,
-T---~. !---i
, ~ F~rezones-~.
2
- --I,
6
--I
,,
-8
H,P. air
Stage IV
Start drilling and linking line
BI, B.2, etc., to llne A holes.
- ~ -
,,, ,,
~
6
--II
-32-
Gos
Stage V
Start gasification L.P. air
toA.1,A.2,etc.,
gas from
B.1,B.2, etc.
React;on
zone
L.P. air
H.P. alr
Stage V!
Drill hole in line C, link
to line B progressively
as gasification proceeds.
(.ater
Supplyair to ,~,~ llne.
Take gas from Jlne.
(All A holescapped.)
Fi~. 24.
as!l !!~
,
:11 :
I
Reaction
zone
L.P.air
-33-
I-~
175 m
--.
Stage V
After linking B~ holes to A proceed
to llnk ~C holesto B beforestarting
gas~flcaHon.
I
~I i
II
II
if
i,
tl
, ,~
i1~
Fire zonesestablished
Gas
Stage V!
Start gasification with L.P. air to A
~
holes taking gas from C holes, B
holes being capped.
III
Ggod~.al
L.P. air ~_~y
" gas
StageV! l
During stage Vl llnk holes D1-D8to
llne C~. ~
Whengas from ~C
~
deteriorates moveair supplyto ~B
holes and drawgas from D and
holes.
ia ter
Whengas from A holes becomes
unusable, cap A holes. Drawgas
from~D~ andprepareI|ne E~ et,.
Lowquality gas
l~Lg. 25. Modif%ed concluding stages for ~,I)roved gasification in brown coal.
This figure presents an alternate, more coml)lex, mode of carrying
out the cocurrcnt combustion gasification as well as further countercurrent combustion ].inking. In th~s case two qualities of product
gas are produced, with the two being co~)Ined to give an acceptable
s
quality gas.
-34-
Secondline of directed
holes to the seam --~
First llne of directed
seam--
holes
,othe
,,,/,, , .
~ . .....
,~
..~.:~...:.~L~..;~
..
Linkage fro~i~_~
formed by
hlgh-pressureair
l~l~,
~~
~,
~p~,~?~
"~i~r
~//i-/,~"l
~Vertical
7"#/
26.
_7]
bore
holes
at
about 50-m cenl These
are [epeated on each llne
of d~rectedholes but have
beenomitted ~or clarity
-35-
Gascontrolvalvesand
expansion
loops-
of air ;njectlonboreholessecondphase
)s of air injection boreholesthird phase
Air inj,
control valves
andexpansion
loops
/ 30m
Thep~ecesblanked
off readyfor secondphasegasconnections
Gasremovalboreholes
Boreholosfor bothgasand
air are drilled on the slope
beyondthe natural lino of
-4- ~:.".-. drawof theoverlyingstrata
teaI
,_u.
.~c~
Ashand debris in
burnod
~sificotlonzone
Fig. 27. Projected layout of boreholes at An~ren to suit thJ.ck brown coal and
heavy subsidence. Tb~.s figure shows how the drilling pattern and
operational method were modified to accomaodate thick coal seams.
The primary problem to be solved was that with thick seams, the
ground subsidence had a tendency to shear off the access pipes
maturely. To resolve this, two modifY.cations were made. (i)
].atcral withdrawal/Injection technique was devoloped.~ In this
method, one of the two functions (gas withdrawal or ir~ec~ion)
perormed by a row of pipes along the s%de of the zone being gasified. The remaining function was nccompllshad with a rectangular
pattern of pipes entarlng t:ha seam directly over the coal to be
gasified. (2) Within ~*e framework of this general pattern, all
pipes were drilled on a slant to keep them out of the sabsldence
region durlnE their functioning lifetime, When gasification is
tattled out in this manner it can be scan that the row of pipes
along the side of the zone being gasified is never affected by subsidence~ and the pipes in the pattern dlrocCly over the coal being
gaslflod are not affected until after they are no longer needed.
Therefore, with this deslgn one is never attempting to operate w4.th
a plp~ that has boon exposed to any ground movement due to subsldonce. This design also has the addJ.tLonal advantage of addtn~
a cross-flow componant to the gas flow which w.Lll hc]p to recover
mounds of coa~. that might othcrwlse he left between
Lateral wlthdrawal/inJocCion is eo~)lex, and no attempt to describe this
process will be ~tde here.
-36-
60
50
900
700
300
50C
300
200
~ 2O
0
1 O0
10
~ O0
0
250
Fig. 28.
300
350
400
450
500
Pressure-- mmHg
550
600
-37-
2O
Fig. 29.
15
30
45
60
75
D|staneeFromblast hole -- m
80
-38-
Coal
30.
Charor ash
-39-
0.6
g 0.4
~ 0.3
~ 0.2
.o_=
0.1
I
1o
5
>
~)
~
Fig,31.,
Blasl" ~ 0/mln
I
0,185
0.37
Blast veloc~b/ -- ~sec
-40-
Oxygen
2
Blast -- Q/mln
Fig. 32.
Change in the velocity of the combustion focus in the reverse direction, for an a~.r blast and a 98~ 02 blast. The gasification channel
is in the form of a borehole in a block of Moscow coal. This figure
illustrates the diforence between air and oxygen for carryin8 out a
counl:ercurrent combustJ.on.10 11: is clearly seen that the flame front
velocity -Ls considerab]$ hi~*er if oxygen is used. This can be
understood in terms of the oxygen generating a hotter flame front
thm% air at the same flow rate, as well as the coal having a lower
ignition temperature ~n oxygen. However, the Soviets also found that
if oxygen is used for ].inking, the resultln~ channel had a ~uch lower
overall conductivity to gas f].ow.~s In fact, the channel conductivity WaS so snmll that it was not directly useable for the process.
Sometimes a chmmel burned countercurrent].y several times with oxygen
cou].d be used, but it is not clear that this was an economical
app~o;tch. They found that air had approx:i~etoly the optimum oxygen
concentration for makiug~ wth a siu|(le burn, a channel with suEf:Lcient
permeabil:[.ty and nu acceptable flame front velocity.
I
I~0 -
4
-5
4,0
Fig.
33.
5,6
7,2
8,8
10,4
Blast flow rate -- ~/mln
12,0
13,6
I.5 2
-42-
"I
0
O0
O~
0
o.5
0
u
]~ig.
34.
I
4
I
8
I
12
I
I
I
20
24
16
Linkingdlstancs~ m
I ....... J
28
32
I
36
38
-43-
40-36--
3.6
C
32--
3.2
28--
2.8
2420--
2.0
16-12--
"~ 1.2
8--
0.8
0.4
0
194:
Fi~. 35.
1950
1952
Years
1954
1956
-44-
Slide
for
Drill steel being
handled from
bed to shde
Telescopic
legs
Positionfor
h e.avycrab
wmchfor
pulling
casing
Borehole
Elevation
Dri!l.gate in ope.n.
pos~honfor handhng
steels on to slide
Plan
Fig. 36.
-45-
I.
Fig,
37.
-46-
Water
Water
Drainage
hole
Dmlnage
hole
Initial groundwater
level
/--
Coal
seam
/. ,,.,,.,.;~,",;;/.,,.-/,/,/,,-/,
, ,~;.;,.,~,-,,;,;.-//,.,,,
,, .-<
~,~,~.~,,,,.,/;,~.<~,/.,;,,/,,~,
~,.~.,.,.~,.,/,,.,,.,,.,
-47-
Oxldatlon zone
Reducing zone
Drying and pyrolysis zone
Fig. 39.
-48-
Seam
width, h
(m)
Station
Luka
Lislchansk
Yazhno-Ablnsk
British
9
9 (alr blast)
19 (oxygen-enrlched
blast)
7
4
24
2-4
1-3
1-3
2
8
0.6-0, 8
experiment
(Neuman
Splnney)
l~:Lg, 40.
-49-
300
200(
1000
//
//
//
//
o,// 2i
Blast-free period----I-,,~-
10
Blast period
3
Hours ~ Technological gas.v2000 kcal/rn
3
Powergas -.,1000 kcal/m
Fig,
41.
-50-
Calculated change in the cost oE 1 Meal in the gas a~: place o production
for Kuzbass
eonditioue
as a fuuc~ion
of tha power oE the
Podze~m~a~
station. This figure preeeuts ty.picnl economic calculation8 I0 made: ou underground
coal gaslflca~a.on
in the USSR.All such
published
cal.culatlons
we foundshowedthatunderground
gaslf.icatlon
abovea certainproductionrate was more than competitive
with other
I! ~29-ss
meansof exCraetJ.ng
coal.l[owaver~
all sucheal.culations
are suspectin termsof being~thleto transferthem intoour economic
eystem~eepeclallytakinginto accountimprovedtechnologyin all
fle].dsof coalextraction.
-51-
References
i.
2.
3.
V. A. Ma~voov, "A Brief Report og Results and of the Mos~ Pressing Probloms in the Field of Undorground Gaslficat~.on of Coal," Podzemnaya
Oa~If~.kats:[ya Uglei, No. 2, 4 (1957) [English transl. No. A.1408/SEH
(National Coal Board, Great Britain, 1957), 55 pp.].
4.
TJ~]~,oz~nd 6asz~o,~#t~o~
6.
7.
hawrenee
9.
10.
P, V. Skafn,
UCRL-Trann-10880
E. Kreintn
and hi.
1).
Rotter,
(~owmber
1975).
Re,a,
~o~"~o~t~o~
(December
UCRL-Trans-10752
G. O. Nustnov,
6au[.~.[ual.4o~
UCRL-Tran,-10805
14.
L. ~. Jolley
15.
S. I.
(December
and N. Booth,
Buyalov,
"Principles
and D. g.
..I"
Coal,
Lawrence
~zagI~,z~7o~
c:~
Co,~Z,
R,eeuZl:,
Lawrence
of
Ltvermore
Laboratory,
1974).
gg, 31 (1945).
(1938).
-52-
Lawrence
1974).
Semenonko,
of Underground
Liver-
1974).
(July
o~ B~,~n 6oaZ,
l,u~.~Z
Labora-
1975).
~dc~,b,~,ound
UCRL-Trans-10810
Laboratory,
N. V. Lavrov,
lhtd~und
(September
Ltvermore
13.
1JCRL-Trans-10979
~eilioat.t:on
I)~t~,eaotd
more Laboratory,
12.
Laboratory,
tory,
ll.
Livormore
Gasif~eacion,"
~qoZ,
No.
16.
17.
and N. A. Fedorov,
S~e ReguZ~)
P~%e)*8
Po~aU~ (]~i~:k~%8~l~
U~Ze4, No. i, 65
(1957).
PiOd~m~d
b~I ~d~@Po~nd
~8~:~on
o~ Co~, Lawrence
Livezmore
Labora-
J. L. Elder,
"Under~rouud
Gasification
of Coal,"
in ~8#~
U%~Z~%4o~ H. II. Lowry, Ed. (John Wiley and Sons, New York, 1963)
pp. 102~i040.
22.
24.
25.
G~a~I~:k~#s~/u
UgZ~,No. 3, 61 (1959).
26.
27.
28.
29.
30.
Coalfield,"
Pod~e~e~
~14ka%.4~
U~Z~4,
A. I. Kovalenko, "A ]{~vlew of An Economic Analysis of Underground Gasification by G. D. Bakulev~" Pc,~o~,x~ G.~:~4~4.k,z%,~4~{aU~Ze4, No. 4, 71
33.
KC/lb/mp/la
-54-